CN103734149B - Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent - Google Patents
Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent Download PDFInfo
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- CN103734149B CN103734149B CN201310740851.5A CN201310740851A CN103734149B CN 103734149 B CN103734149 B CN 103734149B CN 201310740851 A CN201310740851 A CN 201310740851A CN 103734149 B CN103734149 B CN 103734149B
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- CN
- China
- Prior art keywords
- acibenzolar
- benzene oxygen
- oxygen quinoline
- suspending agent
- quinoline compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000000375 suspending agent Substances 0.000 title claims abstract description 23
- CGIHPACLZJDCBQ-UHFFFAOYSA-N acibenzolar Chemical compound SC(=O)C1=CC=CC2=C1SN=N2 CGIHPACLZJDCBQ-UHFFFAOYSA-N 0.000 title claims abstract description 21
- -1 benzene oxygen quinoline compound Chemical class 0.000 title claims abstract description 17
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- CYUIZYSKRBPGNU-UHFFFAOYSA-N N1=CC=CC2=CC=CC=C12.[O].C1=CC=CC=C1 Chemical compound N1=CC=CC2=CC=CC=C12.[O].C1=CC=CC=C1 CYUIZYSKRBPGNU-UHFFFAOYSA-N 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000008119 colloidal silica Substances 0.000 claims abstract description 5
- 239000003517 fume Substances 0.000 claims abstract description 5
- 235000011187 glycerol Nutrition 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- MORMPWNLQJTSOT-UHFFFAOYSA-L disodium;4-dodecyl-2-(4-sulfonatophenoxy)benzenesulfonate Chemical compound [Na+].[Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C(OC=2C=CC(=CC=2)S([O-])(=O)=O)=C1 MORMPWNLQJTSOT-UHFFFAOYSA-L 0.000 claims description 6
- 241000221785 Erysiphales Species 0.000 abstract description 11
- 235000013339 cereals Nutrition 0.000 abstract description 9
- 201000010099 disease Diseases 0.000 abstract description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 235000013399 edible fruits Nutrition 0.000 abstract description 3
- 239000000725 suspension Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- JSOJVSBOEOWZJX-UHFFFAOYSA-N [O].N1=CC=CC2=CC=CC=C21 Chemical compound [O].N1=CC=CC2=CC=CC=C21 JSOJVSBOEOWZJX-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- WRPIRSINYZBGPK-UHFFFAOYSA-N quinoxyfen Chemical compound C1=CC(F)=CC=C1OC1=CC=NC2=CC(Cl)=CC(Cl)=C12 WRPIRSINYZBGPK-UHFFFAOYSA-N 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 101150102768 Dhodh gene Proteins 0.000 description 1
- 241000510928 Erysiphe necator Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 239000005831 Quinoxyfen Substances 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005354 coacervation Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent, be made up of following materials by weight percentage: Acibenzolar 10-20%; Benzene oxygen quinoline 20-30%; Glycerine 4-8%; Fume colloidal silica 0.05-0.15%; Surfactant 4-8%; Surplus is water.Acibenzolar of the present invention and benzene oxygen quinoline compound insecticidal suspending agent, suspensibility is high, plate-out ability and good penetrability, and properties of product are stablized, for preventing and treating the plurality of plant diseases especially powdery mildew in cereal, vegetables, fruit tree, flowers and other crops.
Description
Technical field
The present invention relates to a kind of Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent.
Background technology
Acibenzolar, benzo (1,2,3) thiadiazoles-7-carbothioic acid-S-methyl esters, english common name: acibenzolar, be a kind of plant disease-resistant activator, suitable for crop has paddy rice, wheat, vegetables, banana, tobacco etc.Under recommended dose to crop safety, without poisoning.Powdery mildew, rust, downy mildew etc. can be prevented.
Benzene oxygen quinoline, No. CAS: 124495-18-7, English common name quinoxyfen, chemical name: 5,7-bis-chloro-4-(to fluorophenoxy) quinoline.Benzene oxygen quinoline is systemic fungicide, and has vapor phase activity, contributes to the reallocation of medicament whole plant like this.Benzene oxygen quinoline is growth signals agent interfering.Research shows, it is neither sterol biosynthesis inhibitor, is not again dhodh inhibitors.This product is protective fungicide, and mobility is good, appresorium can be suppressed to grow, do not have eradicant action.It passes through interior suction Xiang Ding, transmits to base portion; And moved by vapor phase, realize the reallocation of medicament in plant.It acts on the preinfective vegetative stage of powdery mildew, effectively can prevent and treat cereal powdery mildew, beet powdery mildew, cucurbits powdery mildew, capsicum and tomato powdery mildew, grape powdery mildew, peach powdery mildew and strawberry and golden hop powdery mildew etc.
Agricultural chemicals suspension agent is the formulation of 20 century 70 development, has now become one of basic processing formulation.Suspending agent (Suspensionconcentrates, be called for short SC) also known as aqueous suspension agent, colloidal suspending agent, concentrated suspension, be under surfactant and other promoter effects, the former medicine being insoluble to or being insoluble in water be distributed in water, form uniform and stable thick suspension system.Because its dispersion medium is water, thus suspending agent to have cost low, to produce, the feature such as storing and use safety, and easily mix with water, easy to use.Compared with taking organic solvent as the formulations of pesticide of medium, there is the advantages such as little to environmental influence of poisoning be light.
Summary of the invention
For solving the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent.
Technical problem to be solved by this invention is achieved by the following technical solution:
Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent, comprise the raw material of following weight percentage: Acibenzolar 10-20%; Benzene oxygen quinoline 20-30%.
Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent, be made up of following materials by weight percentage: Acibenzolar 10-20%; Benzene oxygen quinoline 20-30%; Glycerine 4-8%; Fume colloidal silica 0.05-0.15%; Surfactant 4-8%; Surplus is water.
Described surfactant is poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate and/or α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
Described surfactant, is made up of 70-90 weight portion disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate and poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of 10-30 weight portion α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
Disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, English name: SodiumLaurylDiphenylEtherDisulfonate, No. CAS: 7575-62-4.
α-[three (phenyl methyl) phenyl]-ω-hydroxyl gathers (Oxy-1,2-ethylidene) non-ionic surface active agent, CAS:64422-66-8, molecular formula: (C
2h
4o)
nc
27h
24o.English name: .alpha.-[tris (Phenylmethyl) phenyl]-.omega.-hydroxy-poly (oxy-1,2-ethanediyl) Nonionicsurfactant.
α-[three (phenyl methyl) phenyl]-ω-hydroxyl gathers (Oxy-1,2-ethylidene) non-ionic surface active agent, former being mainly used in suppresses the corrosion in linear cutter and galvano-cautery, sludge in softening working groove, is used as rust-inhibiting additive in low-speed WEDM production process.In prior art, do not have and this raw material is used for any technology enlightenment that agricultural chemicals reagent plays dispersion moistening effect.
Agricultural chemicals suspension agent easily produces a large amount of bubble in process, may affect metering and the packaging of preparation.Therefore, the defoamer of 0.1-0.7wt% can be added in formula, the method such as ultrasonic, vacuum defoamation can certainly be adopted in process of production to carry out froth breaking, and not need to add defoamer.Mould inhibitor or pH adjusting agent can also be added according to actual needs in formula.
Acibenzolar of the present invention and benzene oxygen quinoline compound insecticidal suspending agent can adopt the general method in this area to be prepared, and one is ultramicro grinding method, and another kind is coacervation.
Ultramicro grinding method:
(1) according to formula, Acibenzolar, benzene oxygen quinoline, glycerine, fume colloidal silica, surfactant and water are uniformly mixed pulp thing, are placed in ball mill and pulverize.
(2) be placed in skin grinder and carry out ultramicro grinding, control average grain diameter≤4 μm.
(3) be placed in homogenizer homogeneous, make particle homogenization.
Suspension refers to that former powder of dispersion keeps the ability of suspension time length in suspension, and conventional suspensibility represents.A good suspending agent, should have good storage stability, namely higher suspensibility.
Acibenzolar of the present invention and benzene oxygen quinoline compound insecticidal suspending agent have higher suspension rate, stable during long-term storage, for preventing and treating the plurality of plant diseases especially powdery mildew in cereal, vegetables, fruit tree, flowers and other crops.
Embodiment
Embodiment 1
(1) according to formula, Acibenzolar, benzene oxygen quinoline, glycerine, fume colloidal silica, surfactant and water are uniformly mixed pulp thing, are placed in ball mill and pulverize.
(2) be placed in skin grinder and carry out ultramicro grinding, control average grain diameter≤4 μm.
(3) be placed in homogenizer homogeneous, make particle homogenization.
Obtained suspending agent, the liquid of outward appearance thickness homogeneous phase, measure through Malvern laser fineness gage, its average grain diameter (D50) is 2.5 μm, and D90 is 4.4 μm.
Table 1: Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent formula list position: kilogram
Embodiment 2
Take raw material by table 1 corresponding embodiment 2 data, be prepared by the method for embodiment 1.
Obtained suspending agent, the liquid of outward appearance thickness homogeneous phase, measure through Malvern laser fineness gage, its average grain diameter (D50) is 2.4 μm, and D90 is 4.6 μm.
Embodiment 3
Take raw material by table 1 corresponding embodiment 3 data, be prepared by the method for embodiment 1.
Obtained suspending agent, the liquid of outward appearance thickness homogeneous phase, measure through Malvern laser fineness gage, its average grain diameter (D50) is 2.5 μm, and D90 is 4.4 μm.
High temperature storage 14 days under room temperature storage 14 days, 54 DEG C ± 2 DEG C conditions respectively, adopt " GB/T14825-2006 agricultural-chemical suspension rate assay method " to survey suspensibility, concrete data see the following form 2.As suspensibility >85%, then think that this product is certified products.
Table 2: agricultural-chemical suspension rate determination data list position: %
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Room temperature storage is after 14 days | 99.2 | 98.1 | 97.0 |
| High temperature storage is after 14 days | 97.7 | 96.6 | 95.8 |
Acibenzolar of the present invention and benzene oxygen quinoline compound insecticidal suspending agent, suspensibility is high, plate-out ability and good penetrability, and properties of product are stablized, for preventing and treating the plurality of plant diseases especially powdery mildew in cereal, vegetables, fruit tree, flowers and other crops.
In the present invention, poly-(the Oxy-1 of α-[three (phenyl methyl) phenyl]-ω-hydroxyl being originally used for rust-inhibiting additive in a creative way, 2-ethylidene) non-ionic surface active agent is diverted in insecticidal suspending agent, plays dispersion moistening effect.Especially, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate and α-[three (phenyl methyl) phenyl]-ω-hydroxyl are gathered (Oxy-1,2-ethylidene) non-ionic surface active agent composite, Synergistic, effectively improves suspensibility.
Claims (1)
1. Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent, be made up of following materials by weight percentage: Acibenzolar 10-20%; Benzene oxygen quinoline 20-30%; Glycerine 4-8%; Fume colloidal silica 0.05-0.15%; Surfactant 4-8%; Surplus is water;
Described surfactant is made up of 70-90 weight portion disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate and poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of 10-30 weight portion α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310740851.5A CN103734149B (en) | 2013-12-28 | 2013-12-28 | Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310740851.5A CN103734149B (en) | 2013-12-28 | 2013-12-28 | Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103734149A CN103734149A (en) | 2014-04-23 |
| CN103734149B true CN103734149B (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310740851.5A Expired - Fee Related CN103734149B (en) | 2013-12-28 | 2013-12-28 | Acibenzolar and benzene oxygen quinoline compound insecticidal suspending agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106106524A (en) * | 2016-06-19 | 2016-11-16 | 殷佩琼 | A kind of compositions preventing and treating beet armyworm and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6486341B1 (en) * | 1999-01-15 | 2002-11-26 | Bayer Aktiengesellschaft | N-alkoxy-n-phenylcarbamate derivatives |
| CN101212902A (en) * | 2005-07-01 | 2008-07-02 | 巴斯福股份公司 | Fungicide mixtures based on 3,5-disubstituted pyrazol-carboxylic acid biphenylamides |
| CN101731238A (en) * | 2009-12-23 | 2010-06-16 | 深圳诺普信农化股份有限公司 | Acibenzolar-containing sterilizing composition |
-
2013
- 2013-12-28 CN CN201310740851.5A patent/CN103734149B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6486341B1 (en) * | 1999-01-15 | 2002-11-26 | Bayer Aktiengesellschaft | N-alkoxy-n-phenylcarbamate derivatives |
| CN101212902A (en) * | 2005-07-01 | 2008-07-02 | 巴斯福股份公司 | Fungicide mixtures based on 3,5-disubstituted pyrazol-carboxylic acid biphenylamides |
| CN101731238A (en) * | 2009-12-23 | 2010-06-16 | 深圳诺普信农化股份有限公司 | Acibenzolar-containing sterilizing composition |
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| CN103734149A (en) | 2014-04-23 |
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Effective date of registration: 20181218 Address after: Room 601, Building A1, Kaiyuan Pioneer Park, Xiangshui Economic Development Zone, Yancheng City, Jiangsu Province Patentee after: Gu Wei Address before: 201111 E2128 first, 5500 Yuanjiang Road, Minhang District, Shanghai. Patentee before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd. |
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