CN103721285A - Anion gel air purification refreshing agent and preparation method thereof - Google Patents
Anion gel air purification refreshing agent and preparation method thereof Download PDFInfo
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- CN103721285A CN103721285A CN201410016656.2A CN201410016656A CN103721285A CN 103721285 A CN103721285 A CN 103721285A CN 201410016656 A CN201410016656 A CN 201410016656A CN 103721285 A CN103721285 A CN 103721285A
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Abstract
The invention mainly aims to provide an anion gel air purification refreshing agent and a preparation method thereof. The anion gel air purification refreshing agent comprises the following 100 parts of components by weight: 0.5 to 1 part of gel, 2 to 5 parts of calcium ion aqueous solution, 2 to 10 parts of anion powder, 2 to 10 parts of non-volatile anti-freezing agent, 0 to 0.1 part of preservative and the balance of deionized water. The anion gel air purification refreshing agent disclosed by the invention is free of essences and volatile organic solvents, so that secondary pollution is avoided; anions are released due to addition of natural anion powder, and the anions react with odor molecules and particulate matter in air to remove the odor from the air, so that the effect of purifying air is achieved.
Description
Technical field
The present invention relates to chemical material field, particularly relate to a kind of anion gel air purification agent and preparation method thereof.
Background technology
No matter traditional air freshener is aerosol-type, solid gel type or evaporates type, substantially all contain the compositions such as volatile solvent and essence.During use, volatile solvent helps essence to be distributed to together in the middle of air, with fragrance covering smell, does not have resolving harmful gas, reaches the object of fresh air.But these volatile solvents and essence, or some composition producing after chemolysis in air itself is exactly air pollutants, is the pollution level of aggravation air in essence, and life-time service is known from experience generation pessimal stimulation to people.The aromatic containing in some air freshener even can produce harm to people's nervous system, respiratory system, such as, can stimulate child's respiratory mucosa etc.Traditional air freshener, in order to guarantee the stable of air freshener, need to add antiseptic, and antiseptic also can in use be discharged in the middle of air, and manufacture for the second time and pollute, and also harmful.
In sum, in existing air purification agent field, lack a kind of without perfume, safety non-toxic, can remove the air purification agent product of air abnormal flavour molecule.
Summary of the invention
In order to overcome the above problems, main purpose of the present invention is to provide a kind of anion gel air purification agent and preparation method thereof.Anion gel air purification agent of the present invention does not need to add essence and volatile organic solvent, can not manufacture secondary pollution; By adding natural negative ion powder anion releasing, anion and airborne abnormal flavour molecule and particulate matter effect, remove airborne abnormal flavour, reaches the effect purifying air; The product that adds anion can add less and even not add antiseptic, utilizes the bactericidal property of anion, carries out self-preserving.
A kind of anion gel air purification agent, with listed as parts by weight, comprise following component: gel: 0.5～1 part, calcium ion aqueous solution: 2～5 parts, anion powder: 2～10 parts, non-volatile antifreezing agent: 2～10 parts, antiseptic: 0～0.1 part, deionized water: add to 100 parts.
Preferably, to be selected from be one or more mixing in Methylisothiazolinone, chlormethylisothiazo,ine ketone, benzene isothiazolone, benzyl alcohol, phenoxyethanol, poly hexamethylene biguanide to antiseptic.
Preferably, described non-volatile antifreezing agent is selected from one or more mixing in ethylene glycol, propylene glycol, glycerol.
Preferably, anion gel air purification agent formula, with listed as parts by weight, comprising: gel: 0.8 part, anion powder: 5 parts, calcium ion aqueous solution: 2～3.5 parts, non-volatile antifreezing agent: 2～10 parts, antiseptic: 0.1 part, deionized water: add to 100 parts.
Preferably, anion gel air purification agent formula, with listed as parts by weight, comprising: gel: 0.8 part, anion powder: 2 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 88.7 parts.
Preferably, anion gel air purification agent formula, with listed as parts by weight, comprising: gel: 0.8 part, anion powder: 10 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 80.7 parts.
Preferably, described calcium ion aqueous solution is that mass concentration is 1% calcium chloride water.
Preferably, described gel is selected from one or more the mixing in gellan gum, carrageenan, locust bean gum, sodium alginate.
The present invention also provides a kind of preparation method of anion gel air purification agent, and it comprises the following steps:
1) by proportioning, take after material, gel mixes with deionized water, is heated with stirring to 85～95 ℃, continues to be heated to gel and dissolves completely;
2) calcium ion aqueous solution is added in mixed liquor, after stirring, be cooled to 55～65 ℃ after insulation;
3) to mixed liquor, add non-volatile antifreezing agent, anion powder, stir successively;
4) be cooled to room temperature.
Preferably, the anion gel air purification agent that the present invention contains antiseptic, in the 3rd step and non-volatile antifreezing agent, anion powder, synchronously add, stir.
Anion gel air purification agent of the present invention has following remarkable beneficial effect:
Natural mineral matter anion powder energy anion releasing, anion is mobile " Z " font that presents in air, and carry negative charge to antibacterial, dust, smoke particles and water droplet etc., this microgranule of electric charge and this combines and is polymerized to ball and sinks, thereby reaches the object purifying air.And anion have microbe killing properties can, can carry out self-preserving.By adjusting the concentration of anion powder, to reach the good bactericidal effect that presses down, thereby product also can add antiseptic less, does not even add antiseptic.Gel is heated after swelling, under the effect of calcium ion, and cooling rear and hydrone formation gel carrier, this gel plays the effect of slow release to anion, not only protect the service life of product of the present invention, and air purification effect is extended.Adjust the consumption of calcium ion aqueous solution, with the concentration of adjusting calcium ion to obtain the gel of required intensity.Adjust the consumption of non-volatile antifreezing agent, change the freeze proof temperature of described gel to reach the freeze proof demand of different demands, gel all can keep colloidal state, can not separate out a large amount of water and freeze by the too low colloid of Yin Wendu, affects result of use.
Anion gel air purification agent of the present invention is grouped into without one-tenth such as adding volatile solvent, essence, can not cause secondary pollution, lowers the stimulation of user and harm.
The specific embodiment
Below by embodiment, the present invention will be further described, and its object is only better to understand content of the present invention but not limits the scope of the invention.
Specific embodiment 1
Take in proportion following material: gellan gum: 0.5 part, anion powder: 5 parts, 1% calcium chloride water: 2 parts, propylene glycol: 2 parts, Methylisothiazolinone: 0.1 part, deionized water: 90.4 parts.First gellan gum is mixed with deionized water, be heated with stirring to 90 ℃, continuing to be heated to gellan gum dissolves completely, again 1% calcium chloride water is added in mixed liquor, insulation after being cooled to 60 ℃ after stirring, then to mixed liquor, add propylene glycol, anion powder, Methylisothiazolinone successively, stir, be finally cooled to room temperature.
Specific embodiment 2
Take in proportion following material: gellan gum: 0.4 part, carrageenan: 0.4 part, anion powder: 2 parts, 0.75% calcium chloride water: 5 parts, propylene glycol: 5 parts, Methylisothiazolinone: 0.03 part, benzene isothiazolone: 0.02 part, deionized water: 87.15 parts.First gellan gum and carrageenan are mixed with deionized water, be heated with stirring to 85 ℃, continue to be heated to gellan gum and carrageenan dissolves completely, again 0.75% calcium chloride water is added in mixed liquor, after being cooled to 65 ℃ after stirring, insulation, then adds propylene glycol, anion powder, Methylisothiazolinone to mixed liquor, benzene isothiazolone successively, stir, be finally cooled to room temperature.
Specific embodiment 3
Take in proportion following material: carrageenan: 0.8 part, gellan gum: 0.2 part, anion powder: 7.5 parts, 1% calcium lactate aqueous solution: 3.5 parts, propylene glycol: 5 parts, glycerol: 5 parts, deionized water: 78 parts.First carrageenan and gellan gum are mixed with deionized water, be heated with stirring to 95 ℃, continue to be heated to carrageenan and gellan gum dissolves completely, again 1% calcium lactate aqueous solution is added in mixed liquor, insulation after being cooled to 55 ℃ after stirring, then to mixed liquor, add propylene glycol, glycerol, anion powder successively, stir, be finally cooled to room temperature.
Specific embodiment 4
Take in proportion following material: gellan gum: 0.8 part, anion powder: 5 parts, 0.5% calcium chloride water: 7 parts, propylene glycol: 10 parts, benzyl alcohol: 0.03 part, phenoxyethanol: 0.03 part, poly hexamethylene biguanide: 0.04 part, deionized water: 77.1 parts.First gellan gum is mixed with deionized water, be heated with stirring to 90 ℃, continuing to be heated to gellan gum dissolves completely, again 0.5% calcium chloride water is added in mixed liquor, insulation after being cooled to 65 ℃ after stirring, then to mixed liquor, add propylene glycol, anion powder, benzyl alcohol, phenoxyethanol, poly hexamethylene biguanide successively, stir, be finally cooled to room temperature.
Specific embodiment 5
Take in proportion following material: locust bean gum: 0.8 part, anion powder: 5 parts, 0.65% calcium chloride water: 3.5 parts, ethylene glycol: 10 parts, benzyl alcohol: 0.09 part, phenoxyethanol: 0.01 part, deionized water: 80.6 parts.First locust bean gum is mixed with deionized water, be heated with stirring to 88 ℃, continuing to be heated to locust bean gum dissolves completely, again 0.65% calcium chloride water is added in mixed liquor, insulation after being cooled to 63 ℃ after stirring, then to mixed liquor, add ethylene glycol, anion powder, benzyl alcohol, phenoxyethanol successively, stir, be finally cooled to room temperature.
Specific embodiment 6
Take in proportion following material: locust bean gum: 0.6, sodium alginate: 0.4 part, anion powder: 5 parts, 0.85% calcium chloride water: 3.5 parts, ethylene glycol: 7 parts, phenoxyethanol: 0.1 part, deionized water: 83.4 parts.First locust bean gum and sodium alginate are mixed with deionized water, be heated with stirring to 93 ℃, continue to be heated to locust bean gum and sodium alginate dissolves completely, again 0.85% calcium chloride water is added in mixed liquor, insulation after being cooled to 58 ℃ after stirring, then to mixed liquor, add ethylene glycol, anion powder, phenoxyethanol successively, stir, be finally cooled to room temperature.
Specific embodiment 7
Take in proportion following material: carrageenan: 0.8 part, anion powder: 2 parts, 1% calcium lactate aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 88.7 parts.First carrageenan is mixed with deionized water, be heated with stirring to 95 ℃, continuing to be heated to carrageenan dissolves completely, again 1% calcium lactate aqueous solution is added in mixed liquor, insulation after being cooled to 55 ℃ after stirring, then to mixed liquor, add propylene glycol, anion powder, stir successively, be finally cooled to room temperature.
Specific embodiment 8
Take in proportion following material: gellan gum: 0.8 part, anion powder: 10 parts, 1% calcium chloride water: 3.5 parts, propylene glycol: 5 parts, deionized water: 80.7 parts.First gellan gum is mixed with deionized water, be heated with stirring to 85 ℃ of left and right, continuing to be heated to gellan gum dissolves completely, again 1% calcium chloride water is added in mixed liquor, insulation after being cooled to 60 ℃ after stirring, then to mixed liquor, add propylene glycol, anion powder, stir successively, be finally cooled to room temperature.
Specific embodiment 9
Test is below usingd ammonia as air pollution source, carry out 4 tests, anion gel air purification agent of the present invention is not used in contrast, use the anion gel air purification agent of embodiments of the invention 1 after 2 hours, except ammonia rate reaches 98.59%, minimumly also reach 97.91%, effectively remove airborne pollutant.
Table 1. is usingd ammonia as air pollution source, and 2 hours except ammonia experimental result
Specific embodiment 10
The fungistatic effect separately of having shown the anion gel air purification agent of specific embodiment 7 and specific embodiment 8 in table 2.After 14 days, the mycete of use specific embodiment 7 is decreased significantly while starting, and after 14 days, than the concentration of initial mycete, has increased an order of magnitude, has effectively controlled the breeding of mycete respectively; Use the mycete control of specific embodiment 8 more remarkable, when anion powder concentration is added into 10%, the concentration of mycete, after 14 days, still than little 2 orders of magnitude of initial concentration, presses down bactericidal property very superior.The increase of anion weight portion can increase the effect of antiseptic and inhibiting bacteria function, thereby according to need to not adding antiseptic or adding less antiseptic.
The fungistatic effect of the anion gel air purification agent of table 2. specific embodiment 7 and specific embodiment 8
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also change and revise above-mentioned embodiment.Therefore, the present invention is not limited to the specific embodiment disclosed and described above, to modifications and changes more of the present invention, also should fall in the protection domain of claim of the present invention.In addition,, although used some specific terms in this description, these terms just for convenience of description, do not form any restriction to the present invention.
Claims (10)
1. an anion gel air purification agent, it is characterized in that, with listed as parts by weight, comprise following component: gel: 0.5～1 part, calcium ion aqueous solution: 2～5 parts, anion powder: 2～10 parts, non-volatile antifreezing agent: 2～10 parts, antiseptic: 0～0.1 part, deionized water: add to 100 parts.
2. anion gel air purification agent according to claim 1, is characterized in that it is one or more mixing in Methylisothiazolinone, chlormethylisothiazo,ine ketone, benzene isothiazolone, benzyl alcohol, phenoxyethanol, poly hexamethylene biguanide that described antiseptic is selected from.
3. anion gel air purification agent according to claim 1, is characterized in that described non-volatile antifreezing agent is selected from one or more mixing in ethylene glycol, propylene glycol, glycerol.
4. anion gel air purification agent according to claim 1, it is characterized in that, described anion gel air purification agent formula, with listed as parts by weight, comprising: gel: 0.8 part, anion powder: 5 parts, calcium ion aqueous solution: 2～3.5 parts, non-volatile antifreezing agent: 2～10 parts, antiseptic: 0.1 part, deionized water: add to 100 parts.
5. anion gel air purification agent according to claim 1, it is characterized in that, described anion gel air purification agent formula, with listed as parts by weight, comprising: gel: 0.8 part, anion powder: 2 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 88.7 parts.
6. anion gel air purification agent according to claim 1, it is characterized in that, described anion gel air purification agent formula, with listed as parts by weight, comprising: gel: 0.8 part, anion powder: 10 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 80.7 parts.
7. according to the anion gel air purification agent described in claim 1-6 any one, it is characterized in that described calcium ion aqueous solution is that mass concentration is 1% calcium chloride water.
8. according to the anion gel air purification agent described in claim 1-6 any one, it is characterized in that gel is selected from one or more the mixing in gellan gum, carrageenan, locust bean gum, sodium alginate.
9. a preparation method for anion gel air purification agent as claimed in claim 1, is characterized in that comprising the following steps:
A. by proportioning, take after material, gel mixes with deionized water, is heated with stirring to 85～95 ℃, continues to be heated to gel and dissolves completely;
B. calcium ion aqueous solution is added in mixed liquor, after stirring, be cooled to 55～65 ℃ after insulation;
C. to mixed liquor, add non-volatile antifreezing agent, anion powder, stir successively;
D. be cooled to room temperature.
10. a preparation method for anion gel air purification agent as claimed in claim 9, is characterized in that adding in step 3 antiseptic.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410016656.2A CN103721285B (en) | 2014-01-14 | 2014-01-14 | A kind of anion hydrogel air purifies freshener and preparation method thereof |
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| CN201410016656.2A CN103721285B (en) | 2014-01-14 | 2014-01-14 | A kind of anion hydrogel air purifies freshener and preparation method thereof |
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| CN103721285A true CN103721285A (en) | 2014-04-16 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108159465A (en) * | 2018-01-24 | 2018-06-15 | 合肥华盖生物科技有限公司 | One kind de-tastes antibacterial air freshener of flavouring and preparation method thereof |
| CN110585467A (en) * | 2019-09-25 | 2019-12-20 | 深圳市绿安居科技有限公司 | Air purification gel composition and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102091337A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Nano tourmaline and fragrant flower essential oil air freshening aromatizer |
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2014
- 2014-01-14 CN CN201410016656.2A patent/CN103721285B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102091337A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Nano tourmaline and fragrant flower essential oil air freshening aromatizer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108159465A (en) * | 2018-01-24 | 2018-06-15 | 合肥华盖生物科技有限公司 | One kind de-tastes antibacterial air freshener of flavouring and preparation method thereof |
| CN110585467A (en) * | 2019-09-25 | 2019-12-20 | 深圳市绿安居科技有限公司 | Air purification gel composition and preparation method thereof |
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| CN103721285B (en) | 2016-06-29 |
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Granted publication date: 20160629 Termination date: 20210114 |