CN103710530A - Calcination method for lithionite and industrial waste slag - Google Patents
Calcination method for lithionite and industrial waste slag Download PDFInfo
- Publication number
- CN103710530A CN103710530A CN201210379229.1A CN201210379229A CN103710530A CN 103710530 A CN103710530 A CN 103710530A CN 201210379229 A CN201210379229 A CN 201210379229A CN 103710530 A CN103710530 A CN 103710530A
- Authority
- CN
- China
- Prior art keywords
- lithionite
- industrial residue
- industrial waste
- waste slag
- calcination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to a calcination method for lithionite and industrial waste slag, and relates to the technical field of lithionite calcination. The method comprises steps of mixing the lithionite and the industrial waste slag according to a weight ratio of 1:1-5; adding a proper amount of water into the material mixture; grinding uniformly in a ball mill; filtering, by a filter press, ore pulp obtained by concentrating the ball mill pulp; sending filter slag of the filter press back into a rotary kiln and performing high-temperature calcination at 700-1200 DEG C, wherein Li+ in the molten mass of the lithionite and SO4<2-> in the industrial waste slag are reacted to produce Li2SO4 during the high-temperature calcination of the lithionite and the industrial waste slag at high temperature; and cooling, and crushing by a crusher; and adding washing water and grinding with water to a technology required granularity. According to the method, the industrial waste slag is used as the main auxiliary material, thus achieving comprehensive utilization of the slag, utilizing the thermal energy comprehensively, increasing the production efficiency and achieving objectives of reducing energy consumption and guaranteeing the quality of the calcination material.
Description
?
technical field:
the present invention relates to lithionite roasting technology field, be specifically related to the roasting method of lithionite and industrial residue.
background technology:
yichuan is China largest selecting and purchasing of tantalum niobium and lithionite production base at present, and Feld Spar in Yichun Guimaraesite Mine bed, containing various metals such as tantalum, niobium, lithium, rubidium caesiums, has the advantages that field conditions is good, reserves are large, useful metal is many, comprehensive utilization value is high.
take lithionite in the technique of raw material production product, and the difference of roasting method, can affect the height of cost and the quality of quality product.
summary of the invention:
the roasting method that the object of this invention is to provide lithionite and industrial residue, it usings industrial residue as major auxiliary burden, has realized the comprehensive utilization of slag, and makes full use of heat energy, has improved production efficiency, has reached the object that reduces energy consumption and guarantee roasting material quality.
in order to solve the existing problem of background technology, the present invention adopts following roasting scheme: lithionite and industrial residue are prepared burden by weight 1:1～5, it is levigate even in ball mill that the material preparing adds appropriate water, the dense ore pulp of ball milling slurry after concentrated is through pressure filter press filtration, filter-press residues is sent back to and in rotary kiln, is carried out high-temperature roasting, 700～1200 ℃ of maturing temperatures; At high temperature, lithionite and industrial residue high-temperature roasting, the Li in lithionite molten mass
+
with the SO in industrial residue
4
2-
reaction generates Li
2
sO
4
, cooling by crusher in crushing, add wash water, water mill is levigate to processing requirement granularity.
composition and the weight percent of described lithionite are respectively: Li
2
o 3～5.5%, K
2
o+Na
2
o 9～12%, Al
2
o
3
20～25%
, SiO
2
50～63%, MgO0.1～0.2%, Rb
2
o0.9～1.2%, CaO1.01～0.1%, Cs
2
o0.2～1.0%, F4～7%.
composition and the weight percent of described industrial residue are respectively: Ca20～30%, Mg6～10%, SO
4
2-
40～55%, Cu0.01～0.1%, Na3～9%, Ni0.05～0.1%, Fe8～12%.
the present invention has following beneficial effect: using industrial residue as major auxiliary burden, realized the comprehensive utilization of slag, and make full use of heat energy, improved production efficiency, reached the object that reduces energy consumption and guarantee roasting material quality.
embodiment:
this embodiment adopts following roasting scheme: lithionite and industrial residue are prepared burden by weight 1:1～5, it is levigate even in ball mill that the material preparing adds appropriate water, the dense ore pulp of ball milling slurry after concentrated is through pressure filter press filtration, filter-press residues is sent back to and in rotary kiln, is carried out high-temperature roasting, 700～1500 ℃ of maturing temperatures; At high temperature, lithionite and industrial residue melting, the Li in lithionite molten mass
+
with the SO in industrial residue
4
2-
reaction generates Li
2
sO
4
, cooling by crusher in crushing, add wash water, water mill is levigate to processing requirement granularity.
composition and the weight percent of described lithionite are respectively: Li
2
o 3～5.5%, K
2
o+Na
2
o 9～12%, Al
2
o
3
20～25%
, SiO
2
50～63%, MgO0.1～0.2%, Rb
2
o0.9～1.2%, CaO1.01～0.1%, Cs
2
o0.2～1.0%, F4～7%.
composition and the weight percent of described industrial residue are respectively: Ca20～30%, Mg6～10%, SO
4
2-
40～55%, Cu0.01～0.1%, Na3～9%, Ni0.05～0.1%, Fe8～12%.
this embodiment is usingd industrial residue as major auxiliary burden, has realized the comprehensive utilization of slag, and makes full use of heat energy, has improved production efficiency, has reached the object that reduces energy consumption and guarantee roasting material quality.
Claims (3)
1. the roasting method of lithionite and industrial residue, it is characterized in that it adopts following roasting scheme: lithionite and industrial residue are prepared burden by weight 1:1～5, it is levigate even in ball mill that the material preparing adds appropriate water, the dense ore pulp of ball milling slurry after concentrated is through pressure filter press filtration, filter-press residues is sent back to and in rotary kiln, is carried out high-temperature roasting, 700～1200 ℃ of maturing temperatures; At high temperature, lithionite and industrial residue high-temperature roasting, the Li in lithionite molten mass
+with the SO in industrial residue
4 2-reaction generates Li
2sO
4, cooling by crusher in crushing, add wash water, water mill is levigate to processing requirement granularity.
2. the roasting method of lithionite according to claim 1 and industrial residue, is characterized in that composition and the weight percent of described lithionite is respectively: Li
2o 3～5.5%, K
2o+Na
2o 9～12%, Al
2o
320～25%, SiO
250～63%, MgO0.1～0.2%, Rb
2o0.9～1.2%, CaO1.01～0.1%, Cs
2o0.2～1.0%, F4～7%.
3. the roasting method of lithionite according to claim 1 and industrial residue, is characterized in that composition and the weight percent of described industrial residue is respectively: Ca20～30%, Mg6～10%, SO
4 2-40～55%, Cu0.01～0.1%, Na3～9%, Ni0.05～0.1%, Fe8～12%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210379229.1A CN103710530A (en) | 2012-10-09 | 2012-10-09 | Calcination method for lithionite and industrial waste slag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210379229.1A CN103710530A (en) | 2012-10-09 | 2012-10-09 | Calcination method for lithionite and industrial waste slag |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103710530A true CN103710530A (en) | 2014-04-09 |
Family
ID=50403876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210379229.1A Pending CN103710530A (en) | 2012-10-09 | 2012-10-09 | Calcination method for lithionite and industrial waste slag |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103710530A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106222450A (en) * | 2016-07-21 | 2016-12-14 | 温岭市亿林投资有限公司 | Lithium, rubidium and the extracting method of caesium in a kind of zinnwaldite ore deposit |
| CN106587116A (en) * | 2016-12-05 | 2017-04-26 | 天津二八科技股份有限公司 | Method for extracting lithium carbonate and aluminum hydroxide through lepidolite and fly ash |
| CN108516569A (en) * | 2018-05-21 | 2018-09-11 | 江西南氏锂电新材料有限公司 | The method that lepidolite roasting prepares lithium sulfate solution |
| CN110627359A (en) * | 2019-11-04 | 2019-12-31 | 江西飞宇新能源科技有限公司 | Frit for glaze and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1003008B (en) * | 1985-04-01 | 1989-01-04 | 广州有色金属研究院 | Process for preparing lithium carbonate by treating lepidolite with potassium sulfate method |
| CN1005106B (en) * | 1987-03-14 | 1989-09-06 | 广州有色金属研究院 | Process for preparing lithium carbonate by sulfate method |
| CN1827527A (en) * | 2005-03-02 | 2006-09-06 | 钟辉 | Process for preparing lithium chlorate by lithium extracted from lepidolite |
| CN102295303A (en) * | 2011-08-08 | 2011-12-28 | 江西本源新材料科技有限公司 | Extraction method of lithium carbonate |
-
2012
- 2012-10-09 CN CN201210379229.1A patent/CN103710530A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1003008B (en) * | 1985-04-01 | 1989-01-04 | 广州有色金属研究院 | Process for preparing lithium carbonate by treating lepidolite with potassium sulfate method |
| CN1005106B (en) * | 1987-03-14 | 1989-09-06 | 广州有色金属研究院 | Process for preparing lithium carbonate by sulfate method |
| CN1827527A (en) * | 2005-03-02 | 2006-09-06 | 钟辉 | Process for preparing lithium chlorate by lithium extracted from lepidolite |
| CN102295303A (en) * | 2011-08-08 | 2011-12-28 | 江西本源新材料科技有限公司 | Extraction method of lithium carbonate |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106222450A (en) * | 2016-07-21 | 2016-12-14 | 温岭市亿林投资有限公司 | Lithium, rubidium and the extracting method of caesium in a kind of zinnwaldite ore deposit |
| CN106587116A (en) * | 2016-12-05 | 2017-04-26 | 天津二八科技股份有限公司 | Method for extracting lithium carbonate and aluminum hydroxide through lepidolite and fly ash |
| CN106587116B (en) * | 2016-12-05 | 2018-03-06 | 天津二八科技股份有限公司 | A kind of method for extracting lithium carbonate and aluminium hydroxide using lepidolite and flyash |
| CN108516569A (en) * | 2018-05-21 | 2018-09-11 | 江西南氏锂电新材料有限公司 | The method that lepidolite roasting prepares lithium sulfate solution |
| CN110627359A (en) * | 2019-11-04 | 2019-12-31 | 江西飞宇新能源科技有限公司 | Frit for glaze and preparation method thereof |
| CN110627359B (en) * | 2019-11-04 | 2022-03-18 | 江西飞宇新能源科技有限公司 | Frit for glaze and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110512094B (en) | Process for clean and continuous reduction of metal magnesium | |
| CN101811712A (en) | Method for preparing metallurgical-grade aluminum oxide by using fluid-bed fly ash | |
| CN102585779B (en) | Preparation method of high-purity heat-conduction energy storage molten salt | |
| CN104817099B (en) | The method that the solid fluorine reconstruct lepidolite of a kind of improvement extracts alkali metal compound | |
| CN102923764B (en) | Method for preparing sodium stannate from stannic oxide and sodium salt in reduction roasting manner | |
| CN102134075A (en) | Novel method for producing solar-grade polysilicon | |
| CN102560148A (en) | Method for smelting lithium by vacuum aluminothermic reduction | |
| CN102502721B (en) | Method for preparing lithium carbonate through extracting lithium from lithium ore | |
| CN103710530A (en) | Calcination method for lithionite and industrial waste slag | |
| US8557209B2 (en) | Method for cyclically preparing elemental boron and coproducing sodium cryolite using sodium fluoborate as intermediate material | |
| CN102817041A (en) | Method for preparing magnesium hydroxide, magnesium and magnesium aluminate spinel by bischofite | |
| CN105883843B (en) | A kind of method of alkaline hydrolysis processing boracic tailing high efficiency manufacture borax | |
| CN107964597A (en) | A kind of method for handling lepidolite extraction alkali metal | |
| CN102432011A (en) | Method for synchronously removing iron and silicon impurities in silicon carbide micro powder | |
| CN102303877A (en) | Method for preparing high purity potassium carbonate and high purity aluminium hydroxide through Baiyun ebo potash feldspar concentrate | |
| CN102145907B (en) | Method for preparing low-iron aluminum chloride crystals by using fly ash as raw material | |
| CN102899510A (en) | Production method of high-purity metal vanadium | |
| CN106495104A (en) | A kind of method that sodium sulfide is produced based on vanadium extraction solid waste sodium sulfate | |
| CN106350680B (en) | A method of sodium roasting extracts valuable metal from oil burnning ash | |
| AU2024220207A1 (en) | Method for recovering lithium from aluminum electrolysis waste cathode | |
| CN103173662B (en) | A kind of Al-Nb-Ta ternary alloy and preparation method | |
| CN102153121B (en) | Method for preparing low-iron crystalline aluminium chloride by using fly ash as raw material | |
| EP2631216B1 (en) | Method for cyclically preparing boron and coproducing potassium cryolite using potassium fluoborate as intermediate material | |
| CN105967200B (en) | A kind of production technology of coarse fraction ludwigite mineralising coproduction | |
| CN103693659B (en) | A method of producing potassium chloride and simultaneously mineralizing and fixing CO2 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140409 |