CN103709614A - PBT flame-retardant master batch - Google Patents
PBT flame-retardant master batch Download PDFInfo
- Publication number
- CN103709614A CN103709614A CN201210368740.1A CN201210368740A CN103709614A CN 103709614 A CN103709614 A CN 103709614A CN 201210368740 A CN201210368740 A CN 201210368740A CN 103709614 A CN103709614 A CN 103709614A
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- China
- Prior art keywords
- pbt
- retardant
- fire
- coupling agent
- master granule
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 42
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000004594 Masterbatch (MB) Substances 0.000 title abstract description 9
- 239000007822 coupling agent Substances 0.000 claims abstract description 17
- 239000008187 granular material Substances 0.000 claims description 21
- -1 chloro-2-propyl group Chemical group 0.000 claims description 16
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 150000004645 aluminates Chemical class 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- AHJKRLASYNVKDZ-UHFFFAOYSA-N DDD Chemical group C=1C=C(Cl)C=CC=1C(C(Cl)Cl)C1=CC=C(Cl)C=C1 AHJKRLASYNVKDZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 2
- NWCOUGMDAPWVOK-UHFFFAOYSA-N CC.BrC=1C(=C(C(=C2C1C(=O)NC2=O)Br)Br)Br Chemical compound CC.BrC=1C(=C(C(=C2C1C(=O)NC2=O)Br)Br)Br NWCOUGMDAPWVOK-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 239000000428 dust Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 35
- 229940125904 compound 1 Drugs 0.000 description 2
- YPYSAKSNRPFOET-UHFFFAOYSA-N (2,4-dibromophenyl) dihydrogen phosphate Chemical compound OP(O)(=O)OC1=CC=C(Br)C=C1Br YPYSAKSNRPFOET-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a PBT flame-retardant master batch. The PBT flame-retardant master batch comprises components by mass: 10%-15% of a PBT carrier, 50%-70% of a main flame retardant, 15%-35% of an auxiliary flame retardant, 1%-3% of a coupling agent, 3%-5% of a dispersant and 1%-2% of an antioxidant. The prepared master batch has the characteristics of high concentration, low cost and convenient use. Besides, by using the master batch in producing the PBT, a production process can be simplified; production efficiency is increased; dust flying is reduced; environment pollution is prevented; and clean production is facilitated. The master batch can be easily mixed with a PBT raw material uniformly; and mixing quality and performance indexes of the product can be further increased.
Description
Technical field
The present invention relates to a kind of fire-retardant master granule, specifically a kind of PBT fire-retardant master granule.
Background technology
Polybutylene terephthalate (PBT) is the linear saturated polyester resin of a kind of crystal type, owing to having good electric property, resistance toheat, fatigue performance, low-friction coefficient and lower-price characteristic, is widely used in the industries such as electronic apparatus, household electrical appliances, automotive industry, mechanical means, material of construction.Yet, because PBT easily burns, so it is flame-retardant modified conventionally need to add amount of retardant to carry out at production PBT, using the fire retardant overwhelming majority is at present powder, like this when mixing with PBT raw material, the utmost point is not easy to mix, and the dust of kicking up while mixing pollutes surrounding environment and unhealthful etc. especially, is unfavorable for cleaner production.
Summary of the invention
The object of the present invention is to provide a kind of high density, low cost, cleaner production and PBT fire-retardant master granule easy to use.
The technical solution adopted for the present invention to solve the technical problems is: a kind of PBT fire-retardant master granule, its component by mass percent proportioning is: PBT carrier 10%～15%, main flame retardant 50%～70%, auxiliary fire retardant 15%～35%, coupling agent 1%～3%, dispersion agent 3%～5%, oxidation inhibitor 1%～2%.
Described PBT carrier is polybutylene terephthalate.
Described main flame retardant is TDE, decabromodiphenyl oxide, tetra bromobisphenol A ether, poly-2,6-dibromo phenylene ether, tricresyl phosphate (2, the chloro-2-propyl group of 3-bis-) ester, 1, a kind of in two (tetrabromo phthalimide) ethane, three (2, the 4-dibromo phenyl) phosphoric acid ester of 2-, Wrapped up Phosphorus Fire Retardant.
Described auxiliary fire retardant is a kind of in antimonous oxide, aluminium hydroxide, magnesium hydroxide.
Described coupling agent is a kind of in silane coupling agent, titanate coupling agent, aluminate coupling agent and phosphate coupling agent.
Described dispersion agent is one or more the mixture in polyethylene wax, Poly Propylene Wax, EVA wax, OP wax, TAS-2A.
Described oxidation inhibitor is the compound of antioxidant 1076 and irgasfos 168.
The preparation method of above-mentioned a kind of PBT fire-retardant master granule, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) PBT carrier and main flame retardant, auxiliary fire retardant, coupling agent, dispersion agent, oxidation inhibitor are added in high-speed mixer, fully mix 3～5 minutes;
(3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Compared with prior art, the invention has the beneficial effects as follows, made master batch has high density, low cost and the feature such as easy to use, at production PBT, use this master batch can simplify production technique simultaneously, enhance productivity, can reduce dust from flying again, avoid environmental pollution, be conducive to cleaner production, and use this master batch easily to mix with PBT raw material, thereby further improve performance index of mixing and goods etc.
Embodiment
Below in conjunction with specific embodiment, further illustrate technical scheme of the present invention.
Embodiment 1:
A kind of PBT fire-retardant master granule, its component by mass percent proportioning is: the compound 1% of PBT carrier 12 %, TDE 60%, antimonous oxide 20%, silane coupling agent 3%, polyethylene wax 4%, antioxidant 1076 and irgasfos 168, wherein, described PBT carrier is polybutylene terephthalate.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of PBT carrier and TDE, antimonous oxide, silane coupling agent, polyethylene wax, antioxidant 1076 and irgasfos 168 is added in high-speed mixer, fully mix 3～5 minutes; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Embodiment 2:
A kind of PBT fire-retardant master granule, its component by mass percent proportioning is: PBT carrier 10%, poly-2, the compound 1% of 6-dibromo phenylene ether 70%, antimonous oxide 15%, titanate coupling agent 1%, Poly Propylene Wax 3%, antioxidant 1076 and irgasfos 168, wherein, described PBT carrier is polybutylene terephthalate.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of PBT carrier and poly-2,6-dibromo phenylene ether, antimonous oxide, titanate coupling agent, Poly Propylene Wax, antioxidant 1076 and irgasfos 168 is added in high-speed mixer, fully mix 3～5 minutes; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Embodiment 3:
A kind of PBT fire-retardant master granule, its component by mass percent proportioning is: PBT carrier 15%, three (2,4-dibromo phenyl) compound 2% of phosphoric acid ester 50%, aluminium hydroxide 25%, aluminate coupling agent 3%, OP wax 5%, antioxidant 1076 and irgasfos 168, wherein, described PBT carrier is polybutylene terephthalate.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of PBT carrier and three (2,4-dibromo phenyl) phosphoric acid ester, aluminium hydroxide, aluminate coupling agent, OP wax, antioxidant 1076 and irgasfos 168 is added in high-speed mixer, fully mix 3～5 minutes; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Claims (7)
1. a PBT fire-retardant master granule, is characterized in that, its component by mass percent proportioning is: PBT carrier 10%～15%, main flame retardant 50%～70%, auxiliary fire retardant 15%～35%, coupling agent 1%～3%, dispersion agent 3%～5%, oxidation inhibitor 1%～2%.
2. a kind of PBT fire-retardant master granule according to claim 1, it is characterized in that, described main flame retardant is TDE, decabromodiphenyl oxide, tetra bromobisphenol A ether, poly-2,6-dibromo phenylene ether, tricresyl phosphate (2, the chloro-2-propyl group of 3-bis-) ester, 1, a kind of in two (tetrabromo phthalimide) ethane, three (2, the 4-dibromo phenyl) phosphoric acid ester of 2-, Wrapped up Phosphorus Fire Retardant.
3. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described auxiliary fire retardant is a kind of in antimonous oxide, aluminium hydroxide, magnesium hydroxide.
4. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described coupling agent is a kind of in silane coupling agent, titanate coupling agent, aluminate coupling agent and phosphate coupling agent.
5. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described dispersion agent is one or more the mixture in polyethylene wax, Poly Propylene Wax, EVA wax, OP wax, TAS-2A.
6. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described oxidation inhibitor is the compound of antioxidant 1076 and irgasfos 168.
7. the preparation method of a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) PBT carrier and main flame retardant, auxiliary fire retardant, coupling agent, dispersion agent, oxidation inhibitor are added in high-speed mixer, fully mix 3～5 minutes;
(3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210368740.1A CN103709614A (en) | 2012-09-29 | 2012-09-29 | PBT flame-retardant master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210368740.1A CN103709614A (en) | 2012-09-29 | 2012-09-29 | PBT flame-retardant master batch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103709614A true CN103709614A (en) | 2014-04-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210368740.1A Pending CN103709614A (en) | 2012-09-29 | 2012-09-29 | PBT flame-retardant master batch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709614A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140648A (en) * | 2014-07-17 | 2014-11-12 | 滁州优胜高分子材料有限公司 | Permanent inflaming-retarding pbt material |
| CN104962048A (en) * | 2015-07-12 | 2015-10-07 | 朱雪梅 | Glass fiber reinforced flame-retardant PBT (polybutylene terephthalate) material and preparation method thereof |
| CN105440597A (en) * | 2015-12-16 | 2016-03-30 | 北京航天试验技术研究所 | High-glow-wire flame-retardant reinforced type PBT composite material and preparation method thereof |
| CN106947253A (en) * | 2017-03-27 | 2017-07-14 | 六安载丰新材料有限公司 | A kind of fire-retardant master granule and preparation method thereof |
| CN108034117A (en) * | 2017-12-28 | 2018-05-15 | 广东宇星阻燃新材股份有限公司 | A kind of fire-retardant master granule for wear well polythene and its preparation method and application |
-
2012
- 2012-09-29 CN CN201210368740.1A patent/CN103709614A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140648A (en) * | 2014-07-17 | 2014-11-12 | 滁州优胜高分子材料有限公司 | Permanent inflaming-retarding pbt material |
| CN104140648B (en) * | 2014-07-17 | 2016-01-20 | 滁州优胜高分子材料有限公司 | A kind of permanent fire retardant PBT material |
| CN104962048A (en) * | 2015-07-12 | 2015-10-07 | 朱雪梅 | Glass fiber reinforced flame-retardant PBT (polybutylene terephthalate) material and preparation method thereof |
| CN105440597A (en) * | 2015-12-16 | 2016-03-30 | 北京航天试验技术研究所 | High-glow-wire flame-retardant reinforced type PBT composite material and preparation method thereof |
| CN106947253A (en) * | 2017-03-27 | 2017-07-14 | 六安载丰新材料有限公司 | A kind of fire-retardant master granule and preparation method thereof |
| CN108034117A (en) * | 2017-12-28 | 2018-05-15 | 广东宇星阻燃新材股份有限公司 | A kind of fire-retardant master granule for wear well polythene and its preparation method and application |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140409 |