CN103709591A - Formula of phenolic resin modified plastic - Google Patents
Formula of phenolic resin modified plastic Download PDFInfo
- Publication number
- CN103709591A CN103709591A CN201310707378.0A CN201310707378A CN103709591A CN 103709591 A CN103709591 A CN 103709591A CN 201310707378 A CN201310707378 A CN 201310707378A CN 103709591 A CN103709591 A CN 103709591A
- Authority
- CN
- China
- Prior art keywords
- accounts
- phenolic resin
- formula
- resin modified
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 22
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 22
- 239000004033 plastic Substances 0.000 title claims abstract description 20
- 229920003023 plastic Polymers 0.000 title claims abstract description 20
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical group OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 11
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical group CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- 229920003987 resole Polymers 0.000 claims description 11
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 10
- 150000002576 ketones Chemical class 0.000 claims description 10
- 229950002083 octabenzone Drugs 0.000 claims description 10
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 6
- 230000032683 aging Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 239000004611 light stabiliser Substances 0.000 abstract 2
- 239000012745 toughening agent Substances 0.000 abstract 2
- 230000006750 UV protection Effects 0.000 abstract 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
The invention discloses a formula of a phenolic resin modified plastic. The formula comprises phenolic resin and additives, wherein the additives comprise a weather-proof agent, a light stabilizer, a toughening agent, an adhesive and a coupling agent, the weather-proof agent is 2-hydroxy-4- n-octyloxybenzophenone, the light stabilizer is hexamethylphosphoramide, the toughening agent is PPEK, the adhesive is melamine-formaldehyde resin, and the coupling agent is APTES. Therefore, the prepared modified phenolic resin has the effects of weatherability, ultraviolet resistance, ageing resistance, good toughness, good adhesion and the like.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of formula of phenolic resin modified plastics.
Background technology
Although resol has high, water-fast, heat-resisting, the wear-resisting and good chemical stability of Joint strength, also has following weakness: phenolic hydroxyl group is strong polar group, easily water suction, declines Bakeland electrical property, and physical strength is low; Phenolic hydroxyl group be heated or action of ultraviolet light under easily change, generate quinone or other structures, cause material variable color; Fragility is large; Adhesivity to GF is poor.
Summary of the invention
The object of the present invention is to provide the formula of a kind of weather, uvioresistant, ageing-resistant, good toughness, phenolic resin modified plastics that adhesivity is good.
Technical scheme of the present invention is, a kind of formula of phenolic resin modified plastics, comprise resol and additive, described additive comprises weather resisting agent, photostabilizer, toughner, tackiness agent and coupling agent, described weather resisting agent is Octabenzone, and described photostabilizer is HMPA, and described toughner is polyphenylene oxide ketone, described tackiness agent is melamine-formaldehyde resin, and described coupling agent is aminopropyl triethoxysilane.
In a preferred embodiment of the present invention, each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 80.5%-85.7%, Octabenzone accounts for 3.2%-4.1%, HMPA accounts for 3.6%-4.8%, polyphenylene oxide ketone accounts for 1.3%-2.4%, melamine-formaldehyde resin accounts for 2.8%-3.7%, and aminopropyl triethoxysilane accounts for 3.4%-4.5%.
In a preferred embodiment of the present invention, each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 84.1%, Octabenzone accounts for 3.3%, HMPA accounts for 3.9%, polyphenylene oxide ketone accounts for 1.5%, melamine-formaldehyde resin accounts for 3.1%, and aminopropyl triethoxysilane accounts for 4.1%.
Of the present invention is a kind of formula of phenolic resin modified plastics, make to make phenolic resin modified after there is the effects such as weather, uvioresistant, ageing-resistant, good toughness, adhesivity be good.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Of the present invention is a kind of formula of phenolic resin modified plastics, comprise resol and additive, described additive comprises weather resisting agent, photostabilizer, toughner, tackiness agent and coupling agent, described weather resisting agent is Octabenzone, described photostabilizer is HMPA, described toughner is polyphenylene oxide ketone, and described tackiness agent is melamine-formaldehyde resin, and described coupling agent is aminopropyl triethoxysilane.
Further, each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 80.5%-85.7%, Octabenzone accounts for 3.2%-4.1%, HMPA accounts for 3.6%-4.8%, polyphenylene oxide ketone accounts for 1.3%-2.4%, melamine-formaldehyde resin accounts for 2.8%-3.7%, and aminopropyl triethoxysilane accounts for 3.4%-4.5%.
Further, each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 84.1%, Octabenzone accounts for 3.3%, HMPA accounts for 3.9%, polyphenylene oxide ketone accounts for 1.5%, melamine-formaldehyde resin accounts for 3.1%, and aminopropyl triethoxysilane accounts for 4.1%.
Further, each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 82.4%, Octabenzone accounts for 3.8%, HMPA accounts for 4.6%, polyphenylene oxide ketone accounts for 2.2%, melamine-formaldehyde resin accounts for 3.4%, and aminopropyl triethoxysilane accounts for 3.6%.
Of the present invention is a kind of formula of phenolic resin modified plastics, make to make phenolic resin modified after there is the effects such as weather, uvioresistant, ageing-resistant, good toughness, adhesivity be good.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; the variation that can expect without creative work or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the formula of phenolic resin modified plastics, it is characterized in that: comprise resol and additive, described additive comprises weather resisting agent, photostabilizer, toughner, tackiness agent and coupling agent, described weather resisting agent is Octabenzone, described photostabilizer is HMPA, described toughner is polyphenylene oxide ketone, and described tackiness agent is melamine-formaldehyde resin, and described coupling agent is aminopropyl triethoxysilane.
2. the formula of phenolic resin modified plastics according to claim 1, it is characterized in that: each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 80.5%-85.7%, Octabenzone accounts for 3.2%-4.1%, HMPA accounts for 3.6%-4.8%, polyphenylene oxide ketone accounts for 1.3%-2.4%, melamine-formaldehyde resin accounts for 2.8%-3.7%, and aminopropyl triethoxysilane accounts for 3.4%-4.5%.
3. the formula of phenolic resin modified plastics according to claim 2, it is characterized in that: each composition weight percent of the formula of described phenolic resin modified plastics is that resol accounts for 84.1%, Octabenzone accounts for 3.3%, HMPA accounts for 3.9%, polyphenylene oxide ketone accounts for 1.5%, melamine-formaldehyde resin accounts for 3.1%, and aminopropyl triethoxysilane accounts for 4.1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310707378.0A CN103709591A (en) | 2013-12-20 | 2013-12-20 | Formula of phenolic resin modified plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310707378.0A CN103709591A (en) | 2013-12-20 | 2013-12-20 | Formula of phenolic resin modified plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103709591A true CN103709591A (en) | 2014-04-09 |
Family
ID=50402966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310707378.0A Pending CN103709591A (en) | 2013-12-20 | 2013-12-20 | Formula of phenolic resin modified plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709591A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009429A (en) * | 2016-05-24 | 2016-10-12 | 苏州新区特氟龙塑料制品厂 | High-strength durable polytetrafluoroethylene plastic |
| CN107746528A (en) * | 2017-11-06 | 2018-03-02 | 安徽蓝德集团股份有限公司 | A kind of automobile GPS instrument board protective cases |
| CN108822486A (en) * | 2018-06-21 | 2018-11-16 | 苏州新益特塑胶科技有限公司 | A kind of durable phenoplasts of Anti- tarnishing |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1628346A (en) * | 2000-09-29 | 2005-06-15 | 通用电气公司 | Colored data storage media |
| CN101926302A (en) * | 2009-06-24 | 2010-12-29 | 黄文笔 | Foldable plastic transparent fish bowl |
| CN103160271A (en) * | 2012-12-28 | 2013-06-19 | 北京仁创科技集团有限公司 | Preparation method for lumpish sand prevention proppant |
| CN110926302A (en) * | 2019-12-13 | 2020-03-27 | 四川大学 | Shaft diameter adjustable three-spring pressure sensing mechanical centering device and method |
-
2013
- 2013-12-20 CN CN201310707378.0A patent/CN103709591A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1628346A (en) * | 2000-09-29 | 2005-06-15 | 通用电气公司 | Colored data storage media |
| CN101926302A (en) * | 2009-06-24 | 2010-12-29 | 黄文笔 | Foldable plastic transparent fish bowl |
| CN103160271A (en) * | 2012-12-28 | 2013-06-19 | 北京仁创科技集团有限公司 | Preparation method for lumpish sand prevention proppant |
| CN110926302A (en) * | 2019-12-13 | 2020-03-27 | 四川大学 | Shaft diameter adjustable three-spring pressure sensing mechanical centering device and method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009429A (en) * | 2016-05-24 | 2016-10-12 | 苏州新区特氟龙塑料制品厂 | High-strength durable polytetrafluoroethylene plastic |
| CN107746528A (en) * | 2017-11-06 | 2018-03-02 | 安徽蓝德集团股份有限公司 | A kind of automobile GPS instrument board protective cases |
| CN108822486A (en) * | 2018-06-21 | 2018-11-16 | 苏州新益特塑胶科技有限公司 | A kind of durable phenoplasts of Anti- tarnishing |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2012128596A3 (en) | Adhesive composition | |
| WO2010008934A3 (en) | Process for tailoring water-borne coating compositions | |
| WO2014105466A3 (en) | A coating composition and articles made therefrom | |
| CN104371502A (en) | Insulating paint | |
| CN103709600B (en) | A kind of formula of modified melamine-formaldehyde resin | |
| CN103709591A (en) | Formula of phenolic resin modified plastic | |
| CN103497433A (en) | Butyl rubber waterproof sealing adhesive tape substrate | |
| CN103305003A (en) | Formula of modified polyphenylene sulfide plastic | |
| CN103319825A (en) | Formula of modified polytetrafluoroethylene-ethylene copolymer | |
| CN103772836A (en) | Polystyrene and polycarbonate compound modified plastic | |
| MX2020006752A (en) | Copolyester, aqueous dispersion, and aqueous paint using same. | |
| CN103059665A (en) | Polytetrafluoroethylene coating | |
| CN104893616A (en) | Chloroprene rubber adhesive | |
| CN103666353A (en) | Epoxy resin adhesive | |
| CN103694627A (en) | Phenolic resin and urea resin composite modified plastic | |
| CN104327753B (en) | Water-based adhesive | |
| CN105199276A (en) | Formula of high-viscosity modified polytetrafluoroethylene | |
| CN103319899A (en) | Formula of modified organic silicon resin | |
| CN103897638A (en) | Powerful butyl rubber adhesive | |
| CN104693942A (en) | Insulating varnish | |
| CN104513509A (en) | Novel anti-UV coating | |
| CN105385407A (en) | Sealant | |
| CN105419691A (en) | Environment-friendly corrosion-resistant adhesive | |
| CN104312464A (en) | Adhesive for solid wood | |
| CN104650763A (en) | Improved environmental-protective carpentry glue |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140409 |