CN103668144B - A kind of environment-friendly type organo-metallic treatment solution and preparation method thereof - Google Patents
A kind of environment-friendly type organo-metallic treatment solution and preparation method thereof Download PDFInfo
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- 125000002524 organometallic group Chemical group 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title description 7
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims abstract description 17
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims abstract description 17
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 17
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 17
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000002949 phytic acid Nutrition 0.000 claims abstract description 17
- 239000000467 phytic acid Substances 0.000 claims abstract description 17
- 229940068041 phytic acid Drugs 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 17
- 239000011975 tartaric acid Substances 0.000 claims abstract description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 14
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 239000011734 sodium Substances 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 13
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000008399 tap water Substances 0.000 claims abstract description 4
- 235000020679 tap water Nutrition 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- CAQWNKXTMBFBGI-UHFFFAOYSA-N C.[Na] Chemical compound C.[Na] CAQWNKXTMBFBGI-UHFFFAOYSA-N 0.000 claims 3
- 230000008569 process Effects 0.000 abstract description 8
- 239000003973 paint Substances 0.000 abstract description 3
- 238000005554 pickling Methods 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 230000003750 conditioning effect Effects 0.000 abstract 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 abstract 1
- 150000002903 organophosphorus compounds Chemical class 0.000 abstract 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
- 238000004381 surface treatment Methods 0.000 description 14
- 238000007689 inspection Methods 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000012795 verification Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000001962 electrophoresis Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910000398 iron phosphate Inorganic materials 0.000 description 2
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- OSKILZSXDKESQH-UHFFFAOYSA-K zinc;iron(2+);phosphate Chemical compound [Fe+2].[Zn+2].[O-]P([O-])([O-])=O OSKILZSXDKESQH-UHFFFAOYSA-K 0.000 description 1
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- Chemical Treatment Of Metals (AREA)
Abstract
本发明公开了一种环保型有机磷化液，由如下质量百分比的原料制备而成：植酸5-15%，酒石酸3-8%，季戊四醇0.1-3%，三乙醇胺4-8%，甲酯磺酸钠1-8%，其余为自来水。本发明所述环保型有机磷化液采用有机磷复合液具有如下优点：磷化时间短，3-8分钟；使用温度跨度大，15-45℃均可；工序简单，无需酸洗、调质；成膜薄，质量好，漆面附着力强，各项指标均达到国家标准，槽液使用周期长，废液无污染。The invention discloses an environment-friendly organic phosphating solution, which is prepared from the following raw materials in mass percentage: phytic acid 5-15%, tartaric acid 3-8%, pentaerythritol 0.1-3%, triethanolamine 4-8%, formazan Sodium ester sulfonate 1-8%, the rest is tap water. The environment-friendly organic phosphating solution of the present invention adopts the organic phosphorus compound solution, which has the following advantages: the phosphating time is short, 3-8 minutes; the use temperature span is large, 15-45 ° C; the process is simple, no need for pickling and conditioning ; Thin film, good quality, strong adhesion to the paint surface, all indicators have reached the national standard, the bath solution has a long service life, and the waste solution is pollution-free.
Description
技术领域technical field
本发明涉及一种化学产品及其制备方法，特别是涉及一种环保型有机金属处理液及其制备方法。The invention relates to a chemical product and a preparation method thereof, in particular to an environment-friendly organic metal treatment liquid and a preparation method thereof.
背景技术Background technique
纵观目前黑色金属表面磷化处理，除采用硅烷剂之外，只有传统的磷酸及磷酸盐磷化，为保证磷化膜的质量，往往复合配比或添加各种金属离子铬、锌、钙、锰、镍来弥补磷酸磷化的不足，达到抗腐蚀并使得表面喷涂油漆结合更牢固的目的，然而，传统的磷酸磷化，磷化过程，大量磷酸铁析出沉降，造成磷化液污染，必须匹配附属设备，来处理净化磷化液，以避免磷化液不可使用，同时排放过程给环保处理带来极大的压力；部分磷化配方，需要加热、磷化过程时间长，消耗大量能源等问题。Throughout the current ferrous metal surface phosphating treatment, in addition to the use of silane agents, there are only traditional phosphoric acid and phosphate phosphating. In order to ensure the quality of the phosphating film, various metal ions such as chromium, zinc, and calcium are often compounded or added. , manganese, and nickel to make up for the deficiency of phosphoric acid phosphating, to achieve corrosion resistance and to make the surface spray paint more firmly bonded. However, in the traditional phosphoric acid phosphating, a large amount of iron phosphate precipitates and settles during the phosphating process, causing pollution of the phosphating solution. Auxiliary equipment must be matched to process and purify the phosphating solution to prevent the phosphating solution from being unusable. At the same time, the discharge process brings great pressure to environmental protection; some phosphating formulas require heating, and the phosphating process takes a long time, consuming a lot of energy And other issues.
发明内容Contents of the invention
本发明要解决的技术问题是提供一种代替金属磷化的表面处理液，具有处理时间短、制环保、安全、节能，使用简单的环保型有机金属表面处理液。The technical problem to be solved by the present invention is to provide a surface treatment solution that replaces metal phosphating, which has the advantages of short treatment time, environmental protection, safety, energy saving, and easy to use environment-friendly organic metal surface treatment solution.
一种环保型有机金属表面处理液，其由如下质量百分比的原料制备而成：植酸5-15%，酒石酸3-8%，季戊四醇0.1-3%，三乙醇胺4-8%，脂肪酸甲酯磺酸钠1-8%，其余为水。An environment-friendly organic metal surface treatment solution, which is prepared from the following raw materials in mass percentage: phytic acid 5-15%, tartaric acid 3-8%, pentaerythritol 0.1-3%, triethanolamine 4-8%, fatty acid methyl ester Sodium sulfonate 1-8%, the rest is water.
本发明所述的环保型有机金属处理液，其由如下质量百分比的原料制备而成：植酸5%，酒石酸8%，季戊四醇0.1%，三乙醇胺8%，脂肪酸甲酯磺酸钠1%，其余为水。The environment-friendly organometallic treatment solution of the present invention is prepared from the following raw materials in mass percentage: 5% phytic acid, 8% tartaric acid, 0.1% pentaerythritol, 8% triethanolamine, 1% sodium fatty acid methyl ester sulfonate, The rest is water.
本发明所述的环保型有机金属处理液，其由如下质量百分比的原料制备而成：植酸15%，酒石酸3%，季戊四醇3%，三乙醇胺4%，脂肪酸甲酯磺酸钠8%，其余为水。The environment-friendly organic metal treatment solution of the present invention is prepared from the following raw materials in mass percentage: 15% phytic acid, 3% tartaric acid, 3% pentaerythritol, 4% triethanolamine, 8% sodium fatty acid methyl ester sulfonate, The rest is water.
本发明所述的环保型有机金属处理液，其由如下质量百分比的原料制备而成：植酸10%，酒石酸5%，季戊四醇2%，三乙醇胺6%，脂肪酸甲酯磺酸钠5%，其余为水。The environment-friendly organic metal treatment solution of the present invention is prepared from the following raw materials in mass percentage: 10% phytic acid, 5% tartaric acid, 2% pentaerythritol, 6% triethanolamine, 5% sodium fatty acid methyl ester sulfonate, The rest is water.
本发明所述的环保型有机金属处理液，其中所述水为城市管网供水。The environment-friendly organometallic treatment liquid of the present invention, wherein the water is supplied by urban pipe network.
一种本发明所述的环保型有机金属处理液的制备方法，包括如下步骤：按配比准备原料，将植酸加入水中，搅拌20分钟后，按顺序依次加入酒石酸、季戊四醇、三乙醇胺、脂肪酸甲酯磺酸钠，继续搅拌40分钟后即得产品。A preparation method of the environment-friendly organic metal treatment liquid of the present invention, comprising the steps of: preparing raw materials according to the proportioning, adding phytic acid into water, stirring for 20 minutes, adding tartaric acid, pentaerythritol, triethanolamine, and fatty acid methyl alcohol in sequence Sodium ester sulfonate, continue stirring for 40 minutes to obtain the product.
一种本发明所述环保型有机金属处理液的使用方法，包括如下步骤：使用时，将所述金属处理液与城市管网所供自来水按照重量比1：20混合后，直接使用，在使用过程中根据消耗量补充新液。A method for using the environment-friendly organometallic treatment liquid of the present invention, comprising the following steps: when in use, mix the metal treatment liquid with the tap water provided by the urban pipe network according to a weight ratio of 1:20, and then use it directly. During the process, add new fluid according to consumption.
本发明所述环保型有机金属表面处理液与现有技术不同之处在于：The environmental protection type organometallic surface treatment liquid of the present invention differs from the prior art in that:
本发明所述环保型金属表面处理液具有如下优点：成膜时间短（3-8分钟），使用温度跨度大，15-45℃均可；工序简单，无需酸洗、调质；成膜薄，质量好，漆面附着力强，使用便捷，各项指标均达到国家标准，槽液使用周期长，废液无污染。The environment-friendly metal surface treatment solution described in the present invention has the following advantages: short film-forming time (3-8 minutes), large operating temperature span, 15-45°C; simple process, no need for pickling and tempering; thin film-forming , good quality, strong adhesion of the paint surface, easy to use, all indicators have reached the national standard, the bath liquid has a long service life, and the waste liquid is pollution-free.
电子显微镜检测，本复合配方成膜机理有别于传统磷化为磷酸铁、磷酸锌铁等结晶沉降堆积，为无缝隙整体成膜，膜薄，结合力强，颠覆了传统的磷化理论；磷化电泳（喷涂）后，杯突试验、划痕试验、盐雾试验及水腐蚀周期试验结果，质量均优于国家标准；尤其适合于冷轧钢板。According to electron microscope inspection, the film-forming mechanism of this composite formula is different from the traditional phosphating, which is iron phosphate, zinc-iron phosphate and other crystalline sedimentation accumulations. After phosphating electrophoresis (spraying), the results of cupping test, scratch test, salt spray test and water corrosion cycle test are all better than the national standard; especially suitable for cold-rolled steel plates.
下面结合具体实施例对本发明的环保型有机金属表面处理液作进一步说明。The environment-friendly organometallic surface treatment liquid of the present invention will be further described below in conjunction with specific examples.
具体实施方式detailed description
实施例1Example 1
一种环保型有机金属表面处理液，由如下质量百分比的原料制备而成：An environment-friendly organic metal surface treatment liquid is prepared from the following raw materials in mass percentage:
植酸5%，酒石酸8%，季戊四醇0.1%，三乙醇胺8%，脂肪酸甲酯磺酸钠1%，其余为水，优选为城市管网供水。Phytic acid 5%, tartaric acid 8%, pentaerythritol 0.1%, triethanolamine 8%, sodium fatty acid methyl ester sulfonate 1%, and the rest is water, preferably for urban pipe network water supply.
一种环保型有机金属表面处理液的制备方法，包括如下步骤：A preparation method of an environment-friendly organic metal surface treatment liquid, comprising the steps of:
按配比准备原料，将植酸加入水中，搅拌20分钟后，按顺序加入酒石酸、季戊四醇、三乙醇胺、脂肪酸甲酯磺酸钠，继续搅拌40分钟后即得产品。Prepare raw materials according to the ratio, add phytic acid into water, stir for 20 minutes, then add tartaric acid, pentaerythritol, triethanolamine, sodium fatty acid methyl ester sulfonate in sequence, and continue stirring for 40 minutes to obtain the product.
实施例2Example 2
一种环保型有机金属表面处理液，由如下质量百分比的原料制备而成：An environment-friendly organic metal surface treatment liquid is prepared from the following raw materials in mass percentage:
植酸15%，酒石酸3%，季戊四醇3%，三乙醇胺4%，脂肪酸甲酯磺酸钠8%，其余为水，优选为城市管网供水。Phytic acid 15%, tartaric acid 3%, pentaerythritol 3%, triethanolamine 4%, sodium fatty acid methyl ester sulfonate 8%, the rest is water, preferably for urban pipe network water supply.
一种环保型有机金属表面处理液的制备方法，包括如下步骤：A preparation method of an environment-friendly organic metal surface treatment liquid, comprising the steps of:
按配比准备原料，将植酸加入水中，搅拌20分钟后，按顺序加入酒石酸、季戊四醇、三乙醇胺、脂肪酸甲酯磺酸钠，继续搅拌40分钟后即得产品。Prepare raw materials according to the ratio, add phytic acid into water, stir for 20 minutes, then add tartaric acid, pentaerythritol, triethanolamine, sodium fatty acid methyl ester sulfonate in sequence, and continue stirring for 40 minutes to obtain the product.
实施例3Example 3
一种环保型有机金属表面处理液，由如下质量百分比的原料制备而成：An environment-friendly organic metal surface treatment liquid is prepared from the following raw materials in mass percentage:
植酸10%，酒石酸5%，季戊四醇2%，三乙醇胺6%，脂肪酸甲酯磺酸钠5%，其余为水，优选为城市管网供水。Phytic acid 10%, tartaric acid 5%, pentaerythritol 2%, triethanolamine 6%, sodium fatty acid methyl ester sulfonate 5%, and the rest is water, preferably for urban pipe network water supply.
一种环保型有机金属表面处理液的制备方法，包括如下步骤：A preparation method of an environment-friendly organic metal surface treatment liquid, comprising the steps of:
按配比准备原料，将植酸加入水中，搅拌20分钟后，按顺序加入酒石酸、季戊四醇、三乙醇胺、脂肪酸甲酯磺酸钠，继续搅拌40分钟后即得产品。Prepare raw materials according to the ratio, add phytic acid into water, stir for 20 minutes, then add tartaric acid, pentaerythritol, triethanolamine, sodium fatty acid methyl ester sulfonate in sequence, and continue stirring for 40 minutes to obtain the product.
实施例4Example 4
本发明所述环保型有机金属表面处理液的验证实验：The verification experiment of environment-friendly type organometallic surface treatment liquid of the present invention:
验证一：取配置好的磷化液置于容器中，将冷轧板脱脂后，水洗干净，直接放入处理液中，静置悬挂3分钟，取出，水洗干净，悬挂干燥，检查膜，外表为亮蓝色，电泳后，干燥，杯突检验、划痕检测、盐雾检测，水腐蚀周期检测达到国家标准。Verification 1: Take the prepared phosphating solution in a container, degrease the cold-rolled sheet, wash it with water, put it directly into the treatment solution, let it hang for 3 minutes, take it out, wash it with water, hang it to dry, check the film, appearance It is bright blue, after electrophoresis, drying, cupping inspection, scratch inspection, salt spray inspection, and water corrosion cycle inspection meet national standards.
验证二：将冷轧板脱脂、水洗后悬挂处理液中，5分钟取出，冲洗干净，电泳，完毕，烘干，检测各种指标，完全达标。Verification 2: Degrease and wash the cold-rolled plate, hang it in the treatment solution, take it out for 5 minutes, rinse it, electrophoresis, finish, dry, test various indicators, and fully meet the standards.
验证三：将冷轧板脱脂后水洗后悬挂处理液中，5分钟后取出，冲洗干净，干燥，电喷涂，喷涂完毕，杯突检验、划痕检验，盐雾检验，水腐蚀周期检测，达到国家标准。Verification 3: Degrease the cold-rolled sheet, wash it with water, hang it in the treatment solution, take it out after 5 minutes, rinse it clean, dry it, electrospray, after spraying, cupping inspection, scratch inspection, salt spray inspection, water corrosion cycle inspection, to National standard.
残液检测：使用金属表面处理液中有效成分残余30%，置暴露空气中一周，外观，无浑浊、色变、无异味清澈透明，直接补充处理液，重新使用，质量无变化。Residual liquid detection: use 30% of the active ingredients in the metal surface treatment liquid, put it in the air for a week, the appearance, no turbidity, color change, no peculiar smell, clear and transparent, directly replenish the treatment liquid, reuse, the quality does not change.
实施例5Example 5
一种本发明所述环保型有机金属处理液的使用方法，包括如下步骤：使用时，将所述金属处理液与城市管网所供自来水按照重量比1：20混合后，直接使用，在使用过程中根据消耗量补充新液。A method for using the environment-friendly organometallic treatment liquid of the present invention, comprising the following steps: when in use, mix the metal treatment liquid with the tap water provided by the urban pipe network according to a weight ratio of 1:20, and then use it directly. During the process, add new fluid according to consumption.
以上所述的实施例仅仅是对本发明的优选实施方式进行描述，并非对本发明的范围进行限定，在不脱离本发明设计精神的前提下，本领域普通技术人员对本发明的技术方案作出的各种变形和改进，均应落入本发明权利要求书确定的保护范围内。The above-mentioned embodiments are only descriptions of preferred implementations of the present invention, and are not intended to limit the scope of the present invention. Variations and improvements should fall within the scope of protection defined by the claims of the present invention.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101848987A (en) * | 2007-09-14 | 2010-09-29 | 三洋化成工业株式会社 | Cleaning agent for electronic material |
| CN102660736A (en) * | 2012-05-16 | 2012-09-12 | 广州有色金属研究院 | Magnesium alloy surface conversion treatment liquid and treatment method thereof |
| CN102719818A (en) * | 2012-06-21 | 2012-10-10 | 大连三达奥克化学股份有限公司 | Phosphorus-free and chromium-free conversion coating treatment agent for magnesium alloy workpiece and preparation method thereof |
| CN102877055A (en) * | 2011-07-15 | 2013-01-16 | 日本帕卡濑精株式会社 | Metal surface treatment agent and metal material obtained through processing with same |
| CN103265833A (en) * | 2006-11-13 | 2013-08-28 | 巴斯夫涂料有限公司 | Coat-forming corrosion preventative with good adhesion and process for its electroless application |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265833A (en) * | 2006-11-13 | 2013-08-28 | 巴斯夫涂料有限公司 | Coat-forming corrosion preventative with good adhesion and process for its electroless application |
| CN101848987A (en) * | 2007-09-14 | 2010-09-29 | 三洋化成工业株式会社 | Cleaning agent for electronic material |
| CN102877055A (en) * | 2011-07-15 | 2013-01-16 | 日本帕卡濑精株式会社 | Metal surface treatment agent and metal material obtained through processing with same |
| CN102660736A (en) * | 2012-05-16 | 2012-09-12 | 广州有色金属研究院 | Magnesium alloy surface conversion treatment liquid and treatment method thereof |
| CN102719818A (en) * | 2012-06-21 | 2012-10-10 | 大连三达奥克化学股份有限公司 | Phosphorus-free and chromium-free conversion coating treatment agent for magnesium alloy workpiece and preparation method thereof |
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