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CN103666265B - The adhesion promoter of nylon and glass mixture material and combining method and product - Google Patents

The adhesion promoter of nylon and glass mixture material and combining method and product Download PDF

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CN103666265B
CN103666265B CN201210361705.7A CN201210361705A CN103666265B CN 103666265 B CN103666265 B CN 103666265B CN 201210361705 A CN201210361705 A CN 201210361705A CN 103666265 B CN103666265 B CN 103666265B
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adhesion promoter
nylon
mixture material
organic
coupling agent
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CN103666265A (en
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陈其亮
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Mitac Precision Technology Kunshan Ltd
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Mitac Precision Technology Kunshan Ltd
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Abstract

本发明揭示一种尼龙和玻纤混合物素材的附着力增进剂及结合方法和产品。该附着力增进剂包括按重量百分比计算的下列组分:硅烷偶联剂1%~5%;有机和无机混合的自干型纳米材料1%~4%;其余为无水乙醇、异丙醇、异丁醇中的至少一种。该结合方法包括步骤:(1)将尼龙和玻纤混合物素材涂附着力增进剂作为底漆,所述附着力增进剂包括按重量百分比计算的下列组分:硅烷偶联剂1%~5%;有机和无机混合的自干型纳米材料1%~4%;其余为无水乙醇、异丙醇、异丁醇中的至少一种;(2)将涂有所述附着力增进剂的尼龙和玻纤混合物素材上再涂PU面漆。该产品为上述结合方法处理所产生的产品。素材本身的附着力可以达到0级,无脱落。

The invention discloses an adhesion promoter, a combination method and a product of nylon and glass fiber mixture materials. The adhesion promoter includes the following components calculated by weight percentage: silane coupling agent 1% to 5%; organic and inorganic mixed self-drying nanomaterials 1% to 4%; the rest is absolute ethanol, isopropanol , at least one of isobutanol. The bonding method includes the steps: (1) Coating the nylon and glass fiber mixture material with an adhesion promoter as a primer, and the adhesion promoter includes the following components calculated by weight percentage: silane coupling agent 1% to 5% ; 1% to 4% of self-drying nanomaterials mixed with organic and inorganic materials; the rest is at least one of absolute ethanol, isopropanol, and isobutanol; (2) nylon coated with the adhesion promoter And glass fiber mixture material and then coated with PU topcoat. This product is the product resulting from the combined process described above. The adhesion of the material itself can reach level 0 without falling off.

Description

尼龙和玻纤混合物素材的附着力增进剂及结合方法和产品Adhesion promoter of nylon and glass fiber mixture material, bonding method and product

【技术领域】【Technical field】

本发明涉及一种附着力增进剂及结合方法和产品,具体涉及一种尼龙和玻纤混合物素材的附着力增进剂及结合方法和产品。The invention relates to an adhesion promoter, a bonding method and a product, in particular to an adhesion promoter, a bonding method and a product of a nylon and glass fiber mixture material.

【背景技术】【Background technique】

聚酰胺(polyamide;简称PA)聚酰胺,也叫“尼龙”,为韧性角状半透明或乳白色结晶性树脂。Polyamide (polyamide; PA for short) Polyamide, also called "nylon", is a tough angular translucent or milky white crystalline resin.

玻璃纤维(英文原名为:glassfiber或fiberglass;简称GF)是一种性能优异的无机非金属材料,种类繁多,优点是绝缘性好、耐热性强、抗腐蚀性好,机械强度高,但缺点是性脆,耐磨性较差。它是以玻璃球或废旧玻璃为原料经高温熔制、拉丝、络纱、织布等工艺制造成的,其单丝的直径为几个微米到二十几米个微米,相当于一根头发丝的1/20-1/5,每束纤维原丝都由数百根甚至上千根单丝组成。玻璃纤维通常用作复合材料中的增强材料,电绝缘材料和绝热保温材料,电路基板等国民经济各个领域。Glass fiber (original name in English: glassfiber or fiberglass; GF for short) is an inorganic non-metallic material with excellent performance. It is brittle and has poor wear resistance. It is made of glass balls or waste glass through high-temperature melting, wire drawing, winding, weaving and other processes. The diameter of its single filament is several microns to more than 20 microns, which is equivalent to a hair. 1/20-1/5 of that, each bundle of fiber precursors consists of hundreds or even thousands of monofilaments. The glass fiber is often used as reinforcing material of composite material, electrical insulation and heat insulation materials, substrate and other national economy fields.

对于高玻纤含量的PA+GF素材在笔记本电脑领域已得到应用,但对高玻纤材料而言,提高漆膜对素材的附着性非常重要,传统的PU涂料(是所有聚酯涂料的统称)对PA材料时有附着不良的缺陷产生。PA+GF materials with high glass fiber content have been applied in the field of notebook computers, but for high glass fiber materials, it is very important to improve the adhesion of the paint film to the material. Traditional PU coatings (a general term for all polyester coatings) ) There is a defect of poor adhesion to PA materials.

有鉴于此,实有必要提供一种尼龙和玻纤混合物素材的附着力增进剂及结合方法和产品,以解决上述问题。In view of this, it is necessary to provide an adhesion promoter, a combination method and product of a nylon and glass fiber mixture material, so as to solve the above-mentioned problems.

【发明内容】【Content of invention】

因此,本发明的目的是提供一种尼龙和玻纤混合物素材的附着力增进剂,以解决该种素材上喷涂PU涂料时附着不良的问题。Therefore, the purpose of this invention is to provide a kind of adhesion promoter of nylon and glass fiber mixture material, to solve the problem of poor adhesion when spraying PU coating on this kind of material.

为了达到上述目的,本发明提供的尼龙和玻纤混合物素材的附着力增进剂,包括按重量百分比计算的下列组分:In order to achieve the above object, the adhesion promoter of nylon and glass fiber mixture material provided by the invention comprises the following components calculated by weight percentage:

硅烷偶联剂1%~5%;Silane coupling agent 1% to 5%;

有机和无机混合的自干型纳米材料1%~4%;Organic and inorganic mixed self-drying nanomaterials 1% to 4%;

其余为无水乙醇、异丙醇、异丁醇中的至少一种。The rest is at least one of absolute ethanol, isopropanol and isobutanol.

可选的,所述附着力增进剂的组分为:Optionally, the components of the adhesion promoter are:

硅烷偶联剂2%;Silane coupling agent 2%;

有机和无机混合的自干型纳米材料1%;Organic and inorganic mixed self-drying nanomaterials 1%;

其余为无水乙醇。The rest is absolute ethanol.

可选的,所述附着力增进剂的组分为:Optionally, the components of the adhesion promoter are:

硅烷偶联剂5%;Silane coupling agent 5%;

有机和无机混合的自干型纳米材料2%;Organic and inorganic mixed self-drying nanomaterials 2%;

其余为无水乙醇。The rest is absolute ethanol.

可选的,所述附着力增进剂的组分为:Optionally, the components of the adhesion promoter are:

硅烷偶联剂1%;Silane coupling agent 1%;

有机和无机混合的自干型纳米材料4%;Organic and inorganic mixed self-drying nanomaterials 4%;

其余为无水乙醇。The rest is absolute ethanol.

可选的,所述硅烷偶联剂为KH550。Optionally, the silane coupling agent is KH550.

可选的,所述有机和无机混合的自干型纳米材料为N-7113。Optionally, the organic and inorganic mixed self-drying nanomaterial is N-7113.

本发明还提供一种尼龙和玻纤混合物素材的附着力增进剂的结合方法,该结合方法包括以下步骤:The present invention also provides a method for combining the adhesion promoter of nylon and glass fiber mixture materials, the method for combining comprises the following steps:

(1)将尼龙和玻纤混合物素材涂附着力增进剂作为底漆,所述附着力增进剂包括按重量百分比计算的下列组分:硅烷偶联剂1%~5%;有机和无机混合的自干型纳米材料1%~4%;其余为无水乙醇、异丙醇、异丁醇中的至少一种;(1) Coating the nylon and glass fiber mixture material with an adhesion promoter as a primer, the adhesion promoter includes the following components calculated by weight percentage: silane coupling agent 1% to 5%; organic and inorganic mixed 1% to 4% of self-drying nanomaterials; the rest is at least one of absolute ethanol, isopropanol, and isobutanol;

(2)将涂有所述附着力增进剂的尼龙和玻纤混合物素材上再涂PU面漆。(2) Apply PU topcoat to the nylon and glass fiber mixture material coated with the adhesion promoter.

本发明还提供一种尼龙和玻纤混合物素材的附着力增进剂的结合产品,其为上述结合方法处理所产生的产品。The present invention also provides a combination product of the adhesion promoter of the nylon and glass fiber mixture material, which is the product produced by the above combination method.

本发明的尼龙和玻纤混合物素材的附着力增进剂及结合方法和产品,由于采用上述附着力增进剂作为底漆,在配合PU漆使用时,尼龙和玻纤混合物素材本身的附着力可以达到0级,无脱落现象。The adhesion promoter of nylon and glass fiber mixture material of the present invention and bonding method and product, owing to adopt above-mentioned adhesion promoter as primer, when coordinating PU paint to use, the adhesion of nylon and glass fiber mixture material itself can reach Level 0, no shedding phenomenon.

【附图说明】【Description of drawings】

图1绘示本发明的尼龙和玻纤混合物素材的附着力增进剂的结合方法实施例的流程图。FIG. 1 shows a flow chart of an embodiment of the method for combining the adhesion promoter of the nylon and glass fiber mixture material of the present invention.

【具体实施方式】【detailed description】

为对本发明的目的、方法步骤及功能有进一步的了解,现配合附图详细说明如下:For having further understanding to the object of the present invention, method step and function, now cooperate accompanying drawing to describe in detail as follows:

实施例1Example 1

本发明提供的尼龙和玻纤混合物素材的附着力增进剂,可以为包括按重量百分比计算的下列组分:The adhesion promoter of nylon and glass fiber mixture material provided by the present invention can comprise the following components calculated by weight percentage:

硅烷偶联剂2%;Silane coupling agent 2%;

有机和无机混合的自干型纳米材料1%;Organic and inorganic mixed self-drying nanomaterials 1%;

其余为无水乙醇。The rest is absolute ethanol.

实施例2Example 2

本发明提供的尼龙和玻纤混合物素材的附着力增进剂,可以为包括按重量百分比计算的下列组分:The adhesion promoter of nylon and glass fiber mixture material provided by the present invention can comprise the following components calculated by weight percentage:

可选的,所述附着力增进剂的组分为:Optionally, the components of the adhesion promoter are:

硅烷偶联剂5%;Silane coupling agent 5%;

有机和无机混合的自干型纳米材料2%;Organic and inorganic mixed self-drying nanomaterials 2%;

其余为无水乙醇。The rest is absolute ethanol.

实施例3Example 3

本发明提供的尼龙和玻纤混合物素材的附着力增进剂,可以为包括按重量百分比计算的下列组分:The adhesion promoter of nylon and glass fiber mixture material provided by the present invention can comprise the following components calculated by weight percentage:

硅烷偶联剂1%;Silane coupling agent 1%;

有机和无机混合的自干型纳米材料4%;Organic and inorganic mixed self-drying nanomaterials 4%;

其余为无水乙醇。The rest is absolute ethanol.

当然,可以为选自无水乙醇、异丙醇、异丁醇中的至少一种。Of course, it may be at least one selected from absolute ethanol, isopropanol, and isobutanol.

其中,所述硅烷偶联剂可以为KH550。Wherein, the silane coupling agent may be KH550.

其中,所述有机和无机混合的自干型纳米材料可以为N-7113。Wherein, the organic and inorganic mixed self-drying nanomaterial may be N-7113.

采用该附着力增进剂,尼龙和玻纤混合物素材本身的附着力可以达到0级,无脱落。With this adhesion promoter, the adhesion of the nylon and glass fiber mixture material itself can reach level 0 without falling off.

请参阅图1,图1绘示本发明的尼龙和玻纤混合物素材的附着力增进剂的结合方法实施例的流程图。Please refer to FIG. 1 . FIG. 1 shows a flow chart of an embodiment of the method for combining the adhesion promoter of the nylon and glass fiber mixture material of the present invention.

本发明还提供的尼龙和玻纤混合物素材的附着力增进剂的结合方法,该结合方法包括以下步骤:The present invention also provides the bonding method of the adhesion promoter of nylon and glass fiber mixture material, and this bonding method comprises the following steps:

步骤101:将尼龙和玻纤混合物素材涂附着力增进剂作为底漆,所述附着力增进剂包括按重量百分比计算的下列组分:硅烷偶联剂1%~5%;有机和无机混合的自干型纳米材料1%~4%;其余为无水乙醇、异丙醇、异丁醇中的至少一种;Step 101: Coating the nylon and glass fiber mixture material with an adhesion promoter as a primer, the adhesion promoter includes the following components calculated by weight percentage: silane coupling agent 1% to 5%; organic and inorganic mixed 1% to 4% of self-drying nanomaterials; the rest is at least one of absolute ethanol, isopropanol, and isobutanol;

步骤102:将涂有所述附着力增进剂的尼龙和玻纤混合物素材上再涂PU面漆。Step 102: Coating the PU topcoat on the nylon and glass fiber mixture material coated with the adhesion promoter.

其中,所述硅烷偶联剂可以为KH550。Wherein, the silane coupling agent may be KH550.

其中,所述有机和无机混合的自干型纳米材料可以为N-7113。Wherein, the organic and inorganic mixed self-drying nanomaterial may be N-7113.

本发明还提供一种尼龙和玻纤混合物素材的附着力增进剂的结合产品,其为上述结合方法处理所产生的产品。The present invention also provides a combination product of the adhesion promoter of the nylon and glass fiber mixture material, which is the product produced by the above combination method.

本发明的尼龙和玻纤混合物素材的附着力增进剂及结合方法和产品,由于采用上述附着力增进剂作为底漆,在配合PU漆使用时,尼龙和玻纤混合物素材本身的附着力可以达到0级,无脱落现象。The adhesion promoter of nylon and glass fiber mixture material of the present invention and bonding method and product, owing to adopt above-mentioned adhesion promoter as primer, when coordinating PU paint to use, the adhesion of nylon and glass fiber mixture material itself can reach Level 0, no shedding phenomenon.

Claims (8)

1. an adhesion promoter for nylon and glass mixture material, is characterized in that, comprises the following component counted by weight percentage:
Silane coupling agent 1% ~ 5%;
The self-drying type nano material 1% ~ 4% of organic and inorganic mixing;
All the other are at least one in dehydrated alcohol, Virahol, isopropylcarbinol;
Wherein, described self-drying type nano material that is organic and inorganic mixing is N-7113.
2. the adhesion promoter of nylon according to claim 1 and glass mixture material, is characterized in that, the component of described adhesion promoter is:
Silane coupling agent 2%;
The self-drying type nano material 1% of organic and inorganic mixing;
All the other are dehydrated alcohol.
3. the adhesion promoter of nylon according to claim 1 and glass mixture material, is characterized in that, the component of described adhesion promoter is:
Silane coupling agent 5%;
The self-drying type nano material 2% of organic and inorganic mixing;
All the other are dehydrated alcohol.
4. the adhesion promoter of nylon according to claim 1 and glass mixture material, is characterized in that, the component of described adhesion promoter is:
The component of described adhesion promoter is:
Silane coupling agent 1%;
The self-drying type nano material 4% of organic and inorganic mixing;
All the other are dehydrated alcohol.
5. the adhesion promoter of the nylon according to any one of claim 1-4 and glass mixture material, is characterized in that, described silane coupling agent is KH550.
6. a combining method for the adhesion promoter of nylon and glass mixture material, is characterized in that, this combining method comprises the following steps:
(1) nylon and glass mixture material are coated with adhesion promoter as priming paint, described adhesion promoter comprises the following component counted by weight percentage: silane coupling agent 1% ~ 5%; The self-drying type nano material 1% ~ 4% of organic and inorganic mixing; All the other are at least one in dehydrated alcohol, Virahol, isopropylcarbinol; Wherein, described self-drying type nano material that is organic and inorganic mixing is N-7113;
(2) PU finish paint is coated with again by scribbling on the nylon of described adhesion promoter and glass mixture material.
7. the combining method of the adhesion promoter of nylon according to claim 6 and glass mixture material, is characterized in that, described silane coupling agent is KH550.
8. a bonded products for the adhesion promoter of nylon and glass mixture material, is characterized in that, its product produced for combining method process as claimed in claim 6.
CN201210361705.7A 2012-09-25 2012-09-25 The adhesion promoter of nylon and glass mixture material and combining method and product Active CN103666265B (en)

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CN116462963B (en) * 2023-03-31 2024-05-10 江苏金发科技新材料有限公司 Halogen-free flame-retardant reinforced nylon composition and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1249320A (en) * 1998-09-08 2000-04-05 Ck韦特科公司 Use of emulsified silane coupling agent as priming paint to enhance adhesion of sealing agent adhesive and paint
US20060124225A1 (en) * 2004-12-15 2006-06-15 Ziyan Wu System for bonding glass into a structure
CN1950458A (en) * 2004-05-06 2007-04-18 电化学工业有限公司(国际) Moisture cross-linking composition containing alkoxysilyl functional particles
CN101563412A (en) * 2006-12-19 2009-10-21 陶氏环球技术公司 Adhesion promotion additives and methods for improving coating compositions
CN102482514A (en) * 2009-08-31 2012-05-30 比克化学股份有限公司 Adhesion promoter for coatings on surfaces of different substrates

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1249320A (en) * 1998-09-08 2000-04-05 Ck韦特科公司 Use of emulsified silane coupling agent as priming paint to enhance adhesion of sealing agent adhesive and paint
CN1950458A (en) * 2004-05-06 2007-04-18 电化学工业有限公司(国际) Moisture cross-linking composition containing alkoxysilyl functional particles
US20060124225A1 (en) * 2004-12-15 2006-06-15 Ziyan Wu System for bonding glass into a structure
CN101563412A (en) * 2006-12-19 2009-10-21 陶氏环球技术公司 Adhesion promotion additives and methods for improving coating compositions
CN102482514A (en) * 2009-08-31 2012-05-30 比克化学股份有限公司 Adhesion promoter for coatings on surfaces of different substrates

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