CN103664127B - Can attenuation and absorption electromagnetic suction ripple jewel and manufacture method - Google Patents
Can attenuation and absorption electromagnetic suction ripple jewel and manufacture method Download PDFInfo
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- CN103664127B CN103664127B CN201210325233.XA CN201210325233A CN103664127B CN 103664127 B CN103664127 B CN 103664127B CN 201210325233 A CN201210325233 A CN 201210325233A CN 103664127 B CN103664127 B CN 103664127B
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- 239000010437 gem Substances 0.000 title claims abstract description 60
- 229910001751 gemstone Inorganic materials 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000010521 absorption reaction Methods 0.000 title abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 56
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 19
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims abstract description 18
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 11
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 10
- 239000010955 niobium Substances 0.000 claims abstract description 10
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 10
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims abstract description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- 229960004643 cupric oxide Drugs 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 239000010432 diamond Substances 0.000 claims description 24
- 229910003460 diamond Inorganic materials 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000011236 particulate material Substances 0.000 claims description 11
- 239000010977 jade Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
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- 239000004576 sand Substances 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 9
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- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 6
- 230000003179 granulation Effects 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 239000011049 pearl Substances 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- -1 masonry Chemical compound 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000004223 radioprotective effect Effects 0.000 abstract description 3
- 230000006978 adaptation Effects 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 description 14
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 8
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- 238000010298 pulverizing process Methods 0.000 description 4
- 239000011592 zinc chloride Substances 0.000 description 4
- 235000005074 zinc chloride Nutrition 0.000 description 4
- 241001280173 Crassula muscosa Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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Abstract
The present invention relates to a kind of can attenuation and absorption electromagnetic suction ripple jewel and manufacture method, this suction ripple jewel comprises following component and proportioning: the cobalt sesquioxide of the bismuthous oxide bismuth trioxide of the zinc oxide of the ferric oxide of 60 ~ 70 weight parts, the nickel protoxide of 5 ~ 15 weight parts, 16 ~ 24 weight parts, the cupric oxide of 3 ~ 6.8 weight parts, 0.1 ~ 0.5 weight part, the Vanadium Pentoxide in FLAKES of 0.1 ~ 0.3 weight part, the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and 0.1 ~ 0.5 weight part.This suction ripple jewel is wide to 30MHz ~ 3GHz(two ten octaves) hertzian wave in range of frequency has stronger decay receptivity, its scope is at-5 ~-18dB, can process separately and independently make product, also can coordinate with other materials, be embedded in the surface of daily necessities, artwork, artwork, wrist-watch, belt etc., or make exquisite jewellery, both can be used for body local radioprotective, also the life that can be people increases aesthetic feeling, is the perfect adaptation of modern science and technology and art.
Description
Technical field
Originally the present invention relates to and inhale ripple jewel, more particularly, relate to a kind of energy attenuation and absorption electromagnetic suction ripple jewel and manufacture method.
Background technology
Along with the development of science and technology, the progress of society, all there is electromagnetic radiation pollution in electric equipment products and the equipment of all daily family expenses, office, the pollution that these electromagnetic radiation produce live and work environment mainly within 30MHz ~ 3GHz, to human body generation potential hazard.But in the market there are no both may be used for human body radiation protection, can make exquisite jewellery again, the life for people increases the articles for use of aesthetic feeling.
Summary of the invention
The technical problem to be solved in the present invention is, for the above-mentioned defect of prior art, provides a kind of energy attenuation and absorption electromagnetic suction ripple jewel and manufacture method.
The technical solution adopted for the present invention to solve the technical problems is: structure is a kind of inhales ripple diamond material, and it comprises following component and proportioning: the cobalt sesquioxide of the bismuthous oxide bismuth trioxide of the zinc oxide of the ferric oxide of 60 ~ 70 weight parts, the nickel protoxide of 5 ~ 15 weight parts, 16 ~ 24 weight parts, the cupric oxide of 3 ~ 6.8 weight parts, 0.1 ~ 0.5 weight part, the Vanadium Pentoxide in FLAKES of 0.1 ~ 0.3 weight part, the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and 0.1 ~ 0.5 weight part.
According to another aspect of the present invention, provide a kind of manufacture method of inhaling ripple diamond material, it comprises the following steps:
A1: by the ferric oxide of 60 ~ 70 weight parts, the nickel protoxide of 5 ~ 15 weight parts, the zinc oxide of 16 ~ 24 weight parts, the cupric oxide of 3 ~ 6.8 weight parts, the bismuthous oxide bismuth trioxide of 0.1 ~ 0.5 weight part, the Vanadium Pentoxide in FLAKES of 0.1 ~ 0.3 weight part, the polyvinyl alcohol of the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and the cobalt sesquioxide of 0.1 ~ 0.5 weight part concentration added primarily of 1 weight part to be 9% model be 24-28, the subsidiary material that the dispersant A-15 of 0.8 weight part and the defoamer of 0.005 weight part are formed are to obtain mixing material,
A2: by grinding, described mixing material is carried out Homogeneous phase mixing in sand mill, wherein, the weight ratio of mixing material and abrading-ball and water is 1 ︰ 8 ~ 10 ︰ 1 ~ 1.5;
A3: the mixing material after mixing is carried out spraying dry;
A4: be under the condition of 800 ~ 930 DEG C in temperature, by the mixing material after spraying dry by rotary kiln pre-burning 30 ~ 45 minutes, to obtain described suction ripple diamond material.
According to a further aspect of the invention, provide a kind of and inhale ripple jewel, its use described in suction ripple diamond material make.
According to a further aspect of the invention, a kind of manufacture method of inhaling ripple jewel is provided, it is characterized in that, comprise the following steps:
B1: described suction ripple diamond material is carried out pulverizing granulation is the particulate material of 0.1 ~ 0.3% to obtain size be 0.1 ~ 0.5mm and water content;
B2: described particulate material is carried out forming processes is 3.2 ~ 3.4 grams/cm to obtain density
3green compact;
B3: be under the condition of 1000 ~ 1180 DEG C in temperature, by described green sintering 4 hours to obtain the suction ripple jewel of predetermined shape and size.
B4: by one or more in the following, precision work is carried out to described suction ripple jewel: the working methods same or analogous with artificial gem-jade such as cutting, engraving, boring, grinding and buffing.
In method of the present invention, be many cut surfaces or arc surface via accurately machined suction ripple jewel profile and its outward appearance is sparkling and crystal-clear smooth shiny black or color bright.
In method of the present invention, described step B1 comprises the following steps:
B11: ground by described suction ripple diamond material, to obtain the pulverised material that particle diameter is 0.7 ~ 0.8 μm;
B12: be the ratio of 1 ~ 1.2% in solid content; the polyvinyl alcohol of the concentration adding 1 weight part in pulverised material to be 9% model be 24-28; carry out granulation by sponging granulator, to obtain size be 0.1 ~ 0.5mm and water content be 0.1 ~ 0.3% described particulate material.
In method of the present invention, in described step B11, ground by sand mill or vibromill, wherein, the weight ratio of described suction ripple diamond material and water is 1 ︰ 0.5 ~ 0.7.
In method of the present invention, in described step B2, described particulate material is loaded in blank mould, and uses powder shaping press to make described green compact.
In method of the present invention, in described step B3, in tunnel furnace, described green compact are sintered.
Implement energy attenuation and absorption electromagnetic suction ripple jewel of the present invention and manufacture method, there is following beneficial effect: the hertzian wave of this suction ripple jewel to 30MHz ~ 3GHz frequency range has good decay, receptivity, and its scope is at-5 ~-18dB.In addition, also have the spinel microcosmic crystal phase structure similar to natural gemstone, hardness 6 ~ 8.5 grades, density is up to 5.8g/cm
3, compact structure, matter are hard, and outward appearance is sparkling and crystal-clear shiny black, are smooth to the touch salubrious; Nontoxic, wear-resisting, anticorrosive, be suitable for the working method of gem-jade, can process separately or coordinate with other materials, be embedded among daily necessities or make exquisite jewellery, both can be used for body local radioprotective, the life that also can be people increases aesthetic feeling, is the perfect adaptation of modern science and technology and art.
Accompanying drawing explanation
Below in conjunction with drawings and Examples, the invention will be further described, in accompanying drawing:
Fig. 1 is the structural representation of the decoration with suction ripple jewel of first embodiment of the invention;
Fig. 2 is the structural representation of the decoration with suction ripple jewel of second embodiment of the invention;
Fig. 3 is the structural representation of the decoration with suction ripple jewel of third embodiment of the invention;
Fig. 4 is the structural representation of the decoration with suction ripple jewel of fourth embodiment of the invention.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Suction ripple diamond material of the present invention mainly comprises following component and proportioning: the cobalt sesquioxide of the bismuthous oxide bismuth trioxide of the zinc oxide of the ferric oxide of 60 ~ 70 weight parts, the nickel protoxide of 5 ~ 15 weight parts, 16 ~ 24 weight parts, the cupric oxide of 3 ~ 6.8 weight parts, 0.1 ~ 0.5 weight part, the Vanadium Pentoxide in FLAKES of 0.1 ~ 0.3 weight part, the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and 0.1 ~ 0.5 weight part.Understandable, in concrete use procedure, also can add the oxide compound of other trace element according to demand flexibly.In addition, suction ripple jewel is made by above-mentioned suction ripple diamond material.
Wherein, ferric oxide adopts RUTHNER technique to make, and it contains the chlorine root of 0.1 ~ 0.3%.This material, when pre-sinter process, has Micro Amounts of Chlorine root not volatilize, and generate zinc chloride, and the volatilization temperature of zinc chloride is at 500 DEG C ~ 750 DEG C with the zinc oxide in formula.When this sintering temperature section, zinc chloride volatilization forms smog, through special process process, makes part be attached to the effect that blank surface plays fusing assistant, makes hard mass extexine (0.1 ~ 0.3mm) crystal grain increase 20 ~ 25 μm rapidly.Zinc chloride gas cannot enter blank inside.Micro-Vanadium Pentoxide in FLAKES in blank, Niobium Pentxoxide still play the effect suppressing crystal grain to increase, and bismuthous oxide bismuth trioxide plays reduction sintering temperature and grain refining, acts on uniformly, and the grain-size of blank inside is 3 ~ 5 μm.Cobalt sesquioxide plays and regulates the coercive force of material and the effect of magnetocrystalline anisotropy, makes material have larger decay absorptive character and wider decay to absorb frequency range to hertzian wave.
The surface microstructure of this suction ripple jewel is large, is conducive to appearance after sanding and polishing, obtains the effect of single crystal, shiny black reflective sparkling and crystal-clear, has special aesthetic feeling; And internal grain refinement, evenly, fine and close, void content is little, makes suction ripple jewel have good physical property: the highest 6g/cm nearly of density
3, mohs hardness reaches as high as 8.5 grades, and physical strength can be improved greatly, is conducive to precision work.
The manufacture method of this suction ripple diamond material, mainly comprises the following steps:
A1: the cobalt sesquioxide of the Vanadium Pentoxide in FLAKES of the bismuthous oxide bismuth trioxide of the cupric oxide of the zinc oxide of the nickel protoxide of the ferric oxide of 60 ~ 70 weight parts, 5 ~ 15 weight parts, 16 ~ 24 weight parts, 3 ~ 6.8 weight parts, 0.1 ~ 0.5 weight part, 0.1 ~ 0.3 weight part, the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and 0.1 ~ 0.5 weight part is added main 1 weight part concentration is 9% model be the polyvinyl alcohol of 24-28,0.8 weight part dispersant A-15(preferred, adopt n-Octanol) and the subsidiary material of defoamer formation of 0.005 weight part to obtain mixing material;
A2: by grinding, described mixing material is carried out Homogeneous phase mixing in sand mill, wherein, the weight ratio of mixing material and abrading-ball and water is 1 ︰ 8 ~ 10 ︰ 1 ~ 1.5, and milling time is 45-55 minute.
A3: the mixing material after mixing is carried out spraying dry, drying plant is spray-drier, is formed and have the powder of certain fluidity so that pre-burning after dry.
A4: be under the condition of 800 ~ 930 DEG C in temperature, by the mixing material after spraying dry by rotary kiln pre-burning 30 ~ 45 minutes, to obtain inhaling ripple diamond material.
After obtaining this suction ripple diamond material, this material can be used to carry out inhaling the making of ripple jewel, and its making method comprises the following steps:
B1: suction ripple diamond material is carried out pulverizing granulation is the particulate material of 0.1 ~ 0.3% to obtain size be 0.1 ~ 0.5mm and water content; Can be B11 particularly: suction ripple diamond material is ground by sand mill or vibromill, to obtain the pulverised material that particle diameter is 0.7 ~ 0.8 μm; Wherein, the weight ratio of described suction ripple diamond material and water is 1 ︰ 0.5 ~ 0.7.Then B12: be the ratio of 1 ~ 1.2% in solid content; the polyvinyl alcohol of the concentration adding 1 weight part in pulverised material to be 9% model be 24-28; granulation is carried out by sponging granulator; to obtain the particulate material with predetermined particle diameter magnitude range (preferred, size scope is 0.1 ~ 0.5mm) and predetermined moisture content scope.
B2: particulate material is carried out forming processes is 3.2 ~ 3.4 grams/cm to obtain density
3green compact, particularly, can be that this particulate material is loaded in blank mould, and use powder shaping press to make green compact.
B3: be under the condition of 1000 ~ 1180 DEG C in temperature, in tunnel furnace by green sintering 4 hours to obtain the suction ripple jewel of predetermined shape and size.In addition, by the thickness of the Product processing after sintering to standard, with microstrip methods test on vector grid analyser, check it to electromagnetic decay receptivity.
B4: by one or more in the following, precision work is carried out to described hard mass: the working methods same or analogous with artificial gem-jade such as cutting, engraving, boring, grinding and buffing.Profile via accurately machined suction ripple jewel is many cut surfaces or arc surface and its outward appearance is sparkling and crystal-clear smooth shiny black or color bright.In addition, can with the material-mix such as gold, diamond, silver, jade, jewel, crystal, pearl, stainless steel, titanium alloy, pottery, be embedded on daily necessities or make exquisite jewellery, both having can be used for the preventing local radiation of human body, also can be daily life and increase aesthetic feeling.
In a preferred embodiment, by the ferric oxide of 65 weight parts, the nickel protoxide of 13 weight parts, the zinc oxide of 19 weight parts, the cupric oxide of 3 weight parts, by the bismuthous oxide bismuth trioxide of 0.25 weight part, the Vanadium Pentoxide in FLAKES of 0.15 weight part, the Niobium Pentxoxide of 0.1 weight part, the cobalt sesquioxide of 0.25 weight part, adding primarily of model is 24-28, and concentration is the polyvinyl alcohol of 9%, and model is in the subsidiary material of the dispersion agent of 0.8 weight part of A-15 and the defoamer formation of 0.005 weight part.Above-mentioned raw materials is put into sand mill mix, the weight ratio of mixed slurry and abrading-ball and water is 1 ︰ 10 ︰ 1.5, mixing time 50 minutes.
With spray-drier, the slurry mixed is carried out drying treatment, undertaken by the process specifications of spray-drier used.Weight adjustable spraying Drying Technology Parameter according to compound: inlet temperature 450 DEG C ~ 500 DEG C, temperature out 90 DEG C ~ 120 DEG C, the slurry mixed after sand milling is squeezed into spraying gun through high-pressure pump, be atomized by force, be atomized in high temperature 500 DEG C of air, formed after dry and there is the powder of certain fluidity so that pre-burning.
Dried powder is put into external-heating rotary kiln and carries out pre-burning, undertaken by the operation instructions of rotary kiln, temperature 850 DEG C, according to the weight of powder after drying, regulate the rotating speed of rotary kiln cylinder: 3 ~ 6 revs/min, regulate the inclination angle of cylinder: 7 ~ 9 °, burn-in time 35 minutes.
Material after pre-burning is put into sand mill pulverize, material is 1 ︰ 0.65 with the ratio of water, add the Vanadium Pentoxide in FLAKES of 0.15 weight part, the Niobium Pentxoxide of 0.1 weight part, the dispersion agent of 0.8 weight part, the defoamer of 0.005 weight part, after pulverizing, particle diameter is 0.75 μm, then adding model is 24-28, and concentration is the polyvinyl alcohol of 1 weight part of 9%, high-speed stirring 10 minutes.
Material after pulverizing is put into sponging granulator granulation, is undertaken by the process specifications of sponging granulator.According to weight of material, the parameters such as suitable unit of adjustment time output, spray angle, slip spraying pressure, loose density and powder moisture content.Final requirement is loose density 2.3g/cm
3, moisture content 0.3%, the particle of particle diameter 0.1 ~ 0.4mm accounts for more than 95%.
Made pellet is loaded and inhales ripple jewel blank mould, use powder shaping press to make green compact and prepare sintering.Green density 3.2+0.2 gram/cm
3.
Blank sinters in tunnel kiln, temperature 1180 DEG C, is incubated 4 hours, finally makes the suction ripple jewel of regulation shape and size.
By the Product processing after sintering to the thickness being applicable to testing tool requirement, with microstrip methods test on vector network analyzer, check it to electromagnetic decay receptivity.Require there is good decay receptivity to the hertzian wave of 30MHz ~ 3GHz frequency range, its scope is at-5 ~-18dB.Table 1 is that as can be seen from Table 1, its maximum attenuation absorption loss is all in-5 ~-18dB scope according to the suction ripple jewel of the embodiment of the present invention to the electromagnetic maximum attenuation absorption loss of 30MHz ~ 3GHz frequency range.In addition, table 2 is test values of the mohs hardness of the suction ripple jewel of the foundation embodiment of the present invention, and as can be seen from the data of table 2, the mohs hardness of this suction ripple jewel is suitable with quartz, even exceedes the hardness (such as sample 1) of quartz.
Table 1
Table 2
With the working method of artificial gem-jade and tool equipment, precision work is carried out to suction ripple jewel, namely cut, carve, hole, polish, sandblasting or polishing, form the jewel profile of many cut surfaces or arc surface and sparkling and crystal-clear smooth shiny black outward appearance, separately or with the material-mix such as gold, diamond, silver, jade, jewel, crystal, pearl, stainless steel, titanium alloy, pottery, be embedded on daily necessities or make exquisite jewellery.
This suction ripple jewel and natural gemstone have similar spinel microcosmic crystal phase structure.Modern various electric equipment products enters rapidly individual and household consumption field, and the electromagnetic radiation of these products has even arrived microwave frequency band from low to high, and people day by day worry that potential Electromagnetic Radiation on Environment and human body produce and pollute and harm.Suction ripple jewel of the present invention, can process separately and independently make product, or with the material-mix such as gold, diamond, silver, jade, jewel, crystal, pearl, stainless steel, titanium alloy, pottery, be embedded in the surface of daily necessities, artwork, artwork, wrist-watch, belt etc., or make exquisite jewellery, both can be used for body local radioprotective, and also can be daily life and increase aesthetic feeling.
As Fig. 1 ~ 4 are depicted as the present invention with the decoration inhaling ripple jewel, it mainly comprises decoration main body, this decoration main body is as main load bearing component, the shape of self and the change of structure can be carried out, and for installing other decorative element, decoration main body is removably provided with and inhales ripple jewel, thus by this suction ripple jewel and decoration main body combination structurally and assembled, make this decoration not only have the function of decorative appearance, the electromagnetic radiation that various electric equipment products work produces can also be absorbed.
In the first embodiment as shown in Figure 1, this decoration main body is watch chain; This watch chain comprises limit, left side contiguous block assembly 13 and right edge contiguous block assembly 12, and the differentiation in this embodiment for left side and right side carries out dividing with the visual angle of Fig. 1; Limit, left side contiguous block assembly 13 and right edge contiguous block assembly 12 corresponding are respectively arranged with transverse concave groove, the left and right sides of inhaling ripple jewel 11 are respectively arranged with the projection with this groove match; Inhale ripple jewel 11 by protruding and groove, with limit, left side contiguous block assembly 13 and the clamping of right edge contiguous block assembly 12 phase.In a preferred embodiment, limit, left side contiguous block assembly 13 comprises the multiple left sides contiguous block be connected in series successively, and right edge contiguous block assembly 12 comprises the multiple right edge contiguous blocks be connected in series successively; Can be connected in series at least one inhale ripple jewel 11 in this watch chain.In addition, in this embodiment, this suction ripple jewel is cuboid structure.
In the second embodiment as shown in Figure 2, this decoration main body is bangle, and this bangle comprises chain rope and is serially connected in the chain pearl 22 on chain rope; Inhale ripple jewel 21 to be serially connected on chain rope.In this embodiment, inhale ripple jewel 21 and be configured to ellipsoidal configuration, and on chain rope, be serially connected with multiple suction ripple jewel 21.
In the 3rd embodiment as shown in Figure 3, this decoration main body is necklace, and this necklace comprises chaining 32, and this suction ripple jewel 31 is serially connected on this chaining 32 using as pendant.In this embodiment, this suction ripple jewel 31 is configured to cuboid structure and is provided with three manholes on suction ripple jewel.In the 4th embodiment as shown in Figure 4, this decoration main body is also necklace, and this necklace comprises chaining 42, and this suction ripple jewel 41 is serially connected on this chaining 42 using as pendant.In this embodiment, this suction ripple jewel 41 is configured to sub-elliptical body structure, and at its surface engraving grid decorative pattern.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (6)
1. inhale ripple diamond material for one kind, it is characterized in that, comprise following component and proportioning: 60 ~ 70 weight parts and the cobalt sesquioxide of the bismuthous oxide bismuth trioxide of the cupric oxide of the zinc oxide of nickel protoxide containing the ferric oxide of 0.1 ~ 0.3% chlorine root, 5 ~ 15 weight parts, 16 ~ 24 weight parts, 3 ~ 6.8 weight parts, 0.1 ~ 0.5 weight part, the Vanadium Pentoxide in FLAKES of 0.1 ~ 0.3 weight part, the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and 0.1 ~ 0.5 weight part;
The manufacture method of described suction ripple diamond material comprises the following steps:
A1: the ferric oxide by 60 ~ 70 weight parts and containing 0.1 ~ 0.3% chlorine root, the nickel protoxide of 5 ~ 15 weight parts, the zinc oxide of 16 ~ 24 weight parts, the cupric oxide of 3 ~ 6.8 weight parts, the bismuthous oxide bismuth trioxide of 0.1 ~ 0.5 weight part, the Vanadium Pentoxide in FLAKES of 0.1 ~ 0.3 weight part, the polyvinyl alcohol of the Niobium Pentxoxide of 0.1 ~ 0.2 weight part and the cobalt sesquioxide of 0.1 ~ 0.5 weight part concentration added primarily of 1 weight part to be 9% model be 24-28, the subsidiary material that the dispersant A-15 of 0.8 weight part and the defoamer of 0.005 weight part are formed are to obtain mixing material,
A2: by grinding, described mixing material is carried out Homogeneous phase mixing in sand mill, wherein, the weight ratio of mixing material and abrading-ball and water is 1 ︰ 8 ~ 10 ︰ 1 ~ 1.5;
A3: the mixing material after mixing is carried out spraying dry, is formed after dry and has the powder of certain fluidity so that pre-burning;
A4: be under the condition of 800 ~ 930 DEG C in temperature, by the mixing material after spraying dry by rotary kiln pre-burning 30 ~ 45 minutes, to obtain described suction ripple diamond material.
2. inhale a ripple jewel, it is characterized in that, use ripple diamond material of inhaling as claimed in claim 1 to make.
3. a manufacture method of inhaling ripple jewel as claimed in claim 2, is characterized in that, comprise the following steps:
B1: described suction ripple diamond material is ground by sand mill or vibromill, wherein, the weight ratio of described suction ripple diamond material and water is 1 ︰ 0.5 ~ 0.7, to obtain the pulverised material that particle diameter is 0.7 ~ 0.8 μm, be the ratio of 1 ~ 1.2% in solid content, the polyvinyl alcohol of the concentration adding 1 weight part in pulverised material to be 9% model be 24-28, carries out granulation by sponging granulator, and to obtain size be 0.28 ~ 0.5mm and water content is the particulate material of 0.1 ~ 0.3%;
B2: described particulate material is carried out forming processes is 3.2 ~ 3.4 grams/cm to obtain density
3green compact;
B3: be under the condition of 1000 ~ 1180 DEG C in temperature, by described green sintering 4 hours to obtain the suction ripple jewel of predetermined shape and size, by the Product processing after sintering to the thickness of standard, vector grid analyser tests it to electromagnetic decay receptivity with microstrip line;
B4: by one or more in the following, precision work is carried out to described suction ripple jewel: the working method identical with artificial gem-jade, or coordinate with gold, masonry, silver, jade, jewel, crystal, pearl, stainless steel, titanium alloy, stupalith, be embedded on daily necessities or make exquisite jewellery, the working method of described artificial gem-jade comprises cutting, engraving, boring, grinding and buffing.
4. method according to claim 3, is characterized in that, is many cut surfaces or arc surface and its outward appearance is sparkling and crystal-clear smooth shiny black or color bright via accurately machined suction ripple jewel profile.
5. method according to claim 3, is characterized in that, in described step B2, is loaded in blank mould by described particulate material, and uses powder shaping press to make described green compact.
6. method according to claim 3, is characterized in that, in described step B3, sinters in tunnel furnace to described green compact.
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