CN103651544A - Acaricidal composition of profenofos and etoxazole and formula instance - Google Patents
Acaricidal composition of profenofos and etoxazole and formula instance Download PDFInfo
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- CN103651544A CN103651544A CN201210346778.9A CN201210346778A CN103651544A CN 103651544 A CN103651544 A CN 103651544A CN 201210346778 A CN201210346778 A CN 201210346778A CN 103651544 A CN103651544 A CN 103651544A
- Authority
- CN
- China
- Prior art keywords
- profenofos
- mite
- mite azoles
- mites
- etoxazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical group CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000005897 Etoxazole Substances 0.000 title abstract description 4
- 230000000895 acaricidal effect Effects 0.000 title abstract description 4
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 title abstract description 4
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 5
- 235000013311 vegetables Nutrition 0.000 claims abstract description 4
- 150000003851 azoles Chemical class 0.000 claims description 33
- 239000000642 acaricide Substances 0.000 claims description 18
- 239000000375 suspending agent Substances 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- 235000016623 Fragaria vesca Nutrition 0.000 claims 1
- 240000009088 Fragaria x ananassa Species 0.000 claims 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 claims 1
- 241000488581 Panonychus citri Species 0.000 claims 1
- 201000010099 disease Diseases 0.000 claims 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims 1
- 241000238876 Acari Species 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 230000002045 lasting effect Effects 0.000 abstract description 4
- 241000675108 Citrus tangerina Species 0.000 abstract description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 241001454295 Tetranychidae Species 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 2
- 241001122767 Theaceae Species 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 235000013601 eggs Nutrition 0.000 abstract 1
- 230000002688 persistence Effects 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 210000004681 ovum Anatomy 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- 241000779819 Syncarpia glomulifera Species 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000001739 pinus spp. Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229940036248 turpentine Drugs 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- VUPXKQHLZATXTR-UHFFFAOYSA-N 2,4-diphenyl-1,3-oxazole Chemical class C=1OC(C=2C=CC=CC=2)=NC=1C1=CC=CC=C1 VUPXKQHLZATXTR-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- -1 bromo-2-chlorphenyl Chemical group 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of a pesticide, and particularly relates to an acaricidal composition prepared from profenofos and etoxazole by compounding, and an application thereof in the aspects of prevention and treatment of crop mites. The mass ratio of the etoxazole to the profenofos in the composition disclosed by the invention is 100:1 to 1:100. The acaricidal composition plays a synergic effect through compounding, is wide in application range, and friendly to environment, has fast-acting property and persistence, can be used for preventing and treating a plurality of pest mites such as spider mites on a plurality of crops, such as fruit trees, vegetables, tea leaves, as well as spider mites and rust mites on oranges and tangerines, and has an excellent effect on eggs of mites, and the lasting period can be up to 30 days.
Description
Technical field
The invention belongs to the technical field of agricultural chemicals, be specifically related to a kind ofly contain Profenofos and second mite azoles carries out composite miticide composition, and the application aspect control crops evil mite.
Background technology
The bromo-2-chlorphenyl of Profenofos (Profenofos) chemical name O-ethyl-O-(4-)-S-propyl dithiocarbamate phosphate, belongs to organophosphorus insecticide.Structural formula is as follows:
Former medicine outward appearance is light yellow liquid, tool is garlicky, 100 ℃/1.80Pa of boiling point, vapour pressure 1.24 * 10^ (4) Pa (25 ℃) density 1.455 (20 ℃), KowlogP=4.44, solvability water 28mg/L (25 ℃), with most immiscible organic solvent, more stable under neutral and micro-sour condition, unstable in alkaline environment, Profenofos belongs to the asymmetric high osmosis type broad-spectrum organophosphorous pesticide of ternary, have and tag and stomach toxicity, stifling, straight osmosis, can directly permeate in blade and polypide, thoroughly kill hide in blade (back side), in paddy field, fruit neutralization pierces stalk.Profenofos is the thiophosphate insecticides that a kind of molecule contains positive rosickyite base, and its insecticidal spectrum is wide, easily biological-degradable, and antagonism insect shows high biologically active.
Second mite azoles (Etoxazole) claims to come again good fortune Lu, chemical name (the RS)-5-tert-butyl group-2-[2-(2,6-difluorophenyl)-4,5-dihydro-1.3-uh azoles-4-yl] ethoxybenzene.Structural formula is as follows:
Former medicine outward appearance is white tasteless crystal powder, molten some 101.5-102.5 ℃, proportion 1.2389kg/m3, vapour pressure (25 ℃) 7.0 * 10-6Pa, solvability (g/L, 20 ℃) water 7.04 * 10-5, acetone 309, ethyl acetate 249, normal heptane 18.7, methyl alcohol 104, dimethylbenzene 252.Belonging to 2,4-diphenyl-oxazole derivatives quasi-compound, is a kind of selectivity miticide.Be mainly the process of casting off a skin that suppresses mite class, thereby mite is had to excellent tagging property from ovum, larva to pupa different phase.Its mode of action comprises inhibition cast off a skin normally process and ovicidal activity, although can not directly kill into mite in addition, female one-tenth mite is had to good sterile effect.
Above-mentioned two kinds of medicaments are used separately due to long-term, easily cause the drug-fast generation of mite, cause drug effect obviously to decline, thereby cause dosage greatly to rise, the sprinkling cycle shortens, and result of use is poor, increased cost, the use of a large amount of agricultural chemicals, makes mite resistance more serious, also environment is affected, the medicament residue of agricultural product also increases, have influence on health and the normal existence of the mankind, animal etc., Profenofos and second mite azoles are carried out to composite use control crops acarid evil, there is not yet report both at home and abroad.
Summary of the invention
The object of the invention is to provide a kind of for the problems referred to above and carry out composite miticide composition and application thereof by Profenofos and second mite azoles, by composite, play synergistic effect, applied widely, tool quick-acting and lasting effect, environmentally friendly, can be used to prevent and treat tetranychid and the multiple harmful mite such as the tetranychid on oranges and tangerines, rust mite in the various crop such as fruit tree, vegetables and tealeaves, and mite ovum is also had to tall and erect effect, and the lasting period reaches 30 days.
In the present invention, second mite azoles, the weight of Profenofos, the weight of active ingredient etc. mentioned, all refer to the weight after folding hundred, i.e. the weight of active principle.
Bactericidal composition containing second mite azoles and Profenofos of the present invention, its active ingredient consists of second mite azoles and Profenofos, and the weight ratio of described Profenofos and second mite azoles is, Profenofos: second mite azoles=100:1～1:100.
As preferably, the weight ratio of described Profenofos and second mite azoles is, second mite azoles: Profenofos=1:2～1:10.
Wherein, in said composition, the weight percentage of active ingredient is 1%～90%.
Said composition formulation comprises wetting powder, suspension emulsion, missible oil, oil suspending agent, adds auxiliary agent and excipient, and the production technology of all knowing according to those skilled in the art can be made into required formulation.
This miticide composition can be used to prevent and treat the multiple harmful mites such as tetranychid in the various crop such as fruit tree, vegetables and tealeaves and the tetranychid on oranges and tangerines, rust mite, and mite ovum is also had to tall and erect effect, and the lasting period reaches 30 days.
Beneficial effect of the present invention is: in miticide development and application process, delaying drug resistance or cross resistance are the key factors that extends the product shelf life-span, rationally use miticide, control access times and dosage, the miticide of different mechanism of action is used alternatingly and just seems particularly important.
embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited thereto, and the formulation preparation method in embodiment is conventional method.
Embodiment 1:22.5% Profenofos second mite azoles suspension emulsion, comprises following component by weight:
Former medicine: Profenofos 15%
Former medicine: second mite azoles 7.5%
Stabilizing agent: tributyl phosphate 3%
Emulsifier: ethylene oxide propylene oxide block copolymer 4%
Dispersant: triphen ethyl phenol polyoxyethylene ether phosphate 3%
Suspending agent: xanthans 0.2%
Preservative: Kathon CG 0.2%
Defoamer: organosilan 0.3%
Antifreezing agent: ethylene glycol 4%
Deionized water surplus
The former medicine of second mite azoles, dispersant, wetting agent, part defoamer, deionized water are ground to D90<5 μ m after emulsify at a high speed and are made into suspension; Add emulsifier to be made into oil phase the former medicine of Profenofos, stabilizing agent; Antifreezing agent, defoamer and residue water are mixed, obtain homogeneous water; Second mite azoles suspension and water are slowly added in Profenofos oil phase, clip to target grain size D90<5 μ m, add suspending agent xanthans, preservative Kathon CG, shear-mixed is even, obtains Profenofos second mite azoles suspension emulsion.
The projecting point of this example: suppress the difficult problem that Profenofos is met water decomposition, make the water base chemical preparation of Profenofos become possibility.And this example not containing organic solvent be the formulation of real environment-friendly type, meet national environmental requirement.
Embodiment 2:20% Profenofos second mite azoles wetting powder, comprises following component by weight:
Former medicine: Profenofos 15%
Former medicine: second mite azoles 5%
Adsorbent: white carbon 10%
Dispersant: calcium lignosulfonate 5%
Dispersant: naphthalene sulfonate salt 4%
Wetting agent: lauryl sodium sulfate 0.2%
Filler: anhydrous sodium sulfate 10%
Filler: kaolin surplus
First Profenofos is adsorbed completely with white carbon, then in the above-mentioned ratio in formula, mix, through air-flow crushing, to particle diameter <30 μ m, obtain Profenofos second mite azoles wetting powder.
Embodiment 3:25% Profenofos second mite azoles oil suspending agent, comprises following component by weight:
Former medicine: Profenofos 20%
Former medicine: second mite azoles 5%
Dispersant: ethylene oxide propylene oxide block copolymer 2%
Emulsifier: castor oil polyoxyethylene ether 2%
Emulsifier: Geronol VO/01 15%
Suspending agent: organobentonite 4%
Preservative: Kathon CG 1%
Corn oil surplus
In the above-mentioned ratio in formula, mix, after dispersion machine is dispersed, by sand mill, be ground to particle diameter D90<3 μ m, obtain Profenofos second mite azoles oil suspending agent.
The projecting point of this example: use corn oil as dispersion medium, environmental protection, economy, be conveniently easy to get, meet national requirements for environmental protection.
Embodiment 4:50% Profenofos second mite azoles missible oil, comprises following component by weight:
Former medicine: Profenofos 40%
Former medicine: second mite azoles 10%
Emulsifier: castor oil polyoxyethylene ether 4%
Emulsifier: calcium dodecyl benzene sulfonate 4%
Emulsifier: fatty alcohol-polyoxyethylene ether 2%
Solvent: turpentine-based vegetable oil ND100 surplus
After the former medicinal solvent of second mite azoles is dissolved completely, add Profenofos, emulsifier, stir and make Profenofos second mite azoles missible oil.
The projecting point of this example: do not use three benzene kind solvents, environment for use close friend's turpentine-based vegetable oil, meets national environmental protection, Low-alcohol requirement.
The trend of current Agrochemicals is efficient, safe and environmentally friendly, and some high poison or environmentally safe influential agricultural chemicals are progressively eliminated.In miticide development and application process, delaying drug resistance or cross resistance are the key factors that extends the product shelf life-span, rationally use miticide, control access times and dosage, and the miticide of different mechanism of action is used alternatingly and just seems particularly important.Acaricide composition of the present invention, to preventing and treating the upper evil of agricultural mite, promotes that agricultural sustainable development plays an important role.
Claims (6)
1. containing a miticide composition for Profenofos and second mite azoles, its active ingredient consists of Profenofos and second mite azoles, and the weight ratio of described Profenofos and second mite azoles is, second mite azoles: Profenofos=100:1～1:100.
2. miticide composition according to claim 1, is characterized in that, the weight ratio of described Profenofos and second mite azoles is, second mite azoles: Profenofos=1:2～1:10.
3. miticide composition according to claim 1 and 2, is characterized in that, the weight percentage of described active ingredient is 1%～90%.
4. miticide composition according to claim 1, is characterized in that, said composition formulation comprises missible oil, oil suspending agent, suspension emulsion, wetting powder.
5. miticide composition as claimed in claim 1, for preventing and treating the tetranychid on crop, Panonychus citri disease.
6. miticide composition as claimed in claim 1, for preventing and treating fruit tree, vegetables, tealeaves, cotton, strawberry, the harmful mite of ornamental plant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210346778.9A CN103651544A (en) | 2012-09-19 | 2012-09-19 | Acaricidal composition of profenofos and etoxazole and formula instance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210346778.9A CN103651544A (en) | 2012-09-19 | 2012-09-19 | Acaricidal composition of profenofos and etoxazole and formula instance |
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| Publication Number | Publication Date |
|---|---|
| CN103651544A true CN103651544A (en) | 2014-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210346778.9A Pending CN103651544A (en) | 2012-09-19 | 2012-09-19 | Acaricidal composition of profenofos and etoxazole and formula instance |
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| CN (1) | CN103651544A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103271078A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-profenofos pesticide composition |
| CN104904743A (en) * | 2014-03-11 | 2015-09-16 | 江苏龙灯化学有限公司 | Insect disinfestation composition |
-
2012
- 2012-09-19 CN CN201210346778.9A patent/CN103651544A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103271078A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-profenofos pesticide composition |
| CN103271078B (en) * | 2013-04-10 | 2017-12-01 | 重庆硕奥科技有限公司 | Etoxazole-profenofospesticide pesticide composition |
| CN104904743A (en) * | 2014-03-11 | 2015-09-16 | 江苏龙灯化学有限公司 | Insect disinfestation composition |
| CN104904743B (en) * | 2014-03-11 | 2018-02-13 | 江苏龙灯化学有限公司 | Pesticidal combination |
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Application publication date: 20140326 |