CN103651519A - Compound pesticide composition containing flonicamid and bifenthrin - Google Patents
Compound pesticide composition containing flonicamid and bifenthrin Download PDFInfo
- Publication number
- CN103651519A CN103651519A CN201310706684.2A CN201310706684A CN103651519A CN 103651519 A CN103651519 A CN 103651519A CN 201310706684 A CN201310706684 A CN 201310706684A CN 103651519 A CN103651519 A CN 103651519A
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- CN
- China
- Prior art keywords
- flonicamid
- biphenthrin
- compound
- agent
- bifenthrin
- Prior art date
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- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000005900 Flonicamid Substances 0.000 title claims abstract description 40
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 239000000575 pesticide Substances 0.000 title abstract description 10
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 239000005874 Bifenthrin Substances 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 244000269722 Thea sinensis Species 0.000 claims abstract description 7
- 241001124076 Aphididae Species 0.000 claims abstract description 6
- 239000004480 active ingredient Substances 0.000 claims abstract description 6
- 235000002597 Solanum melongena Nutrition 0.000 claims abstract description 4
- 244000061458 Solanum melongena Species 0.000 claims abstract description 4
- 240000004160 Capsicum annuum Species 0.000 claims abstract 4
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims abstract 3
- 235000007862 Capsicum baccatum Nutrition 0.000 claims abstract 3
- 239000001728 capsicum frutescens Substances 0.000 claims abstract 3
- 244000105624 Arachis hypogaea Species 0.000 claims abstract 2
- 244000003416 Asparagus officinalis Species 0.000 claims abstract 2
- 235000005340 Asparagus officinalis Nutrition 0.000 claims abstract 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 claims abstract 2
- 240000003259 Brassica oleracea var. botrytis Species 0.000 claims abstract 2
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 claims abstract 2
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 claims abstract 2
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 claims abstract 2
- 235000004936 Bromus mango Nutrition 0.000 claims abstract 2
- 244000241235 Citrullus lanatus Species 0.000 claims abstract 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims abstract 2
- 229920000742 Cotton Polymers 0.000 claims abstract 2
- 244000241257 Cucumis melo Species 0.000 claims abstract 2
- 241000219146 Gossypium Species 0.000 claims abstract 2
- 240000005979 Hordeum vulgare Species 0.000 claims abstract 2
- 235000007340 Hordeum vulgare Nutrition 0.000 claims abstract 2
- 235000003228 Lactuca sativa Nutrition 0.000 claims abstract 2
- 240000008415 Lactuca sativa Species 0.000 claims abstract 2
- 240000000894 Lupinus albus Species 0.000 claims abstract 2
- 235000010649 Lupinus albus Nutrition 0.000 claims abstract 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims abstract 2
- 241000220225 Malus Species 0.000 claims abstract 2
- 235000011430 Malus pumila Nutrition 0.000 claims abstract 2
- 235000015103 Malus silvestris Nutrition 0.000 claims abstract 2
- 235000014826 Mangifera indica Nutrition 0.000 claims abstract 2
- 240000007228 Mangifera indica Species 0.000 claims abstract 2
- 240000005561 Musa balbisiana Species 0.000 claims abstract 2
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims abstract 2
- 244000061176 Nicotiana tabacum Species 0.000 claims abstract 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract 2
- 235000010582 Pisum sativum Nutrition 0.000 claims abstract 2
- 240000004713 Pisum sativum Species 0.000 claims abstract 2
- 240000000111 Saccharum officinarum Species 0.000 claims abstract 2
- 235000007201 Saccharum officinarum Nutrition 0.000 claims abstract 2
- 240000003768 Solanum lycopersicum Species 0.000 claims abstract 2
- 244000061456 Solanum tuberosum Species 0.000 claims abstract 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims abstract 2
- 235000009184 Spondias indica Nutrition 0.000 claims abstract 2
- 235000009470 Theobroma cacao Nutrition 0.000 claims abstract 2
- 244000299461 Theobroma cacao Species 0.000 claims abstract 2
- 235000021307 Triticum Nutrition 0.000 claims abstract 2
- 244000098338 Triticum aestivum Species 0.000 claims abstract 2
- 240000008042 Zea mays Species 0.000 claims abstract 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract 2
- 235000020232 peanut Nutrition 0.000 claims abstract 2
- 235000013616 tea Nutrition 0.000 claims abstract 2
- -1 Biphenthrin compound Chemical class 0.000 claims description 11
- 230000000361 pesticidal effect Effects 0.000 claims description 9
- 239000002917 insecticide Substances 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 5
- 239000004530 micro-emulsion Substances 0.000 claims description 5
- 239000000375 suspending agent Substances 0.000 claims description 4
- 239000008041 oiling agent Substances 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims 2
- LKAPTZKZHMOIRE-KVTDHHQDSA-N (2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)oxolane-2-carbaldehyde Chemical compound OC[C@H]1O[C@H](C=O)[C@@H](O)[C@@H]1O LKAPTZKZHMOIRE-KVTDHHQDSA-N 0.000 claims 1
- 244000291564 Allium cepa Species 0.000 claims 1
- 235000010167 Allium cepa var aggregatum Nutrition 0.000 claims 1
- 235000017060 Arachis glabrata Nutrition 0.000 claims 1
- 235000010777 Arachis hypogaea Nutrition 0.000 claims 1
- 235000018262 Arachis monticola Nutrition 0.000 claims 1
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 claims 1
- 244000068988 Glycine max Species 0.000 claims 1
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 241000220324 Pyrus Species 0.000 claims 1
- 241000219793 Trifolium Species 0.000 claims 1
- 235000009754 Vitis X bourquina Nutrition 0.000 claims 1
- 235000012333 Vitis X labruscana Nutrition 0.000 claims 1
- 240000006365 Vitis vinifera Species 0.000 claims 1
- 235000014787 Vitis vinifera Nutrition 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- LKAPTZKZHMOIRE-UHFFFAOYSA-N chitose Natural products OCC1OC(C=O)C(O)C1O LKAPTZKZHMOIRE-UHFFFAOYSA-N 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 235000021017 pears Nutrition 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 201000010099 disease Diseases 0.000 abstract description 6
- 241000607479 Yersinia pestis Species 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 244000295724 Allium chinense Species 0.000 abstract 2
- 235000016790 Allium chinense Nutrition 0.000 abstract 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 abstract 1
- 240000004658 Medicago sativa Species 0.000 abstract 1
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 abstract 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 abstract 1
- 244000046052 Phaseolus vulgaris Species 0.000 abstract 1
- 235000014443 Pyrus communis Nutrition 0.000 abstract 1
- 240000001987 Pyrus communis Species 0.000 abstract 1
- 241000219094 Vitaceae Species 0.000 abstract 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 abstract 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 230000001276 controlling effect Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 244000013123 dwarf bean Species 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 235000021021 grapes Nutrition 0.000 abstract 1
- 235000021331 green beans Nutrition 0.000 abstract 1
- 235000009973 maize Nutrition 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000003905 agrochemical Substances 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241000578422 Graphosoma lineatum Species 0.000 description 4
- 241001454293 Tetranychus urticae Species 0.000 description 4
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 230000010534 mechanism of action Effects 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241001347511 Carposina sasakii Species 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241001441330 Grapholita molesta Species 0.000 description 2
- 241000255967 Helicoverpa zea Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 241000488581 Panonychus citri Species 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 241000255969 Pieris brassicae Species 0.000 description 2
- 241000500437 Plutella xylostella Species 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 241000488533 Tetranychus viennensis Species 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 210000002189 macula lutea Anatomy 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 208000031968 Cadaver Diseases 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 241001046947 Ectropis obliqua Species 0.000 description 1
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 244000089698 Zanthoxylum simulans Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001887 anti-feedant effect Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical compound OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
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- 210000003608 fece Anatomy 0.000 description 1
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- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
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- 230000008595 infiltration Effects 0.000 description 1
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- 230000002045 lasting effect Effects 0.000 description 1
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- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical class NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
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- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 235000019160 vitamin B3 Nutrition 0.000 description 1
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- 239000004562 water dispersible granule Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of pesticides, and in particular relates to a pesticide preparation for a compound pesticide composition containing flonicamid and bifenthrin as well as application thereof to crop diseases and pest prevention. The compound has a ratio of flonicamid to bifenthrin at 1:50 - 50:1, and the synergy effect is achieved through compounding; the compound is a liquid preparation prepared by mainly using active ingredients of flonicamid and bifenthrin and matching with wet dispersing agent, emulsifying agent, anti-freezing agent, thickening agent, de-foaming agent and pH regulating agent. The compound has a broad application scope and a good effect, and can be used for preventing and controlling various lepidopterous larvae, mealworms and aphids in banana, barley, cotton, lettuce, tea, apple, wheat, tomato, peas, beans, white lupine, alfalfa, green beans, pear, sugar cane, dried chilli, melon, potato, scallions, Chinese cabbage, red pepper, mango, eggplant, cauliflower, grapes, peanuts, watermelons, tobacco, maize, cocoa, asparagus, green Chinese onion and the like. The compound is prepared by selecting appropriate matching ratios, thereby improving the using effect of the effective ingredients in the preparation.
Description
Technical field
Invention belongs to the technical field of agricultural chemicals, is specifically related to a kind of flonicamid and Biphenthrin compound agricultural insecticide composition of containing.
Background technology
Using pesticide control disease pest and weed is to guarantee the indispensable means of agricultural product good quality and high output.Agricultural chemicals will be given full play to drug effect, except guaranteeing pesticide solution, on target, effectively sprawl, be detained and deposit, require preparation to there is good physicochemical property and there is lower surface tension, outside target surface has good wetability and permeability, more need to screen the mutual synergy proportioning between different effective ingredients, promote to greatest extent the application effect of agricultural chemicals.Because drug effect is poor, peasant household, in order to reach certain imitation, will inevitably strengthen formulation rate and spraying times, not only improves agricultural chemicals use cost, improves the pesticide resistance of damage by disease and insect, and causes the severe overweight of residue of pesticide.Therefore, improving agricultural chemicals availability is to reduce drug cost, reduces environmental pollution, reduces the effective way of residue of pesticide.
Flonicamid:
General flonicamid by name, flunicotamid; Test code number: 1KI-220, F-1785; Trade name, ARIA, BELEAF, CARBINE, MAlNMAN, SETIS.TEPPEKI.TURBINE.ULALA.CA accession number: 158062-67-0.Chemical name is N-cyanogen methyl .(trifluoromethyl) vitamin PP.
This product outward appearance is white tasteless pressed powder, 157.5 ℃ of fusing points, and vapour pressure (20 ℃) 2.55x10-6pa, solvability (g/L, 20 ℃): water 5.2, acetone 157.1, methyl alcohol 89.0, to thermally-stabilised.
Flonicamid is a kind of novel low toxicity picolinamide class insect growth regulator, IGR insecticides, within 2007, obtains the interim registration card of China's Pesticidal products, and preparation is 10% water dispersible granules.
Mechanism of action flonicamid is tagged and stomach poison function except having, and also has good never poison and quick Antifeedant Effects.The suckings pest such as aphid take food after the water sucking with flonicamid, can be stoped and inhale juice rapidly, do not have within an hour excreta to occur completely, finally because of hungry dead.
This agent of biologically active is effective to various suckings pest, and has good osmosis.It can be from root to stem, the infiltration of leaf portion, but by leaf portion to stem, root osmosis relatively a little less than.This medicament causes effect by hindering insect act of sucking.Insect stops sucking after taking in medicament very soon, last hungry and dead.Insect according to electronics sucks behavior (EM III) parsing, and this agent can make the lancet tissue of the sucking insects such as aphid cannot insert plant tissue and cause effect.
Due to the mechanism of action of flonicamid uniqueness and high biologically active, with and to people, animal, the high safety of environment, simultaneously effective to the insect of other insecticide tool resistances, so there is very large room for development.
Biphenthrin:
Chinese: Biphenthrin Chinese another name: Uranus; The spirit of worm mite; Bi Fenning; ; (1R, S)-cis-(Z)-2,2-dimethyl-3-(2-chloro-3,3, the fluoro-1-acrylic of 3-tri-) cyclopropane-carboxylic acid-2-methyl-3-phenyl benzyl ester; 2-methyl biphenyl-3-ylmethyl (Z)-(1RS, 3RS)-3-(2-chloro-3,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester;
Molecular formula: C46H44Cl2F6O4 molecular weight: 845.7356
Physico-chemical property: sterling is white solid, in water, solvability is 0.1mg/l, is dissolved in acetone, chloroform, carrene, ether, toluene, heptane.Be slightly soluble in pentane, methyl alcohol, former medicine is stablized more than 1 year at 25 ℃, stores at normal temperatures, and stability is greater than 1 year.At PH5-9 (21 ℃), stablize 21 days DT50-65-125 days in soil.
Fusing point: 68-71 ℃ relative density :-[1] dissolubility: 0.01g/100mL density relative density (d25) 1.210 stability are stable to light, also more stable in acid medium, store at normal temperatures 1 year still more stable, but can decompose in alkaline medium.
Purposes: control cotton bollworm, two-spotted spider mite, peach fruit borer, oriental fruit moth, tetranychus viennensis, citrus red mite, macula lutea stinkbug, tea wing stinkbug, vegetable aphid, cabbage caterpillar, diamond-back moth, eggplant two spotted spider mite, 20 various pests such as the thin moth of tea, Trialeurodes vaporariorum Westwood, tea geometrid, tea caterpillar.
Biphenthrin insecticidal activity is very high, is mainly and tags and stomach poison function, without interior suction and fumigation activity.Rapidly, the lasting period is long in its effect, and insecticidal spectrum is wide.
Biphenthrin is used separately due to long-term, cause the drug-fast generation of disease worm, cause drug effect obviously to decline, thereby cause dosage greatly to rise, the sprinkling cycle shortens, and result of use is poor, increased cost, the use of a large amount of agricultural chemicals, make the resistance of damage by disease and insect more serious, also environment is affected, the medicament residue of agricultural product also increases, have influence on the mankind, the health of animal etc. and normal existence, the mechanism of action of flonicamid and Biphenthrin is basic identical, to the resistance of damage by disease and insect seldom, Biphenthrin and flonicamid are carried out to composite use control corps diseases, will play good effect, there is not yet report both at home and abroad.
Present inventor finds after deliberation, by Biphenthrin and the combination of flonicamid pesticide compositional, the liquid pesticidal formulations of preparation (for example microemulsion, aqueous emulsion and, missible oil and suspending agent), can obtain that physico-chemical property is stable, all good pesticidal preparations of preparation effect, so completed the present invention.
Summary of the invention
The object of this invention is to provide a kind of containing flonicamid and Biphenthrin compound agricultural insecticide composition.Said composition plays synergistic effect by composite.Main control cotton bollworm, two-spotted spider mite, peach fruit borer, oriental fruit moth, tetranychus viennensis, citrus red mite, macula lutea stinkbug, tea wing stinkbug, vegetable aphid, cabbage caterpillar, diamond-back moth, eggplant two spotted spider mite, the thin moth of tea etc.Its preparation form is as microemulsion, aqueous emulsion, missible oil and suspending agent preparation.
Another object of the present invention is to provide the preparation method of described preparation.
In the present invention, the weight of the flonicamid of mentioning and the weight of Biphenthrin, active ingredient etc., all refer to the weight after folding hundred, i.e. the weight of active principle.
Pesticidal combination containing flonicamid and Biphenthrin of the present invention, its active ingredient consists of flonicamid and Biphenthrin, and described flonicamid and the weight ratio of Biphenthrin be, flonicamid: Biphenthrin=1:50-50:1.
As preferably, described flonicamid and the weight ratio of Biphenthrin be, flonicamid: Biphenthrin=1:20-20:1.
Wherein, in said composition, the weight percentage of active ingredient is 1%～60%.
In specific embodiment, liquid pesticidal formulations of the present invention contains following component and content (by weight):
One: 5% flonicamid Biphenthrin microemulsion of example
Comprise following component by weight:
Many flonicamids and the former medicinal dimethylbenzene of Biphenthrin are dissolved, add again calcium dodecyl benzene sulfonate, polyoxyethylene nonylphenol ether and three phenethyl polyoxyethylene groups polyoxypropylene base ethers to make oil phase, ethylene glycol, acetic acid, urea are joined in deionized water aqueous solvent, mix mutually with oil phase again, make 5% flonicamid and Biphenthrin microemulsion.
Two: 12.5% flonicamid Biphenthrin water aqueous emulsions of example
Comprise following component by weight:
Many flonicamids and the former medicinal dimethylbenzene of Biphenthrin are dissolved, add again oxireme propylene oxide block copolymer and Nonyl pheno base ether to make oil phase, ethylene glycol, acetic acid, defoamer are joined in pepper water solvent, mix mutually with oil phase again, after high-shear homogenizer is sheared, add again polyvinyl alcohol, Sodium Benzoate, make the Biphenthrin emulsion in water of flonicamid more than 10%.
Three: 20% flonicamid Biphenthrin missible oil of example
Comprise following component by weight:
The former medicinal dimethylbenzene of flonicamid and Biphenthrin, ethanol dissolve, then add calcium dodecyl benzene sulfonate and three phenethyl polyoxyethylene groups polyoxypropylene base ethers again, mix, and obtain 20% flonicamid Biphenthrin missible oil.
Four: 12.5% flonicamid Biphenthrin suspending agents of example
Comprise following component by weight:
Three phenethyl polyoxyethylene ether phosphates, oxireme propylene oxide block copolymer, Nonyl pheno base ether are mixed to dispersion with a small amount of water, adding flonicamid, the former medicine of Biphenthrin and Chinese prickly ash resin and water to mix disperses again, add again a small amount of defoamer, through sand mill, be ground to particle diameter below 90%5 microns, add xanthans and Sodium Benzoate, remaining defoamer mixing and stirring, make the floating agent agent of 12.5% flonicamid Biphenthrin.
Claims (7)
1. the pesticidal preparations containing flonicamid and Biphenthrin compound agricultural insecticide composition, its active ingredient consists of flonicamid and Biphenthrin, described flonicamid and the weight ratio of Biphenthrin be, flonicamid: Biphenthrin=1:50～50:1.
2. bactericidal composition according to claim 1, is characterized in that, the weight ratio of Suo Shu hymexazo and few chitose is, flonicamid: Biphenthrin=1:20～20:1.
3. Pesticidal combination according to claim 1, is characterized in that, described active ingredient flonicamid and the weight percentage of Biphenthrin are 1%～99%.
4. composition according to claim 1, is characterized in that said composition formulation comprises microemulsion, aqueous emulsion, missible oil and suspending agent.
5. Pesticidal combination as claimed in claim 1, for preventing and treating each Species of Lepidopterous Larvae, aleyrodid, the aphid on crop.
6. bactericidal composition as claimed in claim 1, for preventing and treating banana, barley, cotton, lettuce, tea, apple, wheat, tomato, pea, beanpod, white lupin, clover, green soya bean, pears, sugarcane, dry red pepper, muskmelon, potato, verdant, Chinese cabbage, red pepper, mango, eggplant, cauliflower, grape, peanut, watermelon, tobacco, corn, cocoa, asparagus, shallot etc.
7. Pesticidal combination as claimed in claim 1, by flonicamid proportionings different from Biphenthrin are screened, is equipped with suitable formulation structure, thereby obtains optimum control efficiency.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310706684.2A CN103651519A (en) | 2013-12-20 | 2013-12-20 | Compound pesticide composition containing flonicamid and bifenthrin |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310706684.2A CN103651519A (en) | 2013-12-20 | 2013-12-20 | Compound pesticide composition containing flonicamid and bifenthrin |
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| CN103651519A true CN103651519A (en) | 2014-03-26 |
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| CN201310706684.2A Pending CN103651519A (en) | 2013-12-20 | 2013-12-20 | Compound pesticide composition containing flonicamid and bifenthrin |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104255775A (en) * | 2014-09-09 | 2015-01-07 | 青岛润鑫伟业科贸有限公司 | Efficient pesticide containing flonicamid, cyantraniliprole, bifenthrin and beta-cypermethrin |
| CN104273160A (en) * | 2014-09-18 | 2015-01-14 | 青岛润鑫伟业科贸有限公司 | High-efficiency insecticide containing flonicamid, cyphenothrin and amitraz |
| CN111109264A (en) * | 2020-01-17 | 2020-05-08 | 河南远见农业科技有限公司 | Cabbage aphid insecticidal suspending agent |
| CN112293425A (en) * | 2020-12-03 | 2021-02-02 | 苏州遍净植保科技有限公司 | Acetamiprid-and-flonicamid-contained wettable powder |
| CN113826627A (en) * | 2020-06-23 | 2021-12-24 | 江苏功成生物科技有限公司 | Insecticidal composition containing flonicamid and pyrethroids and application |
| CN114642209A (en) * | 2021-03-26 | 2022-06-21 | 山东统防生物科技有限公司 | A kind of flonicamid bifenthrin pesticide preparation and its preparation method and application |
| CN116941633A (en) * | 2023-07-12 | 2023-10-27 | 上海悦联生物科技有限公司 | 20% bifenthrin flonicamid suspending agent and preparation method thereof |
-
2013
- 2013-12-20 CN CN201310706684.2A patent/CN103651519A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104255775A (en) * | 2014-09-09 | 2015-01-07 | 青岛润鑫伟业科贸有限公司 | Efficient pesticide containing flonicamid, cyantraniliprole, bifenthrin and beta-cypermethrin |
| CN104273160A (en) * | 2014-09-18 | 2015-01-14 | 青岛润鑫伟业科贸有限公司 | High-efficiency insecticide containing flonicamid, cyphenothrin and amitraz |
| CN111109264A (en) * | 2020-01-17 | 2020-05-08 | 河南远见农业科技有限公司 | Cabbage aphid insecticidal suspending agent |
| CN113826627A (en) * | 2020-06-23 | 2021-12-24 | 江苏功成生物科技有限公司 | Insecticidal composition containing flonicamid and pyrethroids and application |
| CN112293425A (en) * | 2020-12-03 | 2021-02-02 | 苏州遍净植保科技有限公司 | Acetamiprid-and-flonicamid-contained wettable powder |
| CN114642209A (en) * | 2021-03-26 | 2022-06-21 | 山东统防生物科技有限公司 | A kind of flonicamid bifenthrin pesticide preparation and its preparation method and application |
| CN116941633A (en) * | 2023-07-12 | 2023-10-27 | 上海悦联生物科技有限公司 | 20% bifenthrin flonicamid suspending agent and preparation method thereof |
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