CN103651376A - Synergistic insecticidal composition containing ethiprole and flonicamid and application of synergistic insecticidal composition - Google Patents
Synergistic insecticidal composition containing ethiprole and flonicamid and application of synergistic insecticidal composition Download PDFInfo
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- CN103651376A CN103651376A CN201210323101.3A CN201210323101A CN103651376A CN 103651376 A CN103651376 A CN 103651376A CN 201210323101 A CN201210323101 A CN 201210323101A CN 103651376 A CN103651376 A CN 103651376A
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- flonicamid
- worm nitrile
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- 239000005900 Flonicamid Substances 0.000 title claims abstract description 78
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 37
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 title abstract description 6
- 241001124076 Aphididae Species 0.000 claims abstract description 11
- 241001498622 Cixius wagneri Species 0.000 claims abstract description 7
- 150000002825 nitriles Chemical class 0.000 claims description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 241000238631 Hexapoda Species 0.000 claims description 14
- 239000002917 insecticide Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000000375 suspending agent Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000003905 agrochemical Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 239000004530 micro-emulsion Substances 0.000 claims description 4
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 4
- 241000500437 Plutella xylostella Species 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 3
- 241000607479 Yersinia pestis Species 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000575 pesticide Substances 0.000 abstract description 7
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 6
- 235000009566 rice Nutrition 0.000 abstract description 6
- 239000004480 active ingredient Substances 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 241000258937 Hemiptera Species 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000003814 drug Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- -1 Flunicotamid) Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 5
- 241000209094 Oryza Species 0.000 description 5
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000361 pesticidal effect Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 241001556089 Nilaparvata lugens Species 0.000 description 3
- 241000176086 Sogatella furcifera Species 0.000 description 3
- 238000004166 bioassay Methods 0.000 description 3
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
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- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 239000004562 water dispersible granule Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 241001414989 Thysanoptera Species 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 230000001055 chewing effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
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- 229920002545 silicone oil Polymers 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- 241001136249 Agriotes lineatus Species 0.000 description 1
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- 241001517923 Douglasiidae Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000578422 Graphosoma lineatum Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000661348 Leptocorisa acuta Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
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- 239000002270 dispersing agent Substances 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011708 vitamin B3 Substances 0.000 description 1
- 235000019160 vitamin B3 Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a synergistic insecticidal composition containing ethiprole and flonicamid and an application of the synergistic insecticidal composition. The ethiprole and the flonicamid are used as insecticidal active ingredients of the synergistic insecticidal composition, wherein the weight ratio of the ethiprole to the flonicamid is (0.1-80): (0.2-70). The insecticidal composition is capable of generating a relatively high synergistic effect, overcoming and delaying pest resistance to pesticides and reducing the pesticide cost, high in insecticidal speed and long in lasting period. The synergistic insecticidal composition can be used for preventing and controlling hemiptera pests on crops and particularly preventing and controlling rice planthopper, aleyrodid, aphids and the like, and is remarkably high in effect in comparison with a single dosage of pesticide.
Description
Technical field
The invention belongs to the field of agricultural pesticide that contains heterocyclic compound, be specifically related to a kind of Synergistic insecticidal compositions.
Background technology
Second worm nitrile (Ethiprole), chemical name: 1-(2,6-dichlor-4-trifluoromethyl phenyl)-3-cyano group-4-ethyl sulfinyl-5-amino-pyrazol.Molecular formula is: C
13h
9c
12f
3n
4oS.
Second worm nitrile (Ethiprole) is the Insecticidal and acaricidal agent by rhone-poulenc is found, Beyer Co., Ltd develops, belong to effective to multiple chewing type and sucking pest under the low consumption of insecticide that the second generation acts on GABA, can be used for seed treatment and foliar spray, the lasting period reaches 21-28d.(be mainly used in preventing and treating thrips, stinkbug, curculionid, beet gelechiid, aphid, plant hopper and locust etc., some aleyrodid is also shown to activity (particularly the rice grub green rice bug of extremely difficult control being had to very strong activity).
Flonicamid (Flonicamid, Flunicotamid), chemical name: N-cyanogen methyl-(trifluoromethyl) vitamin PP.
Flonicamid belongs to lower toxicity insecticide variety.This agent is effective to various suckings pest, and has good osmosis.It can be from root to stem, the infiltration of leaf portion, but by leaf portion to stem, root osmosis relatively a little less than.
This medicament causes effect by hindering insect act of sucking.Insect stops sucking after taking in medicament very soon, last hungry and dead.
Insect according to electronics sucks behavior (EM III) parsing, and this agent can make the lancet tissue of the sucking insects such as aphid cannot insert plant tissue and cause effect.10% water dispersible granules, every 667m when the insects such as vegetable aphid such as control cucumber
2use 10% water dispersible granules 30-509 to spray water.When preventing and treating the fruit aphids such as apple, with 10% water dispersible granules, add water 2500-5000 and doubly spray.Through test and land for growing field crops, use proof, flonicamid is to various aphids, plant hopper, aleyrodid, leafhopper, fruit bat, wireworm, thrips, ant class, leaf miner, and the first-class sucking pest of springtail has special efficacy, and pests with chewing mouthparts is also had to good control efficiency.
The Semiptera such as rice fulgorid, aphid insect is under the condition of current long-term prescription, and resistance increases gradually, and agricultural chemicals single dose declines gradually to the effect of control of insect, for the control of Semiptera insect, there is no effective preparation.Inventor finds after deliberation, and the composite of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds that up to now the complex insecticidal composition of relevant second worm nitrile and flonicamid is used for preventing and treating resistance Semiptera insect.
Summary of the invention
The object of this invention is to provide a kind of Synergistic insecticidal compositions containing second worm nitrile and flonicamid.
Another object of the present invention is to provide above-mentioned Synergistic insecticidal compositions and prevents and treats the application in resistance Semiptera insect insecticidal materials in preparation.
For achieving the above object, the present invention is composite by different two kinds of insecticidal materials second worm nitriles and the flonicamid of controlling object, obtains the new and effective multifunctional insecticide composition of a class.The various pests that this Pesticidal combination easily produces resistance to plant hopper, aphid, diamond-back moth has good preventive effect; And suppress insect the pesticide resistance of unitary agent (second worm nitrile or flonicamid) is produced.The following technical scheme of the concrete employing of the present invention:
Containing a Synergistic insecticidal compositions for second worm nitrile and flonicamid, it is active insecticidal components that this Synergistic insecticidal compositions be take second worm nitrile and flonicamid, and wherein, the weight ratio of second worm nitrile and flonicamid is 0.1 ~ 80:0.2 ~ 70.
In this compound pesticide compositions, the weight ratio of second worm nitrile (A) and flonicamid (B) is preferably 0.5 ~ 60:1 ~ 50.A kind of preferred scheme is that the two weight ratio of A and B is further 1 ~ 30:1 ~ 20, most preferably is 1 ~ 10:1 ~ 10.It is that the two weight ratio of A and B is 0.1 ~ 20:1 that another kind is preferably scheme, is further 0.1 ~ 10:1.
This compound pesticide compositions can only contain active component second worm nitrile and flonicamid, also can when using or prepare, in active component, add other components, and the effective ingredient in this Pesticidal combination can also synergy effective dose be present in composition.
In Synergistic insecticidal compositions of the present invention, the two percentage by weight that accounts for composition of second worm nitrile and flonicamid is 3 ~ 80%.Be preferably 5 ~ 50%, most preferably 5 ~ 20%." % " of the present invention is mass percent.
It is main active ingredient (active component) that above-mentioned Insecticidal combinations be take second worm nitrile and flonicamid, be mixed with insecticides adjuvant and excipients any one formulation allowing on agricultural chemicals, described formulation is preferably missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
Aforementionedly can be applicable to the not special restriction of insecticides adjuvant of the present invention, include, but are not limited to calcium dodecyl benzene sulfonate, 600#, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc.Aforementionedly can be applicable to excipient of the present invention and be also not particularly limited, include, but are not limited to cyclohexanone, vegetable oil, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient can alone or mixing use, also can add other auxiliary material allowing on pesticidal preparations.
Above-mentioned Pesticidal combination can be prevented and treated the application in the insecticidal materials of resistance Semiptera insect in preparation, and the control efficiency of the present composition is used apparently higher than its single dose, and described Semiptera insect refers in particular to rice fulgorid, aphid or aleyrodid.
Indoor bioassay and field control effectiveness test show that compound insecticidal medicine of the present invention has significant synergistic insecticidal action to Semiptera insect, especially the insecticidal effect of plant hopper (particularly water rice hopper), aphid, aleyrodid or diamond-back moth are all significantly higher than the effect of corresponding single dose agricultural chemicals.
Beneficial effect of the present invention: the second worm nitrile providing of the present invention and flonicamid Pesticidal combination, can produce higher synergistic function, desinsection speed is fast, overcome and delayed pest resistance to insecticide, expanding prevention spectrum, has reduced drug cost simultaneously, and its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but do not limit the present invention in any way.
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, then carry out field trial.
Embodiment 1:
Take second worm nitrile and flonicamid and be total to 30g, calcium dodecyl benzene sulfonate 4g, 600#4g, phenethyl phenol polyethenoxy ether 6g, solvent naphtha to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and is mixed with the second worm nitrile flonicamid missible oil that main active ingredient weight percentage is 30%, and wherein the concrete ratio of second worm nitrile and flonicamid is in Table 1 and 2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The Toxicity Determination of table 1. second worm nitrile and flonicamid composition and single dose antagonism rice fulgorid thereof
In table, data show, after second worm nitrile and flonicamid are mixed, Brown Planthopper are had to synergistic effect, and three proportioning co-toxicity coefficients listed in table are all much larger than 120, so second worm nitrile and flonicamid are mixed and have significant synergies.
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistance aleyrodid is target pest, and every processing repeats 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The Toxicity Determination of table 2. second worm nitrile and flonicamid Synergistic insecticidal compositions and single dose antagonism aleyrodid thereof
In table, data show, after second worm nitrile and flonicamid are mixed, aleyrodid are had to synergistic effect, and three proportioning co-toxicity coefficients listed in table are all much larger than 120, and second worm nitrile and flonicamid are mixed and have significant synergies.
Adopt the sample of embodiment 2 and 3, according to every mu of ground medication 10g, 20g, 25g preparation, contrast medicament is 10% flonicamid WP30g/ mu, 5% second worm nitrile AS30g/ mu, every mu of ground water 30kg control Brown Planthopper.Within after dispenser 4 days, 10 days, 15 days, 20 days, 30 days, come to an end really, and carry out data processing, the results are shown in Table 3:
Table 3. second worm nitrile and the field test results of flonicamid Synergistic insecticidal compositions to Brown Planthopper
As can be known from the above table, second worm nitrile flonicamid is composite is better than 10% flonicamid wetting powder, 5% second worm nitrile aqua to water rice hopper drug effect, demonstrates the superiority of formula.
Adopt the sample of embodiment 2 and 3, according to every mu of ground medication 10g, 20g, 25g medicament, contrast medicament is 10% flonicamid WP30g/ mu, 5% second worm nitrile AS30g/ mu, every mu of ground water 30kg, the aleyrodid on control cucumber.Within after dispenser 4 days, 10 days, 15 days, 20 days, 30 days, come to an end really, and process, the results are shown in Table 4:
The composite field test results to aleyrodid of table 4. second worm nitrile-flonicamid
As can be known from the above table, second worm nitrile flonicamid is composite is better than 10% flonicamid wetting powder, 5% second worm nitrile aqua to aleyrodid drug effect, demonstrates the superiority of formula.
Embodiment 2:
Take 0.5g second worm nitrile, 10g flonicamid is dissolved in 8g solvent naphtha, then adds 1g ethylene glycol and 5g600# disodium sulfosuccinate, stir.Above-mentioned solution is slowly poured in excess water to gross weight 100g, under fully stirring, made 10.5% second worm nitrile flonicamid aqueous emulsion.
Embodiment 3:
Take 1g second worm nitrile, 10g flonicamid is dissolved in 8g solvent naphtha, then adds 1g ethylene glycol and 5g600# disodium sulfosuccinate, stir.Above-mentioned solution is slowly poured in excess water, under fully stirring, made 11% second worm nitrile flonicamid aqueous emulsion.
Embodiment 4:
Take 45g second worm nitrile, 5g flonicamid is dissolved in 8g solvent naphtha, then adds 1g ethylene glycol and 5g600# disodium sulfosuccinate, stir.Above-mentioned solution is slowly poured in excess water, under fully stirring, made 50% second worm nitrile flonicamid aqueous emulsion.
Embodiment 5:
Take 2g second worm nitrile, 20g flonicamid, 600#5g, phenethyl phenol polyethenoxy ether 6g, 1-METHYLPYRROLIDONE 4g, isopropyl alcohol 6g, solvent naphtha 3g, surplus is water, the method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and makes 22% second worm nitrile flonicamid microemulsion.
Embodiment 6:
Take 5g second worm nitrile, 45g flonicamid, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, makes 50% second worm nitrile flonicamid water dispersion granule by above raw material by the method for water dispersion granule.
Embodiment 7:
Take 75g second worm nitrile, 0.2g flonicamid, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is water, above raw material is prepared routinely to the method for suspending agent, made 75.2% second worm nitrile flonicamid suspending agent.
Embodiment 8:
Take 10g second worm nitrile, 15g flonicamid, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is water, above raw material is prepared routinely to the method for suspending agent, made 25% second worm nitrile flonicamid suspending agent.
Embodiment 9:
Take 5g second worm nitrile, 70g flonicamid, calcium dodecyl benzene sulfonate 4g, 600#4g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and makes 75% second worm nitrile flonicamid missible oil.
Embodiment 10:
Take 0.1g second worm nitrile, 30g flonicamid, calcium dodecyl benzene sulfonate 4g, 600#4g, phenethyl phenol polyethenoxy ether 6g, solvent naphtha to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and makes 30.1% second worm nitrile flonicamid missible oil.
Embodiment 11:
Take 30g second worm nitrile, 20g flonicamid, calcium dodecyl benzene sulfonate 4g, 600#5g, phenethyl phenol polyethenoxy ether 6g, solvent naphtha to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and makes 50% second worm nitrile flonicamid missible oil.
Embodiment 12:
Take 60g second worm nitrile, 5g flonicamid, 1g lauryl sodium sulfate, 0.5g dispersing agent NNO, kaolin to 100g, above raw material is prepared routinely to the method for wetting powder and mixed, form 65% second worm nitrile flonicamid wetting powder.
Claims (10)
1. containing a Synergistic insecticidal compositions for second worm nitrile and flonicamid, it is characterized in that it is active insecticidal components that this Synergistic insecticidal compositions be take second worm nitrile and flonicamid, wherein, the weight ratio of second worm nitrile and flonicamid is 0.1 ~ 80:0.2 ~ 70.
2. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid according to claim 1, is characterized in that in this Synergistic insecticidal compositions, the weight ratio of second worm nitrile and flonicamid is 0.5 ~ 60:1 ~ 50.
3. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid according to claim 2, is characterized in that in this Synergistic insecticidal compositions, the weight ratio of second worm nitrile and flonicamid is 1 ~ 30:1 ~ 20.
4. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid according to claim 3, is characterized in that in this Synergistic insecticidal compositions, the weight ratio of second worm nitrile and flonicamid is 1 ~ 10:1 ~ 10.
5. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid according to claim 1, is characterized in that the two weight percentage that accounts for this Synergistic insecticidal compositions of second worm nitrile and flonicamid is 3 ~ 80%.
6. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid according to claim 5, is characterized in that the two weight percentage that accounts for this Synergistic insecticidal compositions of second worm nitrile and flonicamid is 5 ~ 50%.
7. according to the Synergistic insecticidal compositions containing second worm nitrile and flonicamid described in claim 1,2 or 3, it is characterized in that this Synergistic insecticidal compositions take second worm nitrile and flonicamid and be mixed with the formulation allowing on agricultural chemicals as active insecticidal components and insecticides adjuvant and excipients.
8. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the Synergistic insecticidal compositions containing second worm nitrile and flonicamid claimed in claim 1 is prevented and treated the application in the insecticidal materials of resistance Semiptera insect in preparation.
10. the application of the Synergistic insecticidal compositions containing second worm nitrile and flonicamid claimed in claim 1 in the insecticidal materials of preparation control plant hopper, aleyrodid, diamond-back moth or aphid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210323101.3A CN103651376A (en) | 2012-09-04 | 2012-09-04 | Synergistic insecticidal composition containing ethiprole and flonicamid and application of synergistic insecticidal composition |
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| CN201210323101.3A CN103651376A (en) | 2012-09-04 | 2012-09-04 | Synergistic insecticidal composition containing ethiprole and flonicamid and application of synergistic insecticidal composition |
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| CN201210323101.3A Pending CN103651376A (en) | 2012-09-04 | 2012-09-04 | Synergistic insecticidal composition containing ethiprole and flonicamid and application of synergistic insecticidal composition |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101043815A (en) * | 2004-10-22 | 2007-09-26 | 巴斯福股份公司 | Pesticidal mixtures |
| CN102349504A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Flonicamid-containing ultralow volume liquid agent |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101043815A (en) * | 2004-10-22 | 2007-09-26 | 巴斯福股份公司 | Pesticidal mixtures |
| CN102349504A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Flonicamid-containing ultralow volume liquid agent |
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