CN103641311A - High-calcium and lightweight glass bottle formula - Google Patents
High-calcium and lightweight glass bottle formula Download PDFInfo
- Publication number
- CN103641311A CN103641311A CN201310670404.7A CN201310670404A CN103641311A CN 103641311 A CN103641311 A CN 103641311A CN 201310670404 A CN201310670404 A CN 201310670404A CN 103641311 A CN103641311 A CN 103641311A
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- CN
- China
- Prior art keywords
- formula
- raw material
- glass
- calcium
- glass bottle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 30
- 239000011575 calcium Substances 0.000 title claims abstract description 12
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 28
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 24
- 239000011734 sodium Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 13
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 12
- 239000006004 Quartz sand Substances 0.000 claims abstract description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 12
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 11
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 11
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 11
- 229940000207 selenious acid Drugs 0.000 claims description 11
- MCAHWIHFGHIESP-UHFFFAOYSA-N selenous acid Chemical compound O[Se](O)=O MCAHWIHFGHIESP-UHFFFAOYSA-N 0.000 claims description 11
- 235000017550 sodium carbonate Nutrition 0.000 claims description 11
- 229940001516 sodium nitrate Drugs 0.000 claims description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 abstract description 3
- 239000002893 slag Substances 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229910004883 Na2SiF6 Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- PEUPCBAALXHYHP-UHFFFAOYSA-L zinc;selenite Chemical compound [Zn+2].[O-][Se]([O-])=O PEUPCBAALXHYHP-UHFFFAOYSA-L 0.000 abstract 1
- 235000001465 calcium Nutrition 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000012797 qualification Methods 0.000 description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 5
- 239000010433 feldspar Substances 0.000 description 5
- 239000010436 fluorite Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- QVYIMIJFGKEJDW-UHFFFAOYSA-N cobalt(ii) selenide Chemical compound [Se]=[Co] QVYIMIJFGKEJDW-UHFFFAOYSA-N 0.000 description 4
- 229940056729 sodium sulfate anhydrous Drugs 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002910 solid waste Substances 0.000 description 3
- 229910004261 CaF 2 Inorganic materials 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses a high-calcium and lightweight glass bottle formula. The formula disclosed by the invention comprises 1) a raw material comprising the materials by weight percent: 70-75% of quartz sand SiO2, 12-16% of sodium carbonate NaCO3, 9-12% of calcite CaCO3, 2-3% of aluminum oxide Al2O3, 0.3-0.7% of sodium fluosilicate Na2SiF6, 0.4-0.8% of sodium nitrate NaNO3, 0.002-0.007% of zinc selenite ZnSeO3.2H2O, and 2) a clinker, namely glass slag which is 60% of weight of the raw material. A glass bottle prepared from the high-calcium and lightweight glass bottle formula disclosed by the invention is high in strength, good in color, good in brightness, high in utilization rate of waste glass, and high in yield of finished products.
Description
Technical field
The invention belongs to vial material prescription, especially solid waste glass is recycled melting and is made the formula technique field that vial adopts.
Background technology
At present, adopt the existing glass bottle of filling a prescription and producing that solid waste glass is recycled, easily occur bubble; Insufficient strength, maximum impact resistance is generally 0.5 to 0.6J; Finished product qualification rate is lower, and qualification rate is only 85% to 90%.This existing formula is,
1), raw material:
Quartz sand SiO
2, soda ash NaCO
3, calcite CaCO
3, Feldspar Powder Al
2o
3, fluorite CaF
2:, Sodium sulfate anhydrous.min(99) Na
2sO
4, SODIUMNITRATE NaNO
3, selenium-cobalt discoloring agent;
2), grog: glass dregs.
The accurate formula wherein the most often adopting is:
1), raw material:
Quartz sand SiO
2: 72.0%, soda ash NaCO
3: 14.8%, calcite CaCO
3: 9.8%, Feldspar Powder Al
2o
3: 3.0%, fluorite CaF
2: 0.8%, Sodium sulfate anhydrous.min(99) Na
2sO
4: 0.9%, SODIUMNITRATE NaNO
3: 0.6%, the weight of raw material before selenium-cobalt discoloring agent 8g/200KG();
2), grog: glass dregs is 40% of raw material weight.
The defect that above-mentioned existing solid waste glass is recycled the formula material existence of melting making vial employing is: the Feldspar Powder in existing formula belongs to mineral products, slag is a lot, using Feldspar Powder is mainly the aluminium element using wherein, owing to wherein containing iron, iron can affect the Forming Quality of vial and the intensity of vial;
Fluorite in existing formula, what mainly use is the fluorine element of its inside, for glass metal clarification.Fluorite belongs to mineral products, wherein certainly exists other element, can not use completely, and the element wherein having also can affect quality product, such as iron, magnesium elements;
Sodium sulfate anhydrous.min(99) in existing formula, life-time service can corrode kiln pond, reduces kiln pond work-ing life;
Selenium-cobalt discoloring agent in existing formula, cobalt wherein can affect the quality of vial;
Grog in existing actual formula adopts 40% glass dregs, also not very high to a kind of utilization ratio of scrap glass used in everyday.
The formula of above-mentioned prior art also makes the vial of making easily produce bubble, and impact resistance is also poor, and the qualification rate of finished product is not high yet.
Object of the present invention provides a kind of vial intensity of making high in order to overcome defect that above-mentioned prior art exists and weak point just, color, lightness are good, the high calcium that scrap glass utilization ratio is high, the qualification rate of finished product is high and light-weighted vial formula.
The object of the invention is to realize by following technical solution.
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 70~75%, soda ash NaCO
3: 12~16%, calcite CaCO
3: 9~12%, aluminium oxide Al
2o
3: 2~3%, Sodium Silicofluoride Na
2siF
6: 0.3~0.7%, SODIUMNITRATE NaNO
3: 0.4~0.8%, zincium selenious acid ZnSeO
3.2H
2o 0.002~0.007%;
2), grog: glass dregs is 60% of raw material weight.
Optimum formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 72.5%, soda ash NaCO
3: 13.8%, calcite CaCO
3: 10.296%, aluminium oxide Al
2o
3: 2.3%, Sodium Silicofluoride Na
2siF
6: 0.5%, SODIUMNITRATE NaNO
3: 0.6%, zincium selenious acid ZnSeO
3.2H
2o 0.004%;
2), grog: glass dregs is 60% of raw material weight.
The invention has the beneficial effects as follows, the vial intensity of making is high, and color, lightness are good, and scrap glass utilization ratio is high, the qualification rate of finished product is high.
The bottle that adopts formula of the present invention to produce, bottle is without bubble; Impact resistance can reach 0.7J to 1.0J, intensity enhancing; Finished product qualification rate reaches more than 97%.
The present invention changes aluminum oxide into by original Feldspar Powder: avoided bringing into of other slag, guaranteed glassy product quality.
The present invention changes Sodium Silicofluoride into by the fluorite of use originally, and the ratio of other raw material is adjusted, because its all the components is all operable (such as fluorine, silicon oxide, sodium oxide), has effectively controlled cost.And use, when glass melting, can play to glass metal the effect of clarification.
The present invention does not adopt Sodium sulfate anhydrous.min(99), so long as because life-time service can corrode kiln pond, reduces kiln pond work-ing life.
The present invention changes selenium-cobalt discoloring agent into zincium selenious acid, is mainly because wherein cobalt can affect the quality of vial.Make zincium selenious acid into, because it easily volatilizees, can guarantee the transparency of vial and avoid other color quality to affect quality product.
Grog of the present invention changes 60% into by 40% original glass dregs, and effectively a kind of effective utilization to scrap glass used in everyday, reduces costs, and has also protected environment.
The present invention also further by test of many times and analysis, has found out optimum formula on the basis of revising prior art formula, and this optimum formula has had very significant above-mentioned effect, becomes the preferred of a kind of the present invention's formula.
Embodiment
Embodiment mono-
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 70%, soda ash NaCO
3: 16%, calcite CaCO
3: 10.493%, aluminium oxide Al
2o
3: 2%, Sodium Silicofluoride Na
2siF
6: 0.7%, SODIUMNITRATE NaNO
3: 0.8%, zincium selenious acid ZnSeO
3.2H
2o 0.007%;
2), grog: glass dregs is 60% of raw material weight.
Embodiment bis-
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 75%, soda ash NaCO
3: 12%, calcite CaCO
3: 9.298%, aluminium oxide Al
2o
3: 3%, Sodium Silicofluoride Na
2siF
6: 0.3%, SODIUMNITRATE NaNO
3: 0.4%, zincium selenious acid ZnSeO
3.2H
2o 0.002%;
2), grog: glass dregs is 60% of raw material weight.
31 kinds of high calciums of embodiment and light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 72.5%, soda ash NaCO
3: 13.8%, calcite CaCO
3: 10.296%, aluminium oxide Al
2o
3: 2.3%, Sodium Silicofluoride Na
2siF
6: 0.5%, SODIUMNITRATE NaNO
3: 0.6%, zincium selenious acid ZnSeO
3.2H
2o 0.004%;
2), grog: glass dregs is 60% of raw material weight.
Embodiment tetra-
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 71%, soda ash NaCO
3: 14.094%, calcite CaCO
3: 12%, aluminium oxide Al
2o
3: 2%, Sodium Silicofluoride Na
2siF
6: 0.4%, SODIUMNITRATE NaNO
3: 0.5%, zincium selenious acid ZnSeO
3.2H
2o 0.006%;
2), grog: glass dregs is 60% of raw material weight.
Embodiment five
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 74%, soda ash NaCO
3: 13.197%, calcite CaCO
3: 9%, aluminium oxide Al
2o
3: 2.5%, Sodium Silicofluoride Na
2siF
6: 0.6%, SODIUMNITRATE NaNO
3: 0.7%, zincium selenious acid ZnSeO
3.2H
2o 0.003%;
2), grog: glass dregs is 60% of raw material weight.
Claims (2)
1. high calcium and a light-weighted vial formula, is characterized in that, filling a prescription is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 70~75%, soda ash NaCO
3: 12~16%, calcite CaCO
3: 9~12%, aluminium oxide Al
2o
3: 2~3%, Sodium Silicofluoride Na
2siF
6: 0.3~0.7%, SODIUMNITRATE NaNO
3: 0.4~0.8%, zincium selenious acid ZnSeO
3.2H
2o 0.002~0.007%;
2), grog: glass dregs is 60% of raw material weight.
2. a kind of high calcium according to claim 1 and light-weighted vial formula, is characterized in that, optimum formula is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 72.5%, soda ash NaCO
3: 13.8%, calcite CaCO
3: 10.296%, aluminium oxide Al
2o
3: 2.3%, Sodium Silicofluoride Na
2siF
6: 0.5%, SODIUMNITRATE NaNO
3: 0.6%, zincium selenious acid ZnSeO
3.2H
2o 0.004%;
2), grog: glass dregs is 60% of raw material weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310670404.7A CN103641311A (en) | 2013-12-11 | 2013-12-11 | High-calcium and lightweight glass bottle formula |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310670404.7A CN103641311A (en) | 2013-12-11 | 2013-12-11 | High-calcium and lightweight glass bottle formula |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103641311A true CN103641311A (en) | 2014-03-19 |
Family
ID=50246648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310670404.7A Pending CN103641311A (en) | 2013-12-11 | 2013-12-11 | High-calcium and lightweight glass bottle formula |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103641311A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105330145A (en) * | 2015-10-30 | 2016-02-17 | 太仓市双凤镇薄彩工艺品厂 | Formula of azure stone accessory |
CN109534678A (en) * | 2019-01-22 | 2019-03-29 | 山东景耀玻璃集团有限公司 | A kind of low cost common white material glass and preparation method |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5718737A (en) * | 1995-03-03 | 1998-02-17 | International Cullet Exchange. Inc. | Method of recycling mixed colored cullet into amber, green, or flint glass |
JPH10310446A (en) * | 1996-09-30 | 1998-11-24 | Fuoresuto:Kk | Production of glass product using fine powder of ohyaishi as starting material and glass product produced by same |
CN1569712A (en) * | 2003-07-25 | 2005-01-26 | 阿城市大明玻璃制品有限公司 | Formulation for preparing high-class polyether bottle using varicolored cullet |
CN102584017A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing beer bottles through broken glass |
CN102584016A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing infusion bottles by using broken glass |
CN102765882A (en) * | 2012-08-15 | 2012-11-07 | 黄炳炼 | Milk white glass wine bottle |
-
2013
- 2013-12-11 CN CN201310670404.7A patent/CN103641311A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5718737A (en) * | 1995-03-03 | 1998-02-17 | International Cullet Exchange. Inc. | Method of recycling mixed colored cullet into amber, green, or flint glass |
JPH10310446A (en) * | 1996-09-30 | 1998-11-24 | Fuoresuto:Kk | Production of glass product using fine powder of ohyaishi as starting material and glass product produced by same |
CN1569712A (en) * | 2003-07-25 | 2005-01-26 | 阿城市大明玻璃制品有限公司 | Formulation for preparing high-class polyether bottle using varicolored cullet |
CN102584017A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing beer bottles through broken glass |
CN102584016A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing infusion bottles by using broken glass |
CN102765882A (en) * | 2012-08-15 | 2012-11-07 | 黄炳炼 | Milk white glass wine bottle |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105330145A (en) * | 2015-10-30 | 2016-02-17 | 太仓市双凤镇薄彩工艺品厂 | Formula of azure stone accessory |
CN109534678A (en) * | 2019-01-22 | 2019-03-29 | 山东景耀玻璃集团有限公司 | A kind of low cost common white material glass and preparation method |
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Application publication date: 20140319 |