CN103614649A - High-strength, high-toughness and high-plasticity martensitic stainless steel and preparation method thereof - Google Patents
High-strength, high-toughness and high-plasticity martensitic stainless steel and preparation method thereof Download PDFInfo
- Publication number
- CN103614649A CN103614649A CN201310652072.XA CN201310652072A CN103614649A CN 103614649 A CN103614649 A CN 103614649A CN 201310652072 A CN201310652072 A CN 201310652072A CN 103614649 A CN103614649 A CN 103614649A
- Authority
- CN
- China
- Prior art keywords
- stainless steel
- strength
- martensite stainless
- plasticity
- strong toughness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Heat Treatment Of Steel (AREA)
Abstract
一种高强韧性高强塑性马氏体不锈钢，属于冶金技术领域，成分按重量百分比含C0.15~0.4%，N0~0.12%，Si0.2~2.5%，Mn0.4~3.0%，S≤0.02%，P≤0.02%，Cr13.0~17.0%，Ni0~5.0%，Mo0~2.0%，V0~0.3%，Nb0~0.2%，Ti0~0.05%，Al0~0.8%，余量为Fe及不可避免杂质；制备方法为：（1）按设定成分熔炼钢水，再通过连铸机或铸模凝固制成铸坯；（2）将铸坯热轧制成热轧板坯；（3）加热至950~1100℃保温0.5~2h，然后冷却至25~200℃，再加热至350~500℃保温10~60min，空冷至室温。本发明的方法制备的马氏体不锈钢在显微组织中引入弥散的残留奥氏体，大幅度提高了马氏体不锈钢的强韧性强塑性水平。
A high-strength toughness and high-strength plasticity martensitic stainless steel, belonging to the field of metallurgy technology, the composition contains C0.15~0.4%, N0~0.12%, Si0.2~2.5%, Mn0.4~3.0%, S≤0.02 %, P≤0.02%, Cr13.0~17.0%, Ni0~5.0%, Mo0~2.0%, V0~0.3%, Nb0~0.2%, Ti0~0.05%, Al0~0.8%, the balance is Fe and not Avoid impurities; the preparation method is: (1) melting molten steel according to the set composition, and then solidifying it through a continuous casting machine or a casting mold to make a billet; (2) hot-rolling the billet to make a hot-rolled slab; (3) heating to Heat at 950~1100°C for 0.5~2h, then cool to 25~200°C, heat at 350~500°C for 10~60min, air cool to room temperature. The martensitic stainless steel prepared by the method of the invention introduces dispersed retained austenite into the microstructure, which greatly improves the strength, toughness and strong plasticity level of the martensitic stainless steel.
Description
Technical field
The invention belongs to metallurgical technology field, particularly a kind of high-strong toughness high-strength plasticity Martensite Stainless Steel and preparation method thereof.
Background technology
As the first-selected steel grade under high-load corrosive environment, Martensite Stainless Steel is widely used in cutter, turbine blade, bearing, valve, structural part and wearing piece etc.Martensite Stainless Steel obtains the microstructure of (tempering) martensite+carbide conventionally through quenching-tempering; Although its obdurability can be controlled by changing tempering temperature and time, but due to intensity and these those length that disappear of plasticity, add the reasons such as homogeneity of structure and temper brittleness, cause the plasticity of Martensite Stainless Steel and toughness always lower than the low alloy steel of same intensity rank; Further improving combination of strength and toughness, is the current urgent problem of Martensite Stainless Steel industry.
Summary of the invention
The problems referred to above that exist technically for existing Martensite Stainless Steel, the invention provides a kind of high-strong toughness high-strength plasticity Martensite Stainless Steel and preparation method thereof, to the independent or alloy element such as compound interpolation Ni, Si, Al in traditional Martensite Stainless Steel, and optionally add the micro alloying elements such as Mo, N, Nb, V, Ti, by thermal treatment process, control to introducing certain volume fractional in martensitic stucture and stable retained austenite is prepared into high-strong toughness high-strength plasticity Martensite Stainless Steel.
The composition of high-strong toughness high-strength plasticity Martensite Stainless Steel of the present invention is by weight percentage containing C 0.15 ~ 0.4%, and N 0 ~ 0.12%, and Si 0.2 ~ 2.5%, Mn 0.4 ~ 3.0%, S≤0.02%, P≤0.02%, Cr 13.0 ~ 17.0%, Ni 0 ~ 5.0%, and Mo 0 ~ 2.0%, and V 0 ~ 0.3%, Nb 0 ~ 0.2%, Ti 0 ~ 0.05%, and Al 0 ~ 0.8%, and surplus is Fe and inevitable impurity.
The yield strength of above-mentioned high-strong toughness high-strength plasticity Martensite Stainless Steel is 650 ~ 1250MPa, and tensile strength is 1300 ~ 1800MPa, unit elongation 16 ~ 25%, the summer than v-notch ballistic work at 20 ~ 105J.
Above-mentioned high-strong toughness high-strength plasticity Martensite Stainless Steel be organized as martensite and austenite, wherein austenitic volume fraction is 20 ~ 40%.
The preparation method of high-strong toughness high-strength plasticity Martensite Stainless Steel of the present invention carries out according to the following steps:
1, press set component melting molten steel, then solidify and make strand by continuous caster or mold; Its composition is by weight percentage containing C 0.15 ~ 0.4%, and N 0 ~ 0.12%, and Si 0.2 ~ 2.5%, Mn 0.4 ~ 3.0%, S≤0.02%, P≤0.02%, Cr 13.0 ~ 17.0%, Ni 0 ~ 5.0%, and Mo 0 ~ 2.0%, and V 0 ~ 0.3%, Nb 0 ~ 0.2%, Ti 0 ~ 0.05%, and Al 0 ~ 0.8%, and surplus is Fe and inevitable impurity;
2, strand hot rolling is made to hot rolling slab; Start rolling temperature during hot rolling is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 70 ~ 90%;
3, hot rolling slab is heated to 950 ~ 1100 ℃ of insulation 0.5 ~ 2h, then air cooling or oil cooling to 25 ~ 200 ℃, reheat to 350 ~ 500 ℃ of insulation 10 ~ 60min, and last air cooling, to room temperature, obtains high-strong toughness high-strength plasticity Martensite Stainless Steel.
Above-mentioned oil cooling is to adopting industrial quenching oil to carry out cooling.
Above-mentioned melting molten steel is melting under protective atmosphere condition, and protective atmosphere is argon gas or nitrogen.
In aforesaid method, when C adds weight total content >=0.3% of N in strand, carry out anneal after strand is rolled into slab, during annealing, Heating temperature is 850 ~ 900 ℃, is incubated 1 ~ 2h, cools to 400 ~ 500 ℃ with the furnace, then air cooling is to room temperature, then carry out step 3.
In tradition Martensite Stainless Steel, in the quenching structure of middle Low Carbon Martensite Stainless Steel, only contain≤5% retained austenite, only have the quenching structure of medium high carbon Martensite Stainless Steel just to contain >=10% retained austenite, but these austenitic less stable just can change martensite into when temperature reduces; Martensite Stainless Steel prepared by method of the present invention is introduced disperse and stable retained austenite in microstructure, has increased substantially the strong plasticity level of obdurability of Martensite Stainless Steel.
Method of the present invention by elements such as independent in traditional Martensite Stainless Steel or compound interpolation Ni, Si, Al to regulate martensitic transformation to start end (Mf) temperature improve stabilization of austenite of (Ms) temperature and martensitic transformation, and optionally add Mo, the element such as N, Nb, V, Ti is with raising intensity and corrosion resistance nature; When the weight content <0.3% of C and N, after controlling hot rolling slab heating, there is complete austenitizing, when weight content >=0.3% of C and N, after hot-work, carry out anneal, and heat and roll heating of plate blank incomplete austenitizing occurs in final thermal treatment time control; Heating austenitizing is controlled cooling termination temperature between Ms and Mf temperature later, obtains martensite and adds the tissue that residual austenite two-phase is master; Subsequently again heat up and insulating process in suppress the Carbide Precipitation in martensite, promote the carbon (nitrogen) in martensite to spread enrichment in austenite, the increase of carbon in austenite (nitrogen) content impels its stability to strengthen, and martensitic transformation does not occur in process of cooling again; Through normalizing-tempering (or being called quenching-partition), process the last microstructure that martensite adds retained austenite that obtains, give the combination of strength and toughness of this steel excellence and good corrosion resistance nature.
Accompanying drawing explanation
Fig. 1 is the figure of optical microstructure of the high-strong toughness high-strength plasticity Martensite Stainless Steel in the embodiment of the present invention 1;
Fig. 2 is the transmission electron microscope micro-organization chart (light field) of the high-strong toughness high-strength plasticity Martensite Stainless Steel in the embodiment of the present invention 1;
Fig. 3 is the transmission electron microscope micro-organization chart (details in a play not acted out on stage, but told through dialogues) of the high-strong toughness high-strength plasticity Martensite Stainless Steel in the embodiment of the present invention 1;
Fig. 4 is the figure of optical microstructure of the high-strong toughness high-strength plasticity Martensite Stainless Steel in the embodiment of the present invention 2;
Fig. 5 is the figure of optical microstructure of the high-strong toughness high-strength plasticity Martensite Stainless Steel in the embodiment of the present invention 3.
Embodiment
In the embodiment of the present invention, austenitic martensitic transformation starts the method for calculation of (Ms) temperature and is: Ms(℃)=539-430 * [C]-30 * [Mn]-12 * [Cr]-15 * [Ni]-7 * [Mo]-5.0 * [Si]; Wherein [C], [Mn], [Cr], [Ni], [Mo] and [Si] are respectively C, Mn, Cr, Ni, Mo and the Si weight content in Martensite Stainless Steel; The method of calculation that martensitic transformation finishes (Mf) temperature are: Mf(℃)=Ms-250; It should be noted that: at incomplete austenitizing state, austenitic composition is different from the original composition of steel, its Ms temperature can not be calculated by the original composition of steel, take and surveys as main.
In the embodiment of the present invention, by the method for GB GB/T 228-2002, test yield strength, tensile strength and unit elongation; The equipment adopting is the CMT5105 electronic universal tester that SANS company produces.
In the embodiment of the present invention, by the method for GB GB/T 229-1994, test the summer than v-notch ballistic work.
Embodiment 1
Press set component melting molten steel under protective atmosphere, protective atmosphere is nitrogen; By mold, solidify and make strand again; Its composition is by weight percentage containing C 0.15%, and Si 0.2%, and Mn 0.4%, and S 0.012%, and P 0.016%, and Cr 13.0%, and Ni 5.0%, and Mo 2.0%, and Nb 0.2%, and V 0.3%, and N 0.12%,, surplus is Fe and inevitable impurity;
Strand hot rolling is made to the hot rolling slab that 15mm is thick, and start rolling temperature is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 80%;
Hot rolling slab is heated to 950 ℃ of insulation 2h, then air cooling to 150 ℃,, reheat to 450 ℃ of insulation 10min, air cooling is to room temperature, obtain high-strong toughness high-strength plasticity Martensite Stainless Steel, yield strength is 873MPa, and tensile strength is 1445MPa, unit elongation 22.0%, summer at 70J, is organized as martensite and austenite than v-notch ballistic work, and austenitic volume fraction is 27%; As shown in Figure 1, as shown in Figure 2, as shown in Figure 3, in Fig. 3, shinny part is austenite to transmission electron microscope microstructure (details in a play not acted out on stage, but told through dialogues) to transmission electron microscope microstructure (light field) in optical microstructure, and dark part is martensite.
Embodiment 2
Press set component melting molten steel under protective atmosphere, protective atmosphere is argon gas; By mold, solidify and make strand again; Its composition is by weight percentage containing C 0.28%, and Si 2.5%, and Mn 3.0%, and S 0.008%, and P 0.019%, and Cr 13.0%, and Al 0.8%, and Mo 1.0%, and Nb 0.2%, and Ti 0.05%, and surplus is Fe and inevitable impurity;
Strand hot rolling is made to the hot rolling slab that 20mm is thick, and start rolling temperature is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 80%;
Hot rolling slab is heated to 1050 ℃ of insulation 2h, then air cooling to 25 ℃, reheats to 500 ℃ of insulation 60min, and air cooling is to room temperature, obtain high-strong toughness high-strength plasticity Martensite Stainless Steel, yield strength is 650MPa, and tensile strength is 1695MPa, unit elongation 25.0%, summer than v-notch ballistic work at 56J, be organized as martensite and austenite, austenitic volume fraction Wei40%， optical microstructure as shown in Figure 4.
Embodiment 3
Press set component melting molten steel under protective atmosphere, protective atmosphere is argon gas; By continuous caster, make strand again; Its composition is by weight percentage containing C 0.4%, and Si 0.6%, and Mn 0.4%, and S 0.015%, and P 0.013%, and Cr 17.0%, and Mo 1.0%, and V 0.3%, and Ni 2.8%, and surplus is Fe and inevitable impurity;
Strand hot rolling is made to the hot rolling slab that 25mm is thick, and start rolling temperature is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 70%;
Because C in strand adds weight total content >=0.3% of N, after hot rolling, carry out anneal, during anneal, be heated to 900 ℃ of insulation 2h, then cool to 500 ℃ with the furnace, then air cooling is to room temperature;
Hot rolling slab after anneal is heated to 1050 ℃ of insulation 0.5h, then adopt industrial quenching oil to be cooled to 100 ℃, reheat to air cooling after 350 ℃ of insulation 20min to room temperature, obtain high-strong toughness high-strength plasticity Martensite Stainless Steel, yield strength is 1250MPa, tensile strength is 1800MPa, unit elongation 16.6%, the summer at 20J, is organized as martensite and austenite than v-notch ballistic work, austenitic volume fraction Wei26%， optical microstructure as shown in Figure 5.
Embodiment 4
Press set component melting molten steel under protective atmosphere, protective atmosphere is argon gas; By continuous caster, make strand again; Its composition is by weight percentage containing C 0.22%, and Si 0.9%, and Mn 2.3%, and S 0.015%, and P 0.02%, and Cr 14.1%, and Ni 0.8%, and Mo 0.9%, and Nb 0.14%, and Ti 0.05%, and Al 0.36%, and surplus is Fe and inevitable impurity;
Strand hot rolling is made to the hot rolling slab that 15mm is thick, and start rolling temperature is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 90%;
Hot rolling slab is heated to 1000 ℃ of insulation 1.5h, then air cooling to 200 ℃, reheat to 500 ℃ insulation 20min after air cooling to room temperature, obtain high-strong toughness high-strength plasticity Martensite Stainless Steel, yield strength is 750MPa, and tensile strength is 1300MPa, unit elongation 23.5%, summer at 105J, is organized as martensite and austenite than v-notch ballistic work, and austenitic volume fraction is 20%.
Embodiment 5
Press set component melting molten steel under protective atmosphere, protective atmosphere is argon gas; By continuous caster, make strand again; Its composition is by weight percentage containing C 0.34%, and N 0.008%, and Si 1.2%, and Mn 1.5%, and S 0.017%, and P 0.02%, and Cr 14.8%, and Ni 1.8%, and Nb 0.05%, and Ti 0.05%, and surplus is Fe and inevitable impurity;
Strand hot rolling is made to the thick hot rolling slab of 25mm, and start rolling temperature is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 80%;
Because C in strand adds weight total content >=0.3% of N, after hot rolling, carry out anneal, 850 ℃ of annealing heating temperature, soaking time is 1h, cools to 400 ℃ after anneal with the furnace, air cooling is to room temperature;
Anneal air cooling to the hot rolling slab of room temperature is heated to 1100 ℃ of insulation 1.5h, then air cooling to 25 ℃, reheat to 450 ℃ of insulation 20min, last air cooling, to room temperature, obtains high-strong toughness high-strength plasticity Martensite Stainless Steel, yield strength is 695MPa, tensile strength is 1695MPa, unit elongation 23%, the summer than v-notch ballistic work at 39J, be organized as martensite and austenite, austenitic volume fraction is 36%.
Claims (5)
1. a high-strong toughness high-strength plasticity Martensite Stainless Steel, is characterized in that composition is by weight percentage containing C 0.15 ~ 0.4%, and N 0 ~ 0.12%, Si 0.2 ~ 2.5%, and Mn 0.4 ~ 3.0%, S≤0.02%, P≤0.02%, Cr 13.0 ~ 17.0%, and Ni 0 ~ 5.0%, Mo 0 ~ 2.0%, V 0 ~ 0.3%, and Nb 0 ~ 0.2%, and Ti 0 ~ 0.05%, Al 0 ~ 0.8%, and surplus is Fe and inevitable impurity.
2. a kind of high-strong toughness high-strength plasticity Martensite Stainless Steel according to claim 1, the yield strength that it is characterized in that high-strong toughness high-strength plasticity Martensite Stainless Steel is 650 ~ 1250MPa, tensile strength is 1300 ~ 1800MPa, unit elongation 16 ~ 25%, the summer than v-notch ballistic work at 20 ~ 105J.
3. a kind of high-strong toughness high-strength plasticity Martensite Stainless Steel according to claim 1, what it is characterized in that high-strong toughness high-strength plasticity Martensite Stainless Steel is organized as martensite and austenite, and wherein austenitic volume fraction is 20 ~ 40%.
4. a preparation method for high-strong toughness high-strength plasticity Martensite Stainless Steel claimed in claim 1, is characterized in that carrying out according to the following steps:
(1) press set component melting molten steel, then solidify and make strand by continuous caster or mold; Its composition is by weight percentage containing C 0.15 ~ 0.4%, and N 0 ~ 0.12%, and Si 0.2 ~ 2.5%, Mn 0.4 ~ 3.0%, S≤0.02%, P≤0.02%, Cr 13.0 ~ 17.0%, Ni 0 ~ 5.0%, and Mo 0 ~ 2.0%, and V 0 ~ 0.3%, Nb 0 ~ 0.2%, Ti 0 ~ 0.05%, and Al 0 ~ 0.8%, and surplus is Fe and inevitable impurity;
(2) strand hot rolling is made to hot rolling slab; Start rolling temperature during hot rolling is 1150 ± 50 ℃, and finishing temperature is 850 ± 50 ℃, and total reduction is 70 ~ 90%;
(3) hot rolling slab is heated to 950 ~ 1100 ℃ of insulation 0.5 ~ 2h, then air cooling or oil cooling to 25 ~ 200 ℃, reheat to 350 ~ 500 ℃ of insulation 10 ~ 60min, and last air cooling, to room temperature, obtains high-strong toughness high-strength plasticity Martensite Stainless Steel.
5. the preparation method of high-strong toughness high-strength plasticity Martensite Stainless Steel according to claim 4, while it is characterized in that C adds weight total content >=0.3% of N in strand, step is rolled into strand after slab in (2), carry out anneal, during annealing, Heating temperature is 850 ~ 900 ℃, is incubated 1 ~ 2h, cools to 400 ~ 500 ℃ with the furnace, air cooling, to room temperature, then carries out step (3) again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310652072.XA CN103614649B (en) | 2013-12-06 | 2013-12-06 | A kind of high-strong toughness high-strength plasticity Martensite Stainless Steel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310652072.XA CN103614649B (en) | 2013-12-06 | 2013-12-06 | A kind of high-strong toughness high-strength plasticity Martensite Stainless Steel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103614649A true CN103614649A (en) | 2014-03-05 |
| CN103614649B CN103614649B (en) | 2015-09-30 |
Family
ID=50165363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310652072.XA Expired - Fee Related CN103614649B (en) | 2013-12-06 | 2013-12-06 | A kind of high-strong toughness high-strength plasticity Martensite Stainless Steel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103614649B (en) |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087854A (en) * | 2014-06-17 | 2014-10-08 | 江苏金石铸锻有限公司 | Martensite stainless steel material |
| CN104294160A (en) * | 2014-09-09 | 2015-01-21 | 宝钢不锈钢有限公司 | High-hardness high-toughness low-carbon martensite stainless steel and manufacturing method thereof |
| CN104711482A (en) * | 2015-03-26 | 2015-06-17 | 宝钢不锈钢有限公司 | Nitrogen-controlled martensitic stainless steel and manufacturing method thereof |
| CN105568159A (en) * | 2015-12-22 | 2016-05-11 | 唐艺峰 | High-toughness stainless steel and preparation method thereof |
| CN105568169A (en) * | 2016-01-19 | 2016-05-11 | 溧阳市金昆锻压有限公司 | Martensitic stainless steel circular mould |
| CN106086699A (en) * | 2016-06-22 | 2016-11-09 | 成都成发科能动力工程有限公司 | A kind of large-scale turbomachinery blade and preparation method thereof |
| WO2017009435A1 (en) * | 2015-07-16 | 2017-01-19 | Sandvik Intellectual Property Ab | New martensitic stainless steel |
| CN106350642A (en) * | 2016-10-21 | 2017-01-25 | 上海远高阀业（集团）有限公司 | Technological method for manufacturing carbon steel gate valve and gate |
| CN106591730A (en) * | 2016-11-25 | 2017-04-26 | 邢台钢铁有限责任公司 | Low carbon martensite free-cutting stainless steel and production method thereof |
| CN106906429A (en) * | 2017-03-01 | 2017-06-30 | 西安交通大学 | A kind of superhigh intensity martensitic stain less steel and preparation method thereof |
| US9890436B2 (en) * | 2014-12-09 | 2018-02-13 | Voestalpine Precision Strip Ab | Stainless steel strip for flapper valves |
| CN108165891A (en) * | 2017-12-28 | 2018-06-15 | 北京北冶功能材料有限公司 | A kind of high-strength and high ductility of resistance to extreme environment low-carbon martensite cast steel and preparation method |
| CN108486503A (en) * | 2018-03-12 | 2018-09-04 | 东北大学 | A kind of continuous casting near-net forming preparation method of high carbon martensite stainless steel strip |
| CN109136764A (en) * | 2018-09-28 | 2019-01-04 | 共享铸钢有限公司 | A kind of production method of large thick-wall axis class steel-casting |
| CN109234631A (en) * | 2018-10-26 | 2019-01-18 | 山西太钢不锈钢股份有限公司 | A kind of low temperature resistant stainless steel and preparation method thereof |
| CN109321829A (en) * | 2018-11-06 | 2019-02-12 | 鞍钢股份有限公司 | Stainless steel plate with yield strength of 900MPa and manufacturing method thereof |
| CN109609729A (en) * | 2018-11-06 | 2019-04-12 | 鞍钢股份有限公司 | Stainless steel plate with 650 MPa-grade yield strength and manufacturing method thereof |
| CN109750222A (en) * | 2017-12-08 | 2019-05-14 | 上海落日新材料科技有限公司 | A kind of high-performance martensitic stain less steel and its high flatness board fabrication method |
| CN109811246A (en) * | 2019-03-14 | 2019-05-28 | 南京玖铸新材料研究院有限公司 | High-toughness heat-resistant cast stainless steel and its manufacturing method |
| CN110241364A (en) * | 2019-07-19 | 2019-09-17 | 东北大学 | A kind of high-strength plastic nano/submicron crystal cold-rolled 304 stainless steel strip and its preparation method |
| CN110527929A (en) * | 2019-08-21 | 2019-12-03 | 东北大学 | A kind of boronated stainless steel slab and preparation method thereof that plasticity and toughness are excellent |
| CN112501492A (en) * | 2019-09-16 | 2021-03-16 | 明安国际企业股份有限公司 | Composition alloys for golf club heads |
| CN112575261A (en) * | 2020-12-09 | 2021-03-30 | 广东省科学院材料与加工研究所 | Composite modified martensitic alloy cast steel and preparation method thereof |
| CN114032451A (en) * | 2021-09-25 | 2022-02-11 | 浙江吉森金属科技有限公司 | Stainless steel for valve plate and preparation method thereof |
| CN114196875A (en) * | 2021-09-25 | 2022-03-18 | 浙江吉森金属科技有限公司 | Stainless steel for valve plate and heat treatment method thereof |
| CN114395740A (en) * | 2022-01-07 | 2022-04-26 | 山西太钢不锈钢股份有限公司 | Niobium monostable sizing low-chromium martensitic stainless steel and preparation method thereof |
| CN114457284A (en) * | 2021-09-13 | 2022-05-10 | 北京机科国创轻量化科学研究院有限公司 | High-silicon stainless steel material containing vanadium and titanium and preparation method thereof |
| CN114457283A (en) * | 2021-09-13 | 2022-05-10 | 北京机科国创轻量化科学研究院有限公司 | High-silicon vanadium-titanium-containing stainless steel knife and shear material and preparation method thereof |
| CN114703343A (en) * | 2022-04-18 | 2022-07-05 | 山西太钢不锈钢股份有限公司 | High-strength and high-toughness super martensitic stainless steel extra-thick plate and heat treatment method and application thereof |
| CN115491585A (en) * | 2021-06-18 | 2022-12-20 | 大同特殊钢株式会社 | Martensitic stainless steel, and martensitic stainless steel component and manufacturing method thereof |
| CN115961217A (en) * | 2022-12-21 | 2023-04-14 | 青岛科技大学 | Heat treatment method and device for high-end cast steel pulping grinding disc |
| CN116426837A (en) * | 2023-05-18 | 2023-07-14 | 四川六合特种金属材料股份有限公司 | High-strength high-toughness corrosion-resistant plastic die steel and preparation method thereof |
-
2013
- 2013-12-06 CN CN201310652072.XA patent/CN103614649B/en not_active Expired - Fee Related
Cited By (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087854A (en) * | 2014-06-17 | 2014-10-08 | 江苏金石铸锻有限公司 | Martensite stainless steel material |
| CN104294160A (en) * | 2014-09-09 | 2015-01-21 | 宝钢不锈钢有限公司 | High-hardness high-toughness low-carbon martensite stainless steel and manufacturing method thereof |
| US9890436B2 (en) * | 2014-12-09 | 2018-02-13 | Voestalpine Precision Strip Ab | Stainless steel strip for flapper valves |
| CN104711482A (en) * | 2015-03-26 | 2015-06-17 | 宝钢不锈钢有限公司 | Nitrogen-controlled martensitic stainless steel and manufacturing method thereof |
| US11047028B2 (en) | 2015-07-16 | 2021-06-29 | Sandvik Intellectual Property Ab | Drill component |
| JP2018527458A (en) * | 2015-07-16 | 2018-09-20 | サンドビック インテレクチュアル プロパティー アクティエボラーグ | Drill component |
| WO2017009435A1 (en) * | 2015-07-16 | 2017-01-19 | Sandvik Intellectual Property Ab | New martensitic stainless steel |
| WO2017009436A1 (en) * | 2015-07-16 | 2017-01-19 | Sandvik Intellectual Property Ab | A drill component |
| US10941469B2 (en) | 2015-07-16 | 2021-03-09 | Ab Sandvik Materials Technology | Martensitic stainless steel |
| CN107923022A (en) * | 2015-07-16 | 2018-04-17 | 山特维克知识产权股份有限公司 | Novel martensitic stainless steel |
| JP2018524473A (en) * | 2015-07-16 | 2018-08-30 | サンドビック インテレクチュアル プロパティー アクティエボラーグ | New martensitic stainless steel |
| CN105568159A (en) * | 2015-12-22 | 2016-05-11 | 唐艺峰 | High-toughness stainless steel and preparation method thereof |
| CN105568169A (en) * | 2016-01-19 | 2016-05-11 | 溧阳市金昆锻压有限公司 | Martensitic stainless steel circular mould |
| CN106086699A (en) * | 2016-06-22 | 2016-11-09 | 成都成发科能动力工程有限公司 | A kind of large-scale turbomachinery blade and preparation method thereof |
| CN106350642A (en) * | 2016-10-21 | 2017-01-25 | 上海远高阀业（集团）有限公司 | Technological method for manufacturing carbon steel gate valve and gate |
| CN106591730A (en) * | 2016-11-25 | 2017-04-26 | 邢台钢铁有限责任公司 | Low carbon martensite free-cutting stainless steel and production method thereof |
| CN106906429B (en) * | 2017-03-01 | 2018-10-30 | 西安交通大学 | A kind of superhigh intensity martensitic stain less steel and preparation method thereof |
| CN106906429A (en) * | 2017-03-01 | 2017-06-30 | 西安交通大学 | A kind of superhigh intensity martensitic stain less steel and preparation method thereof |
| CN109750222A (en) * | 2017-12-08 | 2019-05-14 | 上海落日新材料科技有限公司 | A kind of high-performance martensitic stain less steel and its high flatness board fabrication method |
| CN108165891A (en) * | 2017-12-28 | 2018-06-15 | 北京北冶功能材料有限公司 | A kind of high-strength and high ductility of resistance to extreme environment low-carbon martensite cast steel and preparation method |
| CN108486503A (en) * | 2018-03-12 | 2018-09-04 | 东北大学 | A kind of continuous casting near-net forming preparation method of high carbon martensite stainless steel strip |
| CN109136764A (en) * | 2018-09-28 | 2019-01-04 | 共享铸钢有限公司 | A kind of production method of large thick-wall axis class steel-casting |
| CN109136764B (en) * | 2018-09-28 | 2021-02-12 | 共享铸钢有限公司 | Production method of large thick-wall shaft steel casting |
| CN109234631A (en) * | 2018-10-26 | 2019-01-18 | 山西太钢不锈钢股份有限公司 | A kind of low temperature resistant stainless steel and preparation method thereof |
| CN109609729B (en) * | 2018-11-06 | 2020-05-29 | 鞍钢股份有限公司 | A kind of stainless steel plate with yield strength of 650MPa and manufacturing method thereof |
| CN109609729A (en) * | 2018-11-06 | 2019-04-12 | 鞍钢股份有限公司 | Stainless steel plate with 650 MPa-grade yield strength and manufacturing method thereof |
| CN109321829A (en) * | 2018-11-06 | 2019-02-12 | 鞍钢股份有限公司 | Stainless steel plate with yield strength of 900MPa and manufacturing method thereof |
| CN109811246A (en) * | 2019-03-14 | 2019-05-28 | 南京玖铸新材料研究院有限公司 | High-toughness heat-resistant cast stainless steel and its manufacturing method |
| CN110241364B (en) * | 2019-07-19 | 2021-03-26 | 东北大学 | A kind of high-strength plastic nano/submicron crystal cold-rolled 304 stainless steel strip and preparation method thereof |
| CN110241364A (en) * | 2019-07-19 | 2019-09-17 | 东北大学 | A kind of high-strength plastic nano/submicron crystal cold-rolled 304 stainless steel strip and its preparation method |
| CN110527929A (en) * | 2019-08-21 | 2019-12-03 | 东北大学 | A kind of boronated stainless steel slab and preparation method thereof that plasticity and toughness are excellent |
| CN110527929B (en) * | 2019-08-21 | 2020-11-24 | 东北大学 | A boron-containing stainless steel plate with excellent plasticity and toughness and preparation method thereof |
| CN112501492A (en) * | 2019-09-16 | 2021-03-16 | 明安国际企业股份有限公司 | Composition alloys for golf club heads |
| CN112575261A (en) * | 2020-12-09 | 2021-03-30 | 广东省科学院材料与加工研究所 | Composite modified martensitic alloy cast steel and preparation method thereof |
| CN112575261B (en) * | 2020-12-09 | 2022-02-01 | 广东省科学院新材料研究所 | Composite modified martensitic alloy cast steel |
| CN115491585A (en) * | 2021-06-18 | 2022-12-20 | 大同特殊钢株式会社 | Martensitic stainless steel, and martensitic stainless steel component and manufacturing method thereof |
| CN114457283A (en) * | 2021-09-13 | 2022-05-10 | 北京机科国创轻量化科学研究院有限公司 | High-silicon vanadium-titanium-containing stainless steel knife and shear material and preparation method thereof |
| CN114457284B (en) * | 2021-09-13 | 2022-07-19 | 北京机科国创轻量化科学研究院有限公司 | High-silicon stainless steel material containing vanadium and titanium and preparation method thereof |
| CN114457284A (en) * | 2021-09-13 | 2022-05-10 | 北京机科国创轻量化科学研究院有限公司 | High-silicon stainless steel material containing vanadium and titanium and preparation method thereof |
| CN114032451A (en) * | 2021-09-25 | 2022-02-11 | 浙江吉森金属科技有限公司 | Stainless steel for valve plate and preparation method thereof |
| CN114196875B (en) * | 2021-09-25 | 2022-10-28 | 浙江吉森金属科技有限公司 | Stainless steel for valve plate and heat treatment method thereof |
| CN114196875A (en) * | 2021-09-25 | 2022-03-18 | 浙江吉森金属科技有限公司 | Stainless steel for valve plate and heat treatment method thereof |
| CN114395740A (en) * | 2022-01-07 | 2022-04-26 | 山西太钢不锈钢股份有限公司 | Niobium monostable sizing low-chromium martensitic stainless steel and preparation method thereof |
| CN114703343A (en) * | 2022-04-18 | 2022-07-05 | 山西太钢不锈钢股份有限公司 | High-strength and high-toughness super martensitic stainless steel extra-thick plate and heat treatment method and application thereof |
| CN114703343B (en) * | 2022-04-18 | 2024-04-26 | 山西太钢不锈钢股份有限公司 | Super martensitic stainless steel super-thick plate with high strength and toughness, heat treatment method and application thereof |
| CN115961217A (en) * | 2022-12-21 | 2023-04-14 | 青岛科技大学 | Heat treatment method and device for high-end cast steel pulping grinding disc |
| CN116426837A (en) * | 2023-05-18 | 2023-07-14 | 四川六合特种金属材料股份有限公司 | High-strength high-toughness corrosion-resistant plastic die steel and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103614649B (en) | 2015-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103614649A (en) | High-strength, high-toughness and high-plasticity martensitic stainless steel and preparation method thereof | |
| JP6829717B2 (en) | Online quenching cooling method and manufacturing method of seamless steel pipe using residual heat | |
| US11001916B2 (en) | Method for manufacturing a martensitic stainless steel part from a sheet | |
| CN102477518B (en) | Steel used for steam turbine blades and manufacturing method thereof | |
| CN104328359B (en) | High-toughness, easy-spinning and easy-welding ultrahigh-strength D506A steel and preparation method thereof | |
| US10837080B2 (en) | Rolled steel bar or rolled wire rod for cold-forged component | |
| CN102965568B (en) | Phase toughness Low Alloy Steel Plate and preparation method thereof | |
| JP5440203B2 (en) | Manufacturing method of high carbon hot rolled steel sheet | |
| CN105112782A (en) | Low-temperature ferrite LT-FH40 steel plate applied to hot-rolled ships and production method thereof | |
| JPWO2016136888A1 (en) | Ferritic heat resistant steel and its manufacturing method | |
| CN110423950A (en) | Manganese low-temperature steel and preparation method thereof in a kind of Fe-Mn-Al-C system | |
| CN106811580A (en) | A kind of annealing process of H13 hot die steels | |
| JP2012122111A (en) | Method for producing tmcp and tempering process type high-strength thick steel plate having both excellent productivity and weldability, and excellent in drop-weight characteristic after pwht | |
| JP2015183265A (en) | Method for producing steel material excellent in cold workability or machinability | |
| JP6056235B2 (en) | Method for producing high-tensile steel sheet with excellent weldability and delayed fracture resistance and tensile strength of 950 MPa or more | |
| KR101271968B1 (en) | Steel sheet for high temperature applications having excellent property after post weld heat treatment and method for manufacturing the same | |
| CN103469097B (en) | The corrosion-resistant tubing and casing of high strength martensitic ferrite diphasic stainless steel and manufacture method thereof | |
| JP2013227598A (en) | Iron casting and method for manufacturing the same | |
| JP5206056B2 (en) | Manufacturing method of non-tempered steel | |
| CN103805909A (en) | Preparation method of austenitic hot-work die steel | |
| JP5484135B2 (en) | Austenite + martensite duplex stainless steel sheet and method for producing the same | |
| JP2019504213A (en) | Warm rolled steel containing rollable austenite | |
| KR101410363B1 (en) | Method of manufacturing duplex stainless steel using post heat treatment | |
| CN102337472A (en) | Heat treatment method for piercing point of seamless pipe | |
| CN103228802B (en) | Method for quenching mold |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150930 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |