CN103589383A - Polyester resin composition used for flexible flat cables - Google Patents
Polyester resin composition used for flexible flat cables Download PDFInfo
- Publication number
- CN103589383A CN103589383A CN201310532362.0A CN201310532362A CN103589383A CN 103589383 A CN103589383 A CN 103589383A CN 201310532362 A CN201310532362 A CN 201310532362A CN 103589383 A CN103589383 A CN 103589383A
- Authority
- CN
- China
- Prior art keywords
- agent
- resin composition
- arranging wire
- soft arranging
- polyester resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 229920001225 polyester resin Polymers 0.000 title abstract description 4
- 239000004645 polyester resin Substances 0.000 title abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 16
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 9
- 239000011256 inorganic filler Substances 0.000 claims abstract description 8
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 8
- 239000004033 plastic Substances 0.000 claims abstract description 7
- 229920003023 plastic Polymers 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 6
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 5
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims abstract description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical group CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims abstract description 3
- 229920000728 polyester Polymers 0.000 claims description 15
- 239000011342 resin composition Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 11
- 230000008719 thickening Effects 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 2
- 239000004020 conductor Substances 0.000 abstract description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 239000003638 chemical reducing agent Substances 0.000 abstract 3
- 239000002562 thickening agent Substances 0.000 abstract 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 8
- 238000005452 bending Methods 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 239000002313 adhesive film Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 230000008054 signal transmission Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010051246 Photodermatosis Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a polyester resin composition used for flexible flat cables. The composition comprises, by mass: 42wt% of unsaturated polyester resin, 38wt% of a flame retardant, 13wt% of an inorganic filler, 3wt% of an anti-aging agent, 3wt% of a thickening agent, 0.5wt% of a viscosity reducer, and 0.5wt% of a normal temperature curing agent. The flame retardant is a halogen flame retardant, i.e. decabromodiphenylethane. The inorganic filler is titanium dioxide. The anti-aging agent is a plastic anti-aging agent. The thickening agent is matt powder. The viscosity reducer is an ME viscosity reducer. The normal temperature curing agent is methyl ethyl ketone peroxide or cyclohexanone peroxide. The composition not only has a stronger adhesive force to a metal conductor and an insulating layer, but also has good flame resistance and ageing resistance. The flexible flat cables prepared with the composition provided by the invention as an adhesive have excellent electric use performance.
Description
Technical field
The present invention relates to a kind of polyester resin adhesive, relate in particular to the polyester and resin composition for bonding soft arranging wire metallic conductor and insulation film.
Background technology
Soft arranging wire is a kind of flat data line assembly for signal transmission, there is deflection arbitrarily, high speed transmission of signals and can select arbitrarily the advantages such as wire number and spacing, making on line convenient, greatly reducing electronic product volume, reduce production costs, enhance productivity; Be widely used in being connected between the various electronic product moving-members such as computer, printer, mobile phone, liquid-crystal display and mainboard, in modern electrical equipment, almost ubiquitous.
Soft arranging wire mainly comprises metallic conductor, insulating thin layer and stiffening plate three parts, and wherein metallic conductor mostly adopts flat elongated copper conductor, and insulating thin layer mostly adopts PET insulating material, and stiffening plate is adhered to the two ends of soft arranging wire.Because soft rowed line structure is small and exquisite, core arrangement is dense, transmission information amount is large, but soft arranging wire is again often in the comparatively severe and complicated environment for use such as large in the temperature difference, frequent deflection and bending, chemical pollution, light pollution, very easily form the decline rapidly of colloid clinging power, metallic conductor is separated with insulating thin layer, the cracking of adhesive layer, insulation layer and distortion, cause insulation impedance between metallic conductor to decline, metallic conductor play or off normal, have a strong impact on soft arranging wire electrical property, even cause the interruption of data transmission.
Because use range and the use field of soft arranging wire are more and more extensive, and environment for use is ever-changing, this just not only requires soft arranging wire can meet high and low temperature environment, high/low-temperature impact, high humidity, corrosion resistant requirement, and to there is fire-retardant, wear-resisting, anti-frequency bending, aging-resistant Integrated using performance, obviously this wherein caking agent play an important role.Existing soft arranging wire caking agent is mostly used unsaturated polyester resin as caking agent, although unsaturated polyester resin processing performance is good, forming and hardening at normal temperatures and pressures, but unsaturated polyester resin is made soft arranging wire and is still had many deficiencies: while first solidifying due to unsaturated polyester resin, shrinking percentage is larger, and soft arranging wire exists the thickness of coating between metallic conductor top coat and conductor to differ, or the quality of unsaturated polyester resin is uneven, be easy to cause soft arranging wire clinging power everywhere inconsistent, bonding layer is easy to craze and transfiguration.Moreover unsaturated polyester resin has the good transparency, at light especially action of ultraviolet radiation, very easily there is photoetch, in addition under the comprehensive action that soft arranging wire stimulates at light, temperature variation and folding stress, be easy to form aging, affect work-ing life of soft arranging wire.Also have the flame retardant properties of unsaturated polyester resin, the service requirements that resistance to chemical corrosion is all not suitable with current soft arranging wire.
Summary of the invention
For the existing above-mentioned deficiency of prior art, technical problem to be solved by this invention is to provide a kind of soft arranging wire polyester and resin composition, and it not only has the clinging power of stronger metallic conductor and insulation layer, and has good flame retardant resistance and resistance to deterioration.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: a kind of soft arranging wire polyester and resin composition, is characterized in that: the composition of this polyester and resin composition and mass percent (wt%) are: the ambient cure agent of the unsaturated polyester resin of 42wt%, the fire retardant of 38wt%, 13wt% inorganic filler, the antiaging agent of 3wt%, the thickening material of 3wt%, 0.5wt% viscosity-depression agent, 0.5wt%.
Preferably, described fire retardant is halogen flame.Described halogen flame is TDE.
Preferably, described inorganic filler is titanium dioxide.
Preferably, described antiaging agent is plastic anti-aging agent.
Preferably, described thickening material is zero diopter powder.
Preferably, described viscosity-depression agent is polyethers viscosity-depression agent.
Preferably, described ambient cure agent is methylethyl ketone peroxide or cyclohexanone peroxide.
The present invention compared with prior art has following remarkable advantage:
1, adhesive film uniformity of the present invention is good, bonding strength is high.Due to the present invention preferred the mass ratioes in composition such as unsaturated polyester resin, weighting agent and viscosity-depression agent, composition is by interacting, and makes to take the adhesive film that unsaturated polyester resin is matrix homogeneous, and avoided appearance or the precipitation of bubble impurity.In composition of the present invention, unsaturated polyester resin has higher stretching, bending and compressive strength, and water-fast, acid-proof alkaline is excellent; Inorganic filler titanium dioxide not only has reinforcement, anti-aging and filling effect, and surface wettability is good, is easy to disperse antisolvent precipitation, can evenly mix with other material; Viscosity-depression agent effectively reduces the thixotropic viscosity causing due to components such as filler, thickening materials, reinforcement stream levelling and directive action in composition.The homogenous disperse effect of inorganic filler and viscosity-depression agent, the cloth that is beneficial to adhesive film is coated with, coat-thickness uniformity, thereby while having overcome well because of curable polyester resin, shrinking percentage is compared with the thickness of bringing greatly differ caused cracking, distortion, acting in conjunction performance and strengthened the adhesion strength of unsaturated polyester resin, is greatly enhanced the clinging power of metallic conductor and insulating thin layer in soft arranging wire.
2, the present invention has the feature of corrosion-resistant anti-aging, long service life.In the present composition, unsaturated polyester resin resistance to chemical corrosion is excellent, the antiaging agent adding not only has fabulous consistency with unsaturated polyester resin, and composition of the present invention is had can effectively strengthen ultraviolet radiation absorption power, and have long-acting antioxidant property concurrently, in organic weighting material titanium dioxide, the stability of titanium ion is high, be difficult to occur redox reaction, thereby erosion resistance is fabulous, and titanium dioxide specific refractory power is high, opaqueness is high, strong covering power, there is again fabulous anti-photoetch ability, this weighting material and antiaging agent have strengthened the resistance to chemical attack of unsaturated polyester resin effectively, made up unsaturated polyester height transparent, the weakness of anti-photoetch scarce capacity, make composition of the present invention have resistance to chemical attack concurrently, the over-all propertieies such as anti-photoetch, greatly extended the work-ing life of glued membrane, soft arranging wire can not only be adapted to high, low temperature environment, anti-height, low-temperature impact ability is strong, and erosion resistance is good, resist heat, photoaging effect is strong, clinging power is stable, can keep muchly its adhesive performance.
3, the present invention has good flame retardant properties.The present invention has selected organic weighting material, thickening material and the antiager with flame retardancy, and the present invention has added again fire retardant in composition on this basis, and this fire retardant and unsaturated polyester resin have fabulous consistency; The comprehensive interpolation of the compositions such as fire retardant has improved the flame retardant effect of soft arranging wire, can make soft arranging wire when being subject to extraneous burning things which may cause a fire disaster attack, can effectively stop, delay even to stop flame transmission, guarantees the safety and reliability of soft arranging wire data transmission.
4, cost performance of the present invention is high, ambient cure intensity is high.Because the present invention is usingd unsaturated polyester resin as matrix, and added the interpolation composition of easy acquisition, made composition of the present invention cheap, excellent performance, is convenient to make processing; In addition unsaturated polyester resin can at room temperature solidify, and processing performance is flexible, has especially added a certain amount of ambient cure agent, solidification value is lower, can at room temperature carry out, and completion of cure is thorough, solidification intensity is high, and the metallic conductor after solidifying in soft arranging wire and the clinging power of insulation film interlayer are strong.
To sum up state, the present invention has considered the interaction between each component, by a large amount of Experimental Comparisons, the specific component of component thing and the extra fine quality ratio of each component have been screened, formed and there is the extremely strong special bonding of soft arranging wire targetedly composition, its mechanism of action and effect depend on a large amount of real data contrasts more, through a large amount of Experimental Comparisons and the actual use under various environment, its clinging power, anti-high and low-temp impact capacity, resistance to chemical attack ability and flexible bending ability all obtain very large raising in prior art.
Embodiment
Below the specific embodiment of the invention is described in more detail.
Soft arranging wire of the present invention comprises the component of following weight parts with polyester and resin composition: unsaturated polyester resin 42wt%, TDE 38 wt%, titanium dioxide 13 wt%, plastic anti-aging agent 3 wt%, zero diopter powder (aerosil) 3 wt%, viscosity-depression agent 0.5 wt%, ambient cure agent 0.5 wt%.The line polymer that wherein unsaturated polyester resin is formed by monounsaturated dicarboxylic acid, unsaturated dibasic acid and dibasic alcohol polycondensation, through the resin solution with certain viscosity of cross-linking monomer or strong solvent dilution formation.Titanium dioxide adopts climbs steel Group Titanium industry company titanium powder plant product, plastic anti-aging agent adopts Dongguan Yuan Lin plastics company limited product, zero diopter powder is the aerosil product of Dongguan City De Ke Chemical Co., Ltd., viscosity-depression agent is the polyethers viscosity-depression agent (ME type viscosity-depression agent) of Dongguan Tong Cheng finishing material company limited, and ambient cure agent is Jiaxing City Nanhu District Dong Shanhuafei synthetic materials factory product.
During making, first choosing monounsaturated dicarboxylic acid, unsaturated dibasic acid and dibasic alcohol mixes in proportion, and add the additives such as thinner, stopper through fully making unsaturated polyester resin after stirring in this mixture, the preparation of unsaturated polyester resin all adopts the manufacture craft of conventional raw materials.After making the unsaturated polyester resin with certain viscosity, in unsaturated polyester resin by mass ratio of the present invention add successively TDE, titanium dioxide, plastic anti-aging agent, zero diopter powder, ME viscosity-depression agent and ambient cure agent again through abundant blending stir and composition of the present invention.
The inventor is through carrying out debugging and Performance Detection repeatedly to the component of said composition and each component mass ratio, facts have proved and depart from above-mentioned component and proportioning, adjust its component of variation or ratio range and be all difficult to the performance index that reach desirable, even have performance index to become bad trend, so contriver show that said composition component and mass ratio have the conclusion of uniqueness and excellent properties index.Contriver be take said composition as caking agent making FFC soft arranging wire, and to this soft arranging wire carry out high temperature test, low-temperature test, temperature cycling test, humid test, flame retardant test, 180 ° of bending tests, wearability test, thickness detect and metallic conductor is tested with insulation layer clinging power, test result is not only much better than existing FFC production reliability touchstone, and the data such as temperature cycling test, 180 ° of bending tests and clinging power test are particularly excellent.
Claims (8)
1. a soft arranging wire polyester and resin composition, is characterized in that: the composition of this polyester and resin composition and mass percent (wt%) are: the ambient cure agent of the unsaturated polyester resin of 42wt%, the fire retardant of 38wt%, 13wt% inorganic filler, the antiaging agent of 3wt%, the thickening material of 3wt%, 0.5wt% viscosity-depression agent, 0.5wt%.
2. soft arranging wire polyester and resin composition according to claim 1, is characterized in that: described fire retardant is halogen flame.
3. soft arranging wire polyester and resin composition according to claim 2, is characterized in that: described halogen flame is TDE.
4. soft arranging wire polyester and resin composition according to claim 1, is characterized in that: described inorganic filler is titanium dioxide.
5. soft arranging wire polyester and resin composition according to claim 1, is characterized in that: described antiaging agent is plastic anti-aging agent.
6. soft arranging wire polyester and resin composition according to claim 1, is characterized in that: described thickening material is zero diopter powder.
7. soft arranging wire polyester and resin composition according to claim 1, is characterized in that: described viscosity-depression agent is polyethers viscosity-depression agent.
8. soft arranging wire polyester and resin composition according to claim 1, is characterized in that: described ambient cure agent is methylethyl ketone peroxide or cyclohexanone peroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532362.0A CN103589383B (en) | 2013-11-03 | 2013-11-03 | Polyester resin composition used for flexible flat cables |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532362.0A CN103589383B (en) | 2013-11-03 | 2013-11-03 | Polyester resin composition used for flexible flat cables |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103589383A true CN103589383A (en) | 2014-02-19 |
| CN103589383B CN103589383B (en) | 2015-03-25 |
Family
ID=50079712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310532362.0A Active CN103589383B (en) | 2013-11-03 | 2013-11-03 | Polyester resin composition used for flexible flat cables |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103589383B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106957630A (en) * | 2017-02-28 | 2017-07-18 | 江苏金坤科技有限公司 | A kind of Environmental-friendhot hot melt adhesive |
| CN107057624A (en) * | 2017-04-25 | 2017-08-18 | 江苏金坤科技有限公司 | A kind of PUR, a kind of PI hot melt adhesive films and a kind of preparation method of PI hot melt adhesive films |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1364184A (en) * | 2000-01-18 | 2002-08-14 | 通用电气公司 | Curable resin composition, preparation thereof, and articles derived therefrom |
| CN1878814A (en) * | 2004-10-12 | 2006-12-13 | 德古萨公司 | Radiation curable modified, unsaturated, amorphous polyesters |
| JP2011208078A (en) * | 2010-03-30 | 2011-10-20 | Hitachi Cable Ltd | Flame-retardant adhesive composition, and flat cable using the same |
| CN102300901A (en) * | 2009-01-30 | 2011-12-28 | 味之素株式会社 | Resin composition |
| CN102575050A (en) * | 2009-08-10 | 2012-07-11 | 联合碳化化学及塑料技术有限责任公司 | Thermoplastic elastomer compositions comprising intumescent flame retardants and non-phosphorous-based flame retardant synergists |
| CN102732171A (en) * | 2011-04-07 | 2012-10-17 | 日立电线株式会社 | Adhesive film and flat cable using same |
-
2013
- 2013-11-03 CN CN201310532362.0A patent/CN103589383B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1364184A (en) * | 2000-01-18 | 2002-08-14 | 通用电气公司 | Curable resin composition, preparation thereof, and articles derived therefrom |
| CN1878814A (en) * | 2004-10-12 | 2006-12-13 | 德古萨公司 | Radiation curable modified, unsaturated, amorphous polyesters |
| CN102300901A (en) * | 2009-01-30 | 2011-12-28 | 味之素株式会社 | Resin composition |
| CN102575050A (en) * | 2009-08-10 | 2012-07-11 | 联合碳化化学及塑料技术有限责任公司 | Thermoplastic elastomer compositions comprising intumescent flame retardants and non-phosphorous-based flame retardant synergists |
| JP2011208078A (en) * | 2010-03-30 | 2011-10-20 | Hitachi Cable Ltd | Flame-retardant adhesive composition, and flat cable using the same |
| CN102732171A (en) * | 2011-04-07 | 2012-10-17 | 日立电线株式会社 | Adhesive film and flat cable using same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106957630A (en) * | 2017-02-28 | 2017-07-18 | 江苏金坤科技有限公司 | A kind of Environmental-friendhot hot melt adhesive |
| CN107057624A (en) * | 2017-04-25 | 2017-08-18 | 江苏金坤科技有限公司 | A kind of PUR, a kind of PI hot melt adhesive films and a kind of preparation method of PI hot melt adhesive films |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103589383B (en) | 2015-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102523921B1 (en) | High-frequency resin composition and its application | |
| CN106280698B (en) | High-temperature-resistant PI white label ink and preparation method thereof | |
| CN101851390B (en) | Black halogen-free epoxy resin composition and cover film prepared by using same | |
| CN105542470A (en) | Conductive rubber composition and preparing method thereof | |
| CN110669336B (en) | A kind of modified fluorine-containing polyimide resin composition and preparation method thereof | |
| CN103694639B (en) | A kind of Halogen ageing-resistant epoxy resin composition and prepare the method for mulch film with this resin combination | |
| CN102040808A (en) | Glass fiber enhanced PET/PBT (Polyethylene Terephthalate)/(Polybutylene Terephthalate) alloy with high glossiness and low warping degree and preparation method thereof | |
| CN103589383B (en) | Polyester resin composition used for flexible flat cables | |
| CN104673111A (en) | Formula and preparation method of epoxy resin based anisotropic conductive adhesive film | |
| CN104672831A (en) | High-toughness strengthened flame-retardant anti-aging PC composition | |
| CN101704993A (en) | PET/LCP flame-retardant plastic and preparation method thereof | |
| CN103183940A (en) | Impact-modified unsaturated polyester glass fibre reinforced plastic moulding compound | |
| CN112341865B (en) | CNT (carbon nanotube), SNC (sodium stannate) and PEDOT (PEDOT-ethylene glycol terephthalate) ternary aqueous conductive ink and preparation method thereof | |
| CN101514281A (en) | Conductive silver ink for encapsulating LED and preparation method thereof | |
| CN108587098B (en) | Corrosion-resistant unsaturated polyester resin and preparation method and application thereof | |
| CN103254635A (en) | Rare earth modified toughening nylon material and its preparation method | |
| CN102911457A (en) | Acrylonitrile butadiene styrene (ABS) blending modification polyvinyl chloride (PVC) spool and preparation method thereof | |
| CN103183942A (en) | Unsaturated polyester glass fibre reinforced plastic moulding compound | |
| CN105802172A (en) | Low-shrinkage stable bulk molding compound | |
| CN103509160A (en) | Composite bulk molding compound filled with inorganic nano particles and preparation method for composite bulk molding compound | |
| CN107266844A (en) | A kind of bloom scratch-resistant flame retardant PS composites and preparation method thereof | |
| CN103160094A (en) | Halogen-free flame-retardation polystyrene-modified unsaturated polyester glass reinforced plastic molding compound | |
| CN105419277B (en) | A kind of low-dielectric energy composite | |
| CN102924878B (en) | PET composite material, and preparation method and application thereof | |
| CN102977569A (en) | High fire retardation unsaturated polyester molding compound preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160222 Address after: 224212 Jiangsu province Yancheng City Qindong town of stainless steel industrial park Patentee after: JIANGSU JINKUN TECHNOLOGY CO., LTD. Address before: 224212 Jiangsu province Yancheng City Qindong town of stainless steel industrial park Patentee before: JIANGSU JINHAN ELECTRONIC TECHNOLOGY DEVELOPMENT CO., LTD. |