CN103589266B - A kind of preparation method of oiliness stain control agent and application thereof - Google Patents
A kind of preparation method of oiliness stain control agent and application thereof Download PDFInfo
- Publication number
- CN103589266B CN103589266B CN201310568762.7A CN201310568762A CN103589266B CN 103589266 B CN103589266 B CN 103589266B CN 201310568762 A CN201310568762 A CN 201310568762A CN 103589266 B CN103589266 B CN 103589266B
- Authority
- CN
- China
- Prior art keywords
- mass parts
- mass
- parts
- preparation
- control agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 230000003373 anti-fouling effect Effects 0.000 claims abstract description 8
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920006026 co-polymeric resin Polymers 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 7
- YGUFXEJWPRRAEK-UHFFFAOYSA-N dodecyl(triethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OCC)(OCC)OCC YGUFXEJWPRRAEK-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 polysiloxane Polymers 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 3
- 239000002519 antifouling agent Substances 0.000 claims description 25
- 239000002969 artificial stone Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 239000004567 concrete Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 4
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 abstract description 2
- 238000013019 agitation Methods 0.000 abstract 1
- 238000010288 cold spraying Methods 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- 239000004575 stone Substances 0.000 description 3
- 240000002853 Nelumbo nucifera Species 0.000 description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 235000020095 red wine Nutrition 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000013555 soy sauce Nutrition 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000015113 tomato pastes and purées Nutrition 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
技术领域 technical field
本发明属于防污剂制备技术领域，特别涉及一种油性防污剂的制备方法及其应用。该防污剂用于人造石材成品的防污保护处理，包括人造岗石、石英石、实体面材类人造石材台面、墙面、卫浴星盆等的表面防污处理。 The invention belongs to the technical field of antifouling agent preparation, in particular to a preparation method and application of an oily antifouling agent. The antifouling agent is used for antifouling protection treatment of artificial stone products, including surface antifouling treatment of artificial granite, quartz stone, solid surface artificial stone countertops, walls, bathroom basins, etc.
背景技术 Background technique
人造石材因为其性能好、具有色彩艳丽、光洁度高、颜色均匀一致，抗压耐磨、韧性好、结构致密、坚固耐用、比重轻、不吸水、耐侵蚀风化、色差小、不褪色、放射性低等优点。具有资源综合利用的优势，在环保节能方面具有不可低估的作用，也是名副其实的建材绿色环保产品。已成为现代建筑首选的饰面材料。但是人造石材作为装饰面材，目前有个很大的问题影响其外观效果的持久性，那就是易污染，尤其是实体面材类人造石产品，用于生活中，很容易受一些生活食品、日用品、灰尘、污水等污染变脏，影响其持续装饰效果。 Artificial stone because of its good performance, bright color, high finish, uniform color, compression and wear resistance, good toughness, compact structure, strong and durable, light specific gravity, non-absorbent, corrosion and weathering resistance, small color difference, no fading, low radioactivity Etc. It has the advantages of comprehensive utilization of resources, and has an inestimable role in environmental protection and energy saving. It is also a veritable green building material product. It has become the preferred finishing material for modern buildings. However, artificial stone as a decorative surface material currently has a big problem that affects the durability of its appearance effect, that is, it is easy to pollute, especially solid surface material artificial stone products, which are easily affected by some daily food, Daily necessities, dust, sewage and other pollution become dirty, affecting its continuous decorative effect.
本发明针对人造石材树脂基、吸水率低等特性，特别制备一种人造石材用油性防污剂，选用成膜树脂、表面张力小的憎水憎油氟硅材料等搭配，配制一种成膜型防污剂，用于喷涂于人造石材表面，既不影响装饰效果，又能有效的隔离各种污迹侵染。 According to the characteristics of artificial stone resin base and low water absorption, the present invention specially prepares an oily antifouling agent for artificial stone, and uses film-forming resin, water-repellent and oil-repellent fluorosilicon material with small surface tension to prepare a film-forming A type of antifouling agent, used for spraying on the surface of artificial stone, it does not affect the decorative effect, and can effectively isolate various stains.
发明内容 Contents of the invention
本发明的目的是提供一种油性防污剂的制备方法及其应用。 The purpose of the present invention is to provide a kind of preparation method and application of oily antifouling agent.
油性防污剂的制备方法具体步骤为： The preparation method concrete steps of oily antifouling agent are:
将50~90质量份的异丙醇加入反应釜中，保持温度在20℃~30℃，待温度控制后，开始以100~1200转/分钟的搅拌速率搅拌，然后依次将3~10质量份的十二烷基三乙氧基硅烷、5~30质量份的氟硅共聚树脂、2~10质量份的反应性聚硅氧烷、0.1~0.5质量份铝钛复合偶联剂和0.1~0.5质量份缩二脲固化剂加入反应釜中，加料期间保持搅拌状态，加料完毕后以200~2000转/分钟的转速持续搅拌混合5~20分钟，制得无色的透明液体即为油性防污剂。 Add 50~90 parts by mass of isopropanol into the reaction kettle, keep the temperature at 20°C~30°C, after the temperature is controlled, start stirring at a stirring rate of 100~1200 rpm, and then add 3~10 parts by mass of Dodecyltriethoxysilane, 5-30 parts by mass of fluorosilicone copolymer resin, 2-10 parts by mass of reactive polysiloxane, 0.1-0.5 parts by mass of aluminum-titanium composite coupling agent and 0.1-0.5 parts by mass Add parts by mass of biuret curing agent into the reaction kettle, keep stirring during the feeding, and continue stirring and mixing at a speed of 200~2000 rpm for 5~20 minutes after the feeding is completed, and a colorless transparent liquid is obtained, which is oily antifouling agent.
本发明所制得的油性防污剂应用于人造石材成品的表面防污保护处理。 The oily antifouling agent prepared by the invention is applied to the surface antifouling protection treatment of artificial stone products.
本发明的优点如下： The advantages of the present invention are as follows:
(1)本发明所用的原料便宜易得，制备方法简单。 (1) The raw materials used in the present invention are cheap and easy to obtain, and the preparation method is simple.
(2)本发明制得的油性防污剂使用方法简单，常温喷涂即可，效果持久，憎水污憎油污，防污效果明显。 (2) The oily antifouling agent prepared by the invention is simple to use, can be sprayed at room temperature, has a long-lasting effect, is water-repellent and oil-repellent, and has an obvious antifouling effect.
(3)本发明制得的油性防污剂专门针对人造石材特性特制，比市场上其它天然石材的防护剂更实用。 (3) The oily antifouling agent prepared by the present invention is specially made for the characteristics of artificial stone, and is more practical than other natural stone protective agents on the market.
具体实施方式 Detailed ways
实施例1：Example 1:
本实施例制备油性防污剂的主要原料是异丙醇（工业级）、十二烷基三乙氧基硅烷（工业级）、氟硅共聚树脂（工业级）、反应性聚硅氧烷（工业级）、缩二脲固化剂（工业级）和铝钛复合偶联剂（工业级）。 The main raw materials for preparing oily antifouling agent in this example are isopropanol (industrial grade), dodecyltriethoxysilane (industrial grade), fluorosilicone copolymer resin (industrial grade), reactive polysiloxane ( Industrial grade), biuret curing agent (industrial grade) and aluminum-titanium composite coupling agent (industrial grade).
制备油性防污剂的具体步骤为： The concrete steps of preparing oily antifouling agent are:
将70千克的异丙醇加入反应釜中，保持温度25℃，待温度控制后，开始以800转/分钟的搅拌速率搅拌，然后依次将5千克的十二烷基三乙氧基硅烷、20千克的氟硅共聚树脂、4.3千克的反应性聚硅氧烷、0.4千克铝钛复合偶联剂和0.3千克缩二脲固化剂加入反应釜中，加料期间保持搅拌状态，加料完毕以1200转/分钟的转速持续搅拌混合10分钟，制得无色的透明液体即为油性防污剂。 Add 70 kg of isopropanol into the reaction kettle, keep the temperature at 25°C, and after the temperature is controlled, start stirring at a stirring rate of 800 rpm, and then add 5 kg of dodecyltriethoxysilane, 20 Add kilograms of fluorosilicone copolymer resin, 4.3 kilograms of reactive polysiloxane, 0.4 kilograms of aluminum-titanium composite coupling agent and 0.3 kilograms of biuret curing agent into the reactor, keep stirring during the feeding, and complete the feeding at 1200 rpm Continue stirring and mixing at a speed of 10 minutes for 10 minutes to obtain a colorless transparent liquid, which is an oily antifouling agent.
本实施例所制备的油性防污剂的应用： The application of the prepared oily antifouling agent of the present embodiment:
将制备的油性防污剂涂于人造岗石表面，待24小时常温自然固化后，将酱油、番茄酱、墨水、红酒、水性大头笔、油性大头笔等这些能对未处理人造石产生污染的污迹洒于其表面，24小时后，清水清洗，无残留污迹、荷叶效应产生。按GB/T3810.14—1999防污级别从原来2级提高到5级以上。 Apply the prepared oil-based antifouling agent on the surface of artificial stone, and after 24 hours of natural curing at room temperature, apply soy sauce, tomato paste, ink, red wine, water-based pens, oil-based pens, etc. that can pollute untreated artificial stones. Stains are sprinkled on the surface, and after 24 hours, rinse with clean water without residual stains and lotus leaf effect. According to GB/T3810.14-1999, the anti-fouling level is raised from the original level 2 to level 5 or above.
实施例2:Example 2:
本实施例制备油性防污剂的主要原料是异丙醇（工业级）、十二烷基三乙氧基硅烷（工业级）、氟硅共聚树脂（工业级）、反应性聚硅氧烷（工业级）、缩二脲固化剂（工业级）和铝钛复合偶联剂（工业级）。 The main raw materials for preparing oily antifouling agent in this example are isopropanol (industrial grade), dodecyltriethoxysilane (industrial grade), fluorosilicone copolymer resin (industrial grade), reactive polysiloxane ( Industrial grade), biuret curing agent (industrial grade) and aluminum-titanium composite coupling agent (industrial grade).
制备油性防污剂的具体步骤为： The concrete steps of preparing oily antifouling agent are:
将80千克的异丙醇加入反应釜中，保持温度25℃，待温度控制后，开始以600转/分钟的搅拌速率搅拌，然后依次将5千克的十二烷基三乙氧基硅烷、10千克的氟硅共聚树脂、4.2千克的反应性聚硅氧烷、0.4千克铝钛复合偶联剂和0.4千克缩二脲固化剂加入反应釜中，加料期间保持搅拌状态，加料完毕以1000转/分钟的转速持续搅拌混合15分钟，制得无色的透明液体即为油性防污剂。 Add 80 kilograms of isopropanol into the reaction kettle, keep the temperature at 25°C, and after the temperature is controlled, start stirring at a stirring rate of 600 rpm, and then add 5 kilograms of dodecyltriethoxysilane, 10 Add kilograms of fluorosilicone copolymer resin, 4.2 kilograms of reactive polysiloxane, 0.4 kilograms of aluminum-titanium composite coupling agent and 0.4 kilograms of biuret curing agent to the reactor, keep stirring during the feeding, and complete the feeding at 1000 rpm Continue stirring and mixing at a speed of 15 minutes for 15 minutes to obtain a colorless transparent liquid, which is an oily antifouling agent.
本实施例所制备的油性防污剂的应用： The application of the prepared oily antifouling agent of the present embodiment:
将制备的油性防污剂涂用于人造石英石表面，待24小时常温自然固化后，将酱油、番茄酱、墨水、红酒、水性大头笔、油性大头笔等这些能对未处理人造石产生污染的污迹洒于其表面，24小时后，清水清洗，无残留污迹、荷叶效应产生。按GB/T3810.14—1999防污级别从原来2级提高到5级以上。 Apply the prepared oil-based antifouling agent to the surface of artificial quartz stone. After 24 hours of natural curing at room temperature, apply soy sauce, tomato sauce, ink, red wine, water-based pen, oil-based pen, etc. to the untreated artificial stone. Sprinkle stains on the surface, after 24 hours, wash with water, no residual stains, lotus leaf effect. According to GB/T3810.14-1999, the anti-fouling level is raised from the original level 2 to level 5 or above.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568762.7A CN103589266B (en) | 2013-11-15 | 2013-11-15 | A kind of preparation method of oiliness stain control agent and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568762.7A CN103589266B (en) | 2013-11-15 | 2013-11-15 | A kind of preparation method of oiliness stain control agent and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103589266A CN103589266A (en) | 2014-02-19 |
| CN103589266B true CN103589266B (en) | 2015-11-18 |
Family
ID=50079598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310568762.7A Active CN103589266B (en) | 2013-11-15 | 2013-11-15 | A kind of preparation method of oiliness stain control agent and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103589266B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815245B (en) * | 2017-11-02 | 2019-12-10 | 深圳市华宇节耗电子有限公司 | Application of dodecyl triethoxy silane, tin surface protective agent for PCB manufacturing and tin surface protection method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376755A (en) * | 2001-03-27 | 2002-10-30 | 中国科学院化学研究所 | Surface protecting agent for stone of building and its preparing process |
| CN101020750A (en) * | 2007-03-16 | 2007-08-22 | 西北工业大学 | Silicone antifoulant and its prepn |
| CN101875801A (en) * | 2009-04-30 | 2010-11-03 | 北京创意创新经济技术中心 | Product serving as coating or paint |
| CN102174290A (en) * | 2011-02-14 | 2011-09-07 | 成都理工大学 | Method for preparing ceramic tile antifouling agent |
-
2013
- 2013-11-15 CN CN201310568762.7A patent/CN103589266B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376755A (en) * | 2001-03-27 | 2002-10-30 | 中国科学院化学研究所 | Surface protecting agent for stone of building and its preparing process |
| CN101020750A (en) * | 2007-03-16 | 2007-08-22 | 西北工业大学 | Silicone antifoulant and its prepn |
| CN101875801A (en) * | 2009-04-30 | 2010-11-03 | 北京创意创新经济技术中心 | Product serving as coating or paint |
| CN102174290A (en) * | 2011-02-14 | 2011-09-07 | 成都理工大学 | Method for preparing ceramic tile antifouling agent |
Non-Patent Citations (1)
| Title |
|---|
| 氟硅防污剂的合成、复配及其作用机理研究;沈一丁等;《精细化工》;20090731;第26卷(第7期);第711-714、723页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103589266A (en) | 2014-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102584133B (en) | Emulsion bi-component interface agent and preparation method for emulsion bi-component interface agent | |
| CN104403400B (en) | A kind of anti-crack mastic and using method thereof | |
| CN103305124B (en) | Nano-meter SiO_22Composite organic fluoro-resin antifouling paint and its preparation method | |
| CN109692797A (en) | A kind of preparation method of aluminum veneer | |
| CN110105017A (en) | A kind of decorative concrete products and preparation method thereof | |
| CN110330295A (en) | A kind of water-resistant type interfacial agents and its construction method, application | |
| CN102531489B (en) | Middle elastic relief rough coating | |
| CN104448965B (en) | Preparation method of super-weatherable silicate system inorganic coating with self-cleaning function | |
| CN104694003A (en) | Anti-fouling waterproof stone-like coating | |
| CN104110112A (en) | Building wall decoration mortar construction technology | |
| CN103589266B (en) | A kind of preparation method of oiliness stain control agent and application thereof | |
| JP5166336B2 (en) | Coating method | |
| CN103332884B (en) | Colorful heat insulation coating mortar as well as manufacturing method and application thereof | |
| CN207453315U (en) | A kind of aluminium plastic sheet-imitation type coat system of high resistant | |
| CN107419858A (en) | A kind of inner wall render smears construction method | |
| CN103589248A (en) | Coating with marble-like texture | |
| CN202299325U (en) | Paving system for colorful anti-skidding wear-resisting floor | |
| CN103131277A (en) | High temperature-resistant no-shedding paint and preparation method thereof | |
| CN105330192B (en) | Interface treating agent and preparation method thereof | |
| CN105712646A (en) | Inorganic wear-resistant seal solidification agent | |
| CN109575698A (en) | Historical relic's protection performed polymer material and preparation method and guard method | |
| CN101440232A (en) | Multifunctional thick pulp nano colorful wall artistic paint | |
| JP2020029549A (en) | Hydrophilic coating agent | |
| CN101235256A (en) | Cement binder, road marking cement paint and method for making road markings | |
| CN110079207A (en) | A kind of cement foundation wall ground high rigidity water paint and one are all over the molding construction method of scumbling |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140219 Assignee: Guilin Juge Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2022450000141 Denomination of invention: Preparation and Application of an Oily Antifouling Agent Granted publication date: 20151118 License type: Common License Record date: 20221123 |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140219 Assignee: Nanning Zhongli Environmental Protection Equipment Processing Factory Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2022450000530 Denomination of invention: Preparation and Application of an Oily Antifouling Agent Granted publication date: 20151118 License type: Common License Record date: 20221229 |
|
| EE01 | Entry into force of recordation of patent licensing contract |