CN103588507A - White-dotted stereoscopic decorative glazed ceramic product and preparation method thereof - Google Patents
White-dotted stereoscopic decorative glazed ceramic product and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a ceramic product and a preparation method thereof, particularly to a white-dotted stereoscopic decorative glazed ceramic product and a preparation method thereof. The preparation method comprises the steps of applying ground glaze onto a bisque ceramic body with a glaze dipping method, spraying decorative glaze onto the ceramic body from the top down in a gradual change manner, and performing glaze firing after drying. The method employs specially prepared ground glaze and decorative glaze formulae, a specific firing technology, and particularly heating rate control, so that the ceramic product with the white-dotted stereoscopic decorative glaze is prepared; the adopted ground glaze is low in initial smelting point, so that the body and the glaze can be tightly combined; a glaze surface is flat, smooth and clean; the product has a smooth and soft surface, and is vigorous and elegant; the decorative glaze is high in initial solubility, and is slightly soluble in low glaze to form white-dotted stereoscopic glaze with an unique stereoscopic artistic effect; a novel glaze surface with artistic beauty is provided for glaze surface art; a product grade is raised; and new market demands are met.
Description
Technical field
The present invention relates to ceramic and preparation method thereof, be specifically related to a kind of white point stereo decoration glaze ceramic and preparation method thereof.
Background technology
Traditional glazed ceramics goods are generally a kind of primitive colour, and surface is light face, dull coloring, and product is difficult to propose shelves upgrading, can not meet the cultural demand of multi-level, the multi-field consumer group to ceramic.
Summary of the invention
To the object of the invention is, in order addressing the above problem, to adopt rational glaze formula and firing process, provide a kind of with white point stereo decoration glaze ceramic and preparation method, concrete technical scheme is:
White point stereo decoration glaze ceramic, adopts the method for soaking glaze to execute upper ground-coat enamel by ceramic body after biscuiting, then ceramic body from top to bottom gradual change spray decoration glaze, glaze firing after dry.
Described glaze firing, adopts roller kiln oxydizing flame to burn till; Firing period is 4.5-5 hours, and firing temperature is controlled and is: first heat up stage by stage successively, kiln temperature at the uniform velocity rose to 900 ℃ by kiln temperature in 1-1.5 hours, secondly in 1-1.5 hours, at the uniform velocity rises to 1190-1200 ℃;
Then, cooling was stage by stage down to 1080 ℃ in 20-30 minutes successively, secondly in 20 minutes, was down to fast 850 ℃, then in 0.5-1 hour, was down at a slow speed 650 ℃, finally naturally cooled to room temperature, burnt till kiln discharge.
Described ground-coat enamel, is prepared burden according to parts by weight by following ground-coat enamel raw material, feldspar 25-30 part, quartzy 15-20 part, Suzhou soil 5-8 part, calcite 10-15 part, rhombspar 10-15 part, glass powder 8-10 part, Strontium carbonate powder 4-5 part, pigment 8-10 part;
Press the weight ratio=1 ﹕ 1.25-1.35 ﹕ 1.25-1.35 of ground-coat enamel Yuan Liao ﹕ Qiu ﹕ water, the preferred proportioning of 1 ﹕ 1.3 ﹕ 1.3, Ball-milling Time is more than 40 hours, preferably 48 hours, crosses 120 orders and sieve and obtain ground-coat enamel after ball milling.
Described decoration glaze, prepares burden according to parts by weight by decorating below glaze raw material, feldspar 35-40 part, and quartzy 10-15 part, burns Suzhou soil 5-8 part, and calcite 10-15 part, burns talcum 15-18 part, ceramic chamotte 10-15 part, stannic oxide 5-8 part;
By the preferred proportioning of 1 ﹕ 1.3 ﹕ 1.3 of the weight ratio=1 ﹕ 1.25-1.35 ﹕ 1.25-1.35 that decorates glaze Yuan Liao ﹕ Qiu ﹕ water, Ball-milling Time is more than 40 hours, and preferably 48 hours, 120 mesh sieves that sieve after ball milling, sieved and obtained decoration glaze.
Described ceramic body is prepared burden according to parts by weight by following blank, 58 parts of kaolin, and 18 parts of Changxing white claies, 11 parts of Dehua china clay, 12 parts of feldspars, 1 part, talcum, makes base substrate through ball milling, the deironing of sieving, moulding; Ceramic body is carried out to biscuiting, and biscuiting temperature is 1020 ℃.
Dehua china clay, Fujian mud, for the china clay that Dehua County, Fujian Province porcelain stone ore deposit produces, for the feldspathic rock decay of richness forms, is born in Cretaceous volcanic rocks system mostly, and wherein ferrisodium compound is higher, and firing temperature is lower.
Described burning Suzhou soil, for the soil calcining of Tu,Jiang Suzhou, burnt Suzhou is conducive to improve glaze beginning fusing point.
Described glass powder, for white glass grinds makes, initial molten point in ceramic glaze, the mobility of increase glaze, reduces glaze beginning fusing point.
Described burning talcum, is that calcination of talc has destroyed the original sheet structure of talcum through the talcum of calcining, prevents from causing cracking when ceramic burns till, and increases glaze without light effect, can promote the generation of body-glaze intermediate layer, improves hardness of glaze surface.
Described ceramic chamotte, is to be made through pulverizing, deironing by ceramic, can reach the effect of clay burning, the feature that have environmental protection, reduces production costs.
Add Strontium carbonate powder for reducing glaze beginning fusing point, expand firing range, increase glaze mobility, produce unglazed xln.
Add stannic oxide, in glaze, increase whiteness and float turbid effect calcining and can remove organic impurity, thereby reducing bubble and needle pore defect in glaze layer, improve glaze quality.
Present method adopts prepares to obtain ground-coat enamel and decoration glaze formula and the specifically control of firing process, particularly temperature rise rate especially, has made the ceramic with white point stereo decoration glaze; The ground-coat enamel the adopting molten point that begins is low, and base and glaze can be combined closely, and glaze is smooth bright and clean, and product surface is smooth soft, simple and honest generous; Decorate glaze beginning solubility high, and can be slightly soluble in low glaze, form a kind of three-dimensional glaze of the spray white point that is rich in stereo artistic effect of uniqueness, for glaze art provides a kind of glaze of new aesthetic, improved product specification and met the new demand in market.
specific implementation method
Take and prepare coffee-like ceramic wine bottle as embodiment, the specific embodiment of the present invention is described:
embodiment 1
(1) prepare the low glaze of coffee
By following ground-coat enamel raw material, according to parts by weight, prepared burden: 25 parts of feldspars, quartzy 18 parts, 7 parts, Suzhou soil, 15 parts, calcite, 12 parts of rhombspars, 10 parts, glass powder, 4.5 parts of Strontium carbonate powders, 8.8 parts of coffee pigments;
The proportioning of pressing ground-coat enamel Yuan Liao ﹕ Qiu ﹕ water weight ratio=1 ﹕ 1.25 ﹕ 1.25, Ball-milling Time is 50 hours, after ball milling, 120 orders sieve and obtain the low glaze of coffee excessively.
(2) glaze is decorated in preparation
By decorating below glaze raw material, according to parts by weight, prepare burden: 38 parts of feldspars, quartzy 15 parts, burn 7 parts, Suzhou soil, 10 parts, calcite, burns 18 parts, talcum, 13 parts of ceramic chamottes, 7 parts, stannic oxide;
By the proportioning of decorating glaze Yuan Liao ﹕ Qiu ﹕ water weight ratio=1 ﹕ 1.3 ﹕ 1.3, Ball-milling Time is 40 hours, and 120 mesh sieves that sieve after ball milling, obtain decoration glaze.
(3) ceramic body processed
Ceramic body is prepared burden according to parts by weight by following blank, 58 parts of kaolin, and 18 parts of Changxing white claies, 11 parts of Dehua china clay, 12 parts of feldspars, 1 part, talcum, makes ceramic body through ball milling, the deironing of sieving, moulding;
Ceramic body is carried out to biscuiting, and biscuiting temperature is 1020 ℃.
(4) glazing
Adopt the method for soaking glaze to execute upper ground-coat enamel the ceramic body after biscuiting;
Then ceramic body from top to bottom gradual change spray decoration glaze, glaze firing after dry.
(5) glaze firing
Glaze firing adopts roller kiln oxydizing flame to burn till.
Firing period is 4.5-5 hours, and sintering curve is:
First, heat up stage by stage successively, kiln temperature at the uniform velocity rose to 900 ℃ by kiln temperature in 1-1.5 hours, secondly in 1-1.5 hours, at the uniform velocity rose to 1200 ℃;
Then, cooling was stage by stage down to 1080 ℃ in 20-30 minutes successively, secondly in 20 minutes, was down to fast 850 ℃, then in 0.5-1 hour, was down at a slow speed 650 ℃, finally naturally cooled to room temperature, burnt till kiln discharge.
embodiment 2
(1) prepare the low glaze of coffee
By following ground-coat enamel raw material, according to parts by weight, prepared burden: 28 parts of feldspars, quartzy 20 parts, 8 parts, Suzhou soil, 12 parts, calcite, 15 parts of rhombspars, 9 parts, glass powder, 5 parts of Strontium carbonate powders, 10 parts of coffee pigments;
The proportioning of pressing ground-coat enamel Yuan Liao ﹕ Qiu ﹕ water weight ratio=1 ﹕ 1.25 ﹕ 1.25, Ball-milling Time is 48 hours, after ball milling, 120 orders sieve and obtain the low glaze of coffee excessively.
(2) glaze is decorated in preparation
By decorating below glaze raw material, according to parts by weight, prepare burden: 35 parts of feldspars, quartzy 13 parts, burn 8 parts, Suzhou soil, 14 parts, calcite, burns 16 parts, talcum, 15 parts of ceramic chamottes, 5 parts, stannic oxide;
By the proportioning of decorating glaze Yuan Liao ﹕ Qiu ﹕ water weight ratio=1 ﹕ 1.3 ﹕ 1.3, Ball-milling Time is 40 hours, and 120 mesh sieves that sieve after ball milling, obtain decoration glaze.
(3) ceramic body processed
Ceramic body is prepared burden according to parts by weight by following blank, 58 parts of kaolin, and 18 parts of Changxing white claies, 11 parts of Dehua china clay, 12 parts of feldspars, 1 part, talcum, makes ceramic body through ball milling, the deironing of sieving, moulding;
Ceramic body is carried out to biscuiting, and biscuiting temperature is 1020 ℃.
(4) glazing
Adopt the method for soaking glaze to execute upper ground-coat enamel the ceramic body after biscuiting;
Then ceramic body from top to bottom gradual change spray decoration glaze, glaze firing after dry.
(5) glaze firing
Glaze firing adopts roller kiln oxydizing flame to burn till.
Firing period is 4.5-5 hours, and sintering curve is:
First, heat up stage by stage successively, kiln temperature at the uniform velocity rose to 900 ℃ by kiln temperature in 1-1.5 hours, secondly in 1-1.5 hours, at the uniform velocity rose to 1200 ℃;
Then, cooling was stage by stage down to 1080 ℃ in 20-30 minutes successively, secondly in 20 minutes, was down to fast 850 ℃, then in 0.5-1 hour, was down at a slow speed 650 ℃, finally naturally cooled to room temperature, burnt till kiln discharge.
embodiment 3
(1) prepare the low glaze of coffee
By following ground-coat enamel raw material, according to parts by weight, prepared burden: 30 parts of feldspars, quartzy 15 parts, 5 parts, Suzhou soil, 10 parts, calcite, 10 parts of rhombspars, 8 parts, glass powder, 4 parts of Strontium carbonate powders, 8 parts of coffee pigments;
The proportioning of pressing ground-coat enamel Yuan Liao ﹕ Qiu ﹕ water weight ratio=1 ﹕ 1.3 ﹕ 1.3, Ball-milling Time is 48 hours, after ball milling, 120 orders sieve and obtain the low glaze of coffee excessively.
(2) glaze is decorated in preparation
By decorating below glaze raw material, according to parts by weight, prepare burden: 40 parts of feldspars, quartzy 10 parts, burn 5 parts, Suzhou soil, 15 parts, calcite, burns 15 parts, talcum, 10 parts of ceramic chamottes, 8 parts, stannic oxide;
By the proportioning of decorating glaze Yuan Liao ﹕ Qiu ﹕ water weight ratio=1 ﹕ 1.3 ﹕ 1.3, Ball-milling Time is 48 hours, and 120 mesh sieves that sieve after ball milling, obtain decoration glaze.
(3) ceramic body processed
Ceramic body is prepared burden according to parts by weight by following blank, 58 parts of kaolin, and 18 parts of Changxing white claies, 11 parts of Dehua china clay, 12 parts of feldspars, 1 part, talcum, makes ceramic body through ball milling, the deironing of sieving, moulding;
Ceramic body is carried out to biscuiting, and biscuiting temperature is 1020 ℃.
(4) glazing
Adopt the method for soaking glaze to execute upper ground-coat enamel the ceramic body after biscuiting;
Then ceramic body from top to bottom gradual change spray decoration glaze, glaze firing after dry.
(5) glaze firing
Glaze firing adopts roller kiln oxydizing flame to burn till.
Firing period is 4.5-5 hours, and sintering curve is:
First, heat up stage by stage successively, kiln temperature at the uniform velocity rose to 900 ℃ by kiln temperature in 1-1.5 hours, secondly in 1-1.5 hours, at the uniform velocity rose to 1190 ℃;
Then, cooling was stage by stage down to 1080 ℃ in 20-30 minutes successively, secondly in 20 minutes, was down to fast 850 ℃, then in 0.5-1 hour, was down at a slow speed 650 ℃, finally naturally cooled to room temperature, burnt till kiln discharge.
Claims (4)
1. white point stereo decoration glaze ceramic, is characterized in that: by the ceramic body after biscuiting, adopt the method for soaking glaze to execute upper ground-coat enamel, then ceramic body from top to bottom gradual change spray decoration glaze, glaze firing after dry;
Described glaze firing, adopts roller kiln oxydizing flame to burn till; Firing period is 4.5-5 hours, and firing temperature is controlled and is: first heat up stage by stage successively, kiln temperature at the uniform velocity rose to 900 ℃ by kiln temperature in 1-1.5 hours, secondly in 1-1.5 hours, at the uniform velocity rises to 1190-1200 ℃;
Then, cooling was stage by stage down to 1080 ℃ in 20-30 minutes successively, secondly in 20 minutes, was down to fast 850 ℃, then in 0.5-1 hour, was down at a slow speed 650 ℃, finally naturally cooled to room temperature, burnt till kiln discharge.
2. white point stereo decoration glaze ceramic according to claim 1, it is characterized in that: described ground-coat enamel, by following ground-coat enamel raw material, according to parts by weight, prepared burden, feldspar 25-30 part, quartzy 15-20 part, Suzhou soil 5-8 part, calcite 10-15 part, rhombspar 10-15 part, glass powder 8-10 part, Strontium carbonate powder 4-5 part, pigment 8-10 part;
The proportioning of pressing the weight ratio=1 ﹕ 1.25-1.35 ﹕ 1.25-1.35 of ground-coat enamel Yuan Liao ﹕ Qiu ﹕ water, Ball-milling Time is 40-50 hours, after ball milling, 120 orders sieve and obtain ground-coat enamel excessively.
3. white point stereo decoration glaze ceramic according to claim 1, it is characterized in that: described decoration glaze, by decorating below glaze raw material, according to parts by weight, prepare burden, feldspar 35-40 part, quartzy 10-15 part, burns Suzhou soil 5-8 part, calcite 10-15 part, burn talcum 15-18 part, ceramic chamotte 10-15 part, stannic oxide 5-8 part;
By the proportioning of decorating the weight ratio=1 ﹕ 1.25-1.35 ﹕ 1.25-1.35 of glaze Yuan Liao ﹕ Qiu ﹕ water, Ball-milling Time is 40-50 hours, and 120 mesh sieves that sieve after ball milling, have sieved and obtained decoration glaze.
4. according to the white point stereo decoration glaze ceramic described in claim 1 to 3 any one, it is characterized in that: described ceramic body is prepared burden according to parts by weight by following blank, 58 parts of kaolin, 18 parts of Changxing white claies, 11 parts of Dehua china clay, 12 parts of feldspars, 1 part, talcum, makes base substrate through ball milling, the deironing of sieving, moulding; Ceramic body is carried out to biscuiting, and biscuiting temperature is 1020 ℃.
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JPH03293467A (en) * | 1990-04-10 | 1991-12-25 | Toto Ltd | Formation of surface pattern of ceramic product |
CN103204708A (en) * | 2013-04-11 | 2013-07-17 | 厦门万仟堂艺术品有限公司 | Ancient green crackled glaze for ceramic decorations and preparation method of ancient green crackled glaze |
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CN104193416A (en) * | 2014-09-03 | 2014-12-10 | 江苏省宜兴彩陶工艺厂 | Fast firing method for black aventurine glaze ceramic product in roller kiln |
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CN109437973A (en) * | 2018-12-26 | 2019-03-08 | 江苏宜翔陶瓷科技有限公司 | A kind of preparation method of the three-dimensional cream-coloured glaze ceramic vessel of reddish brown scatterplot silk soft quality sense |
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