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CN103579372A - Schottky barrier diode and manufacturing method thereof - Google Patents

Schottky barrier diode and manufacturing method thereof Download PDF

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Publication number
CN103579372A
CN103579372A CN201210268452.9A CN201210268452A CN103579372A CN 103579372 A CN103579372 A CN 103579372A CN 201210268452 A CN201210268452 A CN 201210268452A CN 103579372 A CN103579372 A CN 103579372A
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layer
gallium nitride
conductive layer
substrate
barrier diode
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邱建维
黄宗义
黄智方
杨宗谕
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Richtek Technology Corp
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Richtek Technology Corp
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D8/00Diodes
    • H10D8/60Schottky-barrier diodes 
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/20Electrodes characterised by their shapes, relative sizes or dispositions 
    • H10D64/23Electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. sources, drains, anodes or cathodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/60Electrodes characterised by their materials
    • H10D64/64Electrodes comprising a Schottky barrier to a semiconductor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D8/00Diodes
    • H10D8/01Manufacture or treatment
    • H10D8/051Manufacture or treatment of Schottky diodes

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Abstract

The invention provides a Schottky Barrier Diode (SBD) and a manufacturing method thereof. A schottky barrier diode formed on a substrate, comprising: a gallium nitride (GaN) layer formed on the substrate; an aluminum gallium nitride (AlGaN) layer formed on the GaN layer; an insulating layer formed on the AlGaN layer; an anode conducting layer formed on the insulating layer, wherein a part of the anode conducting layer is in Schottky contact with the GaN layer or the AlGaN layer, and the other part of the anode conducting layer is separated from the AlGaN layer by the insulating layer; and a cathode conductive layer formed on the AlGaN layer and forming ohmic contact with the AlGaN layer, wherein the cathode conductive layer is not directly connected with the anode conductive layer.

Description

肖特基位障二极管及其制造方法Schottky barrier diode and manufacturing method thereof

技术领域 technical field

本发明涉及一肖特基位障二极管(Schottky barrier diode,SBD)及其制造方法,特别是指一种降低漏电流的SBD及其制造方法。The present invention relates to a Schottky barrier diode (Schottky barrier diode, SBD) and its manufacturing method, in particular to an SBD with reduced leakage current and its manufacturing method.

背景技术 Background technique

图1显示一种现有技术肖特基位障二极管(SBD)100,形成于硅基板11上,包含氮化镓(GaN)层、氮化铝镓(AlGaN)层、阳极导电层14、与阴极导电层15。SBD为一半导体元件,相较于p-n接面二极管,其利用金属与半导体的肖特基接触(Schottky contact)所产生的肖特基位障(Schottky barrier),使得操作时顺向电流较大,且回复时间较短。然而由于使得SBD操作于逆向偏压时,会产生很大的漏电流,因此造成电能的损失。1 shows a prior art Schottky barrier diode (SBD) 100, formed on a silicon substrate 11, comprising a gallium nitride (GaN) layer, an aluminum gallium nitride (AlGaN) layer, an anode conductive layer 14, and Cathode conductive layer 15 . SBD is a semiconductor element. Compared with the p-n junction diode, it uses the Schottky barrier (Schottky barrier) generated by the Schottky contact between the metal and the semiconductor, which makes the forward current larger during operation. And the response time is short. However, when the SBD is operated under the reverse bias voltage, a large leakage current will be generated, resulting in loss of electric energy.

有鉴于此,本发明即针对上述现有技术的不足,提出一种肖特基位障二极管及其制造方法,使得肖特基位障二极管操作时,降低漏电流,以减少肖特基位障二极管操作时的电能损耗。In view of this, the present invention aims at the above-mentioned deficiencies in the prior art, and proposes a Schottky barrier diode and a manufacturing method thereof, so that when the Schottky barrier diode is in operation, the leakage current is reduced to reduce the Schottky barrier diode. Power loss during diode operation.

发明内容 Contents of the invention

本发明目的在于克服现有技术的不足与缺陷,提出一种肖特基位障二极管及其制造方法。The purpose of the present invention is to overcome the deficiencies and defects of the prior art, and propose a Schottky barrier diode and a manufacturing method thereof.

为达上述目的,就其中一个观点言,本发明提供了一种肖特基位障二极管,形成于一基板上,包含:一氮化镓(gallium nitride,GaN)层,形成于该基板上;一氮化铝镓(aluminum gallium nitride,AlGaN)层,形成于该GaN层上;一绝缘层,形成于该AlGaN层上;一阳极导电层,形成于该绝缘层上,且部分该阳极导电层与该GaN层或该AlGaN层,形成肖特基接触,且另一部分该阳极导电层与该AlGaN层间,由该绝缘层隔开;以及一阴极导电层,形成于该AlGaN层上,并与该AlGaN层间,形成一欧姆接触,且该阴极导电层与该阳极导电层不直接连接。In order to achieve the above object, in terms of one of the viewpoints, the present invention provides a Schottky barrier diode formed on a substrate, comprising: a gallium nitride (gallium nitride, GaN) layer formed on the substrate; An aluminum gallium nitride (aluminum gallium nitride, AlGaN) layer formed on the GaN layer; an insulating layer formed on the AlGaN layer; an anode conductive layer formed on the insulating layer, and part of the anode conductive layer A Schottky contact is formed with the GaN layer or the AlGaN layer, and another part of the anode conductive layer is separated from the AlGaN layer by the insulating layer; and a cathode conductive layer is formed on the AlGaN layer and is connected with the AlGaN layer. An ohmic contact is formed between the AlGaN layers, and the cathode conductive layer is not directly connected to the anode conductive layer.

就另一观点言,本发明也提供了一种肖特基位障二极管制造方法,包含:形成一氮化镓(gallium nitride,GaN)层于一基板上;形成一氮化铝镓(aluminum gallium nitride,AlGaN)层于该GaN层上;形成一绝缘层于该AlGaN层上;形成一阳极导电层于该绝缘层上,且部分该阳极导电层与该GaN层或该AlGaN层,形成肖特基接触,且另一部分该阳极导电层与该AlGaN层间,由该绝缘层隔开;以及形成一阴极导电层于该AlGaN层上,并与该AlGaN层间,形成一欧姆接触,且该阴极导电层与该阳极导电层不直接连接。From another point of view, the present invention also provides a Schottky barrier diode manufacturing method, comprising: forming a gallium nitride (gallium nitride, GaN) layer on a substrate; forming an aluminum gallium nitride (aluminum gallium Nitride, AlGaN) layer on the GaN layer; form an insulating layer on the AlGaN layer; form an anode conductive layer on the insulating layer, and part of the anode conductive layer and the GaN layer or the AlGaN layer form a Schott base contact, and another part of the anode conductive layer is separated from the AlGaN layer by the insulating layer; and a cathode conductive layer is formed on the AlGaN layer, and forms an ohmic contact with the AlGaN layer, and the cathode The conductive layer is not directly connected to the anode conductive layer.

在其中一种较佳实施型态中,该绝缘层由俯视图视之为格状,形成于该阳极导电层与该GaN层或该AlGaN层之间。In one of the preferred implementation forms, the insulating layer is in a grid shape viewed from a plan view, and is formed between the anode conductive layer and the GaN layer or the AlGaN layer.

在另一种较佳实施型态中,该基板包含一绝缘基板或一导体基板。In another preferred embodiment, the substrate includes an insulating substrate or a conductive substrate.

在又一种较佳实施型态中,该绝缘层厚度小于1微米(um)。In yet another preferred implementation form, the thickness of the insulating layer is less than 1 micron (um).

在另一种较佳实施型态中,该绝缘层具有一高于3.9的介电质常数。In another preferred embodiment, the insulating layer has a dielectric constant higher than 3.9.

下面通过具体实施例详加说明,当更容易了解本发明的目的、技术内容、特点及其所达成的功效。The following will be described in detail through specific embodiments, so that it is easier to understand the purpose, technical content, characteristics and effects of the present invention.

附图说明 Description of drawings

图1显示一种现有技术肖特基位障二极管(SBD)100;Figure 1 shows a prior art Schottky barrier diode (SBD) 100;

图2显示本发明的第一个实施例;Figure 2 shows a first embodiment of the present invention;

图3显示本发明的第二个实施例;Figure 3 shows a second embodiment of the present invention;

图4A-4C显示本发明的第三个实施例;4A-4C show a third embodiment of the present invention;

图5显示本发明的第四个实施例;Figure 5 shows a fourth embodiment of the present invention;

图6A-6B显示现有技术SBD(图6A)与利用本发明的SBD(图6B)的阳极电流对阳极电压的特性图;6A-6B show plots of anodic current versus anode voltage for prior art SBDs (FIG. 6A) and SBDs utilizing the present invention (FIG. 6B);

图7A-7B显示现有技术SBD(图7A)与利用本发明的SBD(图7B)的剖面二维的电场模拟特性图;7A-7B show the cross-sectional two-dimensional electric field simulation characteristic diagrams of the prior art SBD (FIG. 7A) and the SBD using the present invention (FIG. 7B);

图8A-8B显示现有技术SBD(图8A)与利用本发明的SBD(图8B)在阳极边缘的垂直方向的电场模拟特性图;Figures 8A-8B show the electric field simulation characteristic diagrams of the prior art SBD (Figure 8A) and the SBD using the present invention (Figure 8B) in the vertical direction of the anode edge;

图9A-9B显示现有技术SBD(图9A)与利用本发明的SBD(图9B)在通道横向方向的电场模拟特性图。9A-9B show the electric field simulation characteristic diagrams of the prior art SBD (FIG. 9A) and the SBD using the present invention (FIG. 9B) in the transverse direction of the channel.

图中符号说明Explanation of symbols in the figure

11,21  基板11,21 Substrate

12,22  GaN层12,22 GaN layers

13,23  AlGaN层13,23 AlGaN layer

14,24,34  阳极导电层14,24,34 anode conductive layer

15,25,35  阴极导电层15,25,35 Cathode conductive layer

26  绝缘层26 insulation layer

100,200,300,400  肖特基位障二极管100,200,300,400 Schottky barrier diodes

Et,Ep  阳极边缘电场Et,Ep Anode edge electric field

具体实施方式 Detailed ways

本发明中的图式均属示意,主要意在表示制程步骤以及各层之间的上下次序关系,至于形状、厚度与宽度则并未依照比例绘制。The drawings in the present invention are all schematic, mainly intended to represent the manufacturing process steps and the upper and lower sequence relationship between each layer, as for the shape, thickness and width, they are not drawn to scale.

图2显示本发明的第一个实施例。如图2所示,SBD200例如形成于基板21上,而基板21例如但不限于为硅基板、碳化硅基板、或蓝宝石基板等绝缘基板或导体基板。且于基板21上,例如但不限于以外延技术形成氮化镓(GaN)层22。除GaN层22外,SBD200还包含氮化铝镓(AlGaN)层23、绝缘层24、阳极导电层25、以及阴极导电层26。其中,AlGaN层23,形成于GaN层22上;绝缘层24形成于AlGaN层23上;阳极导电层25形成于绝缘层24上,且一部分A阳极导电层25与AlGaN层24,形成肖特基接触,且另一部分B阳极导电层25与AlGaN层23间,由绝缘层24隔开;阴极导电层26,形成于AlGaN层23上,并与AlGaN层23间,形成欧姆接触,且阴极导电层26与阳极导电层25不直接连接。Figure 2 shows a first embodiment of the invention. As shown in FIG. 2 , the SBD 200 is, for example, formed on a substrate 21 , and the substrate 21 is, for example but not limited to, an insulating substrate or a conductive substrate such as a silicon substrate, a silicon carbide substrate, or a sapphire substrate. And on the substrate 21 , for example but not limited to, a gallium nitride (GaN) layer 22 is formed by epitaxial technology. In addition to the GaN layer 22 , the SBD 200 also includes an aluminum gallium nitride (AlGaN) layer 23 , an insulating layer 24 , an anode conductive layer 25 , and a cathode conductive layer 26 . Among them, the AlGaN layer 23 is formed on the GaN layer 22; the insulating layer 24 is formed on the AlGaN layer 23; the anode conductive layer 25 is formed on the insulating layer 24, and a part of the A anode conductive layer 25 and the AlGaN layer 24 form a Schottky contact, and another part of the B anode conductive layer 25 is separated from the AlGaN layer 23 by an insulating layer 24; the cathode conductive layer 26 is formed on the AlGaN layer 23, and forms an ohmic contact with the AlGaN layer 23, and the cathode conductive layer 26 is not directly connected to the anode conductive layer 25.

本实施例与现有技术不同之处,主要在于利用绝缘层24,形成多电场平板,并调整阳极金属层25与AlGaN层23之间的肖特基位障,以提高SBD不导通时的崩溃电压。The difference between this embodiment and the prior art is that the insulating layer 24 is used to form a multi-electric field plate, and the Schottky barrier between the anode metal layer 25 and the AlGaN layer 23 is adjusted to improve the SBD when it is not conducting. breakdown voltage.

图3显示本发明的第二个实施例。本实施例显示应用本发明的SBD300的剖视示意图。与第一个实施例不同的是,本实施例的部分阳极导电层35与GaN层22而并非与AlGaN层23,形成肖特基接触。Fig. 3 shows a second embodiment of the present invention. This embodiment shows a schematic cross-sectional view of an SBD300 applying the present invention. Different from the first embodiment, part of the anode conductive layer 35 in this embodiment forms a Schottky contact with the GaN layer 22 instead of the AlGaN layer 23 .

请参阅图4A-4C,显示本发明的第三个实施例,SBD200的制造流程剖视示意图。如图4A所示,于基板21上,形成GaN层22于基板21上。其中基板21可以为不导电的绝缘基板,例如但不限于为蓝宝石(sapphire)基板,亦可以为导体基板,例如但不限于为碳化硅(SiC)基板。接着形成AlGaN层23于GaN层22上。Please refer to FIGS. 4A-4C , which show a schematic cross-sectional view of the manufacturing process of the SBD 200 according to the third embodiment of the present invention. As shown in FIG. 4A , on the substrate 21 , a GaN layer 22 is formed on the substrate 21 . The substrate 21 can be a non-conductive insulating substrate, such as but not limited to a sapphire substrate, or a conductive substrate, such as but not limited to a silicon carbide (SiC) substrate. Then an AlGaN layer 23 is formed on the GaN layer 22 .

然后如图4B所示,形成绝缘层24于AlGaN层23上其中,绝缘层24例如但不限于以高介电材料制作,其介电常数例如高于二氧化硅的3.9。Then, as shown in FIG. 4B , an insulating layer 24 is formed on the AlGaN layer 23 . The insulating layer 24 is made of, for example but not limited to, high dielectric material, and its dielectric constant is higher than 3.9 of silicon dioxide.

接着如图4C所示,于绝缘层24上,形成阳极导电层25;并于AlGaN层23上,形成阴极导电层26。其中,部分阳极导电层25与AlGaN层23,形成肖特基接触,且另一部分阳极导电层25与AlGaN层23间,由绝缘层24隔开;而阴极导电层26与AlGaN23层间,形成欧姆接触(Ohmic contact),且阴极导电层26与阳极导电层25不直接连接。Next, as shown in FIG. 4C , an anode conductive layer 25 is formed on the insulating layer 24 ; and a cathode conductive layer 26 is formed on the AlGaN layer 23 . Among them, part of the anode conductive layer 25 and the AlGaN layer 23 form a Schottky contact, and another part of the anode conductive layer 25 and the AlGaN layer 23 are separated by an insulating layer 24; and the cathode conductive layer 26 and the AlGaN23 layer form an ohmic contact. Ohmic contact, and the cathode conductive layer 26 is not directly connected to the anode conductive layer 25.

图5显示本发明的第四个实施例。本实施例显示应用本发明的SBD400的剖视示意图。与第一个实施例不同的是,本实施例的绝缘层34由俯视图(未示出)视之为格状,形成于阳极导电层25与GaN层22或AlGaN层23之间。Fig. 5 shows a fourth embodiment of the present invention. This embodiment shows a schematic cross-sectional view of an SBD400 applying the present invention. Different from the first embodiment, the insulating layer 34 of this embodiment is viewed as a grid from a plan view (not shown), and is formed between the anode conductive layer 25 and the GaN layer 22 or the AlGaN layer 23 .

请参阅图6A-6B,显示现有技术SBD与利用本发明的SBD的阳极电流对阳极电压的特性图,如图6A-6B所示,相较于现有技术SBD,利用本发明的SBD在相同阳极电压下,阳极电流较大,表示利用本发明的SBD,其导通特性较佳。Please refer to Figures 6A-6B, which show the characteristic diagrams of the anode current to the anode voltage of the SBD of the prior art and the SBD of the present invention, as shown in Figures 6A-6B, compared with the prior art SBD, the SBD of the present invention is used in Under the same anode voltage, the anode current is larger, indicating that the SBD of the present invention has better conduction characteristics.

请参阅图7A-7B,显示现有技术SBD与利用本发明的SBD的剖面二维的电场模拟特性图,如图6A-6B所示,相较于现有技术的SBD,利用本发明的SBD在相同操作电压下,阳极边缘的电场被分散为两个峰值,且其峰值较低,表示利用本发明的SBD,其电场得到舒缓,因而可增加崩溃电压。Please refer to Figures 7A-7B, which show the two-dimensional electric field simulation characteristic diagrams of the cross-section of the prior art SBD and the SBD utilizing the present invention, as shown in Figure 6A-6B, compared with the SBD of the prior art, the SBD of the present invention is utilized Under the same operating voltage, the electric field at the edge of the anode is dispersed into two peaks, and the peak value is lower, which means that the electric field is relieved by using the SBD of the present invention, thereby increasing the breakdown voltage.

请参阅图8A-8B,显示现有技术SBD与利用本发明的SBD在阳极边缘的垂直方向的电场模拟特性图,如图8A-8B所示,相较于现有技术的SBD,利用本发明的SBD在相同操作电压下,阳极边缘的电场较低,表示利用本发明的SBD,其电场得到舒缓,因而可增加崩溃电压。Please refer to Figures 8A-8B, which show the electric field simulation characteristic diagrams of the prior art SBD and the SBD using the present invention in the vertical direction of the anode edge, as shown in Figures 8A-8B, compared with the prior art SBD, using the present invention Under the same operating voltage of the SBD, the electric field at the edge of the anode is lower, which means that the electric field is relieved by using the SBD of the present invention, thereby increasing the breakdown voltage.

请参阅图9A-9B,显示现有技术SBD与利用本发明的SBD在通道横向方向的电场模拟特性图,如图9A-9B所示,相较于现有技术的SBD,利用本发明的SBD在相同操作电压下,阳极边缘的电场较低,也就是Ep<Et,表示利用本发明的SBD,其电场得到舒缓,因而可增加崩溃电压。Please refer to Figures 9A-9B, which show the electric field simulation characteristic diagrams of the SBD of the prior art and the SBD of the present invention in the lateral direction of the channel, as shown in Figures 9A-9B, compared with the SBD of the prior art, the SBD of the present invention is used Under the same operating voltage, the electric field at the edge of the anode is lower, that is, Ep<Et, which means that the electric field is relaxed by using the SBD of the present invention, thereby increasing the breakdown voltage.

需说明的是,应用本发明的SBD,其绝缘层厚度小于1微米(um),更佳的实施方式为小于0.1微米(um)。表示此绝缘层是用以改变阳极导电层的功函数,并非直接利用较厚的绝缘层来隔离电场,使其减弱。It should be noted that the thickness of the insulating layer applied to the SBD of the present invention is less than 1 micron (um), and a more preferred embodiment is less than 0.1 micron (um). It means that the insulating layer is used to change the work function of the anode conductive layer, instead of directly using a thicker insulating layer to isolate the electric field and weaken it.

以上已针对较佳实施例来说明本发明,只是以上所述,仅为使本领域技术人员易于了解本发明的内容,并非用来限定本发明的权利范围。在本发明的相同精神下,本领域技术人员可以思及各种等效变化。例如,在不影响元件主要的特性下,可加入其它制程步骤或结构,如在形成阴极导电层前,先于SBD的阴极位置,定义并蚀刻出欧姆接触区等。本发明的范围应涵盖上述及其它所有等效变化。The present invention has been described above with reference to preferred embodiments, but the above description is only for those skilled in the art to easily understand the content of the present invention, and is not intended to limit the scope of rights of the present invention. Under the same spirit of the present invention, various equivalent changes can be conceived by those skilled in the art. For example, without affecting the main characteristics of the device, other process steps or structures can be added, such as defining and etching the ohmic contact area before the cathode position of the SBD before forming the cathode conductive layer. The scope of the present invention is intended to cover the above and all other equivalent variations.

Claims (10)

1. a Schottky potential barrier diode, is formed on a substrate, it is characterized in that, comprises:
One gallium nitride layer, is formed on this substrate;
One aluminium gallium nitride alloy layer, is formed on this gallium nitride layer;
One insulating barrier, is formed on this aluminium gallium nitride alloy layer;
One anode conductive layer, is formed on this insulating barrier, and this anode conductive layer of part and this gallium nitride layer or this aluminium gallium nitride alloy layer, forms Schottky contacts, and this anode conductive layer of another part and this aluminium gallium nitride alloy interlayer, by this insulating barrier, is separated; And
One cathode conductive layer, is formed on this aluminium gallium nitride alloy layer, and with this aluminium gallium nitride alloy layer or this aluminium gallium nitride alloy interlayer, form an ohmic contact, and this cathode conductive layer is not directly connected with this anode conductive layer.
2. Schottky potential barrier diode as claimed in claim 1, wherein, what this insulating barrier was looked by vertical view is trellis, is formed between this anode conductive layer and this gallium nitride layer or this aluminium gallium nitride alloy layer.
3. Schottky potential barrier diode as claimed in claim 1, wherein, this substrate comprises an insulated substrate or a conductor substrate.
4. Schottky potential barrier diode as claimed in claim 1, wherein, this thickness of insulating layer is less than 1 micron.
5. Schottky potential barrier diode as claimed in claim 1, wherein, this insulating barrier has one higher than 3.9 dielectric constant.
6. a Schottky potential barrier diode fabricating method, is characterized in that, comprises:
Form a gallium nitride layer on a substrate;
Form an aluminium gallium nitride alloy layer on this gallium nitride layer;
Form an insulating barrier on this aluminium gallium nitride alloy layer;
Form an anode conductive layer on this insulating barrier, and this anode conductive layer of part and this gallium nitride layer or this aluminium gallium nitride alloy layer, form Schottky contacts, and this anode conductive layer of another part and this aluminium gallium nitride alloy interlayer, by this insulating barrier, separated; And
Form a cathode conductive layer on this aluminium gallium nitride alloy layer, and with this aluminium gallium nitride alloy layer or this aluminium gallium nitride alloy interlayer, form an ohmic contact, and this cathode conductive layer is not directly connected with this anode conductive layer.
7. Schottky potential barrier diode fabricating method as claimed in claim 6, wherein, what this insulating barrier was looked by vertical view is trellis, is formed between this anode conductive layer and this gallium nitride layer or this aluminium gallium nitride alloy layer.
8. Schottky potential barrier diode fabricating method as claimed in claim 6, wherein, this substrate comprises an insulated substrate or a conductor substrate.
9. Schottky potential barrier diode fabricating method as claimed in claim 6, wherein, this thickness of insulating layer is less than 1 micron.
10. Schottky potential barrier diode fabricating method as claimed in claim 6, wherein, this insulating barrier has one higher than 3.9 dielectric constant.
CN201210268452.9A 2012-07-30 2012-07-30 Schottky barrier diode and manufacturing method thereof Pending CN103579372A (en)

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Application publication date: 20140212