CN103572310A - Black metal detergent - Google Patents
Black metal detergent Download PDFInfo
- Publication number
- CN103572310A CN103572310A CN201310552474.2A CN201310552474A CN103572310A CN 103572310 A CN103572310 A CN 103572310A CN 201310552474 A CN201310552474 A CN 201310552474A CN 103572310 A CN103572310 A CN 103572310A
- Authority
- CN
- China
- Prior art keywords
- parts
- ferrous metal
- washing composition
- metal detergent
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 35
- 239000002184 metal Substances 0.000 title claims abstract description 35
- 239000003599 detergent Substances 0.000 title abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000012188 paraffin wax Substances 0.000 claims abstract description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- RHQDFWAXVIIEBN-UHFFFAOYSA-N Trifluoroethanol Chemical compound OCC(F)(F)F RHQDFWAXVIIEBN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 23
- 238000005406 washing Methods 0.000 claims description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000013543 active substance Substances 0.000 claims description 7
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 5
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- KWPNNZKRAQDVPZ-UHFFFAOYSA-N 1,3-bis(2-methylphenyl)thiourea Chemical group CC1=CC=CC=C1NC(=S)NC1=CC=CC=C1C KWPNNZKRAQDVPZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 16
- 239000000779 smoke Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 241000589248 Legionella Species 0.000 description 1
- 208000007764 Legionnaires' Disease Diseases 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a black metal detergent. The black metal detergent comprises the following components in parts by weight: 30-40 parts of trifluoroethanol, 10-20 parts of alcohol ether, 10-30 parts of naphthenic hydrocarbon, 10-30 parts of straight-chain paraffin, 15-25 parts of surfactant, 10-20 parts of rust remover and 2-10 parts of inhibitor. The product has strong detergency and good cleaning effect, the finished product contains no phosphor or organic solvent, and the residue after cleaning does not cause pollution to the ecological environment. The black metal detergent can be widely applied to cleaning automobile parts, hubs, smoke exhaust ventilators, kitchen equipment, hearths and the like.
Description
Technical field
The invention belongs to chemical material field, relate to a kind of ferrous metal washing composition.
Background technology
Ferrous metal mainly refers to steel, the pig iron, iron alloy, cast iron etc.Pure iron and chromium are argenteous, and manganese is silver gray.Because steel surface covers the Z 250 of one deck black conventionally, and manganese and chromium are mainly used in the steel alloy of smelting black, so just can be called as ferrous metal.When ferrous metal is longer in the shelf-time, its surface can generate oxide compound, dust, oil stain and dirt because of oxidation, so first being processed must be carried out decontamination, cleaning and acidifying.The object of acidifying is to remove Z 250 ferrous metal surface, black.
Be subject to the impact of the factors such as Traditional Thinking idea and cleaning technique scarcity of resources and disappearance, most enterprises and individual also rest on traditional " destructiveness " technique and idea aspects such as machinery, high pressure water, chemical pickling to the impact of hardware fouling and removing technique, and think simply that metal cleans and only in the situation that having a strong impact on production, just can consider, it does not know the energy consumption that constantly affects enterprise that is created on of incrustation scale, is engulfing the profit of enterprise.And, single in order to reduce the expense of cleaning, selected equipment to have the purging method of infringement and corrosion, the stagnation that causes the seepage of numerous hardwares even to scrap and produce, has paid than the high hundred times of the clean-out system cost of thousands of times even.
At present, in China's cleaning industry for cleaning ferrous matenial material products, as the clean-out system ubiquity of the component of automobile, wheel hub, smoke exhaust, galley equipment, table etc. produces, foam is many, usage quantity is large, cleaning performance is poor, and the raffinate after cleaning can be to defects such as ecotope pollute.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of features high scale-removing effect, the ferrous metal washing composition that corrodibility is little and production cost is low, environmental pollution is little.
For solving above technical problem, a kind of ferrous metal washing composition of the present invention, described ferrous metal washing composition ferrous metal washing composition is to be combined by trifluoroethanol, alcohol ether, naphthenic hydrocarbon and straight-chain paraffin, tensio-active agent, rust remover and inhibiter, and the weight part of each component is as follows:
Above-mentioned tensio-active agent is polyoxyethylene nonylphenol ether.
Above-mentioned rust remover is hydrochloric acid or sulfuric acid.
Above-mentioned inhibiter is di-o-tolyl-thiourea or vulkacit H or their combination.
Further, a kind of ferrous metal washing composition, in described ferrous metal washing composition, the weight part of each component is as follows:
Compared with prior art, the beneficial effect that the present invention has is:
Strong detergency of the present invention, cleaning performance are good, for acarid, legionella etc., have germicidal action.Wettability is good, can by various oils, from various absorbent bodies, wash-out is out at an easy rate.During use, produce that foam volume is few and usage quantity is few, cost-saved.Not phosphorous in finished product, containing organic solvent, the raffinate after cleaning can not pollute ecotope.And with low cost, manufacture craft is simple, can be widely used in the cleaning of automobile component, wheel hub, smoke exhaust, galley equipment, table etc.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art should understand, described embodiment only, for helping to understand the present invention, should not be considered as concrete restriction of the present invention.
As no specific instructions, various raw material of the present invention all can obtain by commercially available; Or prepare according to the ordinary method of this area.Unless otherwise defined or described herein, all specialties used herein and scientific words and the art technology same meaning that skillfully person of entering is familiar.In addition any method similar or impartial to described content and material all can be applicable in the inventive method.
Unless otherwise defined or described herein, the familiar same meaning of all specialties used herein and scientific words and those skilled in the art.In addition any method similar or impartial to described content and material all can be applicable in the inventive method.
Embodiment 1
A washing composition, described ferrous metal washing composition is to be combined by trifluoroethanol, alcohol ether, naphthenic hydrocarbon and straight-chain paraffin, tensio-active agent, rust remover and inhibiter, the weight part of each component is as follows:
In confined reaction tank, add successively as above trifluoroethanol, alcohol ether, naphthenic hydrocarbon, straight-chain paraffin, polyoxyethylene nonylphenol ether, hydrochloric acid, vulkacit H and 30 parts of pure water of component, temperature is controlled between 30-40 ℃, slowly stir 30-40 minute, can obtain ferrous metal washing composition.Ferrous metal after its cleaning reaches following index (table one)
Metal index after table one cleans
| Index name | Index value numerical value |
| Residual water deal (mg/m 2） | ≤50 |
| Remaining impurity content (mg/m 2） | ≤40 |
| Relict mineral oil mass (mg/m 2） | ≤10 |
| Paraffin (mg/m 2） | ≤0.2 |
| Muriate (mg/m 2） | ≤0.2 |
Embodiment 2
A washing composition, described ferrous metal washing composition is to be combined by trifluoroethanol, alcohol ether, naphthenic hydrocarbon and straight-chain paraffin, tensio-active agent, rust remover and inhibiter, the weight part of each component is as follows:
In confined reaction tank, add successively as above trifluoroethanol, alcohol ether, naphthenic hydrocarbon, straight-chain paraffin, polyoxyethylene nonylphenol ether, hydrochloric acid, vulkacit H and 30 parts of pure water of component, temperature is controlled between 30-40 ℃, slowly stir 30-40 minute, can obtain ferrous metal washing composition.Ferrous metal after its cleaning reaches following index (table two)
Metal index after table two cleans
| Index name | Index value numerical value |
| Residual water deal (mg/m 2） | ≤50 |
| Remaining impurity content (mg/m 2） | ≤42 |
| Relict mineral oil mass (mg/m 2） | ≤20 |
| Paraffin (mg/m 2） | ≤0.2 |
| Muriate (mg/m 2） | ≤0.2 |
Embodiment 3
A washing composition, described ferrous metal washing composition is to be combined by trifluoroethanol, alcohol ether, naphthenic hydrocarbon and straight-chain paraffin, tensio-active agent, rust remover and inhibiter, the weight part of each component is as follows:
In confined reaction tank, add successively as above trifluoroethanol, alcohol ether, naphthenic hydrocarbon, straight-chain paraffin, polyoxyethylene nonylphenol ether, hydrochloric acid, vulkacit H and 30 parts of pure water of component, temperature is controlled between 30-40 ℃, slowly stir 30-40 minute, can obtain ferrous metal washing composition.Ferrous metal after its cleaning reaches following index (table three)
Metal index after table three cleans
| Index name | Index value numerical value |
| Residual water deal (mg/m 2） | ≤55 |
| Remaining impurity content (mg/m 2） | ≤48 |
| Relict mineral oil mass (mg/m 2） | ≤10 |
| Paraffin (mg/m 2） | ≤0.1 |
| Muriate (mg/m 2） | ≤0.3 |
Applicant's statement, person of ordinary skill in the field is on the basis of above-described embodiment, by the concrete content point value of above-described embodiment component, combined with the technical scheme of summary of the invention part, thereby the new numerical range producing, also be one of record scope of the present invention, the application, for making specification sheets simple and clear, is no longer enumerated these numerical ranges.
Claims (5)
1. a ferrous metal washing composition, described ferrous metal washing composition is to be combined by trifluoroethanol, alcohol ether, naphthenic hydrocarbon, straight-chain paraffin, tensio-active agent, rust remover and inhibiter, it is characterized in that the weight part of each component is as follows:
2. a kind of ferrous metal washing composition as claimed in claim 1, is characterized in that: described tensio-active agent is polyoxyethylene nonylphenol ether.
3. a kind of ferrous metal washing composition as claimed in claim 1, is characterized in that: described rust remover is hydrochloric acid or sulfuric acid.
4. a kind of ferrous metal washing composition as claimed in claim 1, is characterized in that: described inhibiter is di-o-tolyl-thiourea or vulkacit H or their combination.
5. a kind of ferrous metal washing composition as claimed in claim 1, is characterized in that: the weight part of each component is as follows:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310552474.2A CN103572310A (en) | 2013-11-07 | 2013-11-07 | Black metal detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310552474.2A CN103572310A (en) | 2013-11-07 | 2013-11-07 | Black metal detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103572310A true CN103572310A (en) | 2014-02-12 |
Family
ID=50044999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310552474.2A Pending CN103572310A (en) | 2013-11-07 | 2013-11-07 | Black metal detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103572310A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833924A (en) * | 2017-01-12 | 2017-06-13 | 锐驰高科股份有限公司 | Cleaning agent for removing firm residues from abandoned crude oil pipelines |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1445352A (en) * | 2002-10-16 | 2003-10-01 | 杭州贝尔通讯系统有限公司 | Cleaning agent for electronics equipments |
| CN102995036A (en) * | 2012-12-28 | 2013-03-27 | 杨恒春 | Metal surface cleaning solution |
| CN103122462A (en) * | 2011-11-21 | 2013-05-29 | 天津市浩宇助剂有限公司 | Ferrous metal cleaner |
-
2013
- 2013-11-07 CN CN201310552474.2A patent/CN103572310A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1445352A (en) * | 2002-10-16 | 2003-10-01 | 杭州贝尔通讯系统有限公司 | Cleaning agent for electronics equipments |
| CN103122462A (en) * | 2011-11-21 | 2013-05-29 | 天津市浩宇助剂有限公司 | Ferrous metal cleaner |
| CN102995036A (en) * | 2012-12-28 | 2013-03-27 | 杨恒春 | Metal surface cleaning solution |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833924A (en) * | 2017-01-12 | 2017-06-13 | 锐驰高科股份有限公司 | Cleaning agent for removing firm residues from abandoned crude oil pipelines |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140212 |