CN103563964A - Composite insecticidal composition containing thiamethoxam and methoxyfenozide and application thereof - Google Patents
Composite insecticidal composition containing thiamethoxam and methoxyfenozide and application thereof Download PDFInfo
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- CN103563964A CN103563964A CN201210275798.1A CN201210275798A CN103563964A CN 103563964 A CN103563964 A CN 103563964A CN 201210275798 A CN201210275798 A CN 201210275798A CN 103563964 A CN103563964 A CN 103563964A
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- methoxyfenozide
- diacloden
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- 239000005917 Methoxyfenozide Substances 0.000 title claims abstract description 78
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 13
- 239000002131 composite material Substances 0.000 title abstract description 8
- 239000005941 Thiamethoxam Substances 0.000 title abstract description 5
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 title abstract 4
- 239000004480 active ingredient Substances 0.000 claims abstract description 21
- 241000238631 Hexapoda Species 0.000 claims abstract description 19
- 241001414989 Thysanoptera Species 0.000 claims abstract description 13
- 241000255967 Helicoverpa zea Species 0.000 claims abstract description 12
- 241000500437 Plutella xylostella Species 0.000 claims abstract description 12
- 241000255777 Lepidoptera Species 0.000 claims abstract description 9
- 241000258937 Hemiptera Species 0.000 claims abstract description 8
- 241000254173 Coleoptera Species 0.000 claims abstract description 6
- 241000255925 Diptera Species 0.000 claims abstract description 6
- 241001124076 Aphididae Species 0.000 claims abstract description 5
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- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims description 73
- 239000000575 pesticide Substances 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 24
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- 238000002360 preparation method Methods 0.000 claims description 7
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- 238000009472 formulation Methods 0.000 claims description 5
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- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
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- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 102000015296 acetylcholine-gated cation-selective channel activity proteins Human genes 0.000 description 1
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- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a composite insecticidal composition containing thiamethoxam and methoxyfenozide and an application thereof. The insecticidal composition takes thiamethoxam and methoxyfenozide as main active ingredients, wherein the weight ratio of thiamethoxam to methoxyfenozide is (0.1-80):(0.5-80). The insecticidal composition can generate relatively high synergistic effect, overcomes and delays the drug resistance of insects, and realizes high insecticidal speed and long duration while the application cost is reduced and the prevention effect is obviously better than that of using a single agent. The insecticidal composition disclosed by the invention can prevent coleoptera, diptera, lepidoptera, homoptera, thysanoptera and mite insects on crops and particularly realizes a special effect on the insects such as homoptera plant hopper, whitefly and aphid, lepidoptera plutella xylostella, cotton bollworm and beet armyworm, thysanoptera thrips and mites and the like, and the effect is obviously better than that of using a single agent.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compound pesticide compositions containing Diacloden and methoxyfenozide and uses thereof.
Background technology
Diacloden (Thiamethoxam), chemical name: 3-(the chloro-1,3-thiazoles-5-of 2-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro).Structural formula is:
It is the anabasine insecticide of 1991 Nian You Novartis Co.,Ltd exploitation, its mechanism of action is similar to Imidacloprid, alternative inhibition insect central nervous system nicotinic acid nAChR ligands, and then the normal conduction of blocking-up insect central nervous system, dead while causing insect to occur paralysis machine.Not only have tag, stomach toxicity, systemic activity, and there is higher activity, better safety, wider insecticidal spectrum and the feature such as speed of action is fast, the lasting period is long, be the better kind that replaces those are high to mammalian toxicity, have residual and environmental problem organic phosphor, carbamate, organochlorine insecticides.To coleoptera, diptera, Lepidoptera, thrips, especially homoptera pest has high activity, can effectively prevent and treat the insect that the insects such as various aphids, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato beetle, nematode, ground beetle, leaf miner and knot polytype chemical pesticide produce resistance.With Imidacloprid, Acetamiprid, Nitenpyram without cross resistance.Both can be used for cauline leaf processing, seed treatment, also can be used for soil treatment.Suitable crop is rice class crop, beet, rape, potato, cotton, Kidney bean, fruit tree, peanut, sunflower, soybean, tobacco and citrus etc.
Methoxyfenozide, chemical name: the N-tert-butyl group-N'-(3-methoxyl group-2-methyl benzoyl)-3,5-dimethyl benzene formylhydrazine.Structural formula is:
Sterling is white powder, fusing point 202-205 ℃.Water solubility < 1mg/L in the time of 20 ℃.Solvability in other solvents: dimethyl sulfoxide (DMSO) 11g/L, cyclohexanone 9.9g/L, acetone 9g/L.Stable storage at 25 ℃, 25 ℃, PH=5,7,9 times hydrolysis.
Methoxyfenozide preparation low toxicity, rat acute LD50 of passing through mouth is 5000mg/kg, acute through skin LD50>2000mg/kg.
Methoxyfenozide is a kind of of insect growth regulator, IGR, is mainly that the normal growth of interference insect is grown, though insect molting and dead, and can suppress to ingest.This product is strong to controlling object selectivity, is mainly used in the control of lepidoptera pest.
But diamond-back moth, cotton bollworm and thrips are under the condition of current long-term prescription, and resistance increases gradually, and agricultural chemicals single dose declines gradually to the effect of control of insect.Inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant Diacloden and methoxyfenozide.
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing Diacloden and methoxyfenozide, this Pesticidal combination is the multifunctional insecticide composition of control Homoptera, coleoptera, diptera, Lepidoptera, thrips, mite pest.
Another object of the present invention is to provide this compound pesticide compositions and prevents and treats the application on the insecticidal materials of any one or a few insect in resistance Homoptera, coleoptera, diptera, Lepidoptera, thrips and mite class in preparation.The particularly application on the insecticidal materials of the insects such as preparation control plant hopper, aleyrodid, leafhopper, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for Diacloden and methoxyfenozide, it is main active ingredient that this Pesticidal combination be take Diacloden and methoxyfenozide, and wherein, the weight ratio of Diacloden and methoxyfenozide is 0.1 ~ 80:0.5 ~ 80.Be preferably 0.5 ~ 50:2 ~ 50, more preferably 0.5 ~ 10:4 ~ 30.In this Pesticidal combination, effective ingredient is present in composition with synergy effective dose.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of Diacloden and methoxyfenozide is 3% ~ 80%.Be preferably 5% ~ 55%, most preferably 10% ~ 40%.
Compound pesticide compositions of the present invention be take Diacloden and methoxyfenozide and is mixed with any one formulation allowing on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersion granule as main active ingredient and insecticides adjuvant and excipient.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, agriculture breast 600#, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, solvent naphtha, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Compound pesticide compositions containing Diacloden and methoxyfenozide of the present invention is prevented and treated the application on the insecticidal materials of any one or a few insect in resistance Homoptera, coleoptera, diptera, Lepidoptera, thrips and mite class in preparation.Especially the effect on the insecticidal materials of the insects such as preparation control plant hopper, aleyrodid, leafhopper, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class is the most remarkable.And suppress insect the pesticide resistance of unitary agent (Diacloden or methoxyfenozide are arbitrary) is produced.
Beneficial effect of the present invention compared with prior art:
(1) compare with single dose, said composition antagonism lepidoptera pest, as diamond-back moth and thrips insect thrips etc. has obvious synergistic function, overcomes and has delayed pest resistance to insecticide, expanding prevention spectrum, and desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with methoxyfenozide single dose with Diacloden, produce and use cost reduction; (6) suppress lepidoptera pest, Homoptera, thrips and mite pest the resistance of agricultural chemicals is strengthened, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1:
Taking Diacloden, methoxyfenozide adopts conventional formulation method to be mixed with by different proportion the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 30%.Concrete ratio is in Table 1,2.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selecting resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism diamond-back moth by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of the composite and single dose antagonism diamond-back moth of table 1 Diacloden and methoxyfenozide
As shown in Table 1, Diacloden and methoxyfenozide are composite, and co-toxicity coefficient is all greater than 120, show good synergistic function.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selection resistant bollworm is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism cotton bollworm by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of the composite and single dose antagonism cotton bollworm of table 2 Diacloden and methoxyfenozide
As shown in Table 2, Diacloden and methoxyfenozide are composite, and the co-toxicity coefficient of cotton bollworm is all greater than to 120, show good synergistic function.
Embodiment 2:
Take 5g Diacloden, 50g methoxyfenozide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, forms the Diacloden methoxyfenozide aqueous emulsion that main active ingredient weight percentage is 55%.
Embodiment 3:
Take 2g Diacloden, 18g methoxyfenozide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, cyclohexanone 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide microemulsion that main active ingredient weight percentage is 20%.
Embodiment 3 is prevented and treated to the vegetables diamond-back moth test of pesticide effectiveness, according to the consumption medication in form 3, every mu of ground medication 20g, 30g, contrast medicament is 40% methoxyfenozide EC(missible oil) 30g/ mu and 15% Diacloden EC 30g/ mu, with clear water, do blank, the result of looking into 3 days, 7 days, 14 days and 28 days after medicine, result is in Table 3:
Table 3: the composite field test results to vegetables diamond-back moth of Diacloden methoxyfenozide
Field efficacy result shows, Diacloden methoxyfenozide composition antagonism diamond-back moth has good control efficiency, and control efficiency is all better than the effect that single dose kind is used separately.
Embodiment 3 is prevented and treated to cotton cotton bollworm field medicine effect test, according to the consumption medication in form 4, every mu of ground medication 20g, 30g, contrast medicament is 40% methoxyfenozide EC(missible oil) 30g/ mu and 15% Diacloden EC 30g/ mu, with clear water, do blank, after medicine, look into 3 days, the result of 7 days, 14 days and 28 days, result is in Table 4:
Table 4: the composite field test results to cotton bollworm of Diacloden methoxyfenozide
Field efficacy result shows, Diacloden methoxyfenozide composition antagonism cotton bollworm has good control efficiency, and control efficiency is all better than the effect that single dose kind is used separately.
Embodiment 4:
Take 1g Diacloden, 5g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 6%.
Embodiment 5:
Take 50g Diacloden, 20g methoxyfenozide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 70%.
Embodiment 6:
Take 2g Diacloden, 40g methoxyfenozide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 42%.
Embodiment 7:
Take 0.2g Diacloden, 50g methoxyfenozide, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 50.2%.
Embodiment 8:
Take 5g Diacloden, 0.5g methoxyfenozide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 5.5%.
Embodiment 9:
Take 5g Diacloden, 30g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 35%.
Embodiment 10:
Take 20g Diacloden, 5g methoxyfenozide, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 25%.
Embodiment 11:
Take 30g Diacloden, 12g methoxyfenozide, sodium lignin sulfonate 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, forms the Diacloden methoxyfenozide suspending agent that main active ingredient weight percentage is 42% under the effect of sand mill.
Embodiment 12:
Take 2g Diacloden, 5g methoxyfenozide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g, forms by water dispersible granular agent method the Diacloden methoxyfenozide water dispersible granules that main active ingredient weight percentage is 14% by above raw material.
Embodiment 13:
Take 50g Diacloden, 3g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 53%.
Embodiment 14:
Take 2g Diacloden, 18g methoxyfenozide, sodium lignin sulfonate 10g, Negel 2g, with diatomite, add to 100g, above raw material is mixed in micronizer, form the Diacloden methoxyfenozide wetting powder that main active ingredient weight percentage is 20%.
Embodiment 15:
Take 7g Diacloden, 70g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Diacloden methoxyfenozide missible oil that main active ingredient weight percentage is 77%.
Embodiment 16:
Take 60g Diacloden, 5g methoxyfenozide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, forms by water dispersible granular agent method the Diacloden methoxyfenozide water dispersible granules that main active ingredient weight percentage is 65% by above raw material.
Claims (10)
1. containing a compound pesticide compositions for Diacloden and methoxyfenozide, it is characterized in that it is main active ingredient that this Pesticidal combination be take Diacloden and methoxyfenozide, wherein, the weight ratio of Diacloden and methoxyfenozide is 0.1 ~ 80:0.5 ~ 80.
2. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 1, is characterized in that described Diacloden and the weight ratio of methoxyfenozide are 0.5 ~ 50:2 ~ 50.
3. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 2, is characterized in that described Diacloden and the weight ratio of methoxyfenozide are 0.5 ~ 10:4 ~ 30.
4. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 1, is characterized in that the two weight percentage in this compound pesticide compositions of Diacloden and methoxyfenozide is 3% ~ 80%.
5. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 4, is characterized in that the two weight percentage in this compound pesticide compositions of Diacloden and methoxyfenozide is 5% ~ 55%.
6. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 5, is characterized in that the two weight percentage in this compound pesticide compositions of Diacloden and methoxyfenozide is 10% ~ 40%.
7. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 1, is characterized in that this compound pesticide compositions take Diacloden and methoxyfenozide and be mixed with any one formulation allowing on agricultural chemicals as main active ingredient and insecticides adjuvant, excipients.
8. the compound pesticide compositions containing Diacloden and methoxyfenozide according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersible granules.
9. the compound pesticide compositions containing Diacloden and methoxyfenozide claimed in claim 1 is prevented and treated the application on the insecticidal materials of any one or a few insect in resistance Homoptera, coleoptera, diptera, Lepidoptera, thrips and mite class in preparation.
10. this compound pesticide compositions that is applied as according to claim 9 is prevented and treated the application on the insecticidal materials of the insects such as plant hopper, aleyrodid, leafhopper, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class in preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210275798.1A CN103563964A (en) | 2012-08-05 | 2012-08-05 | Composite insecticidal composition containing thiamethoxam and methoxyfenozide and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210275798.1A CN103563964A (en) | 2012-08-05 | 2012-08-05 | Composite insecticidal composition containing thiamethoxam and methoxyfenozide and application thereof |
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| Publication Number | Publication Date |
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| CN103563964A true CN103563964A (en) | 2014-02-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210275798.1A Pending CN103563964A (en) | 2012-08-05 | 2012-08-05 | Composite insecticidal composition containing thiamethoxam and methoxyfenozide and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689149A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticide composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1216900A (en) * | 1996-04-29 | 1999-05-19 | 诺瓦蒂斯公司 | Pesticidal composition |
| CN1220578A (en) * | 1996-04-29 | 1999-06-23 | 诺瓦蒂斯公司 | Pesticidal compositions |
| US20040078843A1 (en) * | 2001-02-03 | 2004-04-22 | Manfred Kern | Method for controlling harmful organisms in the culture of useful plants |
-
2012
- 2012-08-05 CN CN201210275798.1A patent/CN103563964A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1216900A (en) * | 1996-04-29 | 1999-05-19 | 诺瓦蒂斯公司 | Pesticidal composition |
| CN1220578A (en) * | 1996-04-29 | 1999-06-23 | 诺瓦蒂斯公司 | Pesticidal compositions |
| US20040078843A1 (en) * | 2001-02-03 | 2004-04-22 | Manfred Kern | Method for controlling harmful organisms in the culture of useful plants |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689149A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticide composition |
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