[go: up one dir, main page]

CN103560157B - Strain structure and preparation method thereof - Google Patents

Strain structure and preparation method thereof Download PDF

Info

Publication number
CN103560157B
CN103560157B CN201310583275.8A CN201310583275A CN103560157B CN 103560157 B CN103560157 B CN 103560157B CN 201310583275 A CN201310583275 A CN 201310583275A CN 103560157 B CN103560157 B CN 103560157B
Authority
CN
China
Prior art keywords
bridge
stressor layers
pair
stress
base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310583275.8A
Other languages
Chinese (zh)
Other versions
CN103560157A (en
Inventor
狄增峰
母志强
郭庆磊
叶林
陈达
张苗
王曦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Institute of Microsystem and Information Technology of CAS
Original Assignee
Shanghai Institute of Microsystem and Information Technology of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Institute of Microsystem and Information Technology of CAS filed Critical Shanghai Institute of Microsystem and Information Technology of CAS
Priority to CN201310583275.8A priority Critical patent/CN103560157B/en
Publication of CN103560157A publication Critical patent/CN103560157A/en
Application granted granted Critical
Publication of CN103560157B publication Critical patent/CN103560157B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B3/00Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
    • B81B3/0064Constitution or structural means for improving or controlling the physical properties of a device
    • B81B3/0067Mechanical properties
    • B81B3/0072For controlling internal stress or strain in moving or flexible elements, e.g. stress compensating layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00642Manufacture or treatment of devices or systems in or on a substrate for improving the physical properties of a device
    • B81C1/0065Mechanical properties
    • B81C1/00666Treatments for controlling internal stress or strain in MEMS structures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Micromachines (AREA)
  • Pressure Sensors (AREA)

Abstract

本发明提供一种应变结构及其制作方法,该方法至少包括以下步骤:S1:提供一衬底,在所述衬底表面自下而上依次形成一牺牲层及一第一应力层;S2:将所述第一应力层图形化,形成桥状结构;所述桥状结构包括形成于所述牺牲层表面的一对基座及连接该一对基座的至少一根桥梁;S3:在一对所述基座表面形成第二应力层;S4:采用湿法腐蚀去除所述桥梁下方及所述基座相向两端下方的牺牲层,以使所述桥梁及一对所述基座相向两端悬空,该悬空的两端卷曲使所述桥梁拉伸,得到应变结构。本发明可以给一定范围内的任意材料施加高张应力,方法简单有效、与半导体工艺兼容,具有成本低,且制作速度快的优点。

The present invention provides a strained structure and a manufacturing method thereof. The method at least includes the following steps: S1: providing a substrate, and sequentially forming a sacrificial layer and a first stress layer on the surface of the substrate from bottom to top; S2: Patterning the first stress layer to form a bridge structure; the bridge structure includes a pair of pedestals formed on the surface of the sacrificial layer and at least one bridge connecting the pair of pedestals; S3: in a Form a second stress layer on the surface of the base; S4: Use wet etching to remove the sacrificial layer under the bridge and the opposite ends of the base, so that the bridge and the pair of bases face each other The suspended ends are crimped to stretch the bridge, resulting in a strained structure. The invention can apply high tensile stress to any material within a certain range, the method is simple and effective, compatible with semiconductor technology, and has the advantages of low cost and fast manufacturing speed.

Description

应变结构及其制作方法Strain structure and method of making the same

技术领域technical field

本发明属于半导体制造领域,涉及一种应变结构及其制作方法。The invention belongs to the field of semiconductor manufacturing, and relates to a strain structure and a manufacturing method thereof.

背景技术Background technique

随着半导体器件尺寸的缩小,传统的体硅材料正接近其物理极限,近年来,很多研究小组提出利用高载流子迁移率的新材料来取代传统的硅材料来制作晶体管,以延续摩尔定律的发展。对于应变Si、SiGe等半导体,应力会改变材料的能带结构,降低载流子的有效质量,减小声子的散射等,从而提高载流子的迁移率,改善MOS器件的性能;对于应变Ge也是适用。Ge由于其高的空穴迁移率而受到广泛关注。通过对Ge施加张应力,Ge中电子和空穴的迁移率会得到大大提升,提高器件的性能。并且应变Ge还可以应用于光电器件。As the size of semiconductor devices shrinks, traditional bulk silicon materials are approaching their physical limits. In recent years, many research groups have proposed to use new materials with high carrier mobility to replace traditional silicon materials to make transistors, in order to continue Moore's Law development of. For strained Si, SiGe and other semiconductors, stress will change the energy band structure of the material, reduce the effective mass of carriers, reduce the scattering of phonons, etc., thereby increasing the mobility of carriers and improving the performance of MOS devices; for strain Ge is also applicable. Ge has attracted much attention due to its high hole mobility. By applying tensile stress to Ge, the mobility of electrons and holes in Ge will be greatly improved, improving the performance of the device. And strained Ge can also be applied to optoelectronic devices.

硅基光电集成在近年来的迅速发展被认为能够有效延续摩尔定律的延伸。目前,阻碍硅基光电集成技术的主要障碍是如何解决与硅基兼容的光源问题。当Ge薄膜的张应力到达~2%,Ge就会由原来的间接带隙转变为直接带隙,用来制作激光器,就可以满足光电集成的要求。The rapid development of silicon-based optoelectronic integration in recent years is considered to be able to effectively extend the extension of Moore's Law. At present, the main obstacle hindering silicon-based optoelectronic integration technology is how to solve the problem of light sources compatible with silicon. When the tensile stress of the Ge film reaches ~2%, Ge will change from the original indirect bandgap to a direct bandgap, which can be used to make lasers, which can meet the requirements of optoelectronic integration.

制备张应变Ge有许多方法:1.利用Ge与Si的热膨胀系数的差异在Si上直接外延Ge,可以得到~0.3%的张应变;2.利用Ⅲ-Ⅴ族材料作为缓冲层,可以得到大张应力的Ge。但是由于外延Ⅲ-Ⅴ族材料需要MBE或者MOCVD,价格昂贵,生长速度慢,从而增加了成本。There are many ways to prepare tensile strained Ge: 1. Using the difference in thermal expansion coefficient of Ge and Si to directly epitaxial Ge on Si, a tensile strain of ~0.3% can be obtained; 2. Using III-V materials as a buffer layer, large Ge of tensile stress. However, since epitaxial III-V materials require MBE or MOCVD, the price is expensive and the growth rate is slow, which increases the cost.

此外,对于氧化物、金属等,应变可以改变其相变点等特殊的特性,如VO2;或者应变可以改变导电性等,可以满足各种应用。但是应变氧化物、应变金属的制作同样面临种种问题。In addition, for oxides, metals, etc., strain can change their special characteristics such as phase transition point, such as VO 2 ; or strain can change conductivity, etc., which can meet various applications. However, the production of strained oxides and strained metals also faces various problems.

因此,提供一种新的应变结构及其制作方法实属必要。Therefore, it is necessary to provide a new strain structure and a manufacturing method thereof.

发明内容Contents of the invention

鉴于以上所述现有技术的缺点,本发明的目的在于提供一种应变结构及其制作方法,用于解决现有技术中难以制备高张应变材料、且制备速度慢、成本高的问题。In view of the above-mentioned shortcomings of the prior art, the purpose of the present invention is to provide a strained structure and a manufacturing method thereof, which are used to solve the problems in the prior art that it is difficult to prepare high tensile strain materials, and the preparation speed is slow and the cost is high.

为实现上述目的及其他相关目的,本发明提供一种应变结构的制作方法,至少包括以下步骤:In order to achieve the above purpose and other related purposes, the present invention provides a method for fabricating a strained structure, which at least includes the following steps:

S1:提供一衬底,在所述衬底表面自下而上依次形成一牺牲层及一第一应力层;S1: providing a substrate, and sequentially forming a sacrificial layer and a first stress layer on the surface of the substrate from bottom to top;

S2:将所述第一应力层图形化,形成桥状结构;所述桥状结构包括形成于所述牺牲层表面的一对基座及连接该一对基座的至少一根桥梁;S2: Pattern the first stress layer to form a bridge structure; the bridge structure includes a pair of bases formed on the surface of the sacrificial layer and at least one bridge connecting the pair of bases;

S3:在一对所述基座表面形成第二应力层;S3: forming a second stress layer on a pair of surfaces of the base;

S4:采用湿法腐蚀去除所述桥梁下方及所述基座相向两端下方的牺牲层,以使所述桥梁及一对所述基座相向两端悬空,该悬空的两端卷曲使所述桥梁拉伸,得到应变结构。S4: wet etching is used to remove the sacrificial layer under the bridge and the opposite ends of the base, so that the bridge and the pair of opposite ends of the base are suspended, and the suspended ends are curled to make the The bridge is stretched, resulting in a strained structure.

可选地,所述第二应力层具有张应力,一对所述基座悬空的两端向上卷曲。Optionally, the second stress layer has tensile stress, and a pair of suspended ends of the base are curled upward.

可选地,所述第二应力层具有压应力,一对所述基座悬空的两端向下卷曲。Optionally, the second stress layer has compressive stress, and a pair of suspended ends of the base are curled downward.

可选地,所述第一应力层的材料为金属、氧化物或半导体;所述第二应力层的材料包括金属、氧化物及半导体中的一种或多种。Optionally, the material of the first stress layer is metal, oxide or semiconductor; the material of the second stress layer includes one or more of metal, oxide and semiconductor.

可选地,所述第二应力层为单层或复合层结构。Optionally, the second stress layer is a single-layer or composite-layer structure.

可选地,所述第一应力层的材料为金属Ti、Cr、Pt、Au、Ag、Pd、Fe,或氧化物Al2O3、ZnO、Si3N4、SiO、SiO2,或半导体Si、Ge、Ⅲ-Ⅴ族化合物、SixGe1-x,其中0<x<1;所述第二应力层的材料包括金属Ti、Cr、Pt、Au、Ag、Pd、Fe、Co、Ni,或氧化物Al2O3、ZnO、Si3N4、SiO、SiO2,或半导体Si、Ge、Ⅲ-Ⅴ族化合物、SixGe1-x中的一种或多种,其中0<x<1。Optionally, the material of the first stress layer is metal Ti, Cr, Pt, Au, Ag, Pd, Fe, or oxides Al 2 O 3 , ZnO, Si 3 N 4 , SiO, SiO 2 , or semiconductor Si, Ge, III-V group compounds, Six Ge 1-x , wherein 0<x<1; the material of the second stress layer includes metal Ti, Cr, Pt, Au, Ag, Pd, Fe, Co, Ni, or oxides Al 2 O 3 , ZnO, Si 3 N 4 , SiO, SiO 2 , or one or more of semiconductors Si, Ge, III-V group compounds, Six Ge 1-x , where 0 <x<1.

可选地,所述第一应力层与所述第二应力层的材料不同。Optionally, the materials of the first stress layer and the second stress layer are different.

可选地,所述桥梁为纳米线、微米线或纳米薄膜。Optionally, the bridge is a nanowire, a microwire or a nanofilm.

可选地,所述基座为方形、矩形、梯形、圆形或椭圆形。Optionally, the base is square, rectangular, trapezoidal, circular or oval.

可选地,所述牺牲层的材料选自SiO2、Si3N4、Ge、光刻胶、PDMS及PMMA中的一种,且所述牺牲层与所述第一应力层及第二应力层采用不同的材料。Optionally, the material of the sacrificial layer is selected from one of SiO 2 , Si 3 N 4 , Ge, photoresist, PDMS and PMMA, and the sacrificial layer and the first stress layer and the second stress The layers are made of different materials.

本发明还提供另一种应变结构的制作方法,至少包括以下步骤:The present invention also provides another method for fabricating a strained structure, which at least includes the following steps:

S1:提供一衬底,在所述衬底表面自下而上依次形成一牺牲层及一第一应力层;S1: providing a substrate, and sequentially forming a sacrificial layer and a first stress layer on the surface of the substrate from bottom to top;

S2:在所述第一应力层表面形成第二应力层,并将所述第二应力层图形化,形成一对基板;S2: forming a second stress layer on the surface of the first stress layer, and patterning the second stress layer to form a pair of substrates;

S3:将所述第一应力层图形化,形成桥状结构;所述桥状结构包括形成于所述牺牲层表面的一对基座及连接该一对基座的至少一根桥梁;所述基座位于所述基板下方且与所述基板重合或部分重合;S3: pattern the first stress layer to form a bridge structure; the bridge structure includes a pair of bases formed on the surface of the sacrificial layer and at least one bridge connecting the pair of bases; The base is located below the substrate and overlaps or partially overlaps with the substrate;

S4:采用湿法腐蚀去除所述桥梁下方及所述基座相向两端下方的牺牲层,以使所述桥梁及一对所述基座相向两端悬空,该悬空的两端卷曲使所述桥梁拉伸,得到应变结构。S4: wet etching is used to remove the sacrificial layer under the bridge and the opposite ends of the base, so that the bridge and the pair of opposite ends of the base are suspended, and the suspended ends are curled to make the The bridge is stretched, resulting in a strained structure.

本发明还提供一种应变结构,包括:The present invention also provides a strained structure, comprising:

衬底;Substrate;

形成于所述衬底表面的牺牲层;a sacrificial layer formed on the surface of the substrate;

图形化的第一应力层,形成于所述牺牲层表面;该图形化的第一应力层为桥状结构;所述桥状结构包括一对基座及连接该一对基座的至少一根桥梁;A patterned first stress layer formed on the surface of the sacrificial layer; the patterned first stress layer is a bridge structure; the bridge structure includes a pair of bases and at least one connecting the pair of bases bridge;

形成于所述基座表面的第二应力层;a second stress layer formed on the surface of the base;

所述桥梁及一对所述基座相向两端悬空,且该悬空的两端卷曲,所述桥梁呈拉伸状态。The opposite ends of the bridge and the pair of bases are suspended in the air, and the suspended ends are curled, and the bridge is in a stretched state.

可选地,一对所述基座悬空的两端向上卷曲或向下卷曲。Optionally, the suspended ends of a pair of bases are curled up or down.

可选地,所述桥梁为纳米线、微米线或纳米薄膜。Optionally, the bridge is a nanowire, a microwire or a nanofilm.

可选地,所述第一应力层的材料为金属、氧化物或半导体;所述第二应力层的材料包括金属、氧化物及半导体中的一种或多种。Optionally, the material of the first stress layer is metal, oxide or semiconductor; the material of the second stress layer includes one or more of metal, oxide and semiconductor.

如上所述,本发明的应变结构及其制作方法,具有以下有益效果:本发明通过在桥状结构的基座上形成提供应力的薄膜,将桥梁及一对基座相向两端下方的牺牲层腐蚀掉后,所述桥梁及一对基座相向两端悬空,由于所述基座表面的第二应力层存在应力,就会带着所述基座悬空的端部卷曲使所述桥梁拉伸,形成张应变材料,得到应力结构。本发明的应力结构的制作方法可以给一定范围内的任意材料施加张应力,方法简单有效、与半导体工艺兼容,具有成本低,且制作速度快的优点。本发明的应力结构具有高张应力,能够提高器件的各种性能。As mentioned above, the strained structure of the present invention and its manufacturing method have the following beneficial effects: the present invention forms a stress-providing film on the base of the bridge-like structure, and the bridge and a pair of bases face the sacrificial layer below the two ends. After being corroded, the opposite ends of the bridge and the pair of bases are suspended in the air. Due to the stress in the second stress layer on the surface of the base, the suspended ends of the base will be curled to make the bridge stretch , forming a tensile strained material and obtaining a stress structure. The manufacturing method of the stress structure of the present invention can apply tensile stress to any material within a certain range, and the method is simple and effective, compatible with semiconductor technology, and has the advantages of low cost and fast manufacturing speed. The stress structure of the invention has high tensile stress and can improve various performances of devices.

附图说明Description of drawings

图1显示为本发明的应变结构的制作方法的工艺流程图。FIG. 1 shows a process flow diagram of the manufacturing method of the strained structure of the present invention.

图2显示为本发明的应变结构的制作方法中在衬底上依次形成牺牲层及第一应力层后的结构剖视图。2 is a cross-sectional view of the structure after sequentially forming a sacrificial layer and a first stress layer on the substrate in the manufacturing method of the strained structure of the present invention.

图3显示为本发明的应变结构的制作方法中将第一应力层图形化形成桥状结构后的结构俯视图。FIG. 3 is a top view of the structure after patterning the first stress layer to form a bridge structure in the method for fabricating the strained structure of the present invention.

图4显示为本发明的应变结构的制作方法中在一对基座表面形成第二应力层后的结构俯视图。FIG. 4 is a top view of the structure after forming a second stress layer on the surface of a pair of bases in the manufacturing method of the strained structure of the present invention.

图5显示为本发明的应变结构的剖视图。FIG. 5 shows a cross-sectional view of the strained structure of the present invention.

元件标号说明Component designation description

S1~S4步骤Steps S1~S4

1衬底1 substrate

2牺牲层2 sacrificial layers

3第一应力层3 first stress layer

4基座4 bases

5桥梁5 bridges

6第二应力层6 Second stress layer

具体实施方式detailed description

以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。Embodiments of the present invention are described below through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification. The present invention can also be implemented or applied through other different specific implementation modes, and various modifications or changes can be made to the details in this specification based on different viewpoints and applications without departing from the spirit of the present invention.

请参阅图1至图5。需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图式中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。See Figures 1 through 5. It should be noted that the diagrams provided in this embodiment are only schematically illustrating the basic idea of the present invention, and only the components related to the present invention are shown in the diagrams rather than the number, shape and shape of the components in actual implementation. Dimensional drawing, the type, quantity and proportion of each component can be changed arbitrarily during actual implementation, and the component layout type may also be more complicated.

实施例一Embodiment one

本发明提供一种应变结构的制作方法,请参阅图1,显示为本发明的应变结构的制作方法的工艺流程图,至少包括以下步骤:The present invention provides a method for manufacturing a strained structure, please refer to FIG. 1 , which is a process flow diagram of the method for manufacturing a strained structure of the present invention, at least including the following steps:

步骤S1:提供一衬底,在所述衬底表面自下而上依次形成一牺牲层及一第一应力层;Step S1: providing a substrate, and sequentially forming a sacrificial layer and a first stress layer on the surface of the substrate from bottom to top;

步骤S2:将所述第一应力层图形化,形成桥状结构;所述桥状结构包括形成于所述牺牲层表面的一对基座及连接该一对基座的至少一根桥梁;Step S2: patterning the first stress layer to form a bridge structure; the bridge structure includes a pair of bases formed on the surface of the sacrificial layer and at least one bridge connecting the pair of bases;

步骤S3:在一对所述基座表面形成第二应力层;Step S3: forming a second stress layer on a pair of surfaces of the base;

步骤S4:采用湿法腐蚀去除所述桥梁下方及所述基座相向两端下方的牺牲层,以使所述桥梁及一对所述基座相向两端悬空,该悬空的两端卷曲使所述桥梁拉伸,得到应变结构。Step S4: using wet etching to remove the sacrificial layer under the bridge and the opposite ends of the base, so that the bridge and the pair of opposite ends of the base are suspended in the air, and the suspended ends are curled so that the The bridge is stretched to obtain a strained structure.

首先请参阅图2,执行步骤S1:提供一衬底1,在所述衬底1表面自下而上依次形成一牺牲层2及一第一应力层3。First, please refer to FIG. 2 , step S1 is performed: provide a substrate 1 , and sequentially form a sacrificial layer 2 and a first stress layer 3 on the surface of the substrate 1 from bottom to top.

具体的,所述衬底1为常规的半导体衬底,如Si、Ge、III-V族化合物材料等,本实施例中,所述衬底1优选为Si衬底。Specifically, the substrate 1 is a conventional semiconductor substrate, such as Si, Ge, III-V compound materials, etc. In this embodiment, the substrate 1 is preferably a Si substrate.

所述牺牲层2的材料选自SiO2、Si3N4、Ge、光刻胶、PDMS及PMMA中的一种,且所述牺牲层的材料与所述第一应力层及第二应力层采用不同的材料。其中SiO2可采用热氧化方法在Si衬底上直接形成,或采用化学气相沉积在其它类型衬底上形成;Si3N4可利用低压化学气相沉积技术或等离子体增强化学气相沉积技术在所述衬底上形成;PDMS(聚二甲基硅氧烷)是一种聚合物材料,与硅片之间具有良好的粘附性,可通过旋涂等方法形成于所述衬底上,PDMS易溶于甲苯等有机溶剂;PMMA(聚甲基丙烯酸甲酯),溶于有机溶剂,如苯酚,苯甲醚等,可以通过旋涂可以形成良好的薄膜,具有良好的介电性能。本实施例中,所述牺牲层2优选为SiO2,采用热氧化方法直接在Si衬底上形成。The material of the sacrificial layer 2 is selected from one of SiO 2 , Si 3 N 4 , Ge, photoresist, PDMS and PMMA, and the material of the sacrificial layer is compatible with the first stress layer and the second stress layer Using different materials. Among them, SiO 2 can be directly formed on Si substrates by thermal oxidation method, or formed on other types of substrates by chemical vapor deposition; Si 3 N 4 can be formed by low-pressure chemical vapor deposition technology or plasma-enhanced chemical vapor deposition technology. Formed on the above-mentioned substrate; PDMS (polydimethylsiloxane) is a kind of polymer material, has good adhesion between silicon chip, can be formed on the described substrate by methods such as spin coating, PDMS Easily soluble in organic solvents such as toluene; PMMA (polymethyl methacrylate), soluble in organic solvents such as phenol, anisole, etc., can form a good film by spin coating and has good dielectric properties. In this embodiment, the sacrificial layer 2 is preferably SiO 2 , which is directly formed on the Si substrate by thermal oxidation.

所述第一应力层3的材料为金属、氧化物或半导体,其中,金属包括但不限于Ti、Cr、Pt、Au、Ag、Pd或Fe;氧化物包括但不限于Al2O3、ZnO、Si3N4、SiO或SiO2,半导体包括但不限于Si、Ge、Ⅲ-Ⅴ族化合物或SixGe1-x,其中0<x<1。对于所述第一应力层3的材料为金属或氧化物,可以采用蒸发、溅射、外延等方法形成;对于所述第一应力层3的材料为半导体,可采用化学气相沉积、外延等方法形成。本实施例中,所述第一应力层3的材料以Ge为例,优选采用外延法形成。The material of the first stress layer 3 is metal, oxide or semiconductor, wherein the metal includes but not limited to Ti, Cr, Pt, Au, Ag, Pd or Fe; the oxide includes but not limited to Al 2 O 3 , ZnO , Si 3 N 4 , SiO or SiO 2 , semiconductors include but not limited to Si, Ge, III-V group compounds or Six Ge 1-x , where 0<x<1. For the material of the first stress layer 3 is metal or oxide, methods such as evaporation, sputtering, and epitaxy can be used to form; for the material of the first stress layer 3 is a semiconductor, methods such as chemical vapor deposition and epitaxy can be used. form. In this embodiment, the material of the first stress layer 3 is Ge as an example, preferably formed by epitaxy.

然后请参阅图3,执行步骤S2:将所述第一应力层3图形化,形成桥状结构;所述桥状结构包括形成于所述牺牲层2表面的一对基座4及连接该一对基座4的至少一根桥梁5。Then referring to FIG. 3, step S2 is performed: patterning the first stress layer 3 to form a bridge structure; the bridge structure includes a pair of bases 4 formed on the surface of the sacrificial layer 2 and connecting the one At least one bridge 5 to the base 4 .

具体的,通过光刻及刻蚀工艺图形化所述第一应力层3。所述基座4的横向宽度大于所述桥梁的纵向宽度。所述桥梁5为纳米线、微米线、纳米薄膜或其它形状,所述基座4在水平面上的投影为方形、矩形、梯形、圆形、椭圆形或其它形状。本实施例中,所述桥梁5以纳米线为例,其中,图2中显示了三根纳米线的情形,当然,所述桥梁5的数目可根据实际应用情况予以调整。Specifically, the first stress layer 3 is patterned by photolithography and etching processes. The transverse width of the base 4 is greater than the longitudinal width of the bridge. The bridge 5 is nanowire, micron wire, nanofilm or other shapes, and the projection of the base 4 on the horizontal plane is square, rectangular, trapezoidal, circular, elliptical or other shapes. In this embodiment, the bridge 5 is taken as an example of nanowires, wherein the situation of three nanowires is shown in FIG. 2 , of course, the number of the bridges 5 can be adjusted according to actual application conditions.

再请参阅图4,执行步骤S3:在一对所述基座4表面形成第二应力层6。Referring to FIG. 4 again, step S3 is performed: forming a second stress layer 6 on the surfaces of the pair of bases 4 .

具体的,所述第二应力层6的材料包括金属、氧化物及半导体中的一种或多种,其中,金属包括但不限于Ti、Cr、Pt、Au、Ag、Pd、Fe、Co及Ni,氧化物包括但不限于Al2O3、ZnO、Si3N4、SiO及SiO2;半导体包括但不限于Si、Ge、Ⅲ-Ⅴ族化合物及SixGe1-x中的一种或多种,其中0<x<1。所述第二应力层6可以为单层或复合层结构。Specifically, the material of the second stress layer 6 includes one or more of metals, oxides, and semiconductors, wherein the metals include but are not limited to Ti, Cr, Pt, Au, Ag, Pd, Fe, Co, and Ni, oxides include but not limited to Al 2 O 3 , ZnO, Si 3 N 4 , SiO and SiO 2 ; semiconductors include but not limited to Si, Ge, III-V compounds and one of Six Ge 1- x or more, where 0<x<1. The second stress layer 6 can be a single layer or a composite layer structure.

所述第二应力层6对所述基座4施加压应力或张应力。对于所述第二应力层6的材料为金属或氧化物,可以采用蒸发、溅射、外延等方法形成;对于所述第二应力层6的材料为半导体,可采用化学气相沉积、外延等方法形成。本实施例中,所述第二应力层6的材料优选为Ti、Cr、Si3N4、SiO或SiO2,其中Ti或Cr采用蒸发或溅射法生长,Si3N4、SiO或SiO2采用化学气相沉积法形成。The second stress layer 6 exerts compressive stress or tensile stress on the base 4 . For the material of the second stress layer 6 is metal or oxide, methods such as evaporation, sputtering, and epitaxy can be used to form; for the material of the second stress layer 6 is a semiconductor, methods such as chemical vapor deposition and epitaxy can be used. form. In this embodiment, the material of the second stress layer 6 is preferably Ti, Cr, Si 3 N 4 , SiO or SiO 2 , wherein Ti or Cr is grown by evaporation or sputtering, and Si 3 N 4 , SiO or SiO 2 Formed by chemical vapor deposition.

一般来说半导体材料采用化学气相沉积方法是比较容易做成单晶的,通过调节生长的参数或者改变生长的方式也比较容易得到多晶;而对于金属、氧化物等通常情况下很难做成单晶,一般都是多晶或非晶。Generally speaking, it is easier to make single crystal of semiconductor materials by chemical vapor deposition method, and it is easier to get polycrystalline by adjusting the growth parameters or changing the growth method; but it is usually difficult to make it for metals, oxides, etc. Single crystal, generally polycrystalline or amorphous.

所述第一应力层3与所述第二应力层6可以采用相同材料,通过调节生长参数或改变生长方式使二者之间应力不匹配。本实施例中,所述第一应力层3与所述第二应力层6优选为采用不同材料,使得所述第二应力层6更容易对所述第一应力层3产生压应力或张应力,亦即对所述基座4施加压应力或张应力。由于所述基座形成于所述牺牲层2表面,该应力被束缚住。上述应力包括热应力等。The first stress layer 3 and the second stress layer 6 can be made of the same material, and the stress mismatch between the two can be made by adjusting the growth parameters or changing the growth method. In this embodiment, the first stress layer 3 and the second stress layer 6 are preferably made of different materials, so that the second stress layer 6 is more likely to generate compressive stress or tensile stress on the first stress layer 3 , that is, compressive stress or tensile stress is applied to the base 4 . Since the pedestal is formed on the surface of the sacrificial layer 2, this stress is contained. The aforementioned stress includes thermal stress and the like.

最后请参阅图5,执行步骤S4:采用湿法腐蚀去除所述桥梁5下方及所述基座4相向两端下方的牺牲层2,以使所述桥梁5及一对所述基座4相向两端悬空,该悬空的两端卷曲使所述桥梁5拉伸,得到应变结构。Finally, please refer to FIG. 5, and perform step S4: use wet etching to remove the sacrificial layer 2 under the bridge 5 and the opposite ends of the base 4, so that the bridge 5 and the pair of bases 4 face each other. Both ends are suspended in the air, and the suspended two ends are curled to stretch the bridge 5 to obtain a strained structure.

本实施例中,所述牺牲层2采用二氧化硅,于本步骤中,采用HF溶液腐蚀掉所述桥梁5下方及所述基座4相向两端下方的牺牲层,得到悬空结构。由于所述基座4的横向宽度大于所述桥梁的纵向宽度,通过控制腐蚀时间,可以使得所述桥梁5完全悬空,而所述基座4部分悬空。在其它实施例中,若所述牺牲层为光刻胶,则可以采用显影液等去除,若所述牺牲层PDMS或PMMA,则可以采用有机溶液去除。In this embodiment, the sacrificial layer 2 is made of silicon dioxide. In this step, HF solution is used to etch away the sacrificial layer below the bridge 5 and below the two opposite ends of the base 4 to obtain a suspended structure. Since the transverse width of the base 4 is larger than the longitudinal width of the bridge, by controlling the corrosion time, the bridge 5 can be completely suspended while the base 4 is partially suspended. In other embodiments, if the sacrificial layer is photoresist, it can be removed by using a developing solution, and if the sacrificial layer is PDMS or PMMA, it can be removed by using an organic solution.

具体的,若所述第二应力层6具有张应力,则一对所述基座4悬空的两端向上卷曲;若所述第二应力层6具有压应力,则一对所述基座悬空的两端向下卷曲。本实施例中,优选为使所述第二应力层6具有张应力,使得所述基座4悬空的端部向上卷曲,卷曲空间较大,有利于使所述桥梁5拉伸程度更高,具有更大的张应力。Specifically, if the second stress layer 6 has tensile stress, the suspended ends of the pair of bases 4 are curled up; if the second stress layer 6 has compressive stress, the pair of bases are suspended Curl down at both ends. In this embodiment, it is preferable to make the second stress layer 6 have a tensile stress, so that the suspended end of the base 4 is curled upwards, and the curling space is large, which is beneficial to make the bridge 5 more stretchable. have greater tensile stress.

对于硅基张应变Ge材料,可以使Ge器件的载流子迁移率增加,改善MOS器件的性能,同时高张应变Ge材料的能带发生转变,可以提高Ge的发光性能,有利于其在光电器件方面的应用。对于应变Si、应变SiGe等半导体,应力会改变材料的能带结构,降低载流子的有效质量,减小声子的散射等,同样可以提高载流子的迁移率,改善MOS器件的性能。对于应变氧化物或应变金属,应变可以改变其相变点等特殊特性,或者改变其导电性,适用于不同领域的应用。For silicon-based tensile strain Ge materials, it can increase the carrier mobility of Ge devices and improve the performance of MOS devices. device applications. For semiconductors such as strained Si and strained SiGe, stress will change the energy band structure of the material, reduce the effective mass of carriers, reduce the scattering of phonons, etc., which can also increase the mobility of carriers and improve the performance of MOS devices. For strained oxides or strained metals, the strain can change their special properties such as phase transition point, or change their electrical conductivity, suitable for applications in different fields.

至此,采用本发明的应变结构的制作方法完成了应变结构的制作。本发明的应变结构的制作方法通过在桥状结构的基座上形成提供应力的薄膜,将桥梁及一对基座相向两端下方的牺牲层腐蚀掉后,所述桥梁及一对基座相向两端悬空,由于所述基座表面的第二应力层存在应力,就会带着所述基座悬空的端部卷曲使所述桥梁拉伸,形成张应变材料,得到应力结构。本发明的应力结构的制作方法可以给一定范围内的任意材料施加张应力,方法简单有效、与半导体工艺兼容,具有成本低,且制作速度快的优点。本发明制作的应力结构具有高张应力,能够提高器件的各种性能。So far, the manufacturing method of the strained structure of the present invention is used to complete the manufacturing of the strained structure. The manufacturing method of the strained structure of the present invention forms a stress-providing thin film on the base of the bridge-like structure, and after the sacrificial layer below the opposite ends of the bridge and the pair of bases is corroded, the bridge and the pair of bases face each other. Both ends are suspended in the air, and because the stress exists in the second stress layer on the surface of the base, the suspended end of the base will be curled to stretch the bridge to form a tensile strain material and obtain a stress structure. The manufacturing method of the stress structure of the present invention can apply tensile stress to any material within a certain range, and the method is simple and effective, compatible with semiconductor technology, and has the advantages of low cost and fast manufacturing speed. The stress structure produced by the invention has high tensile stress and can improve various performances of devices.

实施例二Embodiment two

本实施例与实施例一采用基本相同的技术方案,不同之处在于步骤S2与步骤S3的先后顺序有所调整。实施例一中,首先将第一应力层图形化形成桥状结构,然后在桥状结构的基座上形成第二应力层;而本实施例中,形成第一应力层之后接着在所述第一应力层表面形成第二应力层,其中第二应力层与后续将要形成的桥状结构的基座重合,然后再将所述第一应力层图形化形成桥状结构。该制作顺序的调整并不影响最终形成的应变结构。This embodiment adopts basically the same technical solution as Embodiment 1, except that the order of steps S2 and S3 is adjusted. In the first embodiment, the first stress layer is first patterned to form a bridge structure, and then the second stress layer is formed on the base of the bridge structure; and in this embodiment, after the formation of the first stress layer, the second stress layer is formed. A second stress layer is formed on the surface of the first stress layer, wherein the second stress layer coincides with the base of the bridge structure to be formed later, and then the first stress layer is patterned to form the bridge structure. The adjustment of the fabrication order does not affect the finally formed strained structure.

本发明还提供另一种应变结构的制作方法,至少包括以下步骤:The present invention also provides another method for fabricating a strained structure, which at least includes the following steps:

步骤S1:提供一衬底,在所述衬底表面自下而上依次形成一牺牲层及一第一应力层;Step S1: providing a substrate, and sequentially forming a sacrificial layer and a first stress layer on the surface of the substrate from bottom to top;

步骤S2:在所述第一应力层表面形成第二应力层,并将所述第二应力层图形化,形成一对基板;Step S2: forming a second stress layer on the surface of the first stress layer, and patterning the second stress layer to form a pair of substrates;

步骤S3:将所述第一应力层图形化,形成桥状结构;所述桥状结构包括形成于所述牺牲层表面的一对基座及连接该一对基座的至少一根桥梁;所述基座位于所述基板下方且与所述基板重合或部分重合;Step S3: patterning the first stress layer to form a bridge structure; the bridge structure includes a pair of bases formed on the surface of the sacrificial layer and at least one bridge connecting the pair of bases; The base is located below the substrate and overlaps or partially overlaps with the substrate;

步骤S4:采用湿法腐蚀去除所述桥梁下方及所述基座相向两端下方的牺牲层,以使所述桥梁及一对所述基座相向两端悬空,该悬空的两端卷曲使所述桥梁拉伸,得到应变结构。Step S4: using wet etching to remove the sacrificial layer under the bridge and the opposite ends of the base, so that the bridge and the pair of opposite ends of the base are suspended in the air, and the suspended ends are curled so that the The bridge is stretched to obtain a strained structure.

本实施例中各步骤除了先后顺序外,具体的实现方式或方法与实施例一基本相同,请参阅实施例一中相应部分的描述,此处不再赘述。Except for the order of the steps in this embodiment, the specific implementation manner or method is basically the same as that in Embodiment 1. Please refer to the description of the corresponding part in Embodiment 1, and details will not be repeated here.

实施例三Embodiment three

本发明还提供一种应变结构,请参阅图5,显示为该应变结构的剖面示意图,包括:The present invention also provides a strained structure, please refer to Figure 5, which is a schematic cross-sectional view of the strained structure, including:

衬底1;substrate1;

形成于所述衬底1表面的牺牲层2;a sacrificial layer 2 formed on the surface of the substrate 1;

图形化的第一应力层,形成于所述牺牲层2表面;该图形化的第一应力层为桥状结构;所述桥状结构包括一对基座4及连接该一对基座4的至少一根桥梁5;The patterned first stress layer is formed on the surface of the sacrificial layer 2; the patterned first stress layer is a bridge structure; the bridge structure includes a pair of bases 4 and a pair of bases 4 connected at least one bridge5;

形成于所述基座4表面的第二应力层6;A second stress layer 6 formed on the surface of the base 4;

所述桥梁5及一对所述基座4相向两端悬空,且该悬空的两端卷曲,所述桥梁5呈拉伸状态。The opposite ends of the bridge 5 and the pair of bases 4 are suspended in the air, and the suspended ends are curled, and the bridge 5 is in a stretched state.

具体的,一对所述基座4悬空的两端向上卷曲或向下卷曲,所述桥梁5为纳米线、微米线或纳米薄膜。Specifically, the suspended ends of a pair of bases 4 are curled up or down, and the bridges 5 are nanowires, microwires or nanofilms.

所述第一应力层的材料为金属、氧化物或半导体,其中,金属包括但不限于Ti、Cr、Pt、Au、Ag、Pd或Fe;氧化物包括但不限于Al2O3、ZnO、Si3N4、SiO或SiO2,半导体包括但不限于Si、Ge、Ⅲ-Ⅴ族化合物或SixGe1-x,其中0<x<1。对于所述第一应力层的材料为金属或氧化物,可以采用蒸发、溅射、外延等方法形成;对于所述第一应力层的材料为半导体,可采用化学气相沉积、外延等方法形成。本实施例中,所述第一应力层3的材料优选为Ge,采用外延法形成。The material of the first stress layer is metal, oxide or semiconductor, wherein, metal includes but not limited to Ti, Cr, Pt, Au, Ag, Pd or Fe; oxide includes but not limited to Al 2 O 3 , ZnO, Si 3 N 4 , SiO or SiO 2 , semiconductors include but not limited to Si, Ge, III-V group compounds or Six Ge 1-x , where 0<x<1. If the material of the first stress layer is metal or oxide, it can be formed by evaporation, sputtering, epitaxy and other methods; if the material of the first stress layer is semiconductor, it can be formed by chemical vapor deposition, epitaxy and other methods. In this embodiment, the material of the first stress layer 3 is preferably Ge, which is formed by epitaxy.

所述第二应力层6的材料包括金属、氧化物及半导体中的一种或多种,其中,金属包括但不限于Ti、Cr、Pt、Au、Ag、Pd、Fe、Co及Ni,氧化物包括但不限于Al2O3、ZnO、Si3N4、SiO及SiO2;半导体包括但不限于Si、Ge、Ⅲ-Ⅴ族化合物及SixGe1-x中的一种或多种,其中0<x<1。所述第二应力层6可以为单层或复合层结构。本实施例中,所述第而应力层6的材料优选为Ti、Cr、Si3N4、SiO或SiO2The material of the second stress layer 6 includes one or more of metals, oxides and semiconductors, wherein metals include but not limited to Ti, Cr, Pt, Au, Ag, Pd, Fe, Co and Ni, oxides Compounds include but not limited to Al 2 O 3 , ZnO, Si 3 N 4 , SiO and SiO 2 ; semiconductors include but not limited to one or more of Si, Ge, III-V compounds and Six Ge 1- x , where 0<x<1. The second stress layer 6 can be a single layer or a composite layer structure. In this embodiment, the material of the second stress layer 6 is preferably Ti, Cr, Si 3 N 4 , SiO or SiO 2 .

所述第一应力层3与所述第二应力层6可以采用相同材料,也可以采用不同的材料。本实施例中,所述第一应力层3与所述第二应力层6优选为采用不同材料,使得所述第二应力层6更容易对所述第一应力层3产生压应力或张应力,亦即对所述基座4施加压应力或张应力,使所述桥梁5拉伸程度更高,得到更大的张应力。The first stress layer 3 and the second stress layer 6 can be made of the same material or different materials. In this embodiment, the first stress layer 3 and the second stress layer 6 are preferably made of different materials, so that the second stress layer 6 is more likely to generate compressive stress or tensile stress on the first stress layer 3 , that is, applying compressive stress or tensile stress to the base 4, so that the bridge 5 can be stretched to a higher degree, and a larger tensile stress can be obtained.

本发明的应变结构中第一应力层为桥状结构,且该桥状结构的桥梁及一对基座相向两端悬空,由于桥状结构的基座上形成有提供应力的薄膜(第二应力层),所述基座悬空的端部卷曲使所述桥梁拉伸,形成高张应变材料。本发明的应力结构具有高张应力,适用于一定范围内的任意材料,能够满足不同领域的应用,提高器件性能。In the strain structure of the present invention, the first stress layer is a bridge-like structure, and the bridge of the bridge-like structure and a pair of bases are suspended in the air at opposite ends, because a film providing stress (second stress) is formed on the base of the bridge-like structure. layer), the suspended end of the base is crimped to stretch the bridge, forming a high tensile strain material. The stress structure of the present invention has high tensile stress, is applicable to any material within a certain range, can satisfy applications in different fields, and improves device performance.

综上所述,本发明的应变结构及其制作方法通过在桥状结构的基座上形成提供应力的薄膜,将桥梁及一对基座相向两端下方的牺牲层腐蚀掉后,所述桥梁及一对基座相向两端悬空,由于所述基座表面的第二应力层存在应力,就会带着所述基座悬空的端部卷曲使所述桥梁拉伸,形成张应变材料,得到应力结构。本发明的应力结构的制作方法可以给一定范围内的任意材料施加张应力,方法简单有效、与半导体工艺兼容,具有成本低,且制作速度快的优点。本发明制作的应力结构具有高张应力,能够提高器件的各种性能。所以,本发明有效克服了现有技术中的种种缺点而具高度产业利用价值。In summary, the strained structure and its manufacturing method of the present invention form a stress-providing film on the base of the bridge-like structure, and after the sacrificial layer under the bridge and a pair of bases facing opposite ends is corroded, the bridge and a pair of pedestals are suspended at opposite ends, because the stress exists in the second stress layer on the surface of the pedestal, the suspended end of the pedestal will be curled to make the bridge stretch, forming a tensile strain material, and obtaining stress structure. The manufacturing method of the stress structure of the present invention can apply tensile stress to any material within a certain range, and the method is simple and effective, compatible with semiconductor technology, and has the advantages of low cost and fast manufacturing speed. The stress structure produced by the invention has high tensile stress and can improve various performances of devices. Therefore, the present invention effectively overcomes various shortcomings in the prior art and has high industrial application value.

上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above-mentioned embodiments only illustrate the principles and effects of the present invention, but are not intended to limit the present invention. Anyone skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those skilled in the art without departing from the spirit and technical ideas disclosed in the present invention should still be covered by the claims of the present invention.

Claims (15)

1. a manufacture method for strain structure, is characterized in that, at least comprises the following steps:
S1: provide a substrate, forms a sacrifice layer and one first stressor layers from bottom to top successively at described substrate surface;
S2: described first stressor layers is graphical, forms bridge-like structure; Described bridge-like structure comprises the pair of base being formed at described sacrificial layer surface and at least one bridge connecting this pair of base;
S3: base-plates surface forms the second stressor layers described in a pair;
S4: adopt wet etching to remove below described bridge and the sacrifice layer of described pedestal in opposite directions below two ends, two ends are unsettled in opposite directions to make pedestal described in described bridge and a pair, and these unsettled two ends are curling makes described bridge stretch, and obtains strain structure.
2. the manufacture method of strain structure according to claim 1, is characterized in that: described second stressor layers has tensile stress, and the unsettled two ends of pedestal described in a pair upsweep.
3. the manufacture method of strain structure according to claim 1, is characterized in that: described second stressor layers has compression, and the unsettled two ends of pedestal described in a pair are curling downwards.
4. the manufacture method of strain structure according to claim 1, is characterized in that: the material of described first stressor layers is Si 3n 4, metal, oxide or semiconductor; The material of described second stressor layers comprises Si 3n 4, metal, one or more in oxide and semiconductor.
5. the manufacture method of strain structure according to claim 4, is characterized in that: described second stressor layers is individual layer or lamination layer structure.
6. the manufacture method of strain structure according to claim 4, is characterized in that: the material of described first stressor layers is Si 3n 4, metal Ti, Cr, Pt, Au, Ag, Pd, Fe, or oxide Al 2o 3, ZnO, SiO, SiO 2, or semiconductor Si, Ge, III-V compounds of group, Si xge 1-x, wherein 0<x<1; The material of described second stressor layers comprises Si 3n 4, metal Ti, Cr, Pt, Au, Ag, Pd, Fe, Co, Ni, or oxide Al 2o 3, ZnO, SiO, SiO 2, or semiconductor Si, Ge, III-V compounds of group, Si xge 1-xin one or more, wherein 0<x<1.
7. the manufacture method of the strain structure according to claim 1,4,5 or 6, is characterized in that: described first stressor layers is different from the material of described second stressor layers.
8. the manufacture method of strain structure according to claim 1, is characterized in that: described bridge is nano wire, micro wire or nano thin-film.
9. the manufacture method of strain structure according to claim 1, is characterized in that: described pedestal is square, rectangle, trapezoidal, circular or oval.
10. the manufacture method of strain structure according to claim 1, is characterized in that: the material of described sacrifice layer is selected from SiO 2, Si 3n 4, Ge, photoresist, one in PDMS and PMMA, and described sacrifice layer adopts different materials from described first stressor layers and the second stressor layers.
The manufacture method of 11. 1 kinds of strain structure, is characterized in that, at least comprises the following steps:
S1: provide a substrate, forms a sacrifice layer and one first stressor layers from bottom to top successively at described substrate surface;
S2: form the second stressor layers on described first stressor layers surface, and described second stressor layers is graphical, form a pair substrate;
S3: described first stressor layers is graphical, forms bridge-like structure; Described bridge-like structure comprises the pair of base being formed at described sacrificial layer surface and at least one bridge connecting this pair of base; Described pedestal to be positioned at below described substrate and with described substrates while stacking or partially overlap;
S4: adopt wet etching to remove below described bridge and the sacrifice layer of described pedestal in opposite directions below two ends, two ends are unsettled in opposite directions to make pedestal described in described bridge and a pair, and these unsettled two ends are curling makes described bridge stretch, and obtains strain structure.
12. 1 kinds of strain structure, comprising:
Substrate;
Be formed at the sacrifice layer of described substrate surface;
Patterned first stressor layers, is formed at described sacrificial layer surface; This patterned first stressor layers is bridge-like structure; Described bridge-like structure comprises pair of base and connects at least one bridge of this pair of base;
Be formed at the second stressor layers of described base-plates surface;
It is characterized in that:
Described in described bridge and a pair, two ends are unsettled in opposite directions for pedestal, and these unsettled two ends are curling, and described bridge is extended state.
13. strain structure according to claim 12, is characterized in that: the unsettled two ends of pedestal described in a pair upsweep or curling downwards.
14. strain structure according to claim 12, is characterized in that: described bridge is nano wire, micro wire or nano thin-film.
15. strain structure according to claim 12, is characterized in that: the material of described first stressor layers is Si 3n 4, metal, oxide or semiconductor; The material of described second stressor layers comprises Si 3n 4, metal, one or more in oxide and semiconductor.
CN201310583275.8A 2013-11-19 2013-11-19 Strain structure and preparation method thereof Active CN103560157B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310583275.8A CN103560157B (en) 2013-11-19 2013-11-19 Strain structure and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310583275.8A CN103560157B (en) 2013-11-19 2013-11-19 Strain structure and preparation method thereof

Publications (2)

Publication Number Publication Date
CN103560157A CN103560157A (en) 2014-02-05
CN103560157B true CN103560157B (en) 2016-02-24

Family

ID=50014364

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310583275.8A Active CN103560157B (en) 2013-11-19 2013-11-19 Strain structure and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103560157B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104934294B (en) * 2014-03-18 2018-01-30 中国科学院上海微系统与信息技术研究所 Strain film structure and the method for adjusting strain film stress on a kind of insulator
CN105321821B (en) * 2014-07-11 2018-09-25 中国科学院上海微系统与信息技术研究所 Adjustable suspension strain film structure of stress and preparation method thereof
GB201612419D0 (en) * 2016-07-18 2016-08-31 Cambridge Entpr Ltd A scalable quantum-confined device
CN109166790B (en) * 2018-07-28 2022-04-22 西安交通大学 A method for exfoliating perovskite oxide piezoelectric thin films on graphene using metal stress layers
CN112647044B (en) * 2020-11-20 2022-03-18 复旦大学 Micro-nano actuator based on controllable curled vanadium dioxide thin film and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101681695A (en) * 2006-09-06 2010-03-24 伊利诺伊大学评议会 controlled buckling structures in semiconductor interconnects and nanomembranes for stretchable electronics

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008140967A (en) * 2006-12-01 2008-06-19 Keio Gijuku Tunable carbon nanotube device
US8878120B2 (en) * 2010-12-13 2014-11-04 The Trustees Of The Stevens Institute Of Technology Active bandgap tuning of graphene for tunable photodetection applications

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101681695A (en) * 2006-09-06 2010-03-24 伊利诺伊大学评议会 controlled buckling structures in semiconductor interconnects and nanomembranes for stretchable electronics

Also Published As

Publication number Publication date
CN103560157A (en) 2014-02-05

Similar Documents

Publication Publication Date Title
CN103560157B (en) Strain structure and preparation method thereof
TWI734093B (en) Device and method for making an inverted t channel field effect transistor (itfet) including a superlattice
CN103213935B (en) two-dimensional device array
CN101595565B (en) Method of producing precision vertical and horizontal layers in a vertical semiconductor structure
CN109234807A (en) A kind of stretchable crystalline semiconductor nano wire and preparation method thereof
CN103311305B (en) Silicon-based lateral nano wire multiple-gate transistor and preparation method thereof
CN104124272A (en) Integrated nonpolar GaN nanowire transistor high in electron mobility and preparation method thereof
CN102963862B (en) A kind of preparation method of monocrystalline silicon nano line mesh array structure
CN106082121A (en) Nano-wire array preparation method, nano-wire array integrated device and preparation method thereof
CN107849727A (en) A network of nanostructures grown on a substrate
CN103633123B (en) Nanowire substrate structure and preparation method thereof
CN102354669A (en) Production method of silicon nano-wire device
CN105957801A (en) Gallium nitride nanocone and gallium nitride nanorod mixed array manufacturing method
CN105895530B (en) Method for manufacturing two-dimensional material structure and two-dimensional material device
CN108807279A (en) Semiconductor structure and manufacturing method thereof
Sun et al. The morphology evolution of selective area wet etched commercial patterned sapphire substrates
CN104505335A (en) Manufacture method of controllable silicon nanowire array within two-dimensional plane
CN103985788B (en) Tensile strain germanium MSM photoelectric detector and preparation method thereof
CN107871666B (en) Method of fabricating vertically stacked integrated semiconductor nanowires and field effect transistors thereof
CN111435642A (en) Three-dimensional stacked semiconductor nanowire structure and preparation method thereof
CN102263166B (en) Method for improving performances of AlGaN-based detector by using nano particles
CN103441062B (en) A kind of Ge component and the preparation method of bandwidth regulatable SiGe nano belt
CN109962010A (en) Wafer-level large-area semiconductor nanosheet and preparation method thereof
TWI495102B (en) Transistor and manufacturing method thereof
CN103107065A (en) Nanowire device preparation method based on nanowire ordered arrangement

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant