CN103545353B - A kind of heated by electrodes utmost point and processing technology thereof - Google Patents
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- 238000005530 etching Methods 0.000 claims abstract description 53
- 238000002955 isolation Methods 0.000 claims abstract description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 21
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 21
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- 238000001039 wet etching Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
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Abstract
一种电极加热极及其加工工艺,包括基材、加热极层、隔离层和电极层,加热极层通过淀积方式覆在基材上,加热极层上还淀积有二氧化硅隔离层,金属电极层通过淀积方式包覆在加热极层和隔离层上,隔离层上部的电极层通过刻蚀去除。本发明利用二氧化硅的刻蚀速率与金属刻蚀速率差异较大的原理在电极层与加热极层之间增加一层二氧化硅隔离层,在进行电极层的刻蚀时起到了良好的保护作用,有效避免加热极层遭到刻蚀,保证了加热极层的完整性,极大的降低了控制刻蚀时间精度的难度,提高了产品的加热极性能。
An electrode heating electrode and its processing technology, including a substrate, a heating electrode layer, an isolation layer and an electrode layer, the heating electrode layer is deposited on the substrate by deposition, and a silicon dioxide isolation layer is also deposited on the heating electrode layer , the metal electrode layer is coated on the heating electrode layer and the isolation layer by deposition, and the electrode layer on the upper part of the isolation layer is removed by etching. The present invention utilizes the principle that the etching rate of silicon dioxide is quite different from that of metal etching to add a silicon dioxide isolation layer between the electrode layer and the heating electrode layer, which plays a good role in the etching of the electrode layer. The protective function effectively prevents the heating electrode layer from being etched, ensures the integrity of the heating electrode layer, greatly reduces the difficulty of controlling the accuracy of etching time, and improves the heating electrode performance of the product.
Description
技术领域technical field
本发明涉及一种芯片电极,尤其涉及一种电极加热极及其加工工艺。The invention relates to a chip electrode, in particular to an electrode heating electrode and its processing technology.
背景技术Background technique
目前芯片的电极层通常是在基材表面覆上一层薄膜状的电极层,然后采用刻蚀的方式去除多余的电极层,形成最终所需线路的电极层。At present, the electrode layer of the chip is usually covered with a thin film electrode layer on the surface of the substrate, and then the redundant electrode layer is removed by etching to form the electrode layer of the final required circuit.
薄膜淀积是芯片加工过程中常用的一种加工方式,通过淀积工艺可以在基材上生长导各种导电薄膜层、绝缘薄膜层或者半导体薄膜层。电极层之所以非常薄是因为厚度薄可以有非常均匀的电阻温度系数,介电常数低,这样能让信号传输损失更小,薄的电极层通过大电流情况下温升较小,这对于散热和元件寿命都是有很大好处的。然后即是需要将淀积成的整块电极层刻蚀成所需的线路。将芯片的线路设计用光刻机印成胶片,然后把一种主要成分对特定光谱敏感而发生化学反应的感光干膜覆盖在基板上,干膜分两种,光聚合型和光分解型,光聚合型干膜在特定光谱的光照射下会硬化,从水溶性物质变成水不溶性而光分解型则正好相反。用光聚合型感光干膜先盖在基板上,上面再盖一层线路胶片让其曝光,曝光的地方呈黑色不透光,反之则是透明的(线路部分)。光线通过胶片照射到感光干膜上,凡是胶片上透明通光的地方干膜颜色变深开始硬化,紧紧包裹住基板表面的电极层,就像把线路图印在基板上一样,接下来经过显影步骤(使用碳酸钠溶液洗去未硬化干膜),让不需要干膜保护的电极层露出来,这称作脱膜工序。Thin film deposition is a commonly used processing method in chip processing. Through the deposition process, various conductive thin film layers, insulating thin film layers or semiconductor thin film layers can be grown on the substrate. The reason why the electrode layer is very thin is that it can have a very uniform temperature coefficient of resistance and a low dielectric constant, which can make the signal transmission loss smaller, and the thin electrode layer has a smaller temperature rise when passing a large current, which is good for heat dissipation. and component life are of great benefit. Then it is necessary to etch the deposited entire electrode layer into the desired circuit. The circuit design of the chip is printed into a film with a photolithography machine, and then a photosensitive dry film whose main component is sensitive to a specific spectrum and undergoes a chemical reaction is covered on the substrate. There are two types of dry film, photopolymerization type and photodecomposition type. The polymeric dry film will harden under the light of a specific spectrum, changing from water-soluble to water-insoluble, while the photodecomposition type is just the opposite. First cover the substrate with a photopolymerizable photosensitive dry film, and then cover it with a layer of circuit film to expose it. The exposed part is black and opaque, otherwise it is transparent (the circuit part). The light is irradiated on the photosensitive dry film through the film, and the dry film becomes darker and hardens where the film is transparent and transparent, and it tightly wraps the electrode layer on the surface of the substrate, just like printing the circuit diagram on the substrate. The development step (using sodium carbonate solution to wash off the unhardened dry film) exposes the electrode layer that does not need dry film protection, which is called the stripping process.
然后则是需要采用刻蚀的方式去除无用的电极层部分,目前常用的刻蚀方式为干法刻蚀和湿法刻蚀。湿法刻蚀是一个纯粹的化学反应过程,是指利用溶液与预刻蚀材料之间的化学反应来去除未被掩蔽膜材料掩蔽的部分而达到刻蚀目的。干法刻蚀种类很多,包括光挥发、气相腐蚀、等离子体腐蚀等。干法刻蚀的各向异性好,选择比高,可控性、灵活性、重复性好,细线条操作安全,易实现自动化,无化学废液,处理过程未引入污染,洁净度高。Then it is necessary to use etching to remove the useless electrode layer part. Currently, the commonly used etching methods are dry etching and wet etching. Wet etching is a purely chemical reaction process, which refers to using the chemical reaction between the solution and the pre-etching material to remove the part not masked by the masking film material to achieve the purpose of etching. There are many types of dry etching, including light volatilization, vapor phase etching, plasma etching, etc. Dry etching has good anisotropy, high selection ratio, good controllability, flexibility and repeatability, safe operation of thin lines, easy automation, no chemical waste liquid, no pollution in the treatment process, and high cleanliness.
在光分路器器件中,基材上覆有两层薄膜,电极层和加热极层,电极层和加热极层采用不同材质的金属制成,传统的方式为先在基材上淀积一层加热层,再在其上淀积一层电极层,然后再对电极层实施刻蚀形成所需的导电线路。在刻蚀电极层时,由于金属材质的刻蚀速率相近,并且电极层和加热极层相邻,因此加热极也会被刻蚀,电极层和加热极层厚度极薄,控制刻蚀精度的难度过大,一旦控制不好,会造成加热极被刻蚀,造成损伤,严重影响器件性能。In the optical splitter device, the substrate is covered with two layers of thin films, the electrode layer and the heating electrode layer. The electrode layer and the heating electrode layer are made of metals of different materials. The traditional method is to deposit a Layer heating layer, then deposit an electrode layer on it, and then etch the electrode layer to form the required conductive lines. When etching the electrode layer, since the etching rate of the metal material is similar, and the electrode layer and the heating electrode layer are adjacent, the heating electrode will also be etched, and the thickness of the electrode layer and the heating electrode layer is extremely thin, which controls the etching accuracy If the difficulty is too high, once the control is not good, the heating electrode will be etched, causing damage and seriously affecting the performance of the device.
发明内容Contents of the invention
本发明所要解决的技术问题和提出的技术任务是对现有技术进行改进,提供一种电极加热极及其加工工艺,解决目前技术中电极层刻蚀精度控制难度过大,极易造成加热极层被刻蚀,严重影响器件性能的问题。The technical problem to be solved and the technical task proposed by the present invention are to improve the existing technology, provide an electrode heating electrode and its processing technology, and solve the problem that the control of the etching precision of the electrode layer is too difficult in the current technology, which easily causes the heating electrode The layer is etched, which seriously affects the performance of the device.
为解决以上技术问题,本发明的技术方案是:For solving above technical problem, technical scheme of the present invention is:
一种电极加热极,包括基材、加热极层、隔离层和电极层,其特征在于,加热极层通过淀积方式覆在基材上,加热极层上还淀积有隔离层,电极层通过淀积方式包覆在加热极层和隔离层上,隔离层上部的电极层通过刻蚀去除。加热极层的上方有隔离层保护,在进行电极层刻蚀时可确保加热极层不受刻蚀,确保其完整性,从而保证了产品加热极的性能,并且电极层以及加热极层的电气性能也不会受到影响,可安全正常的实现电气及加热功能。An electrode heating pole, comprising a base material, a heating pole layer, an isolation layer and an electrode layer, is characterized in that the heating pole layer is covered on the base material by deposition, and the isolation layer is also deposited on the heating pole layer, and the electrode layer The heating electrode layer and the isolation layer are covered by deposition, and the electrode layer on the upper part of the isolation layer is removed by etching. The top of the heating electrode layer is protected by an isolation layer. When the electrode layer is etched, it can ensure that the heating electrode layer is not etched and its integrity is ensured, thereby ensuring the performance of the product heating electrode, and the electrical properties of the electrode layer and the heating electrode layer. The performance will not be affected, and the electrical and heating functions can be realized safely and normally.
进一步的,所述的隔离层采用二氧化硅制成,二氧化硅的刻蚀速率与金属的刻蚀速率差异较大,在进行金属电极层刻蚀时隔离层二氧化硅不会被快速刻蚀,从而将加热极层与外界隔绝,从而起到良好的保护效果,确保加热极层的完整性。Further, the isolation layer is made of silicon dioxide, the etching rate of silicon dioxide is quite different from the etching rate of metal, and the silicon dioxide of the isolation layer will not be etched rapidly when the metal electrode layer is etched. Corrosion, so as to isolate the heating pole layer from the outside world, so as to play a good protective effect and ensure the integrity of the heating pole layer.
进一步的,所述的隔离层的淀积厚度为2000~30000埃,在确保达到隔离保护加热极层效果上尽量降低隔离层的淀积厚度,减少产品的制作成本。Further, the deposition thickness of the isolation layer is 2000-30000 angstroms, and the deposition thickness of the isolation layer should be reduced as much as possible to ensure the effect of isolating and protecting the heating electrode layer, thereby reducing the production cost of the product.
制作电极加热极的加工工艺,包括如下步骤:薄膜淀积和刻蚀,其特征在于,在基材上淀积一层加热极层,然后在加热极层刻蚀成所需线路图样后再在加热极层淀积一层二氧化硅隔离层,然后进行隔离层刻蚀,去除包覆在加热极层两侧边处的隔离层使隔离层只覆盖于加热极层的顶面,在进行隔离层刻蚀时,由于二氧化硅刻蚀气体基本不刻蚀金属材质,刻蚀二氧化硅后,加热极保持完整,在此基础上再淀积电极层,通过刻蚀去除隔离层顶面的电极层形成所需的线路。在进行电极层刻蚀时,由于隔离层二氧化硅的保护,加热极不会受到损伤,从而极大的降低了刻蚀控制难度,降低了控制精确刻蚀时间的难度,使生产简易化,并且提高产品加热极的性能。The processing technology for making the electrode heating electrode includes the following steps: film deposition and etching, which is characterized in that a layer of heating electrode layer is deposited on the substrate, and then the heating electrode layer is etched into the required circuit pattern and then Deposit a layer of silicon dioxide isolation layer on the heating electrode layer, and then perform isolation layer etching to remove the isolation layer covering the two sides of the heating electrode layer so that the isolation layer only covers the top surface of the heating electrode layer. When etching the silicon dioxide layer, since the silicon dioxide etching gas basically does not etch the metal material, after etching the silicon dioxide, the heating electrode remains intact. On this basis, the electrode layer is deposited, and the top surface of the isolation layer is removed by etching. The electrode layer forms the desired wiring. When etching the electrode layer, due to the protection of the isolation layer silicon dioxide, the heating will not be damaged, which greatly reduces the difficulty of etching control, reduces the difficulty of controlling the precise etching time, and simplifies production. And improve the performance of the heating pole of the product.
进一步的,所述的刻蚀采用干法刻蚀。干法刻蚀物理性刻蚀方向性很强,可以做到各向异性刻蚀,但不能进行选择性刻蚀;化学性刻蚀利用等离子体中的化学活性原子团与被刻蚀材料发生化学反应,从而实现刻蚀目的。由于刻蚀的核心还是化学反应(只是不涉及溶液的气体状态),因此刻蚀的效果和湿法刻蚀有些相近,具有较好的选择性,但各向异性较差。采用干法刻蚀同时兼有各向异性和选择性好的优点,保证刻蚀的效果。Further, the etching adopts dry etching. Dry etching has a strong physical etching direction and can achieve anisotropic etching, but cannot perform selective etching; chemical etching uses chemically active atomic groups in the plasma to chemically react with the etched material , so as to achieve the purpose of etching. Since the core of etching is still a chemical reaction (but it does not involve the gas state of the solution), the etching effect is somewhat similar to wet etching, with better selectivity, but poor anisotropy. The use of dry etching has the advantages of good anisotropy and selectivity at the same time, ensuring the etching effect.
进一步的,所述的薄膜淀积采用化学气相淀积保证膜厚均匀性。化学气相淀积是把含有构成薄膜元素的气态反应剂引入反应室,在晶圆表面发生化学反应,从而生成所需的固态薄膜并淀积在其表面。化学气相淀积法的淀积温度低,薄膜成分和厚度易控,薄膜厚度与淀积时间成正比,均匀性与重复性好,台阶覆盖性良好,操作方便。Further, the film deposition adopts chemical vapor deposition to ensure the uniformity of film thickness. Chemical vapor deposition is to introduce gaseous reactants containing film elements into the reaction chamber, and chemical reactions occur on the surface of the wafer, thereby forming the required solid film and depositing it on the surface. The deposition temperature of the chemical vapor deposition method is low, the film composition and thickness are easy to control, the film thickness is proportional to the deposition time, the uniformity and repeatability are good, the step coverage is good, and the operation is convenient.
与现有技术相比,本发明优点在于:Compared with the prior art, the present invention has the advantages of:
本发明所述的电极加热极及其加工工艺利用二氧化硅的刻蚀速率与金属刻蚀速率差异较大的原理在电极层与加热极层之间增加一层二氧化硅隔离层,在进行电极层的刻蚀时起到了良好的保护作用,有效避免加热极层遭到刻蚀,保证了加热极层的完整性,极大的降低了控制刻蚀时间精度的难度,有效降低生产难度,提高了产品的加热极性能;本发明结构简单,制造工艺技术成熟操作简便,制作成本低,易于量产。The electrode heating electrode and its processing technology according to the present invention use the principle that the etching rate of silicon dioxide is quite different from that of metal etching to add a layer of silicon dioxide isolation layer between the electrode layer and the heating electrode layer. The etching of the electrode layer plays a good protective role, effectively avoiding the etching of the heating electrode layer, ensuring the integrity of the heating electrode layer, greatly reducing the difficulty of controlling the etching time accuracy, and effectively reducing the difficulty of production. The heating polarity of the product is improved; the invention has simple structure, mature manufacturing technology, easy operation, low manufacturing cost and easy mass production.
附图说明Description of drawings
图1为本发明淀积隔离层的结构示意图;Fig. 1 is the structural representation of depositing isolation layer of the present invention;
图2为本发明刻蚀隔离层的结构示意图;Fig. 2 is the structural representation of etching isolation layer of the present invention;
图3为本发明淀积电极层的结构示意图;Fig. 3 is the structure schematic diagram of deposition electrode layer of the present invention;
图4为本发明刻蚀电极层的结构示意图。FIG. 4 is a schematic structural view of an etching electrode layer according to the present invention.
具体实施方式detailed description
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
本发明实施例公开的一种电极加热极及其加工工艺,以降低电极层刻蚀控制难度,保护加热极层,提高产品加热极性能为目的。An electrode heating electrode and its processing technology disclosed in the embodiments of the present invention are aimed at reducing the difficulty of electrode layer etching control, protecting the heating electrode layer, and improving the heating electrode performance of products.
如图1~4所示,一种电极加热极,包括基材1、加热极层2、隔离层3和电极层4,隔离层3选用二氧化硅材质制成,金属材质的加热极层2通过淀积方式覆在基材1上,加热极层2上再淀积上二氧化硅材质的隔离层3,隔离层3的淀积厚度为2000~30000埃,电极层4通过淀积方式包覆在加热极层2和隔离层3上,隔离层3上部的电极层4通过刻蚀去除,在进行电极层刻蚀时,由于隔离层二氧化硅的保护,加热极层不会受到损伤。As shown in Figures 1 to 4, an electrode heating electrode includes a base material 1, a heating electrode layer 2, an isolation layer 3 and an electrode layer 4, the isolation layer 3 is made of silicon dioxide, and the heating electrode layer 2 made of metal Cover the base material 1 by deposition, and then deposit an isolation layer 3 made of silicon dioxide on the heating electrode layer 2. The deposition thickness of the isolation layer 3 is 2000-30000 angstroms, and the electrode layer 4 is covered by deposition. Covering the heating electrode layer 2 and the isolation layer 3, the electrode layer 4 on the upper part of the isolation layer 3 is removed by etching. When the electrode layer is etched, the heating electrode layer will not be damaged due to the protection of the isolation layer silicon dioxide.
在基材1上采用化学气相淀积法淀积一层加热极层2,采用反应离子刻蚀将加热极层2刻蚀成所需线路图样,如图1所示,在加热极层2淀积一层二氧化硅隔离层3,再如图2所示,进行隔离层3的刻蚀,去除包覆在加热极层2两侧边处的隔离层3使隔离层3只覆盖于加热极层2的顶面,由于二氧化硅刻蚀气体基本不刻蚀金属,刻蚀二氧化硅后,加热极的金属保持完整,如图3所示,在此基础上再在加热极层2以及隔离层3上淀积电极层4,使加热极层2的两侧边与电极层相连保证电气联通和热传导,最后如图4所示,通过刻蚀去除隔离层3顶面的电极层4使之形成所需的线路。A heating electrode layer 2 is deposited on the substrate 1 by chemical vapor deposition, and the heating electrode layer 2 is etched into a desired circuit pattern by reactive ion etching. As shown in FIG. 1 , the heating electrode layer 2 is deposited Build up a layer of silicon dioxide spacer layer 3, and then as shown in Figure 2, carry out the etching of spacer layer 3, remove the spacer layer 3 that covers the heating electrode layer 2 two sides place, make spacer layer 3 only cover the heating pole On the top surface of layer 2, since the silicon dioxide etching gas basically does not etch metal, after etching silicon dioxide, the metal of the heating electrode remains intact, as shown in Figure 3. On this basis, the heating electrode layer 2 and Electrode layer 4 is deposited on the isolation layer 3, so that both sides of the heating electrode layer 2 are connected to the electrode layer to ensure electrical communication and heat conduction. Finally, as shown in FIG. 4, the electrode layer 4 on the top surface of the isolation layer 3 is removed by etching to make to form the desired line.
以上仅是本发明的优选实施方式,应当指出的是,上述优选实施方式不应视为对本发明的限制,本发明的保护范围应当以权利要求所限定的范围为准。对于本技术领域的普通技术人员来说,在不脱离本发明的精神和范围内,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above are only preferred implementations of the present invention. It should be noted that the above preferred implementations should not be regarded as limiting the present invention, and the scope of protection of the present invention should be based on the scope defined in the claims. For those skilled in the art, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, and these improvements and modifications should also be regarded as the protection scope of the present invention.
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