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CN103538448B - A kind of manufacture method of windshield - Google Patents

A kind of manufacture method of windshield Download PDF

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CN103538448B
CN103538448B CN201310540770.0A CN201310540770A CN103538448B CN 103538448 B CN103538448 B CN 103538448B CN 201310540770 A CN201310540770 A CN 201310540770A CN 103538448 B CN103538448 B CN 103538448B
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windshield
bearing layer
injection
load
polycarbonate
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CN103538448A (en
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颜悦
姜良宝
郭新涛
厉蕾
李晓宇
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Beijing Aviation Materials Research Institute Co ltd
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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Abstract

本发明涉及风挡玻璃的制造技术,涉及一种轻质、高抗撞的风挡玻璃的制造方法。本发明采用整体注塑工艺制造出带螺栓孔连接结构的聚碳酸酯承力层。提高了风挡玻璃的抗撞水平和制造效率。本发明选用注塑成型聚碳酸酯为承力层,并采用螺栓连接的方式将风挡玻璃连接到车身骨架上,而聚碳酸酯上的螺栓连接孔与承力层为整体注塑成型。这种风挡玻璃不仅轻质、高抗撞,而且结构简单、连接可靠,其制造效率也大大提高。抗撞水平达到1.8Kg飞鸟以500Km/h撞击承力层不碎裂,无碎片脱落。1Kg铝弹以600Km/h冲击不穿透承力层。速度撞击到风挡玻璃上,铝弹不穿透承力层,且承力层上无碎片脱落。

The invention relates to the manufacturing technology of the windshield, in particular to a manufacturing method of the windshield with light weight and high impact resistance. The invention adopts an integral injection molding process to manufacture the polycarbonate load-bearing layer with a bolt hole connection structure. The impact resistance level and manufacturing efficiency of the windshield are improved. The invention selects injection-molded polycarbonate as the load-bearing layer, and connects the windshield glass to the body frame by means of bolt connection, and the bolt connection holes on the polycarbonate and the load-bearing layer are integrally injection-molded. This kind of windshield is not only light in weight and high in impact resistance, but also simple in structure and reliable in connection, and its manufacturing efficiency is also greatly improved. The anti-collision level reaches 1.8Kg and the flying bird hits the load-bearing layer at 500Km/h without breaking or falling off. The impact of 1Kg aluminum bullet at 600Km/h does not penetrate the bearing layer. When the speed hits the windshield, the aluminum bullet does not penetrate the load-bearing layer, and no fragments fall off from the load-bearing layer.

Description

一种风挡玻璃的制造方法A method of manufacturing a windshield

技术领域technical field

本发明涉及风挡玻璃的制造技术,涉及一种轻质、高抗撞的风挡玻璃的制造方法。The invention relates to the manufacturing technology of the windshield, in particular to a manufacturing method of the windshield with light weight and high impact resistance.

背景技术Background technique

风挡玻璃作为车身的一部分不仅要能够承受各种状态下的结构载荷和冲击,还要为驾驶员提供清晰的视界和良好的光学视觉效果,同时还要具有防冰除雾、防雨水、电磁屏蔽好等优异的性能。2002年12月31日开始试运行的上海磁浮运营示范线最高运行速度430Km/h,最高调试时速达到501Km。2003年12月2日日本山梨县在进行的一次磁悬浮列车载人运行试验中创造了时速580Km的列车载人运行世界记录。随着科学技术的飞速发展,列车的速度会越来越快,这也给风挡玻璃的制造技术带来了巨大的挑战。一方面,需要风挡玻璃的抗撞水平越来越高,对于最高速度500Km/h的磁浮列车前窗玻璃,需要考虑异物以相对速度600km/h撞击。根据国际铁路联盟标准UIC651,采用1kg标准铝弹,以600km/h进行撞击试验,要求窗体不被穿透。另一方面要求风挡玻璃在满足结构功能的基础上重量尽可能的轻。现有列车风挡玻璃一般通过多层钢化玻璃层合而成,并采用夹持结构与车身骨架连接。这种连接方式由于支持刚度大,在鸟体撞击载荷作用于支持结构并继续向前挤压边框时,边框夹持结构出现较小的回弹变形,并发生应力集中现象,从而大大降低了风挡玻璃的抗鸟撞水平,同样也不利于列车的减重。As a part of the body, the windshield must not only be able to withstand structural loads and impacts in various states, but also provide the driver with a clear field of vision and good optical visual effects. Good and excellent performance. The Shanghai Maglev Operation Demonstration Line, which started trial operation on December 31, 2002, has a maximum running speed of 430Km/h, and a maximum debugging speed of 501Km. On December 2, 2003, Yamanashi Prefecture, Japan set a world record for a maglev train carrying passengers at a speed of 580Km per hour. With the rapid development of science and technology, the speed of trains will become faster and faster, which also brings great challenges to the manufacturing technology of windshield glass. On the one hand, the anti-collision level of the windshield needs to be higher and higher. For the front window glass of the maglev train with a maximum speed of 500Km/h, it is necessary to consider the impact of foreign objects at a relative speed of 600km/h. According to the standard UIC651 of the International Union of Railways, the 1kg standard aluminum bullet is used for the impact test at 600km/h, and the window is required not to be penetrated. On the other hand, the windshield is required to be as light as possible on the basis of satisfying the structural function. Existing train windshields are generally formed by laminating multiple layers of toughened glass, and are connected to the body frame by a clamping structure. Due to the high support rigidity of this connection method, when the impact load of the bird body acts on the support structure and continues to squeeze the frame forward, the frame clamping structure has a small rebound deformation and stress concentration occurs, thereby greatly reducing the windshield. The level of bird strike resistance of the glass is also not conducive to the weight reduction of the train.

发明内容Contents of the invention

本发明的目的是提供一种风挡玻璃的制造方法。采用此方法制造出的列车风挡玻璃轻质、高抗撞、结构简单、与车身骨架连接可靠。The object of the present invention is to provide a method of manufacturing a windshield. The train windshield manufactured by the method is light in weight, high in impact resistance, simple in structure and reliable in connection with the frame of the vehicle body.

本发明采用以下技术方案:(1)采用注塑成型方法制造出风挡玻璃的承力层;首先,将聚碳酸酯粒料铺放在鼓风干燥箱内,粒料铺层厚度为10~15mm,在120℃下干燥4~8h;然后,对聚碳酸酯进行注塑成型,注塑成型时熔体温度为250-350℃,成型模具温度为50-120℃,注射压力为50-150MPa,冷却时间为10-60s,注射速度为100-150mm/s,保压压力50-70MPa,保压时间10-60s,制备完成风挡玻璃的承力层;(2)对镀有ITO膜的电加热化学强化玻璃进行切割磨边;将切割磨边后的1.5-4mm厚的电加热化学强化玻璃面层、2-6mm厚聚氨酯中间层和注塑成型的聚碳酸酯承力层进行超声清洗,之后使用脱脂棉蘸95%的石油醚擦拭其表面,烘干备用;(3)在承力层和面层之间放置中间层,在中间层和面层之间放置铜电极、温度传感器和导线,组装成风挡玻璃原件;然后,将风挡玻璃原件放入热压釜中,在温度为80-180℃,压力为1-3MPa的条件下保压30-120min,热压层合为风挡玻璃。The present invention adopts the following technical schemes: (1) adopt the injection molding method to manufacture the load-bearing layer of the windshield; first, lay the polycarbonate pellets in the blast drying box, the thickness of the pellet layer is 10-15mm, Dry at 120°C for 4-8 hours; then, perform injection molding on polycarbonate, the melt temperature during injection molding is 250-350°C, the molding mold temperature is 50-120°C, the injection pressure is 50-150MPa, and the cooling time is 10-60s, the injection speed is 100-150mm/s, the holding pressure is 50-70MPa, the holding time is 10-60s, and the load-bearing layer of the windshield is prepared; (2) for the electrothermal chemically strengthened glass coated with ITO film Carry out cutting and edging; after cutting and edging, clean the 1.5-4mm thick electric heating chemically strengthened glass surface layer, 2-6mm thick polyurethane middle layer and injection-molded polycarbonate load-bearing layer, and then use absorbent cotton dipped in 95 % petroleum ether to wipe its surface, and dry it for later use; (3) place an intermediate layer between the load-bearing layer and the surface layer, place copper electrodes, temperature sensors and wires between the intermediate layer and the surface layer, and assemble it into a windshield glass original ; Then, put the original windshield glass into the autoclave, hold the pressure for 30-120min under the conditions of temperature 80-180°C and pressure 1-3MPa, and hot-press laminate it into the windshield glass.

所述风挡玻璃的厚度不超过22mm。The thickness of the windshield is not more than 22mm.

所述的承力层的四周一次注塑成型出安装螺栓孔。Mounting bolt holes are injection molded around the bearing layer at one time.

本发明的发明效果为:本发明采用整体注塑工艺制造出带螺栓孔连接结构的聚碳酸酯承力层。提高了风挡玻璃的抗撞水平和制造效率。The inventive effect of the present invention is: the present invention adopts the integral injection molding process to manufacture the polycarbonate load-bearing layer with the bolt hole connection structure. The impact resistance level and manufacturing efficiency of the windshield are improved.

本发明选用注塑成型聚碳酸酯为承力层,并采用螺栓连接的方式将风挡玻璃连接到车身骨架上,而聚碳酸酯上的螺栓连接孔与承力层为整体注塑成型。这种风挡玻璃不仅轻质、高抗撞,而且结构简单、连接可靠,其制造效率也大大提高。抗撞水平达到1.8Kg飞鸟以500Km/h撞击承力层不碎裂,无碎片脱落。1Kg铝弹以600Km/h冲击不穿透承力层。速度撞击到风挡玻璃上,铝弹不穿透承力层,且承力层上无碎片脱落。The invention selects injection-molded polycarbonate as the load-bearing layer, and connects the windshield glass to the body frame by means of bolt connection, and the bolt connection holes on the polycarbonate and the load-bearing layer are integrally injection-molded. This kind of windshield is not only light in weight and high in impact resistance, but also simple in structure and reliable in connection, and its manufacturing efficiency is also greatly improved. The anti-collision level reaches 1.8Kg and the flying bird hits the load-bearing layer at 500Km/h without breaking or falling off. The impact of 1Kg aluminum bullet at 600Km/h does not penetrate the bearing layer. When the speed hits the windshield, the aluminum bullet does not penetrate the load-bearing layer, and no fragments fall off from the load-bearing layer.

附图说明Description of drawings

图1是本发明风挡玻璃结构示意图侧视图;Fig. 1 is a schematic side view of the windshield structure of the present invention;

图2是本发明风挡玻璃结构示意图俯视图。Fig. 2 is a schematic plan view of the windshield structure of the present invention.

具体实施方式detailed description

下面结合附图和实施例对本发明进行详细的描述。The present invention will be described in detail below in conjunction with the accompanying drawings and embodiments.

(1)采用注塑成型方法制造出风挡玻璃的承力层4:首先,将聚碳酸酯粒料铺放在鼓风干燥箱内,粒料铺层厚度为10~15mm,在120℃下干燥4~8h;然后,对聚碳酸酯进行注塑成型,注塑成型时熔体温度为250-350℃,成型模具温度为50-120℃,注射压力为50-150MPa,冷却时间为10-60s,注射速度为100-150mm/s,保压压力50-70MPa,保压时间10-60s,制备完成风挡玻璃的承力层。注塑成型用模具包括第一模具和与第一模具相配合的第二模具,注塑成型结束后打开模具,顶出制品;(2)对镀有ITO膜2的电加热化学强化玻璃1进行切割磨边;将切割磨边后的1.5-4mm厚的电加热化学强化玻璃面层、2-6mm厚聚氨酯中间层3和注塑成型的聚碳酸酯承力层进行超声清洗,之后使用脱脂棉蘸95%的石油醚擦拭其表面,烘干备用;(3)在承力层和面层之间放置中间层,在中间层和面层之间放置铜电极5、温度传感器6和导线,组装成风挡玻璃原件;然后,将风挡玻璃原件放入热压釜中,在温度为80-180℃,压力为1-3MPa的条件下保压30-120min,热压层合为风挡玻璃。热压层合结束之后,沿着面层玻璃边缘将多余的聚氨酯胶片切掉,并均匀地用密封胶将裸露在外面的中间层和电加热化学强化无机玻璃边缘覆盖。(1) Manufacture the load-bearing layer 4 of the windshield by injection molding: firstly, lay the polycarbonate pellets in a blast drying oven, the thickness of the pellet layer is 10-15mm, and dry at 120°C for 4 ~8h; Then, polycarbonate is injection molded. During injection molding, the melt temperature is 250-350°C, the molding mold temperature is 50-120°C, the injection pressure is 50-150MPa, the cooling time is 10-60s, and the injection speed The pressure is 100-150mm/s, the holding pressure is 50-70MPa, and the holding time is 10-60s, and the load-bearing layer of the windshield is prepared. The mold for injection molding includes a first mold and a second mold matched with the first mold. After the injection molding is finished, the mold is opened to eject the product; (2) cutting and grinding the electrically heated chemically strengthened glass 1 coated with the ITO film 2 Edge: Ultrasonic cleaning of the 1.5-4mm thick electric heating chemically strengthened glass surface layer, 2-6mm thick polyurethane middle layer 3 and injection-molded polycarbonate load-bearing layer after cutting and edging, and then use absorbent cotton dipped in 95% Wipe its surface with petroleum ether, and dry it for later use; (3) place an intermediate layer between the load-bearing layer and the surface layer, place copper electrodes 5, temperature sensors 6 and wires between the intermediate layer and the surface layer, and assemble into a windshield glass original ; Then, put the original windshield glass into the autoclave, hold the pressure for 30-120min under the conditions of temperature 80-180°C and pressure 1-3MPa, and hot-press laminate it into the windshield glass. After the hot-press lamination, the excess polyurethane film is cut off along the edge of the surface glass, and the exposed intermediate layer and the edge of the electric heating chemically strengthened inorganic glass are evenly covered with a sealant.

实施例一Embodiment one

首先将PC粒料放入鼓风干燥箱内,粒料铺层厚度为15mm,在120℃下干燥8h;然后对风挡玻璃聚碳酸酯承力层进行注塑成型,注塑成型时熔体温度为290℃,模具温度为100℃,注射压力为80MPa,冷却时间为20s,注射速度为110mm/s,保压压力65MPa,保压时间30s。将切割磨边后的2.2mm厚的电加热化学强化无机玻璃面层、4mm厚聚氨酯中间层和注塑成型的聚碳酸酯承力层进行超声清洗,之后使用脱脂棉蘸95%的石油醚擦拭其表面,烘干备用。将4mm厚的聚氨酯胶片夹在聚碳酸酯和电加热玻璃之间,在指定位置放置电极、温度传感器和导线,然后将其放入热压釜中在温度为120℃,压力为1.6MPa的条件下保压90min。热压层合完成后,对风挡玻璃进行厚度和抗撞性能测试,测试结果如下:First put the PC pellets into the blast drying oven, the thickness of the pellet layer is 15mm, and dry at 120°C for 8 hours; then the polycarbonate load-bearing layer of the windshield is injection-molded, and the melt temperature is 290 during injection molding. ℃, the mold temperature is 100℃, the injection pressure is 80MPa, the cooling time is 20s, the injection speed is 110mm/s, the holding pressure is 65MPa, and the holding time is 30s. After cutting and edging, the 2.2mm thick electrically heated chemically strengthened inorganic glass surface layer, the 4mm thick polyurethane intermediate layer and the injection-molded polycarbonate bearing layer were ultrasonically cleaned, and then wiped with absorbent cotton dipped in 95% petroleum ether , dry for later use. Sandwich a 4mm thick polyurethane film between polycarbonate and electrically heated glass, place electrodes, temperature sensors and wires at the designated positions, and then put it in an autoclave at a temperature of 120°C and a pressure of 1.6MPa Keep the pressure for 90min. After the hot press lamination is completed, the windshield glass is tested for thickness and impact resistance. The test results are as follows:

实施例二Embodiment two

首先将PC粒料放入鼓风干燥箱内,粒料铺层厚度为15mm,在120℃下干燥6h;然后对风挡玻璃聚碳酸酯承力层进行注塑成型,注塑成型时熔体温度为280℃,模具温度为110℃,注射压力为70MPa,冷却时间为30s,注射速度为120mm/s,保压压力60MPa,保压时间30s。将切割磨边后的2.2mm厚的电加热化学强化无机玻璃面层、4mm厚聚氨酯中间层和注塑成型的聚碳酸酯承力层进行超声清洗,之后使用脱脂棉蘸95%的石油醚擦拭其表面,烘干备用。将4mm厚的聚氨酯胶片夹在聚碳酸酯和电加热玻璃之间,在指定位置放置电极、温度传感器和导线,然后将其放入热压釜中在温度为120℃,压力为1.6MPa的条件下保压90min。热压层合完成后,对风挡玻璃进行厚度和抗撞性能测试,测试结果如下:First put the PC pellets into the blast drying oven, the thickness of the pellet layer is 15mm, and dry at 120°C for 6 hours; then the polycarbonate load-bearing layer of the windshield is injection molded, and the melt temperature is 280 during injection molding. ℃, the mold temperature is 110℃, the injection pressure is 70MPa, the cooling time is 30s, the injection speed is 120mm/s, the holding pressure is 60MPa, and the holding time is 30s. After cutting and edging, the 2.2mm thick electrically heated chemically strengthened inorganic glass surface layer, the 4mm thick polyurethane intermediate layer and the injection-molded polycarbonate bearing layer were ultrasonically cleaned, and then wiped with absorbent cotton dipped in 95% petroleum ether , dry for later use. Sandwich a 4mm thick polyurethane film between polycarbonate and electrically heated glass, place electrodes, temperature sensors and wires at the designated positions, and then put it in an autoclave at a temperature of 120°C and a pressure of 1.6MPa Keep the pressure for 90min. After the hot press lamination is completed, the windshield glass is tested for thickness and impact resistance. The test results are as follows:

Claims (4)

1. a manufacture method for windshield, is characterized in that,
(1) injection molding forming method is adopted to produce the bearing layer of windshield: first, be laid in by polycarbonate pellet in air dry oven, pellet overlay thickness is 10 ~ 15mm, dry 4 ~ 8h at 120 DEG C; Then, injection mo(u)lding is carried out to polycarbonate, during injection mo(u)lding, melt temperature is 250-350 DEG C, forming mould temperature is 50-120 DEG C, and injection pressure is 50-150MPa, and hardening time is 10-60s, injection speed is 100-150mm/s, dwell pressure 50-70MPa, dwell time 10-60s, prepared the bearing layer of windshield;
(2) cutting edging is carried out to the electro heat chemically reinforced glass being coated with ito film; The polycarbonate bearing layer of the thick electro heat chemically reinforced glass surface layer of 1.5-4mm after cutting edging, the thick Polyurethane Interlayer of 2-6mm and injection mo(u)lding is carried out ultrasonic cleaning, uses absorbent cotton to dip in its surface of ligroin wiping of 95%, dry for standby afterwards;
(3) between bearing layer and surface layer, place interlayer, between interlayer and surface layer, place copper electrode, temperature sensor and wire, be assembled into windshield original paper; Then, windshield original paper being put into autoclave, is 80-180 DEG C in temperature, and pressure is pressurize 30-120min under the condition of 1-3MPa, and hot pressing is laminated is windshield.
2. the manufacture method of a kind of windshield as claimed in claim 1, is characterized in that, the thickness of described windshield is no more than 22mm.
3. the manufacture method of a kind of windshield as claimed in claim 1, is characterized in that, the surrounding single injection-molded of described bearing layer goes out hold-down bolt hole.
4. the manufacture method of a kind of windshield as claimed in claim 1, it is characterized in that, the preferred 250-300 DEG C of described melt temperature, the preferred 80-110 DEG C of mold temperature, the preferred 110-140MPa of injection pressure, the preferred 20-50s of hardening time, the preferred 120-140mm/s of injection speed, the preferred 60-70MPa of dwell pressure, dwell time preferred 30-50s.
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FR3074721B1 (en) * 2017-12-13 2020-03-27 Saint-Gobain Glass France GLASS AERONAUTICAL SHEET WITH HIGH RESISTANCE TO BREAKING WITH BIRD SHOCK
CN110281459A (en) * 2019-07-22 2019-09-27 中国航发北京航空材料研究院 A kind of manufacturing method of windscreen bearing layer glass

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CN1242297A (en) * 1998-07-16 2000-01-26 梅岗 A New Manufacturing Method for Safety Glass
CN2394907Y (en) * 1999-08-19 2000-09-06 曹元� High strength electric heating glass
CN2430298Y (en) * 2000-02-24 2001-05-16 曹元� Anti-explosive glass for automobile
CN101100358A (en) * 2006-07-03 2008-01-09 福耀集团(上海)汽车玻璃有限公司 Process for preparing toughened interlayer glass
CN103373024A (en) * 2012-04-26 2013-10-30 衡水晶美玻璃制品有限公司 Bulletproof and smash-proof composite glass and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0459704A1 (en) * 1990-05-26 1991-12-04 Triplex Aircraft And Special Products Limited Aircraft windshield
CN1242297A (en) * 1998-07-16 2000-01-26 梅岗 A New Manufacturing Method for Safety Glass
CN2394907Y (en) * 1999-08-19 2000-09-06 曹元� High strength electric heating glass
CN2430298Y (en) * 2000-02-24 2001-05-16 曹元� Anti-explosive glass for automobile
CN101100358A (en) * 2006-07-03 2008-01-09 福耀集团(上海)汽车玻璃有限公司 Process for preparing toughened interlayer glass
CN103373024A (en) * 2012-04-26 2013-10-30 衡水晶美玻璃制品有限公司 Bulletproof and smash-proof composite glass and manufacturing method thereof

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