CN103525267A - Automobile water-based primer surfacer with excellent chip resistance and preparation method thereof - Google Patents
Automobile water-based primer surfacer with excellent chip resistance and preparation method thereof Download PDFInfo
- Publication number
- CN103525267A CN103525267A CN201210228740.1A CN201210228740A CN103525267A CN 103525267 A CN103525267 A CN 103525267A CN 201210228740 A CN201210228740 A CN 201210228740A CN 103525267 A CN103525267 A CN 103525267A
- Authority
- CN
- China
- Prior art keywords
- parts
- aqueous
- water
- primer surfacer
- automobile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 14
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- 239000000080 wetting agent Substances 0.000 claims abstract description 7
- 229920001225 polyester resin Polymers 0.000 claims abstract description 6
- 239000004645 polyester resin Substances 0.000 claims abstract description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004640 Melamine resin Substances 0.000 claims abstract description 5
- 239000004575 stone Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- -1 12 parts Chemical compound 0.000 claims description 7
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 150000007974 melamines Chemical class 0.000 abstract 1
- 239000003595 mist Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000002987 primer (paints) Substances 0.000 description 17
- 239000003973 paint Substances 0.000 description 13
- 239000000178 monomer Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010020843 Hyperthermia Diseases 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036031 hyperthermia Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides an automobile water-based primer surfacer with excellent chip resistance and a preparation method thereof. The automobile water-based primer surfacer is characterized by consisting of the following components in parts by weight: 18-26 parts of water-based epoxy resin, 36-45 parts of water-based polyester resin, 0.1-0.4 part of gas-phase silicon dioxide anti-settling agent, 7-12 parts of methylated melamine resin, 6-10 parts of talc powder, 10-15 parts of calcium carbonate, 4-7 parts of barium sulfate, 8-13 parts of butyl cellosolve, 0.2-0.5 part of water-based dispersing agent, 0.1-0.4 part of water-based leveling agent and 0.2-0.6 part of water-based wetting agent. The water-based automobile primer surfacer provided by the invention has excellent chip resistance and impact strength, wherein the chip resistance can reach the level 3, and the impact strength is 294N.cm; the performances such as gloss, adhesion, heat and humidity resistance, salt mist resistance and the like reach the standard for a solvent type automobile primer surfacer.
Description
Technical field
The invention belongs to car paint production field, be specifically related to automobile aqueous primer surfacer and method for making thereof that excellent anti-stone hits performance.
Technical background
Automotive Primer Surfacer is also referred to as surfacer, refer between priming paint and finish paint, its major function is to improve the planeness of substrate surface and prime coat, for top coat layer provides good substrate, be conducive to like this ornamental of the clarity of topcoat and fullness ratio and whole coating, so middle japanning has following characteristic: (1) should be good with bottom surface lacquering matching capacity, the bonding force that is coated with interlayer is strong, hardness is supporting moderate, can not stung by the solvent in finish paint; (2) there is the property of filling and leading up, can eliminate the tiny flaws such as stroke line on japanning substrate surface; (3) wear resisting property is good, after wet polishing, can obtain smooth smooth surface, energy hyperthermia drying, and dryness is good, not scab paper during polishing.(4) excellent anti-stone hits performance; while being subject to extraneous various factors to the formed collision of car surface in automobile fast running process; can protect primer coating and base material to exempt from damage; thereby improve the weather resistance of primer coating film; and, can also improve the planeness of car body surface and undercoat, for finish paint provides a good substrate; to improve gloss, clarity and the fullness ratio of topcoat, improve ornamental, anti-hitting property of stone and the weathering resistance of whole coating.
At present, Automotive Primer Surfacer exist paint film more firmly, more crisp, exist the problems such as anti-stone hits poor performance, and resistance to impact shock is inadequate, and weathering resistance is poor.And, in the domestic solvent-borne type Automotive Primer Surfacer generally using, contain a large amount of organic solvents such as benzene,toluene,xylene, in painting dressing automobiles process, discharge a large amount of organic solvents, the volatile organic solvent (VOC) discharging is up to 120g/m2, can cause huge harm to human body health, to environment, bring huge pollution simultaneously.Patent CN101624496A discloses " a kind of aqueous primer surfacer and preparation method thereof ", mentioned a kind of aqueous primer surfacer for painting dressing automobiles and preparation method thereof, it is comprised of 40%-60% aqueous dispersion type resin, 25% color stuffing, 5% auxiliary agent and 10-30% water, the main component of described aqueous dispersion type resin comprises hydrophilic polyester resin, water-compatible amino resin, color stuffing can be titanium dioxide, auxiliary agent can be acrylate, and water can be distilled water; This product environmental protection (its VOC quantity discharged is 30g/m2), easy grinding, easily disperse, height adheres to, high gloss, anticorrosion, easily polishing by force.Patent CN101942064B discloses " in modified poly ester and water-based, being coated with coating composition ", its technological core has been to provide a kind of modified poly ester, described modified poly ester is prepared in accordance with the following methods: a) polyvalent alcohol, alkene diacid and polyprotonic acid reaction under the effect of oxidation inhibitor and catalyzer, obtains polyester; B) in described polyester, add water-based solubility promoter, obtain polyester mixture; C) in described polyester mixture, add the first monomer, the second monomer, the 3rd monomer and radical initiator, continue reaction and obtain the first intermediate product, described the first monomer is one or both in vinylformic acid and methacrylic acid, described the second monomer is one or more in acrylate and vinylbenzene, and described the 3rd monomer is crylic acid hydroxy ester; D) in described the first intermediate product, add neutralizing agent, stir neutralization, obtain modified poly ester.
Summary of the invention
The object of the invention is to provide a kind of automobile aqueous primer surfacer, thoroughly eliminated organic solvent, is a kind of green environment protection water car paint; It not only has excellent anti-stone and hits performance, and can be effectively for finish paint provides a good substrate, to improve gloss, clarity and the fullness ratio of topcoat, reach the ornamental and weathering resistance that improves whole coating, make finish paint there is better decorative effect.
The present invention realizes so to achieve the above object: the automobile aqueous primer surfacer that the anti-stone of excellence of the present invention hits performance by weight, is painted in this composed of the following components: aqueous epoxy resins 18-26 part, aqueous polyester resin 36-45 part, aerosil anti-settling agent 0.1-0.4 part, methyl-etherified melamine resin 7-12 part, talcum powder 6-10 part, calcium carbonate 10-15 part, barium sulfate 4-7 part, butyl glycol ether 8-13 part, aqueous dispersant 0.2-0.5 part, water-based flow agent 0.1-0.4 part, aqueous wetting agent 0.2-0.6 part.
Excellent anti-stone hits the automobile aqueous primer surfacer preparation of performance: by above-mentioned weight part, aqueous epoxy resins, aqueous dispersant, aqueous wetting agent, talcum powder, calcium carbonate, barium sulfate, waterborne polyester and water-based flow agent are joined in homogenizer, rotating speed with 1200-1600rpm stirred after 1-3 hour, obtained mixture; In mixture, add aerosil anti-settling agent, methyl-etherified melamine resin and butyl glycol ether, the rotating speed stirring 4-6 hour with 1800-2200rpm, then, with after 200 object filter-cloth filterings, obtains the automobile aqueous primer surfacer that excellent anti-stone hits performance.
In automobile of the present invention, water-based japanning has excellent anti-stone and hits performance and good shock strength, and the performances such as glossiness, sticking power, wet-heat resisting and salt spray resistance have reached the standard of solvent-borne type Automotive Primer Surfacer.
Embodiment
0.2 part of 22 parts of aqueous epoxy resins, 0.3 part of aqueous dispersant, 0.4 part of aqueous wetting agent, 8 parts of talcum powder, 12 parts, calcium carbonate, 6 parts, barium sulfate, 40 parts of aqueous polyester resins and water-based flow agent is joined in homogenizer, rotating speed with 1400rpm stirred after 2 hours, obtained mixture; Toward adding 10 parts of 0.2 part of aerosil anti-settling agent, 9 parts of methyl-etherified melamine resins and butyl glycol ethers in mixture, rotating speed with 2000rpm stirs 5 hours, then, with after 200 object filter-cloth filterings, obtain the automobile aqueous primer surfacer that excellent anti-stone hits performance.
Japanning in the aqueous automobile obtaining is sprayed on the steel plate that applies electrophoretic primer, dries 6min, 80 ℃ of dry 10min, then, 100 ℃ are toasted 20min, obtain being coated with the model of aqueous primer surfacer, and model is tested.In aqueous automobile, paint coating property and paint film property test result as table 1.
In table 1, aqueous automobile, paint coating property and paint film property test result
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (3)
1. the invention provides automobile aqueous primer surfacer and method for making thereof that excellent anti-stone hits performance, it is characterized in that, by weight, this coating is comprised of aqueous epoxy resins 18-26 part, aqueous polyester resin 36-45 part, aerosil anti-settling agent 0.1-0.4 part, methyl-etherified melamine resin 7-12 part, talcum powder 6-10 part, calcium carbonate 10-15 part, barium sulfate 4-7 part, butyl glycol ether 8-13 part, aqueous dispersant 0.2-0.5 part, water-based flow agent 0.1-0.4 part, aqueous wetting agent 0.2-0.6 part.
2. excellent anti-stone hits automobile aqueous primer surfacer and the method for making thereof of performance, it is characterized in that: according to the weight part of material claimed in claim 1, aqueous epoxy resins, aqueous dispersant, aqueous wetting agent, talcum powder, calcium carbonate, barium sulfate, waterborne polyester and water-based flow agent are joined in homogenizer, rotating speed with 1200-1600rpm stirred after 1-3 hour, obtained mixture; In mixture, add aerosil anti-settling agent, methyl-etherified melamine resin and butyl glycol ether, the rotating speed stirring 4-6 hour with 1800-2200rpm, then, with after 200 object filter-cloth filterings, obtains the automobile aqueous primer surfacer that excellent anti-stone hits performance.
3. excellent anti-stone hits automobile aqueous primer surfacer and the method for making thereof of performance, it is characterized in that: 0.2 part of 22 parts of aqueous epoxy resins, 0.3 part of aqueous dispersant, 0.4 part of aqueous wetting agent, 8 parts of talcum powder, 12 parts, calcium carbonate, 6 parts, barium sulfate, 40 parts of aqueous polyester resins and water-based flow agent is joined in homogenizer, rotating speed with 1400rpm stirred after 2 hours, obtained mixture; Toward adding 10 parts of 0.2 part of aerosil anti-settling agent, 9 parts of methyl-etherified melamine resins and butyl glycol ethers in mixture, rotating speed with 2000rpm stirs 5 hours, then, with after 200 object filter-cloth filterings, obtain the automobile aqueous primer surfacer that excellent anti-stone hits performance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210228740.1A CN103525267A (en) | 2012-07-04 | 2012-07-04 | Automobile water-based primer surfacer with excellent chip resistance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210228740.1A CN103525267A (en) | 2012-07-04 | 2012-07-04 | Automobile water-based primer surfacer with excellent chip resistance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103525267A true CN103525267A (en) | 2014-01-22 |
Family
ID=49927632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210228740.1A Pending CN103525267A (en) | 2012-07-04 | 2012-07-04 | Automobile water-based primer surfacer with excellent chip resistance and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103525267A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105754463A (en) * | 2016-02-26 | 2016-07-13 | 上海大众联合汽车改装有限公司 | Automotive waterborne floating-coat coating and preparation method thereof |
| CN107057537A (en) * | 2017-05-22 | 2017-08-18 | 上海天地涂料有限公司 | Coating and preparation method thereof is applied in a kind of automobile water-based property |
| CN107129745A (en) * | 2017-05-15 | 2017-09-05 | 柳州申通汽车科技有限公司 | A kind of water nano car paint |
| CN113861811A (en) * | 2021-10-26 | 2021-12-31 | 江苏海晟涂料有限公司 | High-adhesion middle coating for metal surface |
| CN116179058A (en) * | 2023-03-27 | 2023-05-30 | 双塔涂料科技有限公司 | Water-based 2K middle paint for passenger car |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101270257A (en) * | 2008-04-25 | 2008-09-24 | 十堰市金凤化工实业有限公司 | Middle coating for vehicle furnace drying |
| CN101314693A (en) * | 2007-05-30 | 2008-12-03 | 巴斯夫上海涂料有限公司 | Floating coat paint for automobile |
| CN101942064A (en) * | 2010-10-13 | 2011-01-12 | 中国科学院长春应用化学研究所 | Modified polyester and water-borne middle coating composition |
| US20120128885A1 (en) * | 2009-02-05 | 2012-05-24 | Basf Coatings Gmbh | Corrosion-resistant multilayer varnish and method for the production thereof |
| CN102504680A (en) * | 2011-10-27 | 2012-06-20 | 重庆三峡油漆股份有限公司 | Automobile bi-component intermediate paint resistant to rock impact |
-
2012
- 2012-07-04 CN CN201210228740.1A patent/CN103525267A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314693A (en) * | 2007-05-30 | 2008-12-03 | 巴斯夫上海涂料有限公司 | Floating coat paint for automobile |
| CN101270257A (en) * | 2008-04-25 | 2008-09-24 | 十堰市金凤化工实业有限公司 | Middle coating for vehicle furnace drying |
| US20120128885A1 (en) * | 2009-02-05 | 2012-05-24 | Basf Coatings Gmbh | Corrosion-resistant multilayer varnish and method for the production thereof |
| CN101942064A (en) * | 2010-10-13 | 2011-01-12 | 中国科学院长春应用化学研究所 | Modified polyester and water-borne middle coating composition |
| CN102504680A (en) * | 2011-10-27 | 2012-06-20 | 重庆三峡油漆股份有限公司 | Automobile bi-component intermediate paint resistant to rock impact |
Non-Patent Citations (2)
| Title |
|---|
| 孟昭辉: "聚酯氨基汽车中涂漆的制备", 《天津科技》, no. 03, 25 June 2009 (2009-06-25) * |
| 朱万强: "《涂料基础教程》", 30 June 2012, 西南交通大学出版设 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105754463A (en) * | 2016-02-26 | 2016-07-13 | 上海大众联合汽车改装有限公司 | Automotive waterborne floating-coat coating and preparation method thereof |
| CN105754463B (en) * | 2016-02-26 | 2018-05-22 | 上海大众联合汽车改装有限公司 | A kind of aqueous middle painting coating of automobile and preparation method thereof |
| CN107129745A (en) * | 2017-05-15 | 2017-09-05 | 柳州申通汽车科技有限公司 | A kind of water nano car paint |
| CN107057537A (en) * | 2017-05-22 | 2017-08-18 | 上海天地涂料有限公司 | Coating and preparation method thereof is applied in a kind of automobile water-based property |
| CN113861811A (en) * | 2021-10-26 | 2021-12-31 | 江苏海晟涂料有限公司 | High-adhesion middle coating for metal surface |
| CN116179058A (en) * | 2023-03-27 | 2023-05-30 | 双塔涂料科技有限公司 | Water-based 2K middle paint for passenger car |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103525267A (en) | Automobile water-based primer surfacer with excellent chip resistance and preparation method thereof | |
| CN103666201B (en) | Long-acting acid and alkali-resistance, solvent-free anticorrosive paint and preparation method thereof and application | |
| CN104877514A (en) | Amino resin stoving varnish containing water-borne acrylic modified alkyd resin and preparation method thereof | |
| CN105026055A (en) | Methods and compositions for coating substrates | |
| JP6727247B2 (en) | Method for forming multilayer coating film | |
| JP2010501649A (en) | Multi-layer composite formed from a composition having improved adhesion | |
| TW200414938A (en) | Continuous process for applying a tricoat finish on a vehicle | |
| CN101775245A (en) | Multifunctional putty and preparation method thereof | |
| KR20220007138A (en) | Coating compositions and systems and methods for applying such coating compositions | |
| CN109206996A (en) | A kind of bloom one-component plain color finishing coat of aqueous solvent-free bottom surface unification and its preparation | |
| CN104559713A (en) | Coating composition of multicomponent organic solvent first coat and repairing and coating method thereof | |
| CN104059533B (en) | Water soluble paint for automobile composition and the painting dressing automobiles method for utilizing the composition | |
| CN106752650A (en) | A kind of aqueous automobile floating coating and preparation method thereof | |
| CN115433492A (en) | Water-based fluorocarbon coating for spraying and preparation method and application thereof | |
| CN107245288A (en) | High-alkali-resistance strong-adhesion water-based metal matte baking paint and preparation and use methods thereof | |
| CN108948906A (en) | A kind of dedicated baking vanish of water-based metal coiled material and its application method | |
| CN106752541A (en) | A kind of aqueous polyurethane ultraviolet-curing paint and preparation method thereof | |
| CN111876060A (en) | High-wear-resistance scratch-resistant waterborne polyurethane paint and preparation method thereof | |
| JP4063358B2 (en) | Method for repairing laminated coating film and coating composition for repair | |
| JP2009102452A (en) | Chipping primer coating composition and method for forming layered coating film | |
| JPH10298458A (en) | Bright pigment-containing coating composition and method for forming composite coating film | |
| CN101624496A (en) | Waterborne primer surfacer and preparation method thereof | |
| CN102746776A (en) | Primer and spraying process using same | |
| JP2022552359A (en) | High-gloss, polishable coating with a matte and/or structured metallic effect and method for its preparation | |
| JP2006122732A (en) | Formation method for coating film and laminated coating film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |