CN103525165B - Novel printing ink cleaning agent and preparation method thereof - Google Patents
Novel printing ink cleaning agent and preparation method thereof Download PDFInfo
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- CN103525165B CN103525165B CN201310501918.XA CN201310501918A CN103525165B CN 103525165 B CN103525165 B CN 103525165B CN 201310501918 A CN201310501918 A CN 201310501918A CN 103525165 B CN103525165 B CN 103525165B
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- 238000002360 preparation method Methods 0.000 title claims description 7
- 238000007639 printing Methods 0.000 title abstract description 12
- 239000012459 cleaning agent Substances 0.000 title abstract description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003350 kerosene Substances 0.000 claims abstract description 9
- 239000003208 petroleum Substances 0.000 claims abstract description 8
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 7
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 7
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010495 camellia oil Substances 0.000 claims abstract description 7
- 239000002283 diesel fuel Substances 0.000 claims abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 7
- 239000000194 fatty acid Substances 0.000 claims abstract description 7
- 229930195729 fatty acid Natural products 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011297 pine tar Substances 0.000 claims abstract description 7
- 229940068124 pine tar Drugs 0.000 claims abstract description 7
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229960004418 trolamine Drugs 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003599 detergent Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 description 6
- 230000006378 damage Effects 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of novel printing ink cleaning agent, it is characterized in that, be made up of the raw material of following weight part: trolamine 1-2, Soxylat A 25-7 3-5, pine tar 10-12, kerosene 20-24, Oleum Cocois 2-3, petroleum sodium sulfonate 1-2, cocoanut fatty acid diethanolamide 1-2, diesel oil 10-12, trimethyl-glycine 3-4, dimethyl succinate 4-5, diethylene glycol monomethyl ether 5-6, polyoxyethylene polyoxypropylene propylene glycol 3-4, tea-seed oil 1-2, auxiliary agent 4-5, water 100-110; The present invention adds auxiliary agent, improves the processing performance of clean-out system, reduces its toxic side effect and the pollution to environment; Cleansing power of the present invention is strong, and nontoxic, non-volatile, harmless, do not have corrodibility, cost of manufacture is low.
Description
Technical field
The present invention relates to printing cleaning technique field, particularly a kind of novel printing ink cleaning agent and preparation method thereof.
Background technology
What often use now in printing industry has the element purge of ink to be clean with organic solvents such as gasoline, kerosene, acetone, alcohol for printing machinery forme, rubber roll, blanket etc.; Such clean-out system also exists inflammable, explosive, contaminate environment, harm bedding sack is healthy, and to cleaning part, as: glue rod, blanket surface burn into swelling action, to parts damages, work-ing life shortens widely, simultaneously to the workman's skin of hand burn into injury using solvent, this solvent cleaning weak effect, gasoline, coal are the products of petroleum refining, and present ballooning oil prices can cause the waste of Nonrenewable resources petroleum-based energy like this.At present, the widely used clean-out system in market, be not be exactly in alkalescence in acidity, can have a strong impact on original true qualities and smooth finish in acid clean-out system, the clean-out system in alkalescence can permeate cleaning objects, causes object to corrode, even comes off.
Chinese patent 200510122330.9 discloses a kind of natural plant type detergent, it is characterized in that by limonene 60 ~ 80 parts, 10 ~ 20 parts, turps, propylene glycol phenylate 10 ~ 15 parts, Terpineol 350 5 ~ 10 parts, citral 1 ~ 3 part, the natural plant solvent that Homogeneous phase mixing is formulated and emulsifying agent mixing composition.But this clean-out system is not invented for cleaning printing-ink, so the effect of its cleaning printing-ink is also short of to some extent.
Summary of the invention
The object of this invention is to provide a kind of novel printing ink cleaning agent and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of novel printing ink cleaning agent, is made up of the raw material of following weight part: trolamine 1-2, Soxylat A 25-7 3-5, pine tar 10-12, kerosene 20-24, Oleum Cocois 2-3, petroleum sodium sulfonate 1-2, cocoanut fatty acid diethanolamide 1-2, diesel oil 10-12, trimethyl-glycine 3-4, dimethyl succinate 4-5, diethylene glycol monomethyl ether 5-6, polyoxyethylene polyoxypropylene propylene glycol 3-4, tea-seed oil 1-2, auxiliary agent 4-5, water 100-110;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, ricinolic acid 3-4,2-amino-2-methyl-1-propanol 1-2, polyoxyethylene sorbitan monooleate 2-3, oxidation inhibitor 10351-2, ethanol 12-14; Preparation method is by Silane coupling reagent KH-570, ricinolic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stir 30-40 minutes, to obtain final product.
Novel printing ink cleaning agent of the present invention, be made up of following concrete steps:
(1) at room temperature trolamine, cocoanut fatty acid diethanolamide, trimethyl-glycine, pine tar, kerosene, Oleum Cocois, diesel oil, tea-seed oil are added in mixing kettle, add in mixing kettle after the water of half amount is heated to 60-75 DEG C, be stirred to and dissolve completely;
(2) Soxylat A 25-7, petroleum sodium sulfonate, dimethyl succinate, diethylene glycol monomethyl ether, polyoxyethylene polyoxypropylene propylene glycol are added in mixing kettle, add the water of surplus, stir 4-6 minute with the speed of 1200-1600 rev/min;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Excellent effect of the present invention is: the present invention adds auxiliary agent, improves the processing performance of clean-out system, reduces its toxic side effect and the pollution to environment; Cleansing power of the present invention is strong, and nontoxic, non-volatile, harmless, do not have corrodibility, cost of manufacture is low.
Embodiment
Below by specific examples, the present invention is described in detail.
A kind of novel printing ink cleaning agent, is made up of the raw material of following weight part (kilogram): trolamine 1, Soxylat A 25-7 3, pine tar 10, kerosene 20, Oleum Cocois 2, petroleum sodium sulfonate 1, cocoanut fatty acid diethanolamide 1, diesel oil 10, trimethyl-glycine 3, dimethyl succinate 4, diethylene glycol monomethyl ether 5, polyoxyethylene polyoxypropylene propylene glycol 3, tea-seed oil 1, auxiliary agent 4, water 100;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): Silane coupling reagent KH-570 3, ricinolic acid 3,2-amino-2-methyl-1-propanol 1, polyoxyethylene sorbitan monooleate 3, oxidation inhibitor 10351, ethanol 12; Preparation method is by Silane coupling reagent KH-570, ricinolic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stir 30-40 minutes, to obtain final product.
Novel printing ink cleaning agent of the present invention, be made up of following concrete steps:
(1) at room temperature trolamine, cocoanut fatty acid diethanolamide, trimethyl-glycine, pine tar, kerosene, Oleum Cocois, diesel oil, tea-seed oil are added in mixing kettle, add in mixing kettle after the water of half amount is heated to 60-75 DEG C, be stirred to and dissolve completely;
(2) Soxylat A 25-7, petroleum sodium sulfonate, dimethyl succinate, diethylene glycol monomethyl ether, polyoxyethylene polyoxypropylene propylene glycol are added in mixing kettle, add the water of surplus, stir 4-6 minute with the speed of 1200-1600 rev/min;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Be applied to by ink on the stainless steel metal thin slice of certain mass, dry under state of nature, steel disc is placed in the beaker filling clean-out system, soak after 5 minutes at 25 DEG C, more at the uniform velocity vibrate 5 minutes, obtaining clean dirt rate is 92.4%, and cleansing power is good.With this clean-out system with compared with gasoline, kerosene, rubber cloth increases the service life 2 years, and ink roller can increase the service life 3 years.
Claims (2)
1. a detergent for ink, it is characterized in that, be made up of the raw material of following weight part: trolamine 1-2, Soxylat A 25-7 3-5, pine tar 10-12, kerosene 20-24, Oleum Cocois 2-3, petroleum sodium sulfonate 1-2, cocoanut fatty acid diethanolamide 1-2, diesel oil 10-12, trimethyl-glycine 3-4, dimethyl succinate 4-5, diethylene glycol monomethyl ether 5-6, polyoxyethylene polyoxypropylene propylene glycol 3-4, tea-seed oil 1-2, auxiliary agent 4-5, water 100-110;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, ricinolic acid 3-4,2-amino-2-methyl-1-propanol 1-2, polyoxyethylene sorbitan monooleate 2-3, oxidation inhibitor 10351-2, ethanol 12-14; The preparation method of auxiliary agent is by Silane coupling reagent KH-570, ricinolic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stir 30-40 minutes, to obtain final product.
2. detergent for ink according to claim 1, is characterized in that, be made up of following concrete steps:
(1) at room temperature trolamine, cocoanut fatty acid diethanolamide, trimethyl-glycine, pine tar, kerosene, Oleum Cocois, diesel oil, tea-seed oil are added in mixing kettle, add in mixing kettle after the water of half amount is heated to 60-75 DEG C, be stirred to and dissolve completely;
(2) Soxylat A 25-7, petroleum sodium sulfonate, dimethyl succinate, diethylene glycol monomethyl ether, polyoxyethylene polyoxypropylene propylene glycol are added in mixing kettle, add the water of surplus, stir 4-6 minute with the speed of 1200-1600 rev/min;
(3) finally auxiliary agent is added in mixing kettle, stir, naturally cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501918.XA CN103525165B (en) | 2013-10-23 | 2013-10-23 | Novel printing ink cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501918.XA CN103525165B (en) | 2013-10-23 | 2013-10-23 | Novel printing ink cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103525165A CN103525165A (en) | 2014-01-22 |
| CN103525165B true CN103525165B (en) | 2016-03-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310501918.XA Active CN103525165B (en) | 2013-10-23 | 2013-10-23 | Novel printing ink cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103525165B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020035499A1 (en) * | 2018-08-15 | 2020-02-20 | Baldwin Jimek Ab | Roll of cleaning fabric and related apparatus and methods |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110437945A (en) * | 2019-08-06 | 2019-11-12 | 湖南伟方环保技术股份有限公司 | Cleaning agent and preparation method thereof for wire-cloth |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526806A (en) * | 2003-09-24 | 2004-09-08 | 辽宁省印刷技术研究所 | Enviroment protection detergent |
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN101824243A (en) * | 2010-04-19 | 2010-09-08 | 江苏海迅实业集团股份有限公司 | Micro-emulsion ink cleaning agent and preparation method thereof |
-
2013
- 2013-10-23 CN CN201310501918.XA patent/CN103525165B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526806A (en) * | 2003-09-24 | 2004-09-08 | 辽宁省印刷技术研究所 | Enviroment protection detergent |
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN101824243A (en) * | 2010-04-19 | 2010-09-08 | 江苏海迅实业集团股份有限公司 | Micro-emulsion ink cleaning agent and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020035499A1 (en) * | 2018-08-15 | 2020-02-20 | Baldwin Jimek Ab | Roll of cleaning fabric and related apparatus and methods |
| US12173257B2 (en) | 2018-08-15 | 2024-12-24 | Baldwin Jimek Ab | Roll of cleaning fabric and related apparatus and methods |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103525165A (en) | 2014-01-22 |
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