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CN103524794B - A kind of enteric materials and shaping dope thereof being applicable to co-extrusion casing technology - Google Patents

A kind of enteric materials and shaping dope thereof being applicable to co-extrusion casing technology Download PDF

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CN103524794B
CN103524794B CN201310530537.4A CN201310530537A CN103524794B CN 103524794 B CN103524794 B CN 103524794B CN 201310530537 A CN201310530537 A CN 201310530537A CN 103524794 B CN103524794 B CN 103524794B
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casing
extrusion
alginates
enteric materials
parts
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CN103524794A (en
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范素琴
王晓梅
刘海燕
解素花
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QINGDAO BRIGHT MOON SEAWEED GROUP CO Ltd
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QINGDAO BRIGHT MOON SEAWEED GROUP CO Ltd
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Abstract

The invention provides a kind of enteric materials and the shaping dope thereof that are applicable to co-extrusion casing technology, described enteric materials comprises the raw material of following masses mark: alginates 70 ~ 80 parts, 8 ~ 15 parts, softening agent, toughener 2 ~ 20 parts; During use and water be dissolved into homogeneous solution in the ratio of 4 ~ 6:100, form alginates casing by co-extrusion casing technical equipment, described shaping dope is acid calcium solution, comprise the composition of following masses per-cent: calcium salt 15 ~ 20%, acid 0.05 ~ 0.4%, softening agent 5 ~ 10%, surplus is water.After the enteric materials that the present invention obtains is dissolved into colloid, extruded by co-extrusion casing device systems, there are good elasticity, tensile strength by the shaping rear obtained alginates casing of shaping dope and fill intensity, comparatively finished product albumen sausage casing, natural casing, there are wide material sources, with low cost, unmanned frock mounts the secondary pollution that finished product casing may cause, and improves the advantage of food safety.

Description

A kind of enteric materials and shaping dope thereof being applicable to co-extrusion casing technology
Technical field
The present invention relates generally to field of food, and emphasis relates to a kind of meat-eating race machining needs edible packing material and production method thereof, particularly relates to a kind of the alginates edibility enteric materials and the shaping dope thereof that are applicable to co-extrusion casing processing technology.
Background technology
At present, the technology making sausage more advanced is the Technology of Co-extruded Sausage, this technology is the important technology innovation of sausage processing industry, the key of sausage co-extrusion technology is " synchronous forming ", two independently subsystems are sub-packed in by meat stuffing and mould material---meat stuffing filling machine and quantitatively send collagen machine, then from the meet of these two subsystems---the coextrusion nozzle of synchronous forming machine is extruded simultaneously, alginates casing (shaping dope that alginates runs into volume pump conveying in the pipeline of nozzle internal layer forms alginates casing) is constantly enclosed within the external table of intestines equably, intestines body continues to be extruded from nozzle concentric(al) circles inner layer sleeve mouth, complete the synchronous forming that meat stuffing is filled.It does not need to shut down loads pre-processed casing, but the gel of meat and casing is together extruded by continuous print, is finally frozen into sausage.The advantage of the Technology of Co-extruded Sausage has: (1) reduces costs, raises the efficiency: continuous seepage, saves the input of labor force; Casing raw material adopts alginates colloid, and cost reduces.(2) production serialization automatization is realized: be filled to sausage cooling from intestines filling and realize continuous and automatic.(3) product specification variation is realized: by changing coextrusion nozzle bore, length cut by sausage, implementation specification variation.(4) improve the quality of products: automatic production high degree avoids pollution, extends the quality guaranteed period.
Existing for many years to the research of the Technology of Co-extruded Sausage abroad, its technology is ripe gradually and be widely adopted.And the research of domestic compounding sea alginate co-extrusion enteric materials is still in the junior stage, key is the requirement that the intensity of enteric materials does not reach equipment and process, and alginates co-extrusion casing batching is in the market all that high price is from external import.
Usual that use or all kinds of natural casing (as hog intestine, sheep casing, beef casing etc.), plastic casing (as nylon casing, PVDC casing etc.) and Collagent casing for sausages in current China sausage production.Wherein natural casing is from animals such as pig, ox, sheep, and its casing caliber size differs, and size is different in size, and quality differs, and is not suitable with mechanize bowel lavage; Plastic casing raw material comes from petrochemical industry, and oil belongs to Nonrenewable resources, and have pollution to environment when producing plastic raw materials, in addition, plastic casing raw material can not be degraded, and has certain destruction during treating refuse to environment; Collagent casing for sausages is being used widely at present, but its production method is more complicated, and production cost is higher, and produces a large amount of organic waste water when producing.
Collagent casing for sausages material is produced at China sausage coextrusion also a small amount of application, there is also production method complexity, production cost be higher, sausage boiling time the defect that easily ftractures, and its production process many application linking agent glutaraldehyde etc.
Along with improving constantly of China's meat-ware factory production automation degree, and people are to the attention of food safety, co-extrusion casing processing technology is promoted imperative in China, but want large-scale promotion co-extrusion technology, first the problem of co-extrusion casing desired raw material must be solved, ensure that when utilizing co-extrusion casing device fabrication co-extrusion casing product technique is simple, materials safety, casing are applicable to production different varieties, the problem of the sausage of different quality, and do not ftracture when sausage boiling.Therefore a kind of enteric materials that can meet the requirement of co-extrusion casing techniques intensity is needed badly.
Summary of the invention
The object of the invention is the defect and the deficiency that solve above-mentioned prior art, a kind of enteric materials and the shaping dope thereof that are applicable to co-extrusion casing technology are provided.
According to the deficiency that present Research and other casing technology of domestic casing co-extrusion technology exist, first technical problem that the present invention will solve is to provide a kind of high-strength composite alginates enteric materials formula being suitable for co-extrusion casing technology; This sodium alginate casing colloid be suitable for mechanize bowel lavage, edible, environment friendly and pollution-free, produce easy, with low cost and not by seasonal effect;
The present invention will solve the formula that second technical problem is to provide a kind of co-extrusion casing technology alginates casing shaping dope; This shaping dope is conducive to alginates casing just can form the higher alginates casing of intensity in tens seconds.Conventional alginates has sodium alginate, potassium alginate, and factory commonly uses sodium alginate.
For solving first technical problem, the present invention adopts following technical proposals to be achieved:
Be applicable to an enteric materials for co-extrusion casing technology, this enteric materials is compounding sea alginate enteric materials, comprises the raw material of following masses mark:
Alginates 70 ~ 80 parts,
8 ~ 15 parts, softening agent,
Toughener 2 ~ 20 parts,
The ratio of above-mentioned raw materials and water 4 ~ 6:100 is in mass ratio dissolved into homogeneous solution, stirring and dissolving, obtains alginates mixing casing glue, forms alginates casing by co-extrusion casing technical equipment.
Described alginates is one or both in sodium alginate, potassium alginate.
Described sodium alginate, potassium alginate viscosity are 150 ~ 300mPa.s.
Described softening agent is one or more in glycerine, Sorbitol Powder, sodium lauryl sulphate (SDS).
Described toughener is one or more in Xylo-Mucine, collagen protein, gelling gum, konjak gum, xanthan gum.
For solving second technical problem, the invention provides a kind of enteric materials shaping dope being applicable to co-extrusion casing technology, described shaping dope is acid calcium solution, comprises the composition of following masses percentage ratio:
Calcium salt 15 ~ 20%,
Acid 0.05 ~ 0.4%,
Softening agent 4 ~ 8%,
Surplus is water.
Sodium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
That is, described calcium salt is food-grade calcium chloride, and the massfraction of the aqueous solution is 15 ~ 20%.Food-grade calcium chloride is safer.
Described acid is citric acid or Gluconolactone, and the massfraction of the aqueous solution is 0.05 ~ 0.4%.
Described softening agent is glycerine, and the massfraction of the aqueous solution is 4 ~ 8%.
After being dissolved as homogeneous colloids by compounding sea alginate enteric materials of the present invention, when carrying out co-extrusion and producing sausage, colloid is placed in the hopper of automatic ration forcing machine, squeezing out quantitative machine flows to annular co-extrusion sausage forming machine colloid, forming machine intermediate conduit is the meat stuffing jet pipe of sausage stuffer, is connected with sausage stuffer.The tank that the shaping dope of compounding sea alginate casing colloid is placed in automatic ration is driven into the snakelike perforated tube of circulating line inside by volume pump, spray calcium liquid on the alginates casing colloid in pipeline gap, make it to become alginates casing.The speed of adjustment sausage stuffer, forcing machine and volume pump, the feed speed forming casing after making meat stuffing and colloid solidification matches, casing is allowed to be enclosed within sausage surface uniformly when meat stuffing is extruded, rinse the calcium solution of sausage excess surface with clear water, such colloid casing being fused together with sausage in sausage surfacing simultaneously.This special ring-type casing coextrusion mold machine major function is: run into calcium liquid when colloid is extruded in pipeline, form sleeve pipe casing, be squeezed out at annular casing coextrusion mold head, and equably sausage meat is wrapped up, picture has worn one deck coat to meat stuffing, sausage sodium alginate casing in transmitting procedure slowly solidifies, and casing intensity is strengthened.After sausage sizing, cut off segmentation or kink segmentation at once, then with transfer roller, sausage is transported to loft drier and carries out drying and obtain finished product.
Compared with prior art, advantage of the present invention and positively effect are:
1, this compounding sea alginate enteric materials boiling higher, resistance to than single alginates enteric materials intensity, mechanical entanglement is without tearing, and high temperature steaming, without explosion, is suitable for power operation and processing condition requirement.
2, this material such as alginates, softening agent, toughener selected by invention enteric materials, is all cross-linked glutaraldehyde used than collagen protein co-extrusion casing, has higher edible safety, more healthy.
This compounding sea alginate enteric materials and shaping dope formula thereof, be applied to sausage to produce, not only labor force can be saved, can also effective saving resource, avoid the secondary pollution that people's frock extension finished product casing may cause, advantageously in control food safety, it is the inevitable direction of meat product enterprise development from now on.
After the enteric materials that the present invention obtains is dissolved into colloid, extruded by co-extrusion casing device systems, there are good elasticity, tensile strength by the shaping rear obtained alginates casing of shaping dope and fill intensity, comparatively finished product albumen sausage casing, natural casing, there are wide material sources, with low cost, unmanned frock mounts the secondary pollution that finished product casing may cause, and improves the advantages such as food safety.
Embodiment
For a better understanding of the present invention, further illustrate below in conjunction with specific embodiment.
embodiment 1
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Sodium alginate 75 parts,
Glycerine 2 parts,
Sorbitol Powder 10 parts
Xanthan gum 5 parts,
Konjak gum 8 parts,
During use and the ratio of water 4:100 be in mass ratio dissolved into homogeneous solution, form alginates casing by co-extrusion casing technical equipment.The viscosity of sodium alginate is 260 mPa.s.
Above-mentioned sodium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 15%,
Citric acid per-cent is 0.05%,
Qualities of glycerin per-cent is 4%,
Solvent is water.
Above-mentioned sodium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
embodiment 2
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Sodium alginate 70 parts,
Glycerine 4 parts,
Sorbitol Powder 13 parts
Xanthan gum 5 parts,
Konjak gum 8 parts,
During use and the ratio of water 6:100 be in mass ratio dissolved into homogeneous solution, form alginates casing by co-extrusion casing technical equipment.The viscosity of sodium alginate is 170 mPa.s.
Above-mentioned sodium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 18%,
Citric acid per-cent is 0.05%,
Qualities of glycerin per-cent is 6%,
Solvent is water.
Above-mentioned sodium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
embodiment 3
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Sodium alginate 75 parts,
Sorbitol Powder 15 parts,
Xylo-Mucine 8 parts,
Gelling gum 2 parts,
During use and the ratio of water 6:100 be in mass ratio dissolved into homogeneous solution, form alginates casing by co-extrusion casing technical equipment.The viscosity of sodium alginate is 170 mPa.s.
Above-mentioned sodium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 15%,
Gluconolactone per-cent is 0.4%,
Qualities of glycerin per-cent is 8%,
Solvent is water.
Above-mentioned sodium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
embodiment 4
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Sodium alginate 73 parts,
Sorbitol Powder 15 parts,
Xylo-Mucine 10 parts,
Gelling gum 2 parts,
During use and the ratio of water 6:100 be in mass ratio dissolved into homogeneous solution, form alginates casing by co-extrusion casing technical equipment.The viscosity of sodium alginate is 200mPa.s.
Above-mentioned sodium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 20%,
Gluconolactone per-cent is 0.5%,
Qualities of glycerin per-cent is 5%,
Solvent is water.
Above-mentioned sodium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
embodiment 5
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Potassium alginate 73 parts,
Sorbitol Powder 15 parts,
Xylo-Mucine 10 parts,
Gelling gum 2 parts,
During use and water be dissolved into homogeneous solution in the ratio of 6:100, form alginates casing by co-extrusion casing technical equipment.The viscosity of potassium alginate is 160mPa.s.
Above-mentioned potassium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 20%,
Gluconolactone per-cent is 0.5%,
Qualities of glycerin per-cent is 5%.
Above-mentioned potassium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
comparative example 1
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Sodium alginate 100 parts,
Sodium alginate and water are dissolved into homogeneous solution in the ratio of 6:100, form alginates casing by co-extrusion casing technical equipment.The viscosity of sodium alginate is 200mPa.s.
Above-mentioned sodium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 15%,
Above-mentioned sodium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
comparative example 2
1, be applicable to a compounding sea alginate enteric materials for co-extrusion casing technology, comprise the raw material of following masses mark:
Potassium alginate 100 parts,
Potassium alginate and water are dissolved into homogeneous solution in the ratio of 6:100, form alginates casing by co-extrusion casing technical equipment.The viscosity of potassium alginate is 200mPa.s.
Above-mentioned sodium alginate casing colloid desired raw material is mixed, adds in room temperature water, stirring and dissolving, obtain sodium alginate mixing casing glue, for subsequent use.
2, be applicable to an alginates casing shaping dope for co-extrusion casing technology, its composition is as follows:
Calcium chloride mass percent is 15%,
Above-mentioned potassium alginate casing colloid shaping dope desired raw material is mixed, adds in room temperature water, stirring and dissolving, for subsequent use.
Above-mentioned stock solution is poured in co-extrusion casing equipment corresponding container, by roasting intestines explained hereafter product.
experimental result
casing stretching strength determination
Sequence number Example 1 Example 2 Example 3 Example 4 Example 5 Contrast 1 Contrast 2
Intensity 300 320 289 305 340 81 101
Integrated strength testing result can be found out:
(1) potassium alginate (contrast 2) casing tensile strength is higher than sodium alginate casing (contrast 1), but due to potassium alginate price higher, food industrialization Commercial cultivation sodium alginate just can reach the requirement of co-extrusion casing.
(2) tensile strength of compounding sea alginate material colloid casing far away higher than the alginates casing (comparative example) not adding any other auxiliary material, and will not ftracture in sausage digestion process.
Certainly; above-mentioned explanation is not limitation of the present invention; the present invention is also not limited in above-mentioned citing, the change that those skilled in the art make in essential scope of the present invention, remodeling, interpolation or replacement, also should belong to protection scope of the present invention.

Claims (3)

1. be applicable to an enteric materials shaping dope for co-extrusion casing technology, this enteric materials is compounding sea alginate enteric materials, comprises the raw material of following masses mark:
Alginates 70 ~ 80 parts,
8 ~ 15 parts, softening agent,
Toughener 2 ~ 20 parts,
The ratio of above-mentioned raw materials and water 4 ~ 6:100 is in mass ratio dissolved into homogeneous solution, stirring and dissolving, obtains alginates mixing casing glue, forms alginates casing by co-extrusion casing technical equipment;
It is characterized in that, in casing process, the shaping dope adopted is acid calcium solution, comprises the composition of following masses percentage ratio:
Calcium salt 15 ~ 20%,
Acid 0.05 ~ 0.4%,
Softening agent 4 ~ 8%,
Surplus is water;
Described acid is citric acid or Gluconolactone.
2. be applicable to the enteric materials shaping dope of co-extrusion casing technology according to claim 1, it is characterized in that, described calcium salt is food-grade calcium chloride.
3. be applicable to the enteric materials shaping dope of co-extrusion casing technology according to claim 1, it is characterized in that, described softening agent is glycerine.
CN201310530537.4A 2013-11-01 2013-11-01 A kind of enteric materials and shaping dope thereof being applicable to co-extrusion casing technology Active CN103524794B (en)

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