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CN103515478A - Base board unit subjected to textured surface processing by using substrate, and forming method thereof - Google Patents

Base board unit subjected to textured surface processing by using substrate, and forming method thereof Download PDF

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CN103515478A
CN103515478A CN201310232126.7A CN201310232126A CN103515478A CN 103515478 A CN103515478 A CN 103515478A CN 201310232126 A CN201310232126 A CN 201310232126A CN 103515478 A CN103515478 A CN 103515478A
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substrate
matte
semiconductor
layer
groove
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朱慧珑
骆志炯
尹海洲
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Poly Day (suzhou) Technology Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/70Surface textures, e.g. pyramid structures
    • H10F77/707Surface textures, e.g. pyramid structures of the substrates or of layers on substrates, e.g. textured ITO layer on a glass substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

本发明提出了一种基板单元、基板结构及其制造方法。所述基板结构包括基板单元阵列,所述阵列包括多个基板单元,每个所述基板单元包括:具有第一掺杂类型的单晶半导体基板,所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面,所述第三表面和第四表面的晶向为{111},以及形成于所述半导体基板的第三表面上的具有第二掺杂类型、表面为绒面的第一半导体层;以及多个基片,其中:对于相间隔的基板单元的每一个,其第二表面与其一侧的相邻基板的第二表面共用一个基片,且其第一表面与其另一侧的相邻基板的第一表面共用另一个基片,以使所述基板结构形成长城型结构。本发明有效地利用了衬底的厚度,提高了晶圆片的可加工的表面积。当用于太阳能电池基板时,所述绒面能够有利地提高陷光效果,增加太阳能电池的进光效率。

Figure 201310232126

The invention provides a substrate unit, a substrate structure and a manufacturing method thereof. The substrate structure includes a substrate unit array, the array includes a plurality of substrate units, each of the substrate units includes: a single crystal semiconductor substrate having a first doping type, the semiconductor substrate includes a first surface and an opposite The second surface, the third surface and the fourth surface opposite to it, the crystal orientation of the third surface and the fourth surface is {111}, and the crystal layer formed on the third surface of the semiconductor substrate has the second doping type, the surface is the first semiconductor layer of texture; and a plurality of substrates, wherein: for each of the spaced apart substrate units, its second surface shares a substrate with the second surface of the adjacent substrate on one side thereof, And the first surface thereof shares another substrate with the first surface of the adjacent substrate on the other side, so that the substrate structure forms a Great Wall structure. The invention effectively utilizes the thickness of the substrate and increases the processable surface area of the wafer. When used as a solar cell substrate, the textured surface can advantageously improve the light trapping effect and increase the light entry efficiency of the solar cell.

Figure 201310232126

Description

一种利用衬底进行绒面加工的基板单元及其形成方法A substrate unit for suede processing using a substrate and its forming method

技术领域technical field

本发明涉及半导体制造领域,特别涉及一种利用衬底进行加工的基板单元、基板结构及其制造方法。The invention relates to the field of semiconductor manufacturing, in particular to a substrate unit processed by using a substrate, a substrate structure and a manufacturing method thereof.

背景技术Background technique

近年来,随着半导体产业的迅速发展,半导体器件不断地朝小体积、高电路密集度、快速、低耗电方向发展,集成电路现已进入亚微米级的技术阶段。因此,为了适应小体积、高集成度的需要,目前提出了两方面的要求,一方面是要求晶圆片的直径逐渐增大,到2005年,直径300mm硅片已成为主流产品,预计到2012年,将开始使用直径450mm(18in)硅片,晶圆片的直径大约以每9年增大1.5倍的速度不断增大,而向大面积发展。另一方面也提出了一种要求,即希望在不增加现有的晶圆片尺寸的基础上增加表面积利用率,从而提高其可加工的表面积。特别地,可以利用衬底的厚度来进行衬底的加工,在对单晶晶圆片进行加工时,晶圆片的晶向能够为衬底的加工提供益处,例如利用各向同性刻蚀能够获得具有特定晶向的表面。在对多晶晶圆片进行加工时,则可以利用各向异性刻蚀,例如RIE。然而,不论是单晶衬底还是多晶衬底,利用衬底厚度进行加工都会带来其他的问题,例如,在太阳能电池基板的加工过程中,为了提高陷光效果,通常希望在进光表面上形成绒面,然而在单晶衬底中通过各向同性刻蚀而获得的表面上制作绒面将会有很大难度,并且在多晶衬底中通过各向异性刻蚀而获得的表面上制作绒面也有很严格的要求。目前为止,还没有提出一种能够基于现有晶圆片的尺寸来增加晶圆片利用率并在特定的表面上形成绒面的方案。In recent years, with the rapid development of the semiconductor industry, semiconductor devices continue to develop in the direction of small size, high circuit density, high speed, and low power consumption. Integrated circuits have now entered the sub-micron technology stage. Therefore, in order to meet the needs of small volume and high integration, two requirements are put forward at present. On the one hand, the diameter of the wafer is required to gradually increase. In 2010, silicon wafers with a diameter of 450mm (18in) will begin to be used, and the diameter of wafers will increase at a rate of 1.5 times every 9 years, and will develop into a large area. On the other hand, there is also a requirement, that is, it is hoped to increase the utilization rate of the surface area without increasing the size of the existing wafer, so as to increase its processable surface area. In particular, the thickness of the substrate can be used to process the substrate. When processing a single-crystal wafer, the crystal orientation of the wafer can provide benefits for the processing of the substrate. For example, using isotropic etching can A surface with a specific crystallographic orientation is obtained. When processing multi-crystalline wafers, anisotropic etching, such as RIE, can be used. However, regardless of whether it is a single crystal substrate or a polycrystalline substrate, processing using the substrate thickness will bring other problems. For example, in the processing of solar cell substrates, in order to improve the light trapping effect, it is usually desired to However, it will be very difficult to form texture on the surface obtained by isotropic etching in single crystal substrate, and the surface obtained by anisotropic etching in polycrystalline substrate There are also very strict requirements for making suede. So far, no solution has been proposed to increase wafer utilization and form texture on a specific surface based on the size of existing wafers.

发明内容Contents of the invention

为了解决上述问题,本发明提供了一种利用衬底进行加工的基板单元:包括:半导体基板,所述半导体基板为具有第一掺杂类型的单晶基板,所述半导体衬底包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面,所述第三表面和第四表面的晶向为{111};形成于所述半导体基板的第三表面上的具有第二掺杂类型、表面为绒面的第一半导体层。In order to solve the above problems, the present invention provides a substrate unit for processing using a substrate: comprising: a semiconductor substrate, the semiconductor substrate is a single crystal substrate with a first doping type, and the semiconductor substrate includes a first surface and the second surface opposite to it, the third surface and the fourth surface opposite to it, the crystal orientation of the third surface and the fourth surface is {111}; formed on the third surface of the semiconductor substrate has a The second doping type, the first semiconductor layer with textured surface.

根据本发明的第二方面还提供了一种利用衬底进行加工的基板结构,所述结构包括:基板单元阵列,所述基板单元阵列包括按照预定方向排列的多个基板单元,每个所述基板单元包括:具有第一掺杂类型的单晶半导体基板,所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面,所述第三表面和第四表面的晶向为{111},以及形成于所述半导体基板的第三表面上的具有第二掺杂类型、表面为绒面的第一半导体层;以及多个基片,所述多个基片分别设置在所述半导体基板的第一表面和第二表面的外侧,其中:对于相间隔的基板单元的每一个,其第二表面与其一侧的相邻基板的第二表面共用一个基片以形成第一沟槽,且其第一表面与其另一侧的相邻基板的第一表面共用另一个基片以形成第二沟槽,所述第一沟槽与所述第二沟槽开口方向相反,以使所述基板结构形成长城型结构。According to the second aspect of the present invention, there is also provided a substrate structure for processing with a substrate, the structure includes: a substrate unit array, the substrate unit array includes a plurality of substrate units arranged in a predetermined direction, each of the The substrate unit includes: a single crystal semiconductor substrate having a first doping type, the semiconductor substrate includes a first surface and a second surface opposite thereto, a third surface and a fourth surface opposite thereto, the third surface and the first surface The crystal orientation of the four surfaces is {111}, and a first semiconductor layer with a second doping type and a textured surface formed on the third surface of the semiconductor substrate; and a plurality of substrates, the plurality of The substrates are respectively arranged on the outer sides of the first surface and the second surface of the semiconductor substrate, wherein: for each of the spaced substrate units, the second surface and the second surface of the adjacent substrate on one side share a base sheet to form a first groove, and its first surface and the first surface of an adjacent substrate on the other side share another substrate to form a second groove, the first groove and the second groove The opening directions are opposite, so that the substrate structure forms a Great Wall structure.

根据本发明的第三方面,本发明还提供了一种用于半导体器件的基板结构的制造方法,其特征在于,包括如下步骤:A.提供半导体衬底,所述衬底为具有第一掺杂类型的单晶衬底,所述衬底包括第一表面和与第一表面相对的第二表面;B.对所述衬底的第一表面和第二表面进行构图;C.从所述第一表面刻蚀半导体衬底以形成至少两个第一沟槽;以及从所述第二表面刻蚀半导体衬底以形成至少一个第二沟槽,其中每个所述第二沟槽位于相邻的两个所述第一沟槽之间,所述第一沟槽和第二沟槽所对应的侧壁的晶向为{111},D.在所述第一沟槽的侧壁形成具有第二类型掺杂的第一半导体层,湿法腐蚀所述第一导体层以在其表面形成绒面层。According to the third aspect of the present invention, the present invention also provides a method for manufacturing a substrate structure for a semiconductor device, which is characterized in that it includes the following steps: A. providing a semiconductor substrate, said substrate being a single crystal substrate having a first doping type, said substrate comprising a first surface and a second surface opposite to the first surface; B. patterning the first surface and the second surface of the substrate; C. Etching the semiconductor substrate from the first surface to form at least two first trenches; and etching the semiconductor substrate from the second surface to form at least one second trench, wherein each of the second trenches The groove is located between two adjacent first grooves, and the crystal orientation of the side walls corresponding to the first groove and the second groove is {111}, D. A first semiconductor layer with second type doping is formed on the sidewall of the first trench, and the first semiconductor layer is wet-etched to form a textured layer on the surface thereof.

此外,本发明还提供了另一种用于半导体器件的基板结构的制造方法,所述方法包括:A、提供半导体衬底,所述半导体衬底具有第一掺杂类型,所述半导体衬底包括第一表面和与其相对的第二表面;B、对所述衬底的第一表面进行构图,以及对所述衬底的第二表面进行构图,以及从所述第一表面刻蚀衬底形成至少两个第一沟槽,以及从所述第二表面刻蚀衬底形成至少一个第二沟槽,以及在所述第一沟槽的内壁形成绒面,其中每个所述第二沟槽位于相邻的两个所述第一沟槽之间;C、进行后续加工。In addition, the present invention also provides another manufacturing method for a substrate structure of a semiconductor device, the method comprising: A, providing a semiconductor substrate, the semiconductor substrate has a first doping type, and the semiconductor substrate Including a first surface and a second surface opposite thereto; B, patterning the first surface of the substrate, and patterning the second surface of the substrate, and etching the substrate from the first surface forming at least two first grooves, and etching the substrate from the second surface to form at least one second groove, and forming a textured surface on the inner wall of the first groove, wherein each of the second grooves The groove is located between two adjacent first grooves; C, performing subsequent processing.

本发明还提供了根据上述方法形成的一种利用衬底进行加工的基板结构,所述结构包括:基板单元阵列,所述基板单元阵列包括按照预定方向排列的多个基板单元,每个基板单元包括:半导体基板,所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面,其中所述第三表面为绒面;以及多个基片,所述多个基片分别设置在所述半导体基板的第一表面和第二表面的外侧,其中:对于相间隔的基板单元的每一个,其第二表面与其一侧的相邻基板的第二表面共用一个基片以形成第一沟槽,且其第一表面与其另一侧的相邻基板的第一表面共用另一个基片以形成第二沟槽,所述第一沟槽与所述第二沟槽开口方向相反,以使所述基板结构形成长城型结构。The present invention also provides a substrate structure processed by using a substrate formed according to the above method, the structure includes: a substrate unit array, the substrate unit array includes a plurality of substrate units arranged in a predetermined direction, each substrate unit Including: a semiconductor substrate, the semiconductor substrate includes a first surface and a second surface opposite to it, a third surface and a fourth surface opposite to it, wherein the third surface is textured; and a plurality of substrates, the A plurality of substrates are respectively arranged on the outside of the first surface and the second surface of the semiconductor substrate, wherein: for each of the spaced apart substrate units, its second surface is shared with the second surface of the adjacent substrate on one side thereof One substrate to form a first groove, and its first surface shares another substrate with the first surface of its adjacent substrate on the other side to form a second groove, the first groove and the second The opening directions of the grooves are opposite, so that the substrate structure forms a Great Wall structure.

此外,本发明还提供了一种用于绒面形成的制作方法,所述方法包括:A、单晶半导体基板,所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面;B、通过各向异性湿法腐蚀至少在第三表面上形成第一绒面;C、在所述第一绒面上形成第二绒面。In addition, the present invention also provides a method for forming a suede surface, said method comprising: A, a single crystal semiconductor substrate, said semiconductor substrate comprising a first surface, a second surface opposite to it, and a third surface and The fourth surface opposite to it; B, forming a first textured surface on at least the third surface by anisotropic wet etching; C, forming a second textured surface on the first textured surface.

以及上述方法形成的利用衬底进行绒面加工的基板单元:包括:具有第一掺杂类型的单晶半导体基板,所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面;形成于所述半导体基板的第三表面上的第一绒面;形成于所述第一绒面上的第二绒面。And the substrate unit using the substrate for textured processing formed by the above method: including: a single crystal semiconductor substrate with a first doping type, the semiconductor substrate includes a first surface and a second surface opposite to it, and a third surface and a fourth surface opposite thereto; a first textured surface formed on the third surface of the semiconductor substrate; a second textured surface formed on the first textured surface.

根据本发明的基板结构有效地利用了衬底的厚度,从而在不增加整个晶圆片尺寸的前提下,提高了晶圆片的可加工的表面积或表面积利用率。同时,本发明还在具有特定晶向的表面上形成具有绒面的表面,在例如太阳能电池基板的加工过程中,能够提高陷光的效果,提高太阳能电池的吸光效率。The substrate structure according to the present invention effectively utilizes the thickness of the substrate, thereby increasing the processable surface area or surface area utilization rate of the wafer without increasing the size of the entire wafer. At the same time, the present invention also forms a suede surface on the surface with a specific crystal orientation, which can improve the light trapping effect and improve the light absorption efficiency of the solar cell during, for example, the processing of the solar cell substrate.

本发明附加的方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。Additional aspects and advantages of the invention will be set forth in part in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.

附图说明Description of drawings

本发明上述的和/或附加的方面和优点从下面结合附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present invention will become apparent and easy to understand from the following description of the embodiments in conjunction with the accompanying drawings, wherein:

图1示出了根据本发明的第一实施例的基板单元的示意图;Figure 1 shows a schematic diagram of a substrate unit according to a first embodiment of the present invention;

图2-4示出了根据本发明的第二实施例的基板结构的示意图;2-4 show schematic diagrams of a substrate structure according to a second embodiment of the present invention;

图5示出了根据本发明的第二实施例的基板结构的形成方法的示意图;5 shows a schematic diagram of a method for forming a substrate structure according to a second embodiment of the present invention;

图6-15示出了根据本发明的第二实施例的基板结构的制造方法的各个阶段的示意图;6-15 are schematic diagrams showing various stages of a manufacturing method of a substrate structure according to a second embodiment of the present invention;

图16-图23示出了根据本发明的第四实施例的基板结构的制造方法的各个阶段的示意图;16-23 are schematic diagrams showing various stages of a method for manufacturing a substrate structure according to a fourth embodiment of the present invention;

图24示出了根据本发明的第四实施例的基板结构形成方法的示意图。FIG. 24 shows a schematic diagram of a method for forming a substrate structure according to a fourth embodiment of the present invention.

具体实施方式Detailed ways

下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能解释为对本发明的限制。下文的公开提供了许多不同的实施例或例子用来实现本发明的不同结构。为了简化本发明的公开,下文中对特定例子的部件和设置进行描述。当然,它们仅仅为示例,并且目的不在于限制本发明。此外,本发明可以在不同例子中重复参考数字和/或字母。这种重复是为了简化和清楚的目的,其本身不指示所讨论各种实施例和/或设置之间的关系。此外,本发明提供了的各种特定的工艺和材料的例子,但是本领域普通技术人员可以意识到其他工艺的可应用于性和/或其他材料的使用。另外,以下描述的第一特征在第二特征之“上”的结构可以包括第一和第二特征形成为直接接触的实施例,也可以包括另外的特征形成在第一和第二特征之间的实施例,这样第一和第二特征可能不是直接接触。Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals designate the same or similar elements or elements having the same or similar functions throughout. The embodiments described below by referring to the figures are exemplary only for explaining the present invention and should not be construed as limiting the present invention. The following disclosure provides many different embodiments or examples for implementing different structures of the present invention. To simplify the disclosure of the present invention, components and arrangements of specific examples are described below. Of course, they are only examples and are not intended to limit the invention. Furthermore, the present invention may repeat reference numerals and/or letters in different instances. This repetition is for the purpose of simplicity and clarity and does not in itself indicate a relationship between the various embodiments and/or arrangements discussed. In addition, various specific process and material examples are provided herein, but one of ordinary skill in the art will recognize the applicability of other processes and/or the use of other materials. Additionally, configurations described below in which a first feature is "on" a second feature may include embodiments where the first and second features are formed in direct contact, and may include additional features formed between the first and second features. For example, such that the first and second features may not be in direct contact.

第一实施例first embodiment

如图1示出了本发明实施例的基板单元200的示意图,所述基板单元是利用衬底进行加工获得,所述衬底是单晶衬底,可以包括例如:单晶Si、单晶Ge、单晶SiGe。该衬底的厚度可为0.2-2mm。所述基板单元包括半导体基板101,所述半导体基板为具有第一掺杂类型的单晶基板,例如N型掺杂配置或者P型掺杂配置,所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面,所述第三表面和第四表面的晶向为{111};形成于所述半导体基板的第三表面上的具有第二掺杂类型、表面为绒面的第一半导体层202。FIG. 1 shows a schematic diagram of a substrate unit 200 according to an embodiment of the present invention. The substrate unit is obtained by processing a substrate, and the substrate is a single crystal substrate, which may include, for example: single crystal Si, single crystal Ge , Single crystal SiGe. The substrate may have a thickness of 0.2-2mm. The substrate unit includes a semiconductor substrate 101, which is a single crystal substrate with a first doping type, such as an N-type doping configuration or a P-type doping configuration, and the semiconductor substrate includes a first surface and an opposite The second surface, the third surface and the fourth surface opposite to it, the crystal orientation of the third surface and the fourth surface is {111}; the second doping type formed on the third surface of the semiconductor substrate 1. The first semiconductor layer 202 with a textured surface.

特别地,所述半导体基板的第一表面和第二表面301/302是半导体衬底的两个表面。In particular, the first surface and the second surface 301/302 of the semiconductor substrate are two surfaces of the semiconductor substrate.

此外,所述基板单元还可以包括形成于所述半导体基板101的第四表面上的具有第一掺杂类型、表面为绒面的第二半导体层(图中未示出)。所述第一和第二半导体层的材料可以是例如:多晶硅、非晶态硅或其组合,其厚度可以为大约1-10μm。In addition, the substrate unit may further include a second semiconductor layer (not shown in the figure) having a first doping type and having a textured surface formed on the fourth surface of the semiconductor substrate 101 . The material of the first and second semiconductor layers may be, for example, polysilicon, amorphous silicon or a combination thereof, and the thickness thereof may be about 1-10 μm.

特别地,在另外的实施例中(图中未示出),所述半导体基板的第三表面和第四表面的晶向可以不是{111},所述半导体基板包括:单晶Si、单晶Ge、单晶SiGe。在所述第三和第四表面晶向为非{111}的实施例中,所述基板单元还可以包括形成于所述半导体基板的第三表面上的第一绒面,以及形成于所述第一绒面上的第二绒面,其中所述第一绒面为晶向{111},所述第二绒面包括多晶硅、非晶硅或其组合。In particular, in another embodiment (not shown in the figure), the crystal orientations of the third surface and the fourth surface of the semiconductor substrate may not be {111}, and the semiconductor substrate includes: single crystal Si, single crystal Ge, single crystal SiGe. In the embodiment where the crystal orientations of the third and fourth surfaces are not {111}, the substrate unit may further include a first textured surface formed on the third surface of the semiconductor substrate, and a first textured surface formed on the The second texture on the first texture, wherein the first texture has a crystal orientation of {111}, and the second texture includes polysilicon, amorphous silicon or a combination thereof.

由此,本发明的实施例提供了一种利用衬底加工的基板单元,该衬底具有第一掺杂类型且为单晶衬底,由此可以利用各向同性刻蚀技术来加工所述衬底从而获得具有特定晶向的表面,进而有效地利用衬底的厚度,提高晶圆片的表面积利用率,而且,在所述基板单元的第三表面还形成了具有第二掺杂类型的、表面为绒面的第一半导体层202,以及在第四表面形成了具有第一掺杂类型的、表面为绒面的第二半导体层。在将所述基板单元用于太阳能电池基板中时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Therefore, an embodiment of the present invention provides a substrate unit processed by using a substrate having a first doping type and being a single crystal substrate, whereby the isotropic etching technique can be used to process the substrate unit The substrate thus obtains a surface with a specific crystal orientation, thereby effectively utilizing the thickness of the substrate and improving the surface area utilization rate of the wafer. Moreover, a second doping type is formed on the third surface of the substrate unit. , the first semiconductor layer 202 with a textured surface, and a second semiconductor layer with the first doping type and a textured surface formed on the fourth surface. When the substrate unit is used in a solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

特别地,在应用于太阳能电池基板中时,所述基板单元200还可以包括分别形成于第一半导体层上的第一电极层,以及形成于第二半导体层上的第二电极层(图中未示出)。其中所述第一电极层为进光面,它可以由TCO材料形成,例如SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、AZO或其组合。所述第二电极层也可以作为进光面,即也可以由TCO材料形成,可选择地,其也可以不作为进光面,并由适于导电的金属材料形成。所述第一电极层和第二电极层的厚度分别为大约10-200nm。In particular, when applied to a solar cell substrate, the substrate unit 200 may also include a first electrode layer respectively formed on the first semiconductor layer, and a second electrode layer formed on the second semiconductor layer (in the figure not shown). Wherein the first electrode layer is a light-incoming surface, which can be formed of TCO materials, such as SnO 2 , In 2 O 3 , ZnO, ITO, CdO, Cd 2 SnO 4 , FTO, AZO or combinations thereof. The second electrode layer can also be used as a light-incoming surface, that is, it can also be formed of a TCO material, alternatively, it can not be used as a light-incoming surface, and can be formed of a metal material suitable for conducting electricity. The thicknesses of the first electrode layer and the second electrode layer are respectively about 10-200 nm.

可选择地,在应用于太阳能电池基板中时,所述基板单元还可以包括形成于所述第一电极层上的减反射层,例如:氮化物材料。所述减反射层的厚度可以为大约40-160nm。从而进一步增加太阳能电池的进光效率。Optionally, when applied to a solar cell substrate, the substrate unit may further include an anti-reflection layer formed on the first electrode layer, such as a nitride material. The anti-reflection layer may have a thickness of about 40-160 nm. Thereby, the light-introduction efficiency of the solar cell is further increased.

作为由衬底进行加工所获得的附带结构,所述基板单元还可以包括形成于所述半导体基板第一表面和第二表面上的侧墙。As an incidental structure obtained by processing the substrate, the substrate unit may further include sidewalls formed on the first surface and the second surface of the semiconductor substrate.

由此,本发明的实施例提供了一种利用衬底加工的基板单元,该衬底具有第一掺杂类型且为单晶衬底,由此可以利用各向同性刻蚀技术来加工所述衬底从而获得具有特定晶向的表面,进而有效地利用衬底的厚度,提高晶圆片的表面积利用率,而且,在所述基板单元的第三表面还形成了具有第二掺杂类型的、表面为绒面的第一半导体层202,以及可选地,在第四表面形成具有第一掺杂类型的、表面为绒面的第二半导体层。在将所述基板单元用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Therefore, an embodiment of the present invention provides a substrate unit processed by using a substrate having a first doping type and being a single crystal substrate, whereby the isotropic etching technique can be used to process the substrate unit The substrate thus obtains a surface with a specific crystal orientation, thereby effectively utilizing the thickness of the substrate and improving the surface area utilization rate of the wafer. Moreover, a second doping type is formed on the third surface of the substrate unit. , the first semiconductor layer 202 with a textured surface, and optionally, a second semiconductor layer with the first doping type and a textured surface formed on the fourth surface. When the substrate unit is used as a solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

第二实施例second embodiment

以上已经根据本发明的第一实施例描述了本发明的基板单元,下面将结合附图描述本发明的第二实施例。The substrate unit of the present invention has been described above according to the first embodiment of the present invention, and the second embodiment of the present invention will be described below with reference to the accompanying drawings.

根据本发明的第二实施例,提供了一种利用衬底进行加工的基板结构,如图2所示,所述结构包括:基板单元阵列。According to the second embodiment of the present invention, there is provided a substrate structure processed by using a substrate. As shown in FIG. 2 , the structure includes: a substrate unit array.

所述基板单元阵列包括按照预定方向排列,例如沿方向A所示的多个基板单元200,优选地,它们可以是基本平行的多个基板单元。每个所述基板单元200包括半导体基板101-x,所述半导体基板为具有第一掺杂类型的单晶基板,其材料可以是例如单晶Si、单晶Ge、单晶SiGe。所述半导体基板包括第一表面301和与其相对的第二表面302以及第三表面303和与其相对的第四表面304。所述第三表面和第四表面的晶向为{111}。所述结构还包括:多个基片307-x以及308-x,所述多个基片分别设置在所述半导体基板的第一表面和第二表面的外侧。所述多个基片可以与所述多个基板单元由相同或者不同材料形成并至少包括一个层,其材料可以是例如:绝缘材料、金属、半导体材料或其组合。The substrate unit array includes a plurality of substrate units 200 arranged in a predetermined direction, for example along direction A, preferably, they may be a plurality of substantially parallel substrate units. Each of the substrate units 200 includes a semiconductor substrate 101-x, which is a single crystal substrate with a first doping type, and its material may be, for example, single crystal Si, single crystal Ge, or single crystal SiGe. The semiconductor substrate includes a first surface 301 and a second surface 302 opposite thereto, a third surface 303 and a fourth surface 304 opposite thereto. The crystal orientations of the third surface and the fourth surface are {111}. The structure further includes: a plurality of substrates 307-x and 308-x, the plurality of substrates are respectively disposed outside the first surface and the second surface of the semiconductor substrate. The plurality of substrates may be formed of the same or different material from the plurality of substrate units and include at least one layer, and the material may be, for example, insulating material, metal, semiconductor material or a combination thereof.

其中,对于相间隔的基板单元200的每一个,其第二表面与其一侧的相邻基板的第二表面共用一个基片,以形成第一沟槽305,且其第一表面与其另一侧的相邻基板的第一表面共用另一个基片,以形成第二沟槽306,所述第一沟槽与所述第二沟槽开口方向相反,以使所述基板结构形成长城型结构。特别地,所述基板结构还包括形成于所述第一沟槽305中的具有第二掺杂类型、表面为绒面的第一半导体层202。Wherein, for each of the spaced substrate units 200, its second surface and the second surface of the adjacent substrate on one side share a substrate to form the first groove 305, and its first surface and the other side The first surfaces of adjacent substrates share another substrate to form a second groove 306, and the opening direction of the first groove is opposite to that of the second groove, so that the substrate structure forms a Great Wall structure. In particular, the substrate structure further includes a first semiconductor layer 202 with a second doping type and a textured surface formed in the first trench 305 .

特别地,所述半导体基板的第一表面和第二表面301/302是半导体衬底的两个表面。优选地,所述基板结构还可以包括形成于所述第二沟槽306中的具有第一掺杂类型、表面为绒面的第二半导体层203,如图3所示。所述第一和第二半导体层的材料可以是例如:多晶硅、非晶态硅或其组合,其厚度可以为大约1-10μm。In particular, the first surface and the second surface 301/302 of the semiconductor substrate are two surfaces of the semiconductor substrate. Preferably, the substrate structure may further include a second semiconductor layer 203 having a first doping type and a textured surface formed in the second trench 306 , as shown in FIG. 3 . The material of the first and second semiconductor layers may be, for example, polysilicon, amorphous silicon or a combination thereof, and the thickness thereof may be about 1-10 μm.

此外,优选地,所述基板单元和与其连接的基片可以保持基本垂直。并且至少所述第一和第二沟槽之一的深度大于基板单元宽度的2倍,所述基板单元宽度为属于同一基板单元的、相邻两沟槽的侧壁所对应的表面之间的距离,也即同一基板单元的第三表面和第四表面之间的距离。所述基片的厚度小于所述基板单元宽度的1/3。Furthermore, preferably, the substrate unit and the substrate connected thereto may be kept substantially vertical. And the depth of at least one of the first and second grooves is greater than twice the width of the substrate unit, and the width of the substrate unit is the distance between the surfaces corresponding to the side walls of two adjacent grooves belonging to the same substrate unit. The distance, that is, the distance between the third surface and the fourth surface of the same substrate unit. The thickness of the substrate is less than 1/3 of the width of the substrate unit.

由此,本发明的实施例提供了一种利用衬底加工的基板结构,该基板结构具有长城型结构。所述衬底具有第一掺杂类型且为单晶衬底,由此可以利用各向同性刻蚀技术来加工所述衬底从而获得具有特定晶向的表面,进而有效地利用衬底的厚度形成长城型结构,提高晶圆片的表面积利用率。而且,在所述基板结构的第一沟槽中还形成了具有第二掺杂类型的、表面为绒面的第一半导体层202,以及可选地,在第二沟槽中形成了具有第一掺杂类型的、表面为绒面的第二半导体层203。在将所述基板单元用于太阳能电池基板中时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Thus, embodiments of the present invention provide a substrate structure utilizing substrate processing, the substrate structure having a Great Wall-like structure. The substrate has the first doping type and is a single crystal substrate, so that the substrate can be processed by an isotropic etching technique to obtain a surface with a specific crystal orientation, thereby effectively utilizing the thickness of the substrate Form a Great Wall structure and improve the utilization rate of the surface area of the wafer. Moreover, a first semiconductor layer 202 with a second doping type and a textured surface is formed in the first trench of the substrate structure, and optionally, a semiconductor layer 202 with a second doping type is formed in the second trench. A doped second semiconductor layer 203 with textured surface. When the substrate unit is used in a solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

特别地,在应用于太阳能电池基板中时,所述基板单元200还可以包括分别形成于第一半导体层上的第一电极层204,以及形成于第二半导体层上的第二电极层205,如图4所示。其中所述第一电极层为进光面,它可以由TCO材料形成,例如SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、AZO或其组合。所述第二电极层也可以作为进光面,即也可以由TCO材料形成。可选择地,第二电极层也可以不作为进光面,并由适于导电的金属材料形成。所述第一电极层和第二电极层的厚度分别为大约10-200nm。In particular, when applied to a solar cell substrate, the substrate unit 200 may further include a first electrode layer 204 respectively formed on the first semiconductor layer, and a second electrode layer 205 formed on the second semiconductor layer, As shown in Figure 4. Wherein the first electrode layer is a light-incoming surface, which can be formed of TCO materials, such as SnO 2 , In 2 O 3 , ZnO, ITO, CdO, Cd 2 SnO 4 , FTO, AZO or combinations thereof. The second electrode layer can also serve as a light-incoming surface, that is, it can also be formed of TCO material. Optionally, the second electrode layer may not serve as a light-incoming surface, and be formed of a metal material suitable for conducting electricity. The thicknesses of the first electrode layer and the second electrode layer are respectively about 10-200 nm.

可选择地,在应用于太阳能电池基板中时,所述基板单元还可以包括形成于所述第一电极层上的减反射层(图中未示出),例如:氮化物材料。所述减反射层的厚度可以为大约40-160nm。从而进一步增加太阳能电池的进光效率。Optionally, when applied to a solar cell substrate, the substrate unit may further include an anti-reflection layer (not shown in the figure), such as a nitride material, formed on the first electrode layer. The anti-reflection layer may have a thickness of about 40-160 nm. Thereby, the light-introduction efficiency of the solar cell is further increased.

以上已经根据附图描述根据本发明的实施例的新型基板单元和结构,所述基板单元和结构可以应用于半导体器件的制造、以及薄膜太阳能电池制造等多种领域中。需要注意的是,本领域技术人员能够根据上述的基板结构可以选择多种工艺进行制造,例如不同类型的产品线,不同的工艺流程等等,但是这些工艺制造的基板单元和结构只要具有与本发明基本相同的结构,达到基本相同的效果,那么也应包含在本发明的保护范围之内。为了能够更清楚的理解本发明,以下将具体描述形成本发明上述的基板单元和结构的方法及工艺,还需要说明的是,以下步骤仅是示意性的,并不是对本发明的限制,本领域技术人员还可通过其他工艺实现。以下实施例是本发明的优选实施例,能够有效降低制造成本。The novel substrate unit and structure according to the embodiments of the present invention have been described above with reference to the accompanying drawings, and the substrate unit and structure can be applied in various fields such as the manufacture of semiconductor devices and the manufacture of thin-film solar cells. It should be noted that those skilled in the art can choose a variety of processes for manufacturing according to the above-mentioned substrate structure, such as different types of product lines, different process flows, etc., but as long as the substrate units and structures manufactured by these processes have the same Inventing basically the same structure and achieving basically the same effect should also be included in the protection scope of the present invention. In order to understand the present invention more clearly, the method and process for forming the above-mentioned substrate unit and structure of the present invention will be specifically described below. It should also be noted that the following steps are only illustrative and not limiting to the present invention. Technicians can also realize it through other techniques. The following embodiments are preferred embodiments of the present invention, which can effectively reduce manufacturing costs.

如图5所示,为本发明实施例的形成基板单元和结构的方法的流程图,包括以下步骤:As shown in FIG. 5, it is a flowchart of a method for forming a substrate unit and a structure according to an embodiment of the present invention, including the following steps:

步骤S101,如图6所示,提供衬底100。在本发明的一个实施例中,所述衬底100为单晶半导体衬底,例如单晶Si、单晶Ge、单晶SiGe或其组合。在其他实施例中,可通过多种方式生成该半导体衬底,例如淀积、外延生长等,所述衬底可以具有N型掺杂配置或P型掺杂配置。其中,该半导体衬底的厚度可为0.2-2mm,当然本发明不限于此。所述衬底包括第一表面301和第二表面302,所述第一表面301和第二表面302相对。特别地,所述衬底可以包括一个或多个层,例如,所述衬底可以包括半导体层300和在所述半导体层的上方和下方形成的材料层307、308,如图7所示。所述材料层也可以包括一个或多个层,可以根据需要配置每个层所使用的材料,例如,可以包括用于刻蚀停止的绝缘层、用于导电的导电层等等。所述材料层可以是由与所述半导体层相同或不同的材料形成,包括但不限于绝缘材料、金属、半导体材料或上述材料的组合。这些都可以根据实际应用过程中的需要进行配置,本发明不做限制。In step S101 , as shown in FIG. 6 , a substrate 100 is provided. In one embodiment of the present invention, the substrate 100 is a single crystal semiconductor substrate, such as single crystal Si, single crystal Ge, single crystal SiGe or a combination thereof. In other embodiments, the semiconductor substrate can be produced in various ways, such as deposition, epitaxial growth, etc., and the substrate can have an N-type doping configuration or a P-type doping configuration. Wherein, the thickness of the semiconductor substrate may be 0.2-2mm, of course, the present invention is not limited thereto. The substrate includes a first surface 301 and a second surface 302, and the first surface 301 and the second surface 302 are opposite to each other. In particular, the substrate may include one or more layers, for example, the substrate may include a semiconductor layer 300 and material layers 307 , 308 formed above and below the semiconductor layer, as shown in FIG. 7 . The material layer may also include one or more layers, and the material used for each layer may be configured as required, for example, may include an insulating layer for etching stop, a conductive layer for conduction, and the like. The material layer may be formed of the same or different material as the semiconductor layer, including but not limited to insulating material, metal, semiconductor material or a combination of the above materials. All of these can be configured according to the needs in the actual application process, which is not limited in the present invention.

步骤S102,如图8-13所示,对所述衬底100的第一表面301和第二表面302进行构图,如图8所示。例如,以图7所示的衬底的结构为例,可以通过如下方式对所述衬底100进行构图:在所述衬底100的第一表面301上形成具有预定间隔配置的多个沟槽的光致抗蚀剂层309,如图9所示;刻蚀所述衬底100,以去除所述第一表面301的多个沟槽处的材料层307,如图10所示;移除所述光致抗蚀剂层309;而后在所述第二表面302上形成具有预定间隔配置的多个沟槽的光致抗蚀剂层310,如图11所示;刻蚀所述衬底100,以去除所述第二表面302的多个沟槽处的材料层308,如图12所示;移除所述光致抗蚀剂层,从而对所述衬底进行构图,如图13所示。当然以上所述的形成构图的步骤仅仅是示例,本领域的技术人员可以通过许多本领域所公知的方法获得本实施例所述的构图的衬底,这些均可以应用到本实施例中,而不脱离本发明的保护范围。Step S102 , as shown in FIGS. 8-13 , patterning the first surface 301 and the second surface 302 of the substrate 100 , as shown in FIG. 8 . For example, taking the structure of the substrate shown in FIG. 7 as an example, the substrate 100 can be patterned in the following manner: on the first surface 301 of the substrate 100, a plurality of grooves with a predetermined interval configuration are formed A photoresist layer 309, as shown in FIG. 9; etch the substrate 100 to remove the material layer 307 at the multiple grooves of the first surface 301, as shown in FIG. 10; remove The photoresist layer 309; then on the second surface 302, a photoresist layer 310 with a plurality of grooves arranged at predetermined intervals is formed, as shown in FIG. 11; the substrate is etched 100, to remove the material layer 308 at the multiple grooves of the second surface 302, as shown in FIG. 12; remove the photoresist layer, thereby patterning the substrate, as shown in FIG. 13 shown. Of course, the patterning steps described above are only examples, and those skilled in the art can obtain the patterned substrate described in this embodiment through many methods known in the art, which can be applied to this embodiment, and Without departing from the protection scope of the present invention.

而后,在步骤S103,如图14所示,从所述衬底100的第一表面301刻蚀至少两个第一沟槽305;以及从所述衬底100的第二表面302刻蚀至少一个第二沟槽306。由于所述衬底为单晶衬底,因此可以选择各向同性刻蚀方法来对所述衬底进行刻蚀,例如可以利用湿法刻蚀,采用氢氧化钾(KOH)、四甲基氢氧化铵(TMAH)或乙二胺-邻苯二酚(EDP)等溶剂进行刻蚀,在所述第一表面和第二表面的晶向为{110}或{112}的情况下,刻蚀剂将会停止在衬底的{111}晶面上,所形成的第一沟槽和第二沟槽其侧壁所对应的表面的晶向为{111},从而获得具有特定晶向的表面。Then, in step S103, as shown in FIG. 14, at least two first grooves 305 are etched from the first surface 301 of the substrate 100; The second trench 306 . Since the substrate is a single crystal substrate, an isotropic etching method can be selected to etch the substrate, for example, wet etching can be used, using potassium hydroxide (KOH), tetramethylhydrogen Ammonium oxide (TMAH) or ethylenediamine-catechol (EDP) and other solvents for etching, when the crystal orientation of the first surface and the second surface is {110} or {112}, the etching The agent will stop on the {111} crystal plane of the substrate, and the crystal orientation of the surfaces corresponding to the sidewalls of the formed first trench and second trench is {111}, thereby obtaining a surface with a specific crystal orientation .

可选地,可以刻蚀全部或部分所述半导体层300,例如可以刻蚀所述衬底的第一表面301并停止在所述第二表面302的材料层308上,并刻蚀所述衬底的第二表面302并停止在所述第一表面301的材料层309上。当然也可以只刻蚀一部分半导体层,即第一沟槽和第二沟槽的底部不接触所述材料层308、309。当所述衬底为一层时,仅可以刻蚀部分衬底。在图14中,使用实线限定的深色区域表示在所述第一表面301上形成的第一沟槽305,使用虚线限定的浅色区域表示在所述第二表面302上形成的第二沟槽306。所述第一沟槽和第二沟槽可以具有相等或者不等的间隔,Optionally, all or part of the semiconductor layer 300 can be etched, for example, the first surface 301 of the substrate can be etched and stop on the material layer 308 of the second surface 302, and the substrate can be etched. The second surface 302 of the bottom rests on the material layer 309 of the first surface 301 . Of course, only a part of the semiconductor layer may be etched, that is, the bottoms of the first trench and the second trench do not contact the material layers 308 , 309 . When the substrate is one layer, only part of the substrate can be etched. In FIG. 14 , the dark area defined by the solid line indicates the first trench 305 formed on the first surface 301, and the light area defined by the dotted line indicates the second trench 305 formed on the second surface 302. groove 306 . The first groove and the second groove may have equal or unequal intervals,

特别地,可以构图所述衬底,以使所述第一沟槽和第二沟槽为基本平行,这些均可以根据设计需要来设置。这样,每个所述第二沟槽306位于相邻的两个所述第一沟槽305之间,以将所述衬底分割成至少两个基板和至少一个基片,所述基板由第一沟槽305和第二沟槽306的侧壁所限定,所述基片连接相邻的两个所述基板,从而获得具有长城型结构的基板结构,如图15所示。优选地,所述第一305和第二沟槽306之一的深度311大于基板宽度(属于同一基板的、相邻两沟槽的侧壁所对应的表面之间的距离)310的2倍。In particular, the substrate can be patterned so that the first groove and the second groove are substantially parallel, and these can be set according to design requirements. In this way, each of the second grooves 306 is located between two adjacent first grooves 305, so as to divide the substrate into at least two substrates and at least one substrate, and the substrate is formed by the first Defined by the side walls of a groove 305 and a second groove 306, the substrate connects two adjacent substrates, thereby obtaining a substrate structure with a Great Wall structure, as shown in FIG. 15 . Preferably, the depth 311 of one of the first groove 305 and the second groove 306 is greater than twice the substrate width (the distance between surfaces corresponding to the sidewalls of two adjacent grooves belonging to the same substrate) 310 .

特别地,当所述多个第一沟槽305和所述多个第二沟槽306基本平行时,所述基板阵列可以是包括基本平行的多个基板。特别地,所述基板和与其连接的基片可以是基本垂直的,即所述第一沟槽和第二沟槽可以是基本矩形的形状。In particular, when the plurality of first grooves 305 and the plurality of second grooves 306 are substantially parallel, the substrate array may include a plurality of substantially parallel substrates. In particular, the substrate and the substrate connected thereto may be substantially vertical, ie the first groove and the second groove may be substantially rectangular in shape.

而后,在步骤S104,在所述第一沟槽305的侧壁形成具有第二类型掺杂的第一半导体层,而后湿法腐蚀所述第一导体层以在其表面形成绒面层202,如图2所示。可选地,如图3所示,还可以在所述第二沟槽306的侧壁形成具有第一类型掺杂的第二半导体层,而后湿法腐蚀所述第二导体层以在其表面形成绒面层203。所述第一和第二半导体层的材料可以是例如:多晶硅、非晶态硅或其组合,其厚度可以为大约1-10μm。Then, in step S104, a first semiconductor layer with second-type doping is formed on the sidewall of the first trench 305, and then the first conductive layer is wet-etched to form a textured layer 202 on its surface, as shown in picture 2. Optionally, as shown in FIG. 3 , a second semiconductor layer with the first type of doping may also be formed on the sidewall of the second trench 306, and then wet etch the second semiconductor layer to form a The suede layer 203 is formed. The material of the first and second semiconductor layers may be, for example, polysilicon, amorphous silicon or a combination thereof, and the thickness thereof may be about 1-10 μm.

由此,本发明的实施例提供了一种形成基板结构的方法,所述方法能够形成长城型结构的基板结构。利用具有第一掺杂类型的单晶衬底,进行各向同性刻蚀技术来加工所述衬底从而获得具有特定晶向的表面,进而有效地利用衬底的厚度形成长城型结构,提高晶圆片的表面积利用率。而且,在所述基板结构的第一沟槽中还形成了具有第二掺杂类型的、表面为绒面的第一半导体层202,以及可选地,在第二沟槽中形成了具有第一掺杂类型的、表面为绒面的第二半导体层203。在将所述基板结构用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Thus, embodiments of the present invention provide a method of forming a substrate structure capable of forming a Great Wall-like structured substrate structure. Utilize the single crystal substrate with the first doping type, process the substrate with isotropic etching technology to obtain a surface with a specific crystal orientation, and then effectively use the thickness of the substrate to form a Great Wall structure and improve the crystallinity. Surface area utilization of the wafer. Moreover, a first semiconductor layer 202 with a second doping type and a textured surface is formed in the first trench of the substrate structure, and optionally, a semiconductor layer 202 with a second doping type is formed in the second trench. A doped second semiconductor layer 203 with textured surface. When the substrate structure is used in the application of the solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

特别地,在将所述方法获得的基板结构应用于太阳能电池领域中时,还可以在所述第一沟槽205的第一半导体层202上形成第一电极层204,以及在第二半导体层203上形成第二电极层205,如图4所示。其中所述第一电极层204为进光面,它可以由TCO材料形成,例如SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、AZO或其组合。所述第二电极层205也可以作为进光面,即也可以由TCO材料形成。可选择地,第二电极层205也可以不作为进光面,并由适于导电的金属材料形成。所述第一电极层和第二电极层的厚度分别为大约10-200nm。In particular, when the substrate structure obtained by the method is applied to the field of solar cells, the first electrode layer 204 can also be formed on the first semiconductor layer 202 of the first groove 205, and the second semiconductor layer 203 is formed on the second electrode layer 205, as shown in FIG. 4 . Wherein the first electrode layer 204 is a light-incoming surface, which can be formed of TCO materials, such as SnO 2 , In 2 O 3 , ZnO, ITO, CdO, Cd 2 SnO 4 , FTO, AZO or combinations thereof. The second electrode layer 205 can also serve as a light-incoming surface, that is, it can also be formed of TCO material. Optionally, the second electrode layer 205 may not serve as a light-incoming surface, and be formed of a metal material suitable for conducting electricity. The thicknesses of the first electrode layer and the second electrode layer are respectively about 10-200 nm.

可选择地,在将所述方法获得的基板结构应用于太阳能电池领域中时,还可以在所述第一电极层204上形成减反射层(图中未示出),例如:氮化物材料。所述减反射层的厚度可以为大约40-160nm。从而进一步增加太阳能电池的进光效率。Optionally, when the substrate structure obtained by the method is applied in the field of solar cells, an anti-reflection layer (not shown in the figure), such as a nitride material, may also be formed on the first electrode layer 204 . The anti-reflection layer may have a thickness of about 40-160 nm. Thereby, the light-introduction efficiency of the solar cell is further increased.

进一步地,可以延第一沟槽和第二沟槽切割所述基板结构从而形成基板单元,或者当所述基片的厚度足够薄时,例如小于所述基板宽度的1/3,可以通过适当的工艺,容易地拉伸所述基板结构,从而使基板单元阵列形成在基本同一平面,从而适于下一步的处理和加工。Further, the substrate structure can be cut along the first groove and the second groove to form a substrate unit, or when the thickness of the substrate is sufficiently thin, for example, less than 1/3 of the width of the substrate, it can be appropriately The process can easily stretch the substrate structure, so that the substrate unit arrays are formed on substantially the same plane, which is suitable for the next treatment and processing.

第三实施例third embodiment

以上在第一实施例中对单晶基板单元进行了描述,第二实施例中对单晶晶向{111}的基板结构及其制造方法进行了描述,以下将对单晶晶向非{111}的基板单元、结构及其制造方法进行详细描述(图示可参考第二实施例)。The single crystal substrate unit has been described above in the first embodiment, and the substrate structure of the single crystal crystal orientation {111} and its manufacturing method have been described in the second embodiment, and the single crystal crystal orientation non-{111} }’s substrate unit, structure and manufacturing method are described in detail (see the second embodiment for illustration).

根据本发明第三实施例,提供了一种利用衬底进行加工的基板结构,所述结构包括:基板单元阵列。According to a third embodiment of the present invention, a substrate structure processed by using a substrate is provided, and the structure includes: a substrate unit array.

所述基板单元阵列包括按照预定方向排列,优选地,它们可以是基本平行的多个基板单元。每个所述基板单元包括半导体基板,所述半导体基板为具有第一掺杂类型的单晶基板,其材料可以是例如单晶Si、单晶Ge、单晶SiGe。所述半导体基板包括第一表面和与其相对的第二表面以及第三表面和与其相对的第四表面。所述第三表面和第四表面的晶向不是{111}。所述结构还包括:多个基片,所述多个基片分别设置在所述半导体基板的第一表面和第二表面的外侧。所述多个基片可以与所述多个基板单元由相同或者不同材料形成并至少包括一个层,其材料可以是例如:绝缘材料、金属、半导体材料或其组合。The substrate unit array includes a plurality of substrate units arranged in a predetermined direction, preferably, they may be substantially parallel. Each of the substrate units includes a semiconductor substrate, and the semiconductor substrate is a single crystal substrate with a first doping type, and its material may be, for example, single crystal Si, single crystal Ge, or single crystal SiGe. The semiconductor substrate includes a first surface and a second surface opposite thereto, and a third surface and a fourth surface opposite thereto. The crystal orientations of the third surface and the fourth surface are not {111}. The structure further includes: a plurality of substrates disposed outside the first surface and the second surface of the semiconductor substrate, respectively. The plurality of substrates may be formed of the same or different material from the plurality of substrate units and include at least one layer, and the material may be, for example, insulating material, metal, semiconductor material or a combination thereof.

其中,对于相间隔的基板单元的每一个,其第二表面与其一侧的相邻基板的第二表面共用一个基片,以形成第一沟槽,且其第一表面与其另一侧的相邻基板的第一表面共用另一个基片,以形成第二沟槽,所述第一沟槽与所述第二沟槽开口方向相反,以使所述基板结构形成长城型结构。特别地,所述基板结构还包括形成于所述第一沟槽中的第一绒面,以及形成于第一绒面上的具有第二类型掺杂的第二绒面,其中所述第一绒面为晶向{111},所述第二绒面包括多晶硅、非晶硅或其组合。Wherein, for each of the spaced substrate units, its second surface and the second surface of the adjacent substrate on one side share a substrate to form the first groove, and its first surface is opposite to the second surface on the other side. The first surface adjacent to the substrate shares another substrate to form a second groove, and the opening direction of the first groove is opposite to that of the second groove, so that the substrate structure forms a Great Wall structure. In particular, the substrate structure further includes a first textured surface formed in the first groove, and a second textured surface with a second type of doping formed on the first textured surface, wherein the first textured surface The texture has a crystal orientation of {111}, and the second texture includes polysilicon, amorphous silicon or a combination thereof.

特别地,所述半导体基板的第一表面和第二表面是半导体衬底的两个表面。优选地,所述基板结构还可以包括形成于所述第二沟槽中的第三绒面,以及形成于第三绒面上的具有第一类型掺杂的第四绒面,其中所述第三绒面为晶向{111},所述第四绒面包括多晶硅、非晶硅或其组合。In particular, the first surface and the second surface of the semiconductor substrate are two surfaces of the semiconductor substrate. Preferably, the substrate structure may further include a third texture formed in the second groove, and a fourth texture with the first type of doping formed on the third texture, wherein the first texture The third textured surface has a crystal orientation of {111}, and the fourth textured surface includes polysilicon, amorphous silicon or a combination thereof.

此外,优选地,所述基板单元和与其连接的基片可以保持基本垂直。并且至少所述第一和第二沟槽之一的深度大于基板单元宽度的2倍,所述基板单元宽度为属于同一基板单元的、相邻两沟槽的侧壁所对应的表面之间的距离,也即同一基板单元的第三表面和第四表面之间的距离。所述基片的厚度小于所述基板单元宽度的1/3。Furthermore, preferably, the substrate unit and the substrate connected thereto may be kept substantially vertical. And the depth of at least one of the first and second grooves is greater than twice the width of the substrate unit, and the width of the substrate unit is the distance between the surfaces corresponding to the side walls of two adjacent grooves belonging to the same substrate unit. The distance, that is, the distance between the third surface and the fourth surface of the same substrate unit. The thickness of the substrate is less than 1/3 of the width of the substrate unit.

由此,本发明的实施例提供了一种利用衬底加工的基板结构,该基板结构具有长城型结构。所述衬底具有第一掺杂类型且为单晶衬底,由此可以利用各向同性刻蚀技术来加工所述衬底从而获得具有特定晶向的表面,进而有效地利用衬底的厚度形成长城型结构,提高晶圆片的表面积利用率。而且,在所述基板结构的第一沟槽中还形成了第一绒面以及第二绒面,以及可选地,在第二沟槽中形成了第三绒面和第四绒面。在将所述基板单元用于太阳能电池基板中时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Thus, embodiments of the present invention provide a substrate structure utilizing substrate processing, the substrate structure having a Great Wall-like structure. The substrate has the first doping type and is a single crystal substrate, so that the substrate can be processed by an isotropic etching technique to obtain a surface with a specific crystal orientation, thereby effectively utilizing the thickness of the substrate Form a Great Wall structure and improve the utilization rate of the surface area of the wafer. Moreover, a first texture and a second texture are formed in the first groove of the substrate structure, and optionally, a third texture and a fourth texture are formed in the second groove. When the substrate unit is used in a solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

以下将描述本实施例形成基板单元和结构的方法,仅将描述区别于第二实施例的内容,相同的将不再赘述。The method for forming the substrate unit and the structure of this embodiment will be described below, and only the content that is different from that of the second embodiment will be described, and the same will not be repeated.

在步骤S101’,提供衬底。在本发明的一个实施例中,所述衬底为单晶半导体衬底,例如单晶Si、单晶Ge、单晶SiGe或其组合。所述衬底包括第一表面和第二表面,所述第一表面和第二表面相对,其中所述第三和第四表面的晶向不是{111}。In step S101', a substrate is provided. In one embodiment of the present invention, the substrate is a single crystal semiconductor substrate, such as single crystal Si, single crystal Ge, single crystal SiGe or a combination thereof. The substrate includes a first surface and a second surface, the first surface and the second surface are opposite, wherein crystal orientations of the third and fourth surfaces are not {111}.

在步骤S102’,对所述衬底的第一表面和第二表面进行构图,同第二实施例,不再赘述。In step S102', the first surface and the second surface of the substrate are patterned, which is the same as the second embodiment, and will not be described again.

在步骤S103’,从所述衬底的第一表面刻蚀至少两个第一沟槽;以及从所述衬底的第二表面刻蚀至少一个第二沟槽;以及在第一和/或第二沟槽内形成绒面层。In step S103', etching at least two first trenches from the first surface of the substrate; and etching at least one second trench from the second surface of the substrate; and etching the first and/or A suede layer is formed in the second groove.

在一个实施例中,可以通过各向异性的刻蚀方法,例如RIE的方法,从第一表面刻蚀至少两个第一沟槽,所述第一沟槽的侧壁即为半导体基板的第三和第四表面,而后,通过各向异性湿法腐蚀,例如KOH或TMAH溶剂,经腐蚀后,在所述第一沟槽的第三和第四表面上形成了晶向为{111}的第一绒面,而后,可以在所述第一绒面上沉淀多晶硅、非晶硅或其组合,并再次进行腐蚀以形成第二绒面,所述第二绒面可以具有第二类型掺杂,从而在第一沟槽内形成了包括第一和第二绒面的绒面层。而后,可以通过各向异性的刻蚀方法,例如RIE的方法,从第二表面刻蚀至少一个第二沟槽。In one embodiment, at least two first grooves can be etched from the first surface by an anisotropic etching method, such as RIE method, and the sidewalls of the first grooves are the first grooves of the semiconductor substrate. The third and fourth surfaces, and then, by anisotropic wet etching, such as KOH or TMAH solvent, after etching, a crystal orientation of {111} is formed on the third and fourth surfaces of the first trench. The first textured surface, polysilicon, amorphous silicon, or a combination thereof may then be deposited on the first textured surface, and etched again to form a second textured surface, which may have a second type of doping , so that a suede layer including the first and the second suede is formed in the first groove. Then, at least one second trench can be etched from the second surface by anisotropic etching method, such as RIE method.

在另一实施例中,可以通过各向异性的刻蚀方法,例如RIE的方法,分别从第一表面刻蚀至少两个第一沟槽、第二表面刻蚀至少一个第二沟槽,第一和第二沟槽的侧壁为半导体基本的第三和第四表面。而后,通过各向异性湿法腐蚀,例如KOH或TMAH溶剂,经腐蚀后,在所述第一沟槽的第三和第四表面上形成了晶向为{111}的第一绒面,在所述第二沟槽的第三和第四表面上形成了晶向为{111}的第三绒面,而后,可以在所述第一绒面以及第三绒面上沉淀多晶硅、非晶硅或其组合,并再次进行腐蚀以在第一绒面上形成第二绒面、第三绒面上形成第四绒面,所述第二绒面可以具有第二类型掺杂,所述第三绒面可以具有第一类型掺杂,从而在第一沟槽内形成了包括第一和第二绒面的绒面层,在第二沟槽内形成了包括第三和第四绒面的绒面层。In another embodiment, an anisotropic etching method, such as RIE, can be used to etch at least two first grooves from the first surface and at least one second groove from the second surface, respectively. The sidewalls of the first and second trenches are the basic third and fourth surfaces of the semiconductor. Then, by anisotropic wet etching, such as KOH or TMAH solvent, after etching, a first textured surface with a crystal orientation of {111} is formed on the third and fourth surfaces of the first trench, and the A third texture with a crystal orientation of {111} is formed on the third and fourth surfaces of the second groove, and then polysilicon and amorphous silicon can be deposited on the first texture and the third texture or a combination thereof, and etch again to form a second texture on the first texture and a fourth texture on the third texture, the second texture may have a second type of doping, the third texture The texture may have a doping of the first type such that a texture layer comprising first and second textures is formed in the first groove and a texture layer comprising third and fourth textures is formed in the second groove Surface layer.

由此,本发明的实施例提供了一种形成基板结构的方法,所述方法能够形成长城型结构的基板结构。利用具有第一掺杂类型的单晶衬底,进行刻蚀来加工所述衬底,进而有效地利用衬底的厚度形成长城型结构,提高晶圆片的表面积利用率。而且,在所述基板结构的第一沟槽中还形成了第一和第二绒面,以及可选地,在第二沟槽中形成了第三和第四绒面。在将所述基板结构用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Thus, embodiments of the present invention provide a method of forming a substrate structure capable of forming a Great Wall-like structured substrate structure. The single crystal substrate with the first doping type is used to process the substrate by etching, and then the thickness of the substrate is effectively used to form a Great Wall structure, thereby improving the utilization rate of the surface area of the wafer. Furthermore, first and second textures are formed in the first groove of the substrate structure, and optionally, third and fourth textures are formed in the second groove. When the substrate structure is used in the application of the solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

特别地,可以将所述方法获得的基板结构应用于太阳能电池领域中,可以在上述结构上形成后续步骤,例如在所述第二绒面上形成第一电极,以及在所述第二沟槽内壁或第四绒面上形成第二电极,或其他所需步骤,同第二实施例所述,不再赘述。In particular, the substrate structure obtained by the method can be applied to the field of solar cells, and subsequent steps can be formed on the above structure, such as forming a first electrode on the second textured surface, and forming a first electrode on the second trench Forming the second electrode on the inner wall or the fourth suede, or other required steps, are the same as those described in the second embodiment, and will not be repeated here.

第四实施例Fourth embodiment

以上已经结合附图描述了本发明的第一实施例、第二实施例和第三实施例,它们是基于单晶衬底而实现的。下面将结合附图描述根据本发明第三实施例的基于多晶衬底的基板结构及其制造方法。The first embodiment, the second embodiment and the third embodiment of the present invention have been described above with reference to the accompanying drawings, and they are implemented based on a single crystal substrate. A substrate structure based on a polycrystalline substrate and a manufacturing method thereof according to a third embodiment of the present invention will be described below with reference to the accompanying drawings.

根据本发明的第四实施例,提供了一种利用衬底进行加工的基板结构,参考图19、图21,所述结构包括:基板单元阵列。According to the fourth embodiment of the present invention, there is provided a substrate structure processed by using a substrate. Referring to FIG. 19 and FIG. 21 , the structure includes: a substrate unit array.

如图19所示,所述基板单元阵列包括按照预定方向排列的多个基板单元,例如沿方向A所示的多个基板单元200,优选地,它们可以是基本平行的多个基板单元。每个基板单元200包括半导体基板101-x,所述半导体基板101-x可以是多晶衬底,可以包括例如:多晶Si、多晶Ge、多晶SiGe、III–V或II-VI化合物半导体或其组合。所述半导体基板包括第一表面301和与其相对的第二表面302以及第三表面303和与其相对的第四表面304,其中所述第三表面303为绒面,此外,可选地,所述基板单元的第四表面304也可以为绒面,如图21所示。所述结构还包括:多个基片307-x以及308-x,所述多个基片分别设置在所述半导体基板的第一表面和第二表面的外侧。所述多个基片可以与所述多个基板单元由相同或者不同材料形成并至少包括一个层,其材料可以是例如:绝缘材料、金属、半导体材料或其组合。As shown in FIG. 19 , the substrate unit array includes a plurality of substrate units arranged in a predetermined direction, such as a plurality of substrate units 200 shown along direction A, preferably, they may be substantially parallel substrate units. Each substrate unit 200 includes a semiconductor substrate 101-x, which may be a polycrystalline substrate and may include, for example: polycrystalline Si, polycrystalline Ge, polycrystalline SiGe, III-V or II-VI compounds Semiconductors or combinations thereof. The semiconductor substrate includes a first surface 301 and a second surface 302 opposite thereto, a third surface 303 and a fourth surface 304 opposite thereto, wherein the third surface 303 is textured, and optionally, the The fourth surface 304 of the substrate unit can also be a suede surface, as shown in FIG. 21 . The structure further includes: a plurality of substrates 307-x and 308-x, the plurality of substrates are respectively disposed outside the first surface and the second surface of the semiconductor substrate. The plurality of substrates may be formed of the same or different material from the plurality of substrate units and include at least one layer, and the material may be, for example, insulating material, metal, semiconductor material or a combination thereof.

其中,对于相间隔的基板单元200的每一个,其第二表面与其一侧的相邻基板的第二表面共用一个基片,以形成第一沟槽305,且其第一表面与其另一侧的相邻基板的第一表面共用另一个基片,以形成第二沟槽306,所述第一沟槽与所述第二沟槽开口方向相反,以使所述基板结构形成长城型结构。特别地,所述基板结构还包括形成于所述第一沟槽305中的具有第二掺杂类型、表面为绒面的第一半导体层202。Wherein, for each of the spaced substrate units 200, its second surface and the second surface of the adjacent substrate on one side share a substrate to form the first groove 305, and its first surface and the other side The first surfaces of adjacent substrates share another substrate to form a second groove 306, and the opening direction of the first groove is opposite to that of the second groove, so that the substrate structure forms a Great Wall structure. In particular, the substrate structure further includes a first semiconductor layer 202 with a second doping type and a textured surface formed in the first trench 305 .

特别地,所述半导体基板的第一表面和第二表面301/302是半导体衬底的两个表面。In particular, the first surface and the second surface 301/302 of the semiconductor substrate are two surfaces of the semiconductor substrate.

此外,优选地,所述基板单元和与其连接的基片可以保持基本垂直。并且至少所述第一和第二沟槽之一的深度大于基板单元宽度的2倍,所述基板单元宽度为属于同一基板单元的、相邻两沟槽的侧壁所对应的表面之间的距离,也即同一基板单元的第三表面和第四表面之间的距离。所述基片的厚度小于所述基板单元宽度的1/3。Furthermore, preferably, the substrate unit and the substrate connected thereto may be kept substantially vertical. And the depth of at least one of the first and second grooves is greater than twice the width of the substrate unit, and the width of the substrate unit is the distance between the surfaces corresponding to the side walls of two adjacent grooves belonging to the same substrate unit. The distance, that is, the distance between the third surface and the fourth surface of the same substrate unit. The thickness of the substrate is less than 1/3 of the width of the substrate unit.

由此,本发明的实施例提供了一种利用衬底加工的基板结构,该基板结构具有长城型结构,有效地利用衬底的厚度,提高晶圆片的表面积利用率,而且,所述基板单元的第三表面为绒面,以及可选地,在第四表面也可以为绒面。在将所述基板单元用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Therefore, the embodiment of the present invention provides a substrate structure processed by using the substrate. The substrate structure has a Great Wall structure, which effectively utilizes the thickness of the substrate and improves the utilization rate of the surface area of the wafer. Moreover, the substrate The third surface of the unit is textured, and optionally the fourth surface may also be textured. When the substrate unit is used as a solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

特别地,在应用于太阳能电池基板中时,参考图22、图23,所述基板单元还包括:形成于所述半导体基板101的绒面的第三表面303上的、具有第二掺杂类型的第一半导体层202及其上的第一电极层204,以及形成于半导体基板101第四表面304上的第二电极层205。此外,还可以包括:形成于所述半导体基板的第四表面304与第二电极层205之间的、具有第一掺杂类型的第二半导体层203。其中所述第一电极层为进光面,它可以由TCO材料形成,例如SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、AZO或其组合。所述第二电极层也可以作为进光面,即也可以由TCO材料形成,可选择地,其也可以不作为进光面,并由适于导电的金属材料形成。所述第一电极层和第二电极层的厚度分别为大约10-200nm。其中所述第一和第二半导体层分别包括:多晶硅、非晶态硅或其组合。所述第一和第二半导体层的厚度分别为大约10-500nm。In particular, when applied to a solar cell substrate, referring to FIG. 22 and FIG. 23 , the substrate unit further includes: a second dopant doping layer formed on the textured third surface 303 of the semiconductor substrate 101 ; The first semiconductor layer 202 and the first electrode layer 204 thereon, and the second electrode layer 205 formed on the fourth surface 304 of the semiconductor substrate 101 . In addition, it may further include: a second semiconductor layer 203 with the first doping type formed between the fourth surface 304 of the semiconductor substrate and the second electrode layer 205 . Wherein the first electrode layer is a light-incoming surface, which can be formed of TCO materials, such as SnO 2 , In 2 O 3 , ZnO, ITO, CdO, Cd 2 SnO 4 , FTO, AZO or combinations thereof. The second electrode layer can also be used as a light-incoming surface, that is, it can also be formed of a TCO material, alternatively, it can not be used as a light-incoming surface, and can be formed of a metal material suitable for conducting electricity. The thicknesses of the first electrode layer and the second electrode layer are respectively about 10-200 nm. Wherein the first and second semiconductor layers respectively include: polysilicon, amorphous silicon or a combination thereof. The thickness of the first and second semiconductor layers is about 10-500 nm, respectively.

可选择地,在应用于太阳能电池基板中时,所述基板单元还可以包括形成于所述第一电极层上的减反射层,例如:氮化物材料。所述减反射层的厚度可以为大约40-160nm。从而进一步增加太阳能电池的进光效率。Optionally, when applied to a solar cell substrate, the substrate unit may further include an anti-reflection layer formed on the first electrode layer, such as a nitride material. The anti-reflection layer may have a thickness of about 40-160 nm. Thereby, the light-introduction efficiency of the solar cell is further increased.

以上已经根据附图描述根据本发明的第三实施例的新型基板结构,所述基板结构可以应用于半导体器件的制造、以及薄膜太阳能电池制造等多种领域中。需要注意的是,本领域技术人员能够根据上述的基板结构可以选择多种工艺进行制造,例如不同类型的产品线,不同的工艺流程等等,但是这些工艺制造的基板单元和结构只要具有与本发明基本相同的结构,达到基本相同的效果,那么也应包含在本发明的保护范围之内。为了能够更清楚的理解本发明,以下将具体描述形成本发明上述的基板单元和结构的方法及工艺,还需要说明的是,以下步骤仅是示意性的,并不是对本发明的限制,本领域技术人员还可通过其他工艺实现。以下实施例是本发明的优选实施例,能够有效降低制造成本。The novel substrate structure according to the third embodiment of the present invention has been described above with reference to the accompanying drawings, and the substrate structure can be applied in various fields such as the manufacture of semiconductor devices and the manufacture of thin-film solar cells. It should be noted that those skilled in the art can choose a variety of processes for manufacturing according to the above-mentioned substrate structure, such as different types of product lines, different process flows, etc., but as long as the substrate units and structures manufactured by these processes have the same Inventing basically the same structure and achieving basically the same effect should also be included in the protection scope of the present invention. In order to understand the present invention more clearly, the method and process for forming the above-mentioned substrate unit and structure of the present invention will be specifically described below. It should also be noted that the following steps are only illustrative and not limiting to the present invention. Technicians can also realize it through other techniques. The following embodiments are preferred embodiments of the present invention, which can effectively reduce manufacturing costs.

图24示出了本发明实施例的基板结构的制造方法的流程图,为了简化目的,与本发明第二实施例相似的步骤在本方法中不再赘述。FIG. 24 shows a flow chart of a method for manufacturing a substrate structure according to an embodiment of the present invention. For the purpose of simplification, steps similar to those in the second embodiment of the present invention will not be repeated in this method.

在步骤S201,如图6所示,提供衬底100。在本发明的一个实施例中,所述衬底100为多晶半导体衬底,例如多晶Si、多晶Ge、多晶SiGe、III–V或II-VI化合物半导体或其组合。在其他实施例中,可通过多种方式生成该半导体衬底,例如淀积、外延生长等,所述衬底可以具有N型掺杂配置或P型掺杂配置。其中,该半导体衬底的厚度可为0.2-2mm,当然本发明不限于此。所述衬底包括第一表面301和第二表面302,所述第一表面301和第二表面302相对。特别地,所述衬底可以包括一个或多个层,例如,所述衬底可以包括半导体层300和在所述半导体层的上方和下方形成的材料层307、308,如图7所示。所述材料层也可以包括一个或多个层,可以根据需要配置每个层所使用的材料,例如,可以包括用于刻蚀停止的绝缘层、用于导电的导电层等等。所述材料层可以是由与所述半导体层相同或不同的材料形成,包括但不限于绝缘材料、金属、半导体材料或上述材料的组合。这些都可以根据实际应用过程中的需要进行配置,本发明不做限制。In step S201 , as shown in FIG. 6 , a substrate 100 is provided. In one embodiment of the present invention, the substrate 100 is a polycrystalline semiconductor substrate, such as polycrystalline Si, polycrystalline Ge, polycrystalline SiGe, III-V or II-VI compound semiconductors or combinations thereof. In other embodiments, the semiconductor substrate can be produced in various ways, such as deposition, epitaxial growth, etc., and the substrate can have an N-type doping configuration or a P-type doping configuration. Wherein, the thickness of the semiconductor substrate may be 0.2-2mm, of course, the present invention is not limited thereto. The substrate includes a first surface 301 and a second surface 302, and the first surface 301 and the second surface 302 are opposite to each other. In particular, the substrate may include one or more layers, for example, the substrate may include a semiconductor layer 300 and material layers 307 , 308 formed above and below the semiconductor layer, as shown in FIG. 7 . The material layer may also include one or more layers, and the material used for each layer may be configured as required, for example, may include an insulating layer for etching stop, a conductive layer for conduction, and the like. The material layer may be formed of the same or different material as the semiconductor layer, including but not limited to insulating material, metal, semiconductor material or a combination of the above materials. All of these can be configured according to the needs in the actual application process, which is not limited in the present invention.

在步骤S202,从所述第一表面301刻蚀衬底100形成至少两个第一沟槽305,以及从所述第二表面302刻蚀衬底100形成至少一个第二沟槽306,其中每个所述第二沟槽306位于相邻的两个所述第一沟槽305之间,且至少在所述第一沟槽305的内壁形成绒面,参考图19、图21。In step S202, etching the substrate 100 from the first surface 301 to form at least two first trenches 305, and etching the substrate 100 from the second surface 302 to form at least one second trench 306, wherein each Each of the second grooves 306 is located between two adjacent first grooves 305, and at least the inner wall of the first groove 305 forms a suede surface, as shown in FIG. 19 and FIG. 21 .

在本发明的一个实施例中,从所述第一表面301和第二表面302分别刻蚀衬底形成沟槽305、306,且只在第一沟槽305内壁形成绒面,如图16、17所示。具体来说,首先,对所述衬底100的第一表面301进行构图:在所述衬底100的第一表面301上形成具有预定间隔配置的多个沟槽的光致抗蚀剂层309;刻蚀所述衬底100,以去除所述第一表面301的多个沟槽处的材料层307;移除所述光致抗蚀剂层309,从而在第一表面上形成了具有多个沟槽的材料层307,实现对第一表面301的构图。而后,对衬底100构图,以第一表面上的材料层307为硬掩膜,从第一表面301刻蚀所述衬底100,以形成至少两个第一沟槽305,如图16所示,可以选择各向异性刻蚀方法来对所述衬底进行刻蚀,例如RIE(反应离子刻蚀)的方法。而后,湿法腐蚀所述器件,例如采用氢氧化钾(KOH)或四甲基氢氧化铵(TMAH)等溶剂进行刻蚀,刻蚀剂将会选择性停止在衬底的{111}晶面上,从而在所述第一沟槽305的内壁形成了不平整的绒面303表面,如图17所示。而后,可以对所述衬底100的第二表面302进行构图:在所述第二表面302上形成具有预定间隔配置的多个沟槽的光致抗蚀剂层310;刻蚀所述衬底100,以去除所述第二表面302的多个沟槽处的材料层308;移除所述光致抗蚀剂层,从而在第二表面上形成了具有多个沟槽的材料层308,实现对第二表面302的构图,如图18所示。而后对所述衬底进行构图,以第二表面上的材料层308为硬掩膜,从第二表面302刻蚀所述衬底100,以形成至少一个第二沟槽306,其中每个所述第二沟槽306位于相邻的两个所述第一沟槽305之间,如图19所示,可以选择各向异性刻蚀方法来对所述衬底进行刻蚀,例如RIE(反应离子刻蚀)的方法。In one embodiment of the present invention, the substrate is respectively etched from the first surface 301 and the second surface 302 to form grooves 305, 306, and a textured surface is only formed on the inner wall of the first groove 305, as shown in Fig. 16, 17. Specifically, first, the first surface 301 of the substrate 100 is patterned: on the first surface 301 of the substrate 100, a photoresist layer 309 having a plurality of grooves arranged at predetermined intervals is formed ; etch the substrate 100 to remove the material layer 307 at the plurality of trenches of the first surface 301; remove the photoresist layer 309, thereby forming a multi- The first surface 301 is patterned by a layer of material 307 with two grooves. Then, the substrate 100 is patterned, and the substrate 100 is etched from the first surface 301 with the material layer 307 on the first surface as a hard mask to form at least two first grooves 305, as shown in FIG. 16 As shown, an anisotropic etching method may be selected to etch the substrate, such as a RIE (Reactive Ion Etching) method. Then, the device is wet etched, for example, using a solvent such as potassium hydroxide (KOH) or tetramethylammonium hydroxide (TMAH), and the etchant will selectively stop at the {111} crystal plane of the substrate. , so that an uneven suede 303 surface is formed on the inner wall of the first groove 305, as shown in FIG. 17 . Then, the second surface 302 of the substrate 100 can be patterned: a photoresist layer 310 having a plurality of grooves arranged at predetermined intervals is formed on the second surface 302; the substrate is etched 100, to remove the material layer 308 at the multiple grooves of the second surface 302; remove the photoresist layer, thereby forming the material layer 308 with multiple grooves on the second surface, The patterning of the second surface 302 is realized, as shown in FIG. 18 . Then the substrate is patterned, using the material layer 308 on the second surface as a hard mask, etching the substrate 100 from the second surface 302 to form at least one second trench 306, wherein each of the The second trench 306 is located between two adjacent first trenches 305, as shown in FIG. 19, an anisotropic etching method can be selected to etch the substrate, such as RIE (reaction ion etching) method.

在本发明的另一个实施例中,从所述第一表面301和第二表面305分别刻蚀衬底形成沟槽305、306,并在第一305和第二沟槽306内壁形成绒面,如图20所示。具体来说,对所述衬底100的第一表面301和第二表面302进行构图:在所述衬底100的第一表面301上形成具有预定间隔配置的多个沟槽的光致抗蚀剂层309;刻蚀所述衬底100,以去除所述第一表面301的多个沟槽处的材料层307;移除所述光致抗蚀剂层309;而后在所述第二表面302上形成具有预定间隔配置的多个沟槽的光致抗蚀剂层310;刻蚀所述衬底100,以去除所述第二表面302的多个沟槽处的材料层308;移除所述光致抗蚀剂层,从而对所述衬底进行构图,从而分别在第一301和第二表面302上形成了具有多个沟槽的材料层307、308。而后以材料层307、308为硬掩膜,从所述衬底100的第一表面301刻蚀至少两个第一沟槽305,以及从所述衬底100的第二表面302刻蚀至少一个第二沟槽306,其中每个所述第二沟槽306位于相邻的两个所述第一沟槽305之间,如图20所示,可以选择各向异性刻蚀方法来对所述衬底进行刻蚀,例如RIE(反应离子刻蚀)的方法。而后,湿法腐蚀所述器件,例如采用氢氧化钾(KOH)或四甲基氢氧化铵(TMAH)等溶剂进行刻蚀,刻蚀剂将会选择性停止在衬底的{111}晶面上,从而在所述第一沟槽305的内壁形成了不平整的绒面303表面,以及在所述第二沟槽306的内壁形成了不平整的绒面304表面,如图21所示。In another embodiment of the present invention, the substrate is respectively etched from the first surface 301 and the second surface 305 to form grooves 305 and 306, and textured surfaces are formed on the inner walls of the first 305 and the second groove 306, As shown in Figure 20. Specifically, the first surface 301 and the second surface 302 of the substrate 100 are patterned: on the first surface 301 of the substrate 100, a photoresist with a plurality of grooves arranged at predetermined intervals is formed Resist layer 309; etch the substrate 100 to remove the material layer 307 at the plurality of grooves on the first surface 301; remove the photoresist layer 309; and then on the second surface Form 302 a photoresist layer 310 with a plurality of grooves arranged at predetermined intervals; etch the substrate 100 to remove the material layer 308 at the plurality of grooves on the second surface 302; remove The photoresist layer, thereby patterning the substrate, forms material layers 307, 308 with a plurality of grooves on the first 301 and second surface 302, respectively. Then, using the material layers 307, 308 as hard masks, at least two first grooves 305 are etched from the first surface 301 of the substrate 100, and at least one trench is etched from the second surface 302 of the substrate 100. The second trenches 306, wherein each of the second trenches 306 is located between two adjacent first trenches 305, as shown in FIG. The substrate is etched by a method such as RIE (Reactive Ion Etching). Then, the device is wet etched, for example, using a solvent such as potassium hydroxide (KOH) or tetramethylammonium hydroxide (TMAH), and the etchant will selectively stop at the {111} crystal plane of the substrate. Therefore, an uneven suede surface 303 is formed on the inner wall of the first groove 305, and an uneven suede surface 304 is formed on the inner wall of the second groove 306, as shown in FIG. 21 .

当然以上所述实施例的形成构图的步骤仅仅是示例,本领域的技术人员可以通过许多本领域所公知的方法获得本实施例所述的构图的衬底,这些均可以应用到本实施例中,而不脱离本发明的保护范围。Of course, the patterning steps of the above-mentioned embodiments are only examples, and those skilled in the art can obtain the patterned substrate described in this embodiment through many methods known in the art, and these can be applied to this embodiment , without departing from the protection scope of the present invention.

可选地,可以刻蚀全部或部分所述半导体层300,例如可以刻蚀所述衬底的第一表面301并停止在所述第二表面302的材料层308上,以及刻蚀所述衬底的第二表面302并停止在所述第一表面301的材料层309上。当然也可以只刻蚀一部分半导体层,即第一沟槽和第二沟槽的底部不接触所述材料层308、309。当所述衬底为一层时,仅可以刻蚀部分衬底。在图14中,使用实线限定的深色区域表示在所述第一表面301上形成的第一沟槽305,使用虚线限定的浅色区域表示在所述第二表面302上形成的第二沟槽306。所述第一沟槽和第二沟槽可以具有相等或者不等的间隔。Optionally, all or part of the semiconductor layer 300 can be etched, for example, the first surface 301 of the substrate can be etched and stop on the material layer 308 of the second surface 302, and the substrate can be etched. The second surface 302 of the bottom rests on the material layer 309 of the first surface 301 . Of course, only a part of the semiconductor layer may be etched, that is, the bottoms of the first trench and the second trench do not contact the material layers 308 , 309 . When the substrate is one layer, only part of the substrate can be etched. In FIG. 14 , the dark area defined by the solid line indicates the first trench 305 formed on the first surface 301, and the light area defined by the dotted line indicates the second trench 305 formed on the second surface 302. groove 306 . The first groove and the second groove may have equal or unequal intervals.

特别地,可以构图所述衬底,以使所述第一沟槽和第二沟槽为基本平行,这些均可以根据设计需要来设置。这样,每个所述第二沟槽306位于相邻的两个所述第一沟槽305之间,以将所述衬底分割成至少两个基板和至少一个基片,所述基板由第一沟槽305和第二沟槽306的侧壁所限定,所述基片连接相邻的两个所述基板,从而获得具有长城型结构的基板结构。优选地,所述第一305和第二沟槽306之一的深度311大于基板宽度(属于同一基板的、相邻两沟槽的侧壁所对应的表面之间的距离)310的2倍。In particular, the substrate can be patterned so that the first groove and the second groove are substantially parallel, and these can be set according to design requirements. In this way, each of the second grooves 306 is located between two adjacent first grooves 305, so as to divide the substrate into at least two substrates and at least one substrate, and the substrate is formed by the first Defined by the side walls of the first groove 305 and the second groove 306, the substrate connects two adjacent substrates, so as to obtain a substrate structure with a Great Wall structure. Preferably, the depth 311 of one of the first groove 305 and the second groove 306 is greater than twice the substrate width (the distance between surfaces corresponding to the sidewalls of two adjacent grooves belonging to the same substrate) 310 .

特别地,当所述多个第一沟槽305和所述多个第二沟槽306基本平行时,所述基板阵列可以是包括基本平行的多个基板。特别地,所述基板和与其连接的基片可以是基本垂直的,即所述第一沟槽和第二沟槽可以是基本矩形的形状。In particular, when the plurality of first grooves 305 and the plurality of second grooves 306 are substantially parallel, the substrate array may include a plurality of substantially parallel substrates. In particular, the substrate and the substrate connected thereto may be substantially vertical, ie the first groove and the second groove may be substantially rectangular in shape.

由此,本发明的实施例提供了一种形成基板结构的方法,所述方法能够形成长城型结构的基板结构,有效地利用衬底的厚度形成长城型结构,提高晶圆片的表面积利用率。而且,在所述基板结构的第一沟槽的内壁形成绒面,以及可选地,在第二沟槽的侧壁形成了绒面,在将所述基板结构用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。Therefore, the embodiment of the present invention provides a method for forming a substrate structure, the method can form a substrate structure with a Great Wall structure, effectively utilize the thickness of the substrate to form a Great Wall structure, and improve the surface area utilization rate of the wafer . Moreover, a textured surface is formed on the inner wall of the first groove of the substrate structure, and optionally, a textured surface is formed on the side wall of the second groove, when the substrate structure is used for the application of a solar cell substrate , the suede surface can advantageously improve the light trapping effect, thereby increasing the light entering efficiency of the solar cell.

在步骤S203,对基板结构进行后续加工。在将所述方法获得的基板结构应用于太阳能电池领域中时,进一步地,参考图22、图23,首先,可以至少在所述第一沟槽305的侧壁形成具有第二类型掺杂的第一半导体层202,而后在所述第一沟槽305侧壁的第一半导体层202上形成第一电极层204,以及在第二沟槽306的侧壁上形成和第二电极层205,所述第一电极层204由TCO材料形成,所述TCO包括:SnO2、In2O3、ZnO、ITO、CdO、Cd2SnO4、FTO、AZO或其组合,在这个示例中,所述第一电极层204为进光面。可选地,还可以至少在所述第二沟槽306的侧壁与所述第二电极205之间形成具有第一类型掺杂的第二半导体层203,所述第二电极层205也可以作为进光面,即也可以由TCO材料形成。可选择地,第二电极层205也可以不作为进光面,并由适于导电的金属材料形成。所述第一电极层204和第二电极层205的厚度分别为大约300-1000nm。第一202和第二半导体层203分别包括:多晶硅、非晶态硅或其组合,厚度分别为大约10-500nm。可选择地,进一步地,还可以在进光面(第一电极层和/或第二电极层)上形成减反射层(图中未示出),例如:氮化物材料。所述减反射层的厚度可以为大约40-160nm。从而进一步增加太阳能电池的进光效率。In step S203, subsequent processing is performed on the substrate structure. When applying the substrate structure obtained by the method to the field of solar cells, further, referring to FIG. 22 and FIG. The first semiconductor layer 202, and then the first electrode layer 204 is formed on the first semiconductor layer 202 on the sidewall of the first trench 305, and the second electrode layer 205 is formed on the sidewall of the second trench 306, The first electrode layer 204 is formed of a TCO material, and the TCO includes: SnO 2 , In 2 O 3 , ZnO, ITO, CdO, Cd 2 SnO 4 , FTO, AZO or a combination thereof. In this example, the The first electrode layer 204 is a light-incoming surface. Optionally, the second semiconductor layer 203 with the first type of doping can also be formed at least between the sidewall of the second trench 306 and the second electrode 205, and the second electrode layer 205 can also be As the light-incoming surface, it can also be formed of TCO material. Optionally, the second electrode layer 205 may not serve as a light-incoming surface, and be formed of a metal material suitable for conducting electricity. The thicknesses of the first electrode layer 204 and the second electrode layer 205 are about 300-1000 nm respectively. The first 202 and the second semiconductor layer 203 respectively include: polysilicon, amorphous silicon or a combination thereof, and have a thickness of about 10-500 nm. Optionally, further, an anti-reflection layer (not shown in the figure), such as a nitride material, may also be formed on the light incident surface (the first electrode layer and/or the second electrode layer). The anti-reflection layer may have a thickness of about 40-160 nm. Thereby, the light-introduction efficiency of the solar cell is further increased.

进一步地,可以沿第一沟槽和第二沟槽切割所述基板结构从而形成基板单元,或者当所述基片的厚度足够薄时,例如小于所述基板宽度的1/3,可以通过适当的工艺,容易地拉伸所述基板结构,从而使基板单元阵列形成在基本同一平面,从而适于下一步的处理和加工。Further, the substrate structure can be cut along the first groove and the second groove to form a substrate unit, or when the thickness of the substrate is thin enough, for example, less than 1/3 of the width of the substrate, it can be appropriately The process can easily stretch the substrate structure, so that the substrate unit arrays are formed on substantially the same plane, which is suitable for the next treatment and processing.

以上对本发明实施例利用半导体衬底形成基板结构的制造方法进行了详细的描述,所述方法能够形成长城型结构的基板结构,有效地利用衬底的厚度形成长城型结构,提高晶圆片的表面积利用率。而且,在所述基板结构的第一沟槽的内壁形成绒面,以及可选地,在第二沟槽的侧壁形成了绒面,在将所述基板结构用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。而且,在所述基板结构的第一沟槽中还形成了具有第二掺杂类型的的第一半导体层,以及可选地,在第二沟槽中形成了具有第一掺杂类型的的第二半导体层。在将所述基板结构用于太阳能电池基板的应用时,所述绒面能够有利地提高陷光效果,从而增加太阳能电池的进光效率。The method for manufacturing a substrate structure by using a semiconductor substrate in the embodiment of the present invention has been described above in detail. The method can form a substrate structure with a Great Wall structure, effectively utilize the thickness of the substrate to form a Great Wall structure, and improve the reliability of the wafer. Surface area utilization. Moreover, a textured surface is formed on the inner wall of the first groove of the substrate structure, and optionally, a textured surface is formed on the side wall of the second groove, when the substrate structure is used for the application of a solar cell substrate , the suede surface can advantageously improve the light trapping effect, thereby increasing the light entering efficiency of the solar cell. Moreover, a first semiconductor layer with a second doping type is formed in the first trench of the substrate structure, and optionally, a semiconductor layer with the first doping type is formed in the second trench. second semiconductor layer. When the substrate structure is used in the application of the solar cell substrate, the textured surface can advantageously improve the light trapping effect, thereby increasing the light entry efficiency of the solar cell.

虽然关于示例实施例及其优点已经详细说明,应当理解在不脱离本发明的精神和所附权利要求限定的保护范围的情况下,可以对这些实施例进行各种变化、替换和修改。对于其他例子,本领域的普通技术人员应当容易理解在保持本发明保护范围内的同时,工艺步骤的次序可以变化。Although the example embodiments and their advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made to these embodiments without departing from the spirit and scope of the invention as defined by the appended claims. For other examples, those of ordinary skill in the art will readily understand that the order of process steps may be varied while remaining within the scope of the present invention.

此外,本发明的应用范围不局限于说明书中描述的特定实施例的工艺、机构、制造、物质组成、手段、方法及步骤。从本发明的公开内容,作为本领域的普通技术人员将容易地理解,对于目前已存在或者以后即将开发出的工艺、机构、制造、物质组成、手段、方法或步骤,其中它们执行与本发明描述的对应实施例大体相同的功能或者获得大体相同的结果,依照本发明可以对它们进行应用。因此,本发明所附权利要求旨在将这些工艺、机构、制造、物质组成、手段、方法或步骤包含在其保护范围内。In addition, the scope of application of the present invention is not limited to the process, mechanism, manufacture, material composition, means, method and steps of the specific embodiments described in the specification. From the disclosure of the present invention, those of ordinary skill in the art will easily understand that for the processes, mechanisms, manufacturing, material compositions, means, methods or steps that currently exist or will be developed in the future, they are implemented in accordance with the present invention Corresponding embodiments described which function substantially the same or achieve substantially the same results may be applied in accordance with the present invention. Therefore, the appended claims of the present invention are intended to include these processes, mechanisms, manufacture, material compositions, means, methods or steps within their protection scope.

Claims (10)

1. the manufacture method that the formation method of utilizing substrate to carry out the base board unit of matte processing forms for matte, described method comprises:
A, provide single crystalline semiconductor substrate, described semiconductor substrate comprises first surface and second surface corresponding thereto and the 3rd surface and the 4th surface corresponding thereto;
B, by anisotropic wet, corrode on the 3rd surface and form the first matte;
C, on described the first matte, form the second matte.
2. method according to claim 1, also comprises:
D, by anisotropic wet, corrode and on the 4th surface, form the 3rd matte;
E, on described the 3rd matte, form the 4th matte.
3. method according to claim 1, wherein said semiconductor substrate comprises: single crystalline Si, monocrystalline Ge, single crystalline Si Ge.
4. method according to claim 1 and 2, wherein said the first matte, the 3rd matte are crystal orientation { 111}.
5. method according to claim 1 and 2, wherein said step C comprises:
A, on described the first matte, precipitate polysilicon, amorphous silicon or its combination;
B, by etching, form described the second matte;
Wherein step e comprises:
A, on described the 3rd matte, precipitate polysilicon, amorphous silicon or its combination;
B, by etching, form described the 4th matte.
6. a base board unit that utilizes substrate to carry out matte processing: comprising:
The single crystalline semiconductor substrate with the first doping type, described semiconductor substrate comprises first surface and second surface corresponding thereto and the 3rd surface and the 4th surface corresponding thereto;
Be formed at the 3rd lip-deep the first matte of described semiconductor substrate;
Be formed at the second matte on described the first matte.
7. base board unit according to claim 6, also comprises
Form the 4th lip-deep the 3rd matte with described semiconductor substrate;
Be formed at the 4th matte on described the 3rd matte.
8. base board unit according to claim 6, wherein said semiconductor substrate comprises: single crystalline Si, monocrystalline Ge, single crystalline Si Ge.
9. according to the base board unit described in claim 6 or 7, wherein said the first matte, the 3rd matte are crystal orientation { 111}.
10. according to the base board unit described in claim 6 or 7, wherein said the second matte, the 4th matte comprise polysilicon, amorphous silicon or its combination.
CN201310232126.7A 2009-08-17 2010-08-17 Base board unit subjected to textured surface processing by using substrate, and forming method thereof Pending CN103515478A (en)

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