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CN103510034A - Method and apparatus for processing multilayer-metal-based composite material by multiple electric arc spraying - Google Patents

Method and apparatus for processing multilayer-metal-based composite material by multiple electric arc spraying Download PDF

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CN103510034A
CN103510034A CN201310398427.7A CN201310398427A CN103510034A CN 103510034 A CN103510034 A CN 103510034A CN 201310398427 A CN201310398427 A CN 201310398427A CN 103510034 A CN103510034 A CN 103510034A
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processing
spraying
metal matrix
layer metal
matrix composites
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CN103510034B (en
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于金库
乔琪
王跃华
祝文沙
康少明
刘宾
褚子敬
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Yanshan University
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Abstract

一种多元电弧喷涂加工多层金属基复合材料的方法及装置,其方法主要是:在环形基体转动的过程中,控制各喷涂加工单元按设定的次序交替向环形基体的表面喷涂金属或合金,在环形基体表面至少形成两层组分相同或不同的喷涂层,形成所需层数的多层金属基复合材料;其装置主要是:在环形基体周围设多个喷涂加工单元,每个喷涂加工单元分别与电弧喷涂电源、储气罐、空气压缩机及金属丝材传输机构相连。本发明可以很方便地制备两种或两种以上子层交替的多层金属基复合材料,这些多层金属基复合材料的子层可以是纯金属、合金等,晶体结构也可以多种多样,具有设备简单、节约成本、高效快捷、容易控制、加工过程足够稳定等优点。

Figure 201310398427

A method and device for processing multi-layer metal matrix composite materials by multi-element arc spraying, the method mainly includes: during the rotation process of the annular base, control each spraying processing unit to alternately spray metal or alloy on the surface of the annular base according to the set order , at least two layers of sprayed coatings with the same or different components are formed on the surface of the annular base to form a multi-layer metal matrix composite material with the required number of layers; The processing unit is respectively connected with the electric arc spraying power supply, the gas storage tank, the air compressor and the metal wire transmission mechanism. The present invention can easily prepare two or more sub-layers alternate multi-layer metal matrix composites, the sub-layers of these multi-layer metal matrix composites can be pure metals, alloys, etc., and the crystal structure can also be various, It has the advantages of simple equipment, cost saving, high efficiency and quickness, easy control, and stable enough processing process.

Figure 201310398427

Description

Method and the device of polynary electric arc spraying processing multiple layer metal based composites
Technical field the present invention relates to a kind of EDM Technology, especially a kind of method and device of electric arc spraying processing multiple layer metal based composites.
Background technology multiple layer metal based composites refers to that the component or the structure that by one or more material alternating deposits, are formed replace the artificial fine structure material changing, and each layer of metal or alloy thickness can reach nano level or grade.Multiple layer metal based composites material has integral material and the unapproachable various properties of any one-component material, can meet various special applications demands, in recent years the research of this material is aroused great concern, become the focus of domestic and international research and development.At present, prepare multiple layer metal based composites and mainly contain combined techniques, lamination hot rolling method, diffusion pressure connection, welding method, built-up welding hot rolling method etc. between solid-liquid phase combined techniques, solid phase.But these method complex technical process, preparation time is long, and cost is higher.
Summary of the invention the object of the present invention is to provide a kind ofly can carry out accurately controlling to the component of multiple layer metal based composites and structure, can reduce costs, method and the device that simple and quick, multiple layer metal based composites is processed in polynary electric arc spraying that effectively prepare high-quality multiple layer metal based composites.
One, working method of the present invention comprises the following steps:
1, make to be sprayed annular matrix and rotate with the speed of setting, the material of the velocity of rotation of this setting and the diameter of annular matrix, metallic coating and thickness and spray process cell parameters are relevant;
2, be located at annular matrix a plurality of spray process unit around, each is independent separately;
In the process of 3, rotating at annular matrix, control each spray process unit and replace the surface spraying metal or alloy to annular matrix by the order of setting, it is terminal that annular matrix be take a machining cell, in the process rotating a circle, layer of metal or alloy sublayer are just adhered in its surface, ring-type matrix has a plurality of machining cells around, so just with the same composition corresponding with a plurality of machining cells and the sublayer of non-same composition, these sublayers are superimposed and form multiple layer metal based composites on annular matrix.The thickness of sublayer be not less than described in 0.2mm by alternately spraying of the order of setting, it can be: control in the process that a plurality of spray process unit rotates a circle at annular matrix, replace continuously one by one spraying, form the multiple layer metal based composites with the corresponding different components of machining cell number and weave construction; Also can be: by a spray process unit, form after the given sublayer thickness of a certain component, then carry out the spraying of next component by another spray process units alternately, can realize thus the permutation and combination of any component, sublayer thickness.The alternately spraying of the above-mentioned order by setting, it can be by controlling power switch or annular matrix rotating speed Artificial Control, but preferably by computer control.
While 4, being provided with abrasive article in working chamber, abrasive article is located in a certain diametric(al) of matrix, and abrasive article is symmetrically existing about matrix medullary ray, and distance is controlled.Control abrasive article and contact with annular matrix surface, with in real time, effectively remove the defects such as buildup, burr of annular matrix sprayed surface, improve sprayed coating quality, obtain the even continuous multiple layer metal based composites in sublayer.
Two, the structure of apparatus of the present invention is as follows:
The present invention mainly includes annular matrix, matrix is an annular solid (being workpiece to be processed) of being made by carbon steel, stainless steel or aluminium alloy etc., it is connected with one end of web member, and the other end of this web member is connected with transmission rig, this annular solid and web member looping matrix.Above-mentioned annular solid outer ring surface is placed in treatment chamber middle part, preferably annular matrix and treatment chamber coaxial line.This treatment chamber has one by the fixing cylinder of web member, and the cylinder two ends that this axis is level are provided with perpendicular two connected annular end plates, and this two end plates center-hole diameter is corresponding with annular matrix external diameter and can overlap thereon.In the cylinder for the treatment of chamber, can be provided with as required several radially dividing plates, these dividing plate one end are fixed on treatment chamber cylinder, and dual-side is separately fixed in two end plates, and the other end and annular matrix are adjacent, preferably between dividing plate and annular matrix, are provided with sealing member.Aforementioned barriers is divided into separately independently a plurality of working chambers by treatment chamber.On treatment chamber cylindrical wall, be provided with through hole, on it, be vertically fixed with arc spraying rifle, this arc spraying rifle is positioned at the outlet of working chamber and waits to be coated with surperficial relative with annular matrix, the part that this arc spraying rifle is positioned at outside working chamber forms spray process unit with anode and negative electrode, each spray process unit is all connected with an arc pistol power supply separately, each machining cell is all connected with gas-holder and the air compressor supporting with it separately by airway again, each machining cell is also connected with wire transport sector respectively, by reeling machine and wire drive feeder, be transported to spray gun, different metal or alloy are stored in respectively in different wire material transport sectors.
Separately in the above-mentioned working chamber that arc pistol is not installed, be provided with hard particles or friction member, wherein being deposited in hard particles in working chamber fills and is adjacent to annular matrix surface, be preferably in above-mentioned working chamber bottom and set up the electromagnetic driver that impels particle generation high-frequency vibration, to more effectively grind sprayed coating surface; Friction member is adjacent to annular matrix surface, friction member adopts stepper-motor to add spring assembly, step motor control abrasive article is to the distance of central axis, spring guarantees that abrasive article contacts with permanent tension force with revolution matrix, at above-mentioned working chamber, set up the electromagnetic driver that makes friction member and sprayed surface keep permanent tension force and can shake up and down along revolution matrix axis direction, make friction member and sprayed surface keep permanent tension force, to sprayed coating surface is ground in real time when annular matrix rotates, the defects such as the buildup of removal annular matrix sprayed surface, burr.
Described drive unit is for impelling particle generation high-frequency vibration electromagnetic type device; Or make friction member and spraying
The electromagnetic type device that surface keeps permanent tension force and can shake up and down along revolution matrix axis direction.
Principle of work of the present invention is summarized as follows: by computer control annular matrix, rotated, continuously through machining cell, the impact jet flow of each spray process unit can replace spraying to annular matrix surface, also can be by electrical arc spraying power source switching electricity, form a kind of component and spray after given thickness, then carry out the spraying of next component; Can adopt hard particles or friction member to grind in real time sprayed coating surface, effectively remove the defect such as buildup, burr on sprayed coating surface, improve multilayer materials quality.
The present invention compared with prior art tool has the following advantages:
1, the present invention adopts arc spraying technology, and metal or alloy molten drop is sprayed to annular matrix with high-speed jet form, obtains the multilayer materials of dense structure, grain refining.
2, the present invention is by using annular matrix, and in rotation process, the impact jet flow of each machining cell goes Uniform Scanning to cross matrix surface, obtains the even and smooth multiple layer metal based composites in sublayer.Meanwhile, can phase mutual interference between each spray process unit yet.
3, by changing the component of machining cell number, spraying wire and parameter etc., can prepare the multiple layer metal based composites that two or more sublayer replaces, its component and structure also can be ever-changing, and by the alternately spraying of computer control machining cell, can realize the permutation and combination of anyon layer component, sublayer thickness, spraying process is easy to realize computer monitoring simultaneously.
4, can utilize friction member to grind in real time sprayed coating surface, not only can improve sprayed coating quality, and can obtain the multiple layer metal based composites of good modulated structure.When using solid particles to grind, all right extraneous vibration source, impels solid particles high-frequency vibration, makes grinding more evenly, effectively.
5, adopt working method of the present invention and device, can realize easily the component of multiple layer metal based composites, modulation wavelength, isoparametric accurate control of microtexture, artificially design and prepare the multiple layer metal based composites of desired characteristic, prepare the multiple layer metal based composites that two or more sublayer replaces, the sublayer of these multilayer materials can be pure metal, alloy etc., crystalline structure also can be varied, have that equipment is simple, cost-saving, efficient quick, easily control, the advantage such as the course of processing enough is stablized.
Accompanying drawing explanation
Fig. 1 is that the master of apparatus of the present invention looks simplified schematic diagram.
Fig. 2 is the section simplified schematic diagram for the treatment of chamber in Fig. 1.
Fig. 3 is that the master that treatment chamber that the present invention is provided with hard particles removes end cap looks simplified schematic diagram.
Fig. 4 is that the master that treatment chamber that the present invention is provided with friction member removes end cap looks simplified schematic diagram.
Fig. 5 is that the present invention is that the master that the working chamber of 3 spray process unit removes end cap looks simplified schematic diagram.
Fig. 6 is that the present invention is that the master that the working chamber of 4 spray process unit removes end cap looks simplified schematic diagram.
In figure: 1, air compressor; 2, gas-holder; 3, airway; 4, electrical arc spraying power source; 5, first metal wire material transport sector (spray process unit); 6, first arc pistol; 7, revolution matrix; 8, second arc pistol; 9, second metal wire material transport sector (spray process unit); 10, electrical arc spraying power source; 11, airway; 12, gas-holder; 13, air compressor; 14, dividing plate; 15, hard particles; 16, friction member; 17, constant tension device; 18, stepper-motor; 19, the third arc pistol; 20, fourth arc pistol.
Embodiment
Below in conjunction with drawings and Examples, the present invention is further illustrated.
In the treatment chamber section simplified schematic diagram of the polynary electric arc spraying processing multiple layer metal based composites device shown in Fig. 2, the annular solid of being made by carbon steel is connected with one end of web member, the other end of this web member is connected with transmission rig, this annular solid and web member looping matrix.Above-mentioned annular solid outer ring surface is placed in treatment chamber middle part and both coaxial lines.This treatment chamber has one by the fixing cylinder of web member, and the cylinder two ends that this axis is level are provided with perpendicular two connected annular end plates, and this two end plates center-hole diameter is corresponding with annular matrix external diameter and can overlap thereon.In the cylinder for the treatment of chamber, be provided with 4 radially dividing plates, these dividing plate one end are fixed on treatment chamber cylinder, and dual-side is separately fixed in two end plates, and the other end and annular matrix are adjacent, between dividing plate and annular matrix, are provided with sealing member.Aforementioned barriers is divided into separately independently a plurality of working chambers by treatment chamber.On treatment chamber cylindrical wall, be provided with through hole, on it, be vertically fixed with arc spraying rifle, this arc spraying rifle is positioned at the outlet of working chamber and treats that with annular matrix painting surface is relative, and this arc spraying rifle is positioned at part and anode and the negative electrode composition spray process unit outside working chamber.Master in the apparatus of the present invention shown in Fig. 1 looks in simplified schematic diagram,
Each spray process unit is all connected with an arc pistol power supply separately, each machining cell is all connected with gas-holder and the air compressor supporting with it separately by airway again, each machining cell is also connected with wire transport sector respectively, and different metal or alloy are stored in respectively in different wire material transport sectors.The master that the working chamber that is provided with hard particles in the present invention shown in Fig. 3 removes end cap looks in simplified schematic diagram, in the above-mentioned working chamber that arc pistol is not installed, be provided with hard particles (as corundum, silicon carbide, diamond etc.), be wherein deposited in hard particles in working chamber and fill and be adjacent to annular matrix surface.The master that the working chamber that is provided with friction member in the present invention shown in Fig. 4 removes end cap looks in simplified schematic diagram, in the above-mentioned working chamber that arc pistol is not installed, is provided with friction member (as garnet, flint, oilstone etc.).
The master that the treatment chamber that is 3 spray process unit in the present invention shown in Fig. 5 removes end cap looks in simplified schematic diagram, in the cylinder for the treatment of chamber, be provided with 3 radially dividing plates, aforementioned barriers is divided into separately independently 3 working chambers by treatment chamber, on the cylindrical wall of each working chamber, be equipped with through hole, on each through hole, be all vertically fixed with arc spraying rifle.The master that the treatment chamber that is 4 spray process unit in the present invention shown in Fig. 6 removes end cap looks in simplified schematic diagram, in the cylinder for the treatment of chamber, be provided with 4 radially dividing plates, aforementioned barriers is divided into separately independently 4 working chambers by treatment chamber, on the cylindrical wall of each working chamber, be equipped with through hole, on each through hole, be all vertically fixed with arc spraying rifle.
Embodiment 1
As shown in Figure 1, be located at annular matrix 2 spray process unit around, each is independent separately, and first spray process unit is connected with A wire and B wire transport sector respectively, and second spray process unit is connected with C wire and D wire transport sector respectively.First open the electric motor being connected with annular revolution matrix, adjust transmission rig, make to be sprayed annular matrix and rotate with the speed of 0.1m/s.Open again the electrical arc spraying power source being connected with first spray process unit, in the process of rotating at annular matrix, control each spray process unit and replace the surface spraying metal or alloy to annular matrix by the order of setting, be that annular matrix be take first machining cell as terminal, in the process rotating a circle, it is 0.5mm metal A sublayer that a layer thickness is just adhered on its surface, closes the electrical arc spraying power source being connected with first spray process unit.The electrical arc spraying power source that unlatching is connected with second spray process unit.Annular matrix be take second machining cell again as terminal, and in the process rotating a circle, in metal A sub-layer surface, just adhering to a layer thickness is 0.5mm metal C sublayer; Close the electrical arc spraying power source being connected with second spray process unit.The electrical arc spraying power source that unlatching is connected with first spray process unit, annular matrix be take first machining cell again as terminal, in the process rotating a circle, in metal C sub-layer surface, just adhering to a layer thickness is 0.5mm metal B sublayer, closes the electrical arc spraying power source being connected with first spray process unit.The electrical arc spraying power source that unlatching is connected with second spray process unit.Annular matrix be take second machining cell again as terminal, and in the process rotating a circle, in metal B sub-layer surface, just adhering to a layer thickness is 0.5mm metal D sublayer.These sublayers are superimposed and form 4 layers of metal-base composites.
Embodiment 2
As shown in Figure 1, be located at annular matrix 2 spray process unit around, each is independent separately, and first spray process unit is connected with alloy A silk transport sector respectively, and second spray process unit is connected with metal C silk transport sector respectively.First open the electric motor being connected with annular revolution matrix, adjust transmission rig, make to be sprayed annular matrix and rotate with the speed of 0.2m/s.By computer control the first and second spray process unit, replace continuously one by one spraying, open the electrical arc spraying power source being connected with first spray process unit, just on annular matrix, adhere to one deck alloy A sublayer, when annular matrix rotates 1/2 week, the electrical arc spraying power source that unlatching is connected with second spray process unit, just at annular matrix, with on alloy A sublayer, adhere to layer of metal C sublayer, annular matrix be take respectively the first and second machining cells as terminal, in the process rotating a circle, just form the multiple layer metal based composites with the corresponding different components of machining cell number and weave construction.

Claims (9)

1.一种多元电弧喷涂加工多层金属基复合材料的方法,其特征是:它包括以下步骤:  1. A method for processing multilayer metal matrix composites by multi-element arc spraying is characterized in that: it may further comprise the steps: 1)使被喷涂环形基体以设定的速度转动;  1) Make the sprayed annular substrate rotate at a set speed; 2)设在环形基体周围的多个喷涂加工单元,每个各自独立;  2) Multiple spraying processing units arranged around the annular substrate, each independently; 3)在环形基体转动的过程中,控制各喷涂加工单元按设定的次序交替向环形基体的表面喷涂金属或合金,在环形基体表面至少形成两层组分相同或不同的喷涂层,形成所需层数的多层金属基复合材料。  3) During the rotation of the annular substrate, control the spraying processing units to alternately spray metal or alloy on the surface of the annular substrate according to the set order, and at least two layers of spray coatings with the same or different components are formed on the surface of the annular substrate to form the desired Multilayer metal matrix composites that require a number of layers. the 2.根据权利要求1所述的多元电弧喷涂加工多层金属基复合材料的方法,其特征是:所述的按设定的次序交替喷涂,  2. The method for processing multi-layer metal matrix composites by multi-element arc spraying according to claim 1, characterized in that: the alternate spraying according to the set order, 或是:控制多个喷涂加工单元在环形基体旋转一周的过程中,一个接一个地连续进行交替喷涂,形成与加工单元数相应的不同组分和组织结构的多层金属基复合材料;  Or: control multiple spraying processing units to alternately spray one after another during the rotation of the annular substrate to form multi-layer metal matrix composites with different components and organizational structures corresponding to the number of processing units; 或是:由一个喷涂加工单元,形成某一组分给定的子层厚度后,再由另一个喷涂加工单元交替进行下一组分的喷涂,由此可以实现任意组分、子层厚度的排列组合。  Or: After forming a given sub-layer thickness of a certain component by one spraying processing unit, another spraying processing unit alternately sprays the next component, so that any component and sub-layer thickness can be realized. Permutations. the 3.根据权利要求2所述的多元电弧喷涂加工多层金属基复合材料的方法,其特征是:按设定的次序交替喷涂是采用人工控制电源开关,或人工控制环形基体转速,或计算机控制。  3. The method for processing multi-layer metal matrix composites by multi-element arc spraying according to claim 2, characterized in that: the alternate spraying according to the set order is by manually controlling the power switch, or manually controlling the rotational speed of the annular substrate, or computer-controlled . the 4.根据权利要求2所述的多元电弧喷涂加工多层金属基复合材料的方法,其特征是:子层的厚度不小于0.2mm。 4. The method for processing multi-layer metal matrix composites by multi-element arc spraying according to claim 2, characterized in that: the thickness of the sub-layers is not less than 0.2 mm. 5.根据权利要求1所述的多元电弧喷涂加工多层金属基复合材料的方法,其特征是:在所述的喷涂加工单元之间设置有放置硬质粒子或摩擦件 的工作腔,控制工作腔中的硬质粒子或摩擦件与环形基体表面相接处。  5. The method for processing multi-layer metal matrix composites by multi-element arc spraying according to claim 1, characterized in that: a working chamber for placing hard particles or friction parts is arranged between the described spraying processing units, and the working chamber is controlled The hard particles or friction parts in the cavity meet the surface of the annular base. the 6.一种多元电弧喷涂加工多层金属基复合材料的装置,其特征是:环形体外环面置于处理室中部,环形基体与处理室同轴线,该处理室有一通过连接件固定的圆筒,该轴线呈水平的圆筒两端设有与其垂直相连的两圆环形端板,该两端板中心孔直径与环形基体外径相对应并可套于其上,处理室的圆筒内可设有径向隔板,这些隔板一端固定在处理室圆筒上,两侧边分别固定在两端板上,另一端与环形基体相邻,在处理室圆筒壁上设有通孔,其上垂直固定有电弧喷射枪,该电弧喷射枪位于工作腔内的出口与环形基体待涂表面相对,该电弧喷射枪位于工作腔外的部分与阳极和阴极组成喷涂加工单元,每个喷涂加工单元均单独与一个电弧喷枪电源相连,每个加工单元又均通过导气管单独与储气罐及与其配套的空气压缩机相连,每个加工单元还分别与金属丝传输机构相连,不同金属或合金分别储存在不同的金属丝材料传输机构中。  6. A device for processing multilayer metal matrix composites by multi-element arc spraying, characterized in that: the outer ring surface of the ring is placed in the middle of the processing chamber, the ring base is coaxial with the processing chamber, and the processing chamber has a Cylinder, the two ends of the cylinder with a horizontal axis are provided with two circular end plates vertically connected to it, the diameter of the center hole of the two end plates corresponds to the outer diameter of the annular base and can be sleeved on it, the circle of the processing chamber The cylinder can be provided with radial partitions, one end of these partitions is fixed on the cylinder of the processing chamber, the two sides are respectively fixed on the two end plates, the other end is adjacent to the annular base, and there is a A through hole, on which an arc spray gun is vertically fixed, the outlet of the arc spray gun located in the working chamber is opposite to the surface to be coated of the annular substrate, and the part of the arc spray gun located outside the working chamber forms a spraying processing unit with the anode and cathode, each Each spray processing unit is individually connected to an arc spray gun power supply, and each processing unit is individually connected to the air storage tank and its matching air compressor through the air guide tube, and each processing unit is also connected to the wire transmission mechanism, different Metals or alloys are stored separately in separate wire material transport mechanisms. the 7.根据权利要求6所述的多元电弧喷涂加工多层金属基复合材料的装置,其特征是:在未安装电弧喷枪的工作腔中设有硬质粒子或摩擦件,并且堆放在工作腔中的硬质粒子装满贴紧环形基体表面,摩擦件贴紧环形基体表面。  7. The device for processing multi-layer metal matrix composites by multi-element arc spraying according to claim 6, characterized in that: hard particles or friction parts are arranged in the working chamber where the arc spray gun is not installed, and are stacked in the working chamber The hard particles are filled and adhere to the surface of the annular substrate, and the friction parts are closely attached to the surface of the annular substrate. the 8.根据权利要求7所述的多元电弧喷涂加工多层金属基复合材料的装置,其特征是:在上述工作腔底部增设促使粒子发生高频振动的电磁式驱动装置。  8. The device for processing multi-layer metal matrix composites by multi-element arc spraying according to claim 7, characterized in that: an electromagnetic driving device to induce high-frequency vibration of particles is added at the bottom of the working chamber. the 9.根据权利要求7所述的多元电弧喷涂加工多层金属基复合材料的装置,其特征是:在上述工作腔增设使摩擦件与喷涂表面保持恒张力并可以 沿回转基体某一直径方向上下移动的电磁式驱动装置。  9. The multi-element arc spraying device for processing multi-layer metal matrix composites according to claim 7, characterized in that: the above-mentioned working chamber is additionally set to keep the friction member and the sprayed surface at constant tension and can move up and down along a certain diameter direction of the rotating base Electromagnetic drive for movement. the
CN201310398427.7A 2013-09-04 2013-09-04 The method of polynary electric arc spraying processing multiple layer metal based composites and device Expired - Fee Related CN103510034B (en)

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WO2018014592A1 (en) * 2016-07-20 2018-01-25 中原内配集团股份有限公司 Thermal spraying apparatus and thermal spraying system, and thermal spraying technique thereof
CN108149243A (en) * 2017-12-22 2018-06-12 中国人民解放军陆军装甲兵学院 A kind of bundling electrode electric spark deposition reparation and reproducing method and device
CN108441861A (en) * 2018-01-15 2018-08-24 中国人民解放军陆军装甲兵学院 A kind of method and device of bundling electrode electric spark deposition machining multilayer film
CN112170037A (en) * 2020-08-11 2021-01-05 江苏大学 A kind of double spray gun alternate spraying preparation device and method of laminated composite material
CN114134448A (en) * 2021-11-29 2022-03-04 浙江康盛热交换器有限公司 Rotary zinc spraying device for refrigeration aluminum pipe

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CN108149243B (en) * 2017-12-22 2021-01-12 中国人民解放军陆军装甲兵学院 Method and device for repairing and remanufacturing cluster electrode through electric spark deposition
CN108441861A (en) * 2018-01-15 2018-08-24 中国人民解放军陆军装甲兵学院 A kind of method and device of bundling electrode electric spark deposition machining multilayer film
CN108441861B (en) * 2018-01-15 2021-01-12 中国人民解放军陆军装甲兵学院 Method and device for processing multilayer film by cluster electrode electric spark deposition
CN112170037A (en) * 2020-08-11 2021-01-05 江苏大学 A kind of double spray gun alternate spraying preparation device and method of laminated composite material
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CN114134448B (en) * 2021-11-29 2023-12-12 浙江康盛热交换器有限公司 Rotary zinc spraying device for refrigeration aluminum pipe

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