CN103509292B - A kind of resistant to elevated temperatures polyvinyl chloride cable material - Google Patents
A kind of resistant to elevated temperatures polyvinyl chloride cable material Download PDFInfo
- Publication number
- CN103509292B CN103509292B CN201310473860.2A CN201310473860A CN103509292B CN 103509292 B CN103509292 B CN 103509292B CN 201310473860 A CN201310473860 A CN 201310473860A CN 103509292 B CN103509292 B CN 103509292B
- Authority
- CN
- China
- Prior art keywords
- polyvinyl chloride
- sepiolite
- resistant
- elevated temperatures
- weight part
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 33
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 21
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004113 Sepiolite Substances 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 16
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 230000032683 aging Effects 0.000 claims abstract description 10
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 claims abstract description 6
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims abstract description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 6
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 Lauryl Alcohol ester Chemical class 0.000 claims abstract description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 6
- 239000008116 calcium stearate Substances 0.000 claims abstract description 6
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 6
- 229960001708 magnesium carbonate Drugs 0.000 claims abstract description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000014380 magnesium carbonate Nutrition 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 6
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 6
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 claims abstract description 6
- 239000010445 mica Substances 0.000 claims abstract description 6
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims abstract description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010451 perlite Substances 0.000 claims abstract description 6
- 235000019362 perlite Nutrition 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010455 vermiculite Substances 0.000 claims abstract description 6
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 6
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 235000005747 Carum carvi Nutrition 0.000 claims description 5
- 240000000467 Carum carvi Species 0.000 claims description 5
- 229940037003 alum Drugs 0.000 claims description 5
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 239000011021 lapis lazuli Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 239000000341 volatile oil Substances 0.000 claims description 5
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 5
- 102100030988 Angiotensin-converting enzyme Human genes 0.000 claims description 3
- 108010083141 dipeptidyl carboxypeptidase Proteins 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 abstract description 6
- 235000019504 cigarettes Nutrition 0.000 abstract description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 241000143437 Aciculosporium take Species 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 206010023126 Jaundice Diseases 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention provides a kind of resistant to elevated temperatures polyvinyl chloride cable material, prepared by the component raw material of following weight part and obtain: polyvinyl chloride (PVC) RESINS 50-60, trioctyl trimellitate 10-15, trioctyl phosphate 10-12, acetic acid 1-2, tribasic lead sulfate 0.2-0.3, dibasic lead stearate 0.2-0.3, dihydroxyphenyl propane? 1-2, two Lauryl Alcohol ester 1-2, sepiolite 8-10, magnesiumcarbonate 5-6, mica powder 8-10, perlite 5-7, vermiculite power 4-6, magnesium hydroxide 8-10, barium sulfate 1-2, zinc oxide 1-2, dicumyl peroxide DCP1-2, phosphoguanidine 1-2, calcium stearate 1-2, tetramethylolmethane 1-2, melamine cyanurate 1-2, inspissated wax 0.2-0.4, modified filler 5-8.The cable that CABLE MATERIALS of the present invention is processed into has high temperature resistant, low cigarette, ageing-resistant, and flame retardant properties is good.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of resistant to elevated temperatures polyvinyl chloride cable material.
Background technology
Electric wire is important materials indispensable in industrial and agricultural production and the modern life, China is that the maximum electric wire in the whole world produces country, wires and cables industry occupies very important status in the national economy of China, but, at present, CABLE MATERIALS on market also exists non-refractory, not ageing-resistant, and after weathering test, material occurs that jaundice becomes fragile phenomenon.Electric wire is aging and fire that is that cause also gets more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of the resistant to elevated temperatures polyvinyl chloride cable material of halide-free smokeless is increasing, the production of the resistant to elevated temperatures polyvinyl chloride cable material of current halide-free smokeless is in polyolefin substrate, add a large amount of Shawinigan blacks or Shawinigan black to reach flame retardant effect mostly, but, adding of a large amount of inorganic materials, have impact on physical and mechanical properties and the processing of CABLE MATERIALS.Fire-retardant, low cigarette, environmental protection, good weatherability, CABLE MATERIALS that cost is low become the direction of CABLE MATERIALS development.
Summary of the invention
The invention provides a kind of resistant to elevated temperatures polyvinyl chloride cable material and preparation method thereof.The cable be processed into by CABLE MATERIALS of the present invention has high temperature resistant, low cigarette, ageing-resistant, and flame retardant properties is good.
The technical solution used in the present invention is:
A kind of resistant to elevated temperatures polyvinyl chloride cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride (PVC) RESINS 50-60, trioctyl trimellitate 10-15, trioctyl phosphate 10-12, acetic acid 1-2, tribasic lead sulfate 0.2-0.3, dibasic lead stearate 0.2-0.3, dihydroxyphenyl propane 1-2, two Lauryl Alcohol ester 1-2, sepiolite 8-10, magnesiumcarbonate 5-6, mica powder 8-10, perlite 5-7, vermiculite power 4-6, magnesium hydroxide 8-10, barium sulfate 1-2, zinc oxide 1-2, dicumyl peroxide DCP1-2, phosphoguanidine 1-2, calcium stearate 1-2, tetramethylolmethane 1-2, melamine cyanurate 1-2, inspissated wax 0.2-0.4, modified filler 5-8,
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
Described resistant to elevated temperatures polyvinyl chloride cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride (PVC) RESINS 55, trioctyl trimellitate 13, trioctyl phosphate 11, acetic acid 1, tribasic lead sulfate 0.3, dibasic lead stearate 0.2, dihydroxyphenyl propane 1, two Lauryl Alcohol ester 2, sepiolite 10, magnesiumcarbonate 5, mica powder 9, perlite 6, vermiculite power 5, magnesium hydroxide 9, barium sulfate 1, zinc oxide 2, dicumyl peroxide DCP1, phosphoguanidine 2, calcium stearate 1, tetramethylolmethane 1, melamine cyanurate 2, inspissated wax 0.3, modified filler 7,
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
The preparation method of CABLE MATERIALS of the present invention:
Take each constitutive material by formula rate, constitutive material is dropped into homogenizer mixing 3-5min, blowing, the material mixed is put in twin screw extruder, extruding pelletization, then after entering and carrying out drying in hot air dryer, obtain resistant to elevated temperatures polyvinyl chloride cable material, when extruding, twin screw extruder temperature is set to: feeding section 105 DEG C, melt zone 170 DEG C, melt conveying zone 170-180 DEG C, mixing section 185 DEG C, homogenizing zone 185 DEG C, head metering zone 180 DEG C.
Beneficial effect
The cable that CABLE MATERIALS of the present invention is processed into has high temperature resistant, low cigarette, ageing-resistant, and flame retardant properties is good.
Embodiment
A kind of resistant to elevated temperatures polyvinyl chloride cable material, prepared by the component raw material of following weight (kg) and obtain:
Polyvinyl chloride (PVC) RESINS 55, trioctyl trimellitate 13, trioctyl phosphate 11, acetic acid 1, tribasic lead sulfate 0.3, dibasic lead stearate 0.2, dihydroxyphenyl propane 1, two Lauryl Alcohol ester 2, sepiolite 10, magnesiumcarbonate 5, mica powder 9, perlite 6, vermiculite power 5, magnesium hydroxide 9, barium sulfate 1, zinc oxide 2, dicumyl peroxide DCP1, phosphoguanidine 2, calcium stearate 1, tetramethylolmethane 1, melamine cyanurate 2, inspissated wax 0.3, modified filler 7
Wherein, modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
The preparation method of resistant to elevated temperatures polyvinyl chloride cable material:
Take each constitutive material by formula rate, constitutive material is dropped into homogenizer mixing 3-5min, blowing, the material mixed is put in twin screw extruder, extruding pelletization, then after entering and carrying out drying in hot air dryer, obtain resistant to elevated temperatures polyvinyl chloride cable material, when extruding, twin screw extruder temperature is set to: feeding section 105 DEG C, melt zone 170 DEG C, melt conveying zone 170-180 DEG C, mixing section 185 DEG C, homogenizing zone 185 DEG C, head metering zone 180 DEG C.
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:
Claims (2)
1. a resistant to elevated temperatures polyvinyl chloride cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride (PVC) RESINS 50-60, trioctyl trimellitate 10-15, trioctyl phosphate 10-12, acetic acid 1-2, tribasic lead sulfate 0.2-0.3, dibasic lead stearate 0.2-0.3, dihydroxyphenyl propane 1-2, two Lauryl Alcohol ester 1-2, sepiolite 8-10, magnesiumcarbonate 5-6, mica powder 8-10, perlite 5-7, vermiculite power 4-6, magnesium hydroxide 8-10, barium sulfate 1-2, zinc oxide 1-2, dicumyl peroxide DCP1-2, phosphoguanidine 1-2, calcium stearate 1-2, tetramethylolmethane 1-2, melamine cyanurate 1-2, inspissated wax 0.2-0.4, modified filler 5-8,
Described modified filler is prepared by following method and obtains:
A, take off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
2. resistant to elevated temperatures polyvinyl chloride cable material according to claim 1, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride (PVC) RESINS 55, trioctyl trimellitate 13, trioctyl phosphate 11, acetic acid 1, tribasic lead sulfate 0.3, dibasic lead stearate 0.2, dihydroxyphenyl propane 1, two Lauryl Alcohol ester 2, sepiolite 10, magnesiumcarbonate 5, mica powder 9, perlite 6, vermiculite power 5, magnesium hydroxide 9, barium sulfate 1, zinc oxide 2, dicumyl peroxide DCP1, phosphoguanidine 2, calcium stearate 1, tetramethylolmethane 1, melamine cyanurate 2, inspissated wax 0.3, modified filler 7,
Described modified filler is prepared by following method and obtains:
A, take off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473860.2A CN103509292B (en) | 2013-10-12 | 2013-10-12 | A kind of resistant to elevated temperatures polyvinyl chloride cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473860.2A CN103509292B (en) | 2013-10-12 | 2013-10-12 | A kind of resistant to elevated temperatures polyvinyl chloride cable material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103509292A CN103509292A (en) | 2014-01-15 |
| CN103509292B true CN103509292B (en) | 2016-03-02 |
Family
ID=49892750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310473860.2A Active CN103509292B (en) | 2013-10-12 | 2013-10-12 | A kind of resistant to elevated temperatures polyvinyl chloride cable material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103509292B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558966A (en) * | 2015-01-15 | 2015-04-29 | 无为县华祥电缆材料有限公司 | Chlorinated-esterified polybutadiene rubber modified polyvinyl chloride cable material |
| CN105623154A (en) * | 2016-03-30 | 2016-06-01 | 苗庆龄 | Heat-resistant and anti-tensile special cable material for automobile wire harness and preparation method for cable material |
| CN108659265B (en) * | 2017-03-31 | 2020-09-08 | 中国石油化工股份有限公司 | Flame-retardant smoke-inhibiting polyvinyl chloride cable material and preparation method thereof |
| CN114429842B (en) * | 2022-03-02 | 2023-12-26 | 广东新亚光电缆股份有限公司 | Preparation method of strip steel core tight compression type cable |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977280B2 (en) * | 2003-06-11 | 2005-12-20 | Teknor Apex Company | Polyvinyl chloride or polyolefin melt processable compositions containing polytetrafluoroethylene micropowder |
| CN101412834A (en) * | 2008-11-12 | 2009-04-22 | 江苏三角洲塑化有限公司 | High temperature resistant environment-protective polychloroethylene material for electric wire and cable |
| CN101463169A (en) * | 2008-12-30 | 2009-06-24 | 深圳市领亚电子有限公司 | Dual wave soldering high temperature resistant polychloroethylene composition for electric wire and cable and preparation thereof |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
| CN102408619A (en) * | 2011-09-22 | 2012-04-11 | 安徽塞帕斯电缆材料有限公司 | Modified high-temperature-resistant polyvinyl chloride cable material and preparation method thereof |
-
2013
- 2013-10-12 CN CN201310473860.2A patent/CN103509292B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977280B2 (en) * | 2003-06-11 | 2005-12-20 | Teknor Apex Company | Polyvinyl chloride or polyolefin melt processable compositions containing polytetrafluoroethylene micropowder |
| CN101412834A (en) * | 2008-11-12 | 2009-04-22 | 江苏三角洲塑化有限公司 | High temperature resistant environment-protective polychloroethylene material for electric wire and cable |
| CN101463169A (en) * | 2008-12-30 | 2009-06-24 | 深圳市领亚电子有限公司 | Dual wave soldering high temperature resistant polychloroethylene composition for electric wire and cable and preparation thereof |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
| CN102408619A (en) * | 2011-09-22 | 2012-04-11 | 安徽塞帕斯电缆材料有限公司 | Modified high-temperature-resistant polyvinyl chloride cable material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103509292A (en) | 2014-01-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103509295B (en) | A kind of environment-friendly heatproof composite elastic cable material for wires and cables | |
| CN103509228B (en) | A kind of fire-retardant polyethylene cable material with mould-proof function | |
| CN103509296B (en) | A kind of silicone hydride crosslinked non-halogen flame-proof polyvinyl chloride granula for cable | |
| CN103509229B (en) | A kind of photovoltaic cable irradiation crosslinking type low-smoke halogen-free flame-retardant polyolefin CABLE MATERIALS | |
| CN103524904B (en) | A kind of Special cable material and preparation method thereof | |
| CN103524937B (en) | A kind of high-flame-retardant polyvinyl | |
| CN103571031B (en) | A kind of low cigarette environment-friendly cable material | |
| CN103524933B (en) | A kind of fire-resistant cable material and preparation method thereof | |
| CN103554807B (en) | A kind of wear-resistant cable material of nano modification | |
| CN103509293B (en) | A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable | |
| CN103509292B (en) | A kind of resistant to elevated temperatures polyvinyl chloride cable material | |
| CN103554715B (en) | A kind of halogen-free flame-proof environmental protection cross-linked polrvinyl chloride CABLE MATERIALS | |
| CN103509236B (en) | A kind of high-flame-retardance low-smoke halogen-free cable material and preparation method thereof | |
| CN103467820B (en) | A kind of low smoke halogen-free fire retardant polyolefin cable material and preparation method thereof | |
| CN104109306A (en) | Optical fiber cable-used insulated cable material and preparation method thereof | |
| CN103509235B (en) | A kind of Environment-friendlypolyethylene polyethylene cable material and preparation method thereof | |
| CN103524935B (en) | A kind of modified PVC CABLE MATERIALS and preparation method thereof | |
| CN103524868A (en) | Low-temperature-resistant oil-resistant low-smoke halogen-free flame-retardant polyolefin cable material | |
| CN103613882A (en) | Radiation-resisting cable material and preparation method thereof | |
| CN103524907B (en) | A kind of Mine cable rubber sheath material and preparation method thereof | |
| CN103540061B (en) | A kind of environment-friendly polyvinyl chloride CABLE MATERIALS | |
| CN103509294B (en) | A kind of cold-resistant fire-retardant PVC CABLE MATERIALS | |
| CN103524847B (en) | A kind of organosilane cross-linked poly-ethylene cable material and preparation method thereof | |
| CN103524939B (en) | A kind of Cold-resistant oil-resistant flame-retardant polyvinyl chloride cable material | |
| CN103509237B (en) | A kind of fast ceramic flame-resistant cable |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Zhen Inventor before: Xie Hua |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171110 Address after: 266000 Hechuan road 3, Licang District, Shandong, Qingdao Patentee after: Qingdao aoter mesnac kaimei Technology Co. Ltd. Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: Lvbao Cable (Group) Co., Ltd. |