CN103509275B - A kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce - Google Patents
A kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce Download PDFInfo
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- CN103509275B CN103509275B CN201310393407.0A CN201310393407A CN103509275B CN 103509275 B CN103509275 B CN 103509275B CN 201310393407 A CN201310393407 A CN 201310393407A CN 103509275 B CN103509275 B CN 103509275B
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- Prior art keywords
- polyvinyl chloride
- cable
- waste polyvinyl
- add
- produce
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- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 27
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 25
- 239000002699 waste material Substances 0.000 title claims abstract description 19
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical class [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 7
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 7
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 7
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 4
- 239000006004 Quartz sand Substances 0.000 claims abstract description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 4
- 239000003549 soybean oil Substances 0.000 claims abstract description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- 229910017083 AlN Inorganic materials 0.000 claims description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229910052601 baryte Inorganic materials 0.000 claims description 2
- 239000010428 baryte Substances 0.000 claims description 2
- -1 polyethylene Polymers 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 206010001557 Albinism Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce, it is obtained by the raw material of following weight parts: waste polyvinyl chloride cable particle 90-95, SG-3 polyvinyl chloride 10-12, Silane coupling agent KH550? 0.6-0.8, chlorinatedpolyethylene 4-8, barium stearate 1-2, triethyl citrate 1.3-2.2, ferric oxide 2.4-2.5, molybdic oxide 1-2, soybean oil 2-3, quartz sand 4-6, modified barite powder 48-55.
Description
Technical field
The present invention relates to CABLE MATERIALS field, is exactly a kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce.
Background technology
Polyvinyl chloride (PVC) true qualities are that micro-yellow is translucent, glossy.Transparency is better than polyethylene, polypropylene, is worse than polystyrene, and different with auxiliary dosage, be divided into soft, rigid polyvinyl chloride, soft goods is soft and tough, and feel is glued, and the hardness of boardy product is higher than Low Density Polyethylene, and lower than polypropylene, in flexion, place there will be albinism.
Along with the development of science and technology, the various auxiliary agent of PVC and the development of stopping composition, also make the performance of PVC cable material constantly improve and improve.
Summary of the invention
The object of the present invention is to provide a kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce.
Above-mentioned purpose is realized by following scheme:
The CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce, is characterized in that: it is obtained by the raw material of following weight parts: waste polyvinyl chloride cable particle 90-95, SG-3 polyvinyl chloride 10-12, Silane coupling agent KH550 0.6-0.8, chlorinatedpolyethylene 4-8, barium stearate 1-2, triethyl citrate 1.3-2.2, ferric oxide 2.4-2.5, molybdic oxide 1-2, soybean oil 2-3, quartz sand 4-6, modified barite powder 48-55;
The preparation method of described modified barite powder is: by 40-55 part barite, 3-5 part diatomite, 1-2 part calcium carbonate calcines 1-2 hour at 800-850 DEG C, then, take out, with 4-6 part aluminium hydroxide, 1-2 part aluminium nitride mixes, and add in suitable quantity of water and grind, add concentration be 12-14% hydrochloric acid soln adjust PH be 4.2-5.3, after ground slurry to 500-600 order, repeated hydrogenation sodium oxide is adjusted to neutrality, dry, 0.1-0.2 part zinc oxide is added in gained powder, 0.3-0.5 part clorafin, 0.1-0.2 part silane coupling agent KH580 mixes, ground and mixed evenly after and get final product.
Described a kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce, is characterized in that:
Preparation method is: (1) takes modified barite powder and drops in high-speed mixer, then adds Silane coupling agent KH550, triethyl citrate, stirs 8-12min in 1800-2200r/min;
(2) add waste polyvinyl chloride cable particle, molybdic oxide again, 500-600r/min stirs 3min, then in kneader 160-180 DEG C mediate 3-5 minute, take out cooling, mix with surplus stock, at 170-175 DEG C, twin screw extruder extruding pelletization, gets product.
Beneficial effect of the present invention for: the polyvinyl chloride raw material that present method adopts for domestic waste and old cable disassemble enterprise the waste and old cable sheath disassembled out, cost-saving, environmental protection, gained CABLE MATERIALS intensity is high, nontoxic.
Embodiment
Utilize the CABLE MATERIALS that waste polyvinyl chloride cable material is produced, it is obtained by the raw material of following weight parts (kg): waste polyvinyl chloride cable particle 95, SG-3 polyvinyl chloride 10, Silane coupling agent KH550 0.8, chlorinatedpolyethylene 6, barium stearate 1, triethyl citrate 1.8, ferric oxide 2.4, molybdic oxide 2, soybean oil 3, quartz sand 6, modified barite powder 48;
The preparation method of described modified barite powder is: 55 parts of (kg) barites, 4 parts of diatomite, 2 parts of calcium carbonate are calcined 2 hours at 800 DEG C, then, take out, mix with 6 parts of aluminium hydroxides, 2 parts of aluminium nitride, and add in suitable quantity of water and grind, add concentration be 12% hydrochloric acid soln adjust PH be 5.3, after ground slurry to 500 order, repeated hydrogenation sodium oxide is adjusted to neutrality, dry, add 0.2 part of zinc oxide in gained powder, 0.5 part of clorafin, 0.2 part of silane coupling agent KH580 mix, ground and mixed evenly after and get final product.
Described a kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce, preparation method is:
(1) take modified barite powder to drop in high-speed mixer, then add Silane coupling agent KH550, triethyl citrate, stir 12min in 1800r/min;
(2) add waste polyvinyl chloride cable particle, molybdic oxide again, 600r/min stirs 3min, then in kneader 180 DEG C mediate 5 minutes, take out cooling, mix with surplus stock, at 175 DEG C, twin screw extruder extruding pelletization, gets product.
The present embodiment is carried out performance test, and the data obtained is as follows:
From the present embodiment test result, product of the present invention is through the aging of 100 DEG C × 168h and 80 DEG C × 6h Apparatus for Pressure at high-temp, the change of its mechanical and physical performance meets corresponding mark requirement, has good physical and mechanical properties, meets the demand of differing temps environmental change.
Claims (2)
1. the CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce, is characterized in that: it is obtained by the raw material of following weight parts: waste polyvinyl chloride cable particle 90-95, SG-3 polyvinyl chloride 10-12, Silane coupling agent KH550 0.6-0.8, chlorinatedpolyethylene 4-8, barium stearate 1-2, triethyl citrate 1.3-2.2, ferric oxide 2.4-2.5, molybdic oxide 1-2, soybean oil 2-3, quartz sand 4-6, modified barite powder 48-55, the preparation method of described modified barite powder is: by 40-55 part barite, 3-5 part diatomite, 1-2 part calcium carbonate calcines 1-2 hour at 800-850 DEG C, then, take out, with 4-6 part aluminium hydroxide, 1-2 part aluminium nitride mixes, and add in suitable quantity of water and grind, add concentration be 12-14% hydrochloric acid soln adjust pH be 4.2-5.3, after ground slurry to 500-600 order, repeated hydrogenation sodium oxide is adjusted to neutrality, dry, 0.1-0.2 part zinc oxide is added in gained powder, 0.3-0.5 part clorafin, 0.1-0.2 part silane coupling agent KH580 mixes, ground and mixed evenly after and get final product.
2. a kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce according to claim 1, is characterized in that: preparation method is:
(1) take modified barite powder to drop in high-speed mixer, then add Silane coupling agent KH550, triethyl citrate, stir 8-12min in 1800-2200r/min;
(2) add waste polyvinyl chloride cable particle, molybdic oxide again, 500-600r/min stirs 3min, then in kneader 160-180 DEG C mediate 3-5 minute, take out cooling, mix with surplus stock, at 170-175 DEG C, twin screw extruder extruding pelletization, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310393407.0A CN103509275B (en) | 2013-09-02 | 2013-09-02 | A kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310393407.0A CN103509275B (en) | 2013-09-02 | 2013-09-02 | A kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103509275A CN103509275A (en) | 2014-01-15 |
| CN103509275B true CN103509275B (en) | 2016-01-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310393407.0A Active CN103509275B (en) | 2013-09-02 | 2013-09-02 | A kind of CABLE MATERIALS utilizing waste polyvinyl chloride cable material to produce |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263015A (en) * | 2014-08-21 | 2015-01-07 | 安徽吉安特种线缆制造有限公司 | Modified barite used for high-strength wear-resistant cable sheath material and preparing method thereof |
| CN107011600A (en) * | 2017-06-06 | 2017-08-04 | 合肥市闵葵电力工程有限公司 | A kind of ageing-resistant environmental-friendflame-retardant flame-retardant cable crane span structure of high intensity antistatic and preparation method thereof |
| BE1030616B1 (en) * | 2022-06-13 | 2024-01-22 | Brussels Recycling Metal Br Met | Micronized powder in recycled soft PVC and articles made from this powder |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1219549A (en) * | 1997-12-12 | 1999-06-16 | 易友生 | Technical process for producing PVC cable granules by use of waste polyvinyl chloride |
| CN102532739A (en) * | 2010-12-07 | 2012-07-04 | 安徽绿能技术研究院 | Process for preparing PVC (polyvinyl chloride) section material from waste PVC material |
| CN102585399A (en) * | 2012-02-23 | 2012-07-18 | 扬州市好年华橡塑有限公司 | Black 70 DEG C polyvinyl chloride (PVC) cable sheath material |
-
2013
- 2013-09-02 CN CN201310393407.0A patent/CN103509275B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1219549A (en) * | 1997-12-12 | 1999-06-16 | 易友生 | Technical process for producing PVC cable granules by use of waste polyvinyl chloride |
| CN102532739A (en) * | 2010-12-07 | 2012-07-04 | 安徽绿能技术研究院 | Process for preparing PVC (polyvinyl chloride) section material from waste PVC material |
| CN102585399A (en) * | 2012-02-23 | 2012-07-18 | 扬州市好年华橡塑有限公司 | Black 70 DEG C polyvinyl chloride (PVC) cable sheath material |
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| CN103509275A (en) | 2014-01-15 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151028 Address after: 239200 Anhui city of Chuzhou province Lai'an industrial district Applicant after: Anhui He Xin Electrical Appliances Co., Ltd Address before: 239200 New Development Zone, Lai County, Anhui, Chuzhou Applicant before: The rich Rex Rabbit electric wire of Chuzhou City Co., Ltd |
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Effective date of registration: 20200617 Address after: 215500 Room 301, building 3, No. 88, Xianshi Road, Suzhou high tech Industrial Development Zone, Jiangsu Province Patentee after: Changshu Zijin Intellectual Property Service Co.,Ltd. Address before: 239200 Industrial New District, Lai County, Anhui, Chuzhou Patentee before: Anhui He Xin Electrical Appliances Co.,Ltd. |