CN103507370A - Scratch-resistant stain-repellent solar heat insulation membrane - Google Patents
Scratch-resistant stain-repellent solar heat insulation membrane Download PDFInfo
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- CN103507370A CN103507370A CN201210204965.3A CN201210204965A CN103507370A CN 103507370 A CN103507370 A CN 103507370A CN 201210204965 A CN201210204965 A CN 201210204965A CN 103507370 A CN103507370 A CN 103507370A
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Abstract
The invention discloses a scratch-resistant stain-repellent solar heat insulation membrane. The main structure of the scratch-resistant stain-repellent solar heat insulation membrane comprises a scratch-resistant stain-repellent layer, a first optical thin film layer, a polyurethane adhesive layer, an ultraviolet infrared ray isolated strengthening layer, a metal or metal oxide layer, a second optical thin film layer, a mounting adhesive layer and a release film. The invention also discloses a making method of the scratch-resistant stain-repellent solar heat insulation membrane. The scratch-resistant stain-repellent solar heat insulation membrane provided by the invention is easy to mount, no adhesive residue is left on a screen surface after the scratch-resistant stain-repellent solar heat insulation membrane is removed, and the scratch-resistant stain-repellent solar heat insulation membrane has the functions of scratching resistance, excellent abradability, stain repellence and the like, and can be widely applied to installation and use of automobile glass and construction glass. The making method of the scratch-resistant stain-repellent solar heat insulation membrane provided by the invention is simple, is easy to operate and suitable for industrial production.
Description
Technical field
The present invention relates to a kind of diaphragm, be specifically a kind of protect vehicle glass and external wall glass there is solar energy thermal isolation film of anti-scratch anti-pollution function and preparation method thereof.
Background technology
Along with socioeconomic development, being surging forward of auto industry, growing stronger day by day of building trade, is used vehicle glass and building curtain wall glass in a large number.For fear of glass surface, be subject to scratch or wearing and tearing, affect result of use, generally can on the surface label of glass, there is the diaphragm of scratch resistant function.
But when pasting, the solar energy thermal isolation film adopting in the market easily produces bubble, be difficult for discharging, affected the aesthetics of product after pad pasting, and the solar energy thermal isolation film light transmittance using is at present not high, resistance to scraping is poor, solar energy thermal isolation film surface is still easily by the hard thing scratch such as finger, suspension member, and the film surface after pad pasting does not have anti-scratch and antifouling function concurrently.
The present invention easily installs, can utilize and on the glass surface of wiping clean, spray water smoke in advance, stick and utilize after this anti-scratch antifouling solar energy thermal isolation film scraper plate can get rid of fast bubble scraping when anhydrating, and remove rear glass surface and do not stay cull, anti scuffing ability can control to 3H～6H, can effectively prevent that the article such as finger, hard thing from injuring friction injury to scraping of glass surface, most critical is that this solar energy thermal isolation film has anti-pollution function, no matter be that oil stain, spot stick to its surface, can with rag, effectively remove whenever and wherever possible.
Summary of the invention
Goal of the invention: the object of the invention is to overcome the deficiencies in the prior art, provide a kind of easy installation, anti scuffing, can fast automatic eliminating bubble, do not stay cull after removing rear glass surface, there is the anti-scratch antifouling solar energy thermal isolation film of splendid resistance to soiling.
Technical scheme: to achieve these goals, the invention provides a kind of anti-scratch antifouling solar energy thermal isolation film, it comprises: anti-scratch stain-proofing layer, the first optical grade thin layer, polyurethane glue-line, every the infrared enhancement Layer of ultraviolet, metal or metal oxide layer, the second optical grade thin layer, glue-line and mould release membrance are installed;
On the corona surface of the second described optical grade thin layer, by chemical vapor deposition legal system, make metal or metal oxide layer, surface at metal or metal oxide layer makes every the infrared enhancement Layer of ultraviolet by magnetron sputtering method, on the corona surface of the first optical grade thin layer, be coated with polyurethane glue-line, this polyurethane glue-line is with compound every the infrared enhancement Layer of ultraviolet; Then on the non-corona surface of the second optical grade thin layer, glue-line is installed in coating, more compound with installation glue-line with mould release membrance; Finally on the non-corona surface of the first optical grade thin layer, be coated with anti-scratch stain-proofing layer.
Wherein, in the glue of described anti-scratch stain-proofing layer, containing UV reactive F is interfacial agent.
Preferably, described UV reactive F is that interfacial agent is selected from one or more in fluorinated acrylate, fluorochemical polyether.
Described fluorinated acrylate is preferably Hexafluorobutyl mathacrylate, methacrylic acid 2, one or more in 2,2-trifluoro ethyl ester, dodecafluoroheptyl methacrylate, dodecafluorhe-ptylacrylate, methacrylic acid ten trifluoro monooctyl esters, acrylic acid ten trifluoro monooctyl esters.
Described fluorochemical polyether is preferably: one or more in polyether-modified fluorine-containing dimethyl silicone polymer, fluorochemical polyether bisphosphate, fluorochemical polyether isocyanates.
The thickness of wherein said each rete, each glue-line is respectively:
Anti-scratch stain-proofing layer 2 um～8 um
The first optical grade thin layer 16 um～36 um
Polyurethane glue-line 2 um～20 um
Every the infrared enhancement Layer 2 um～30um of ultraviolet
Metal or metal oxide layer 2 um～30 um
The second optical grade thin layer 16 um～36 um
Glue-line 10 um～40 um are installed
Mould release membrance 9 um～50 um.
Above-mentioned anti-scratch stain-proofing layer, every the infrared enhancement Layer of ultraviolet, metal or metal oxide layer, what glue-line employing was installed is all silicone based resin or acrylic resin, wherein every the infrared enhancement Layer of ultraviolet for adding every the ultrared material of ultraviolet as nanometer tungsten in glue at this resin etc., nano-oxide metal titanium dioxide, vanadium dioxide etc., nano nitride titanium nitride etc., nano-carbide titanium carbide etc., nano fluoride magnesium fluoride etc., nanometer sulfide zinc sulphide etc., nanometer antimonide tin-antiomony oxide etc., nanometer selenium compound cadmium selenide etc., nano tellurium compound cadmium telluride etc. is made, metal or metal oxide layer be for add metal or metal oxide in the glue of this resin, as one or more in tungsten, copper, vanadium dioxide, aluminium oxide, tri-iron tetroxide or zinc oxide.
The first optical grade thin layer, the second optical grade thin layer, mould release membrance are PET film, and the light transmittance of PET film is more than 92%, mist degree < 1%.
The preparation method of above-mentioned anti-scratch antifouling solar energy thermal isolation film is also provided in the present invention, and the concrete steps of preparation method are as follows:
(1), on the corona surface of the second optical grade thin layer (6) of 16 um～36 um, by chemical vapor deposition legal system, make metal or the metal oxide layer (5) of 2 um～30 um; To the requirement of PET film substrate, be wherein the high grade of transparency, visible light transmissivity>92%, mist degree<1%.The metal of making by chemical vapor deposition method or metal oxide layer (5) have the ultraviolet feature of heat insulation.
(2), metal or above metal oxide layer (5) by magnetron sputtering method make 2 um～30um every the infrared enhancement Layer of ultraviolet (4);
(3) the polyurethane glue-line (3) that, is coated with 2 um～20 um on the corona surface of the first optical grade thin layer (2) of 16 um～36 um is with compound every the infrared enhancement Layer of ultraviolet (4);
(4), then on the non-corona surface of the second optical grade thin layer (6), be coated with the installation glue-line (7) of 10 um～40 um, compound with the mould release membrance (8) of 9 um～50 um;
(5), finally on the non-corona surface of the first optical grade thin layer (2), be coated with the anti-scratch stain-proofing layer (1) of 2 um～8 um, obtain product of the present invention, the anti-scratch ability of anti-scratch layer is more than 2H, the every increase 1um of anti-scratch layer can improve 1H.
Beneficial effect: anti-scratch antifouling solar energy thermal isolation film of the present invention, compared with prior art tool has the following advantages: owing to having added UV reactive F in anti-scratch layer, be interfacial agent, thereby have very strong soil resistance; Easily install, can utilize and on the glass surface of wiping clean, spray water smoke in advance, stick and utilize after solar energy thermal isolation film scraper plate scraping when anhydrating and can getting rid of fast bubble, remove rear glass surface and do not stay cull, visible light transmissivity is up to 92%; Anti scuffing ability can control between 3H～6H, can effectively prevent that the article such as finger, hard thing from injuring friction injury to scraping of glass surface, most critical is that this solar energy thermal isolation film has anti-pollution function, no matter be that oil stain, spot stick to its surface, can with rag, effectively remove whenever and wherever possible.The preparation method of anti-scratch antifouling solar energy thermal isolation film of the present invention is simple, easy to operate, is applicable to industrial production.
Accompanying drawing explanation
Accompanying drawing is the structural representation of anti-scratch antifouling solar energy thermal isolation film of the present invention.
the specific embodiment:
Below in conjunction with specific embodiment, further illustrate the present invention, should understand these embodiment is only not used in and limits the scope of the invention for the present invention is described, after having read the present invention, those skilled in the art all fall within the application's claims to the modification of the various equivalent form of values of the present invention and limit.
Embodiment 1:
Anti-scratch stain-proofing layer 2 um～8 um
The first optical grade thin layer 16 um～36 um
Polyurethane glue-line 2 um～20 um
Every the infrared enhancement Layer 2 um～30um of ultraviolet
Metal or metal oxide layer 2 um～30 um
The second optical grade thin layer 16 um～36 um
Glue-line 10 um～40 um are installed
Mould release membrance 9 um～50 um.
A kind of anti-scratch antifouling solar energy thermal isolation film as shown in Figure 1, it comprises: the anti-scratch stain-proofing layer that thickness is 3um, the mould release membrance 8 that the second optical grade thin layer base material 6 that the metal level 5, the thickness that are 2um every the infrared enhancement Layer 4 of ultraviolet, thickness that the first optical grade thin layer base material 2 that thickness is 23um, polyurethane glue-line 3, the thickness that thickness is 8um are 4um is 23um, the installation glue-line 7 that thickness is 8um and thickness are 23um; Anti-scratch stain-proofing layer 1 in the present embodiment, every the infrared enhancement Layer 4 of ultraviolet, metal or metal oxide layer 5, the acrylic resin that is that glue-line 7 adopts is installed, polyurethane glue-line 3 adopts polyurethane to make.
The preparation method concrete steps of above-mentioned scratch resistant antifouling solar energy thermal isolation film are as follows:
(1), on the corona surface of the second optical grade thin layer of 23 um, by chemical vapor deposition legal system, make the metal level of 2 um; To the requirement of PET film substrate, be wherein the high grade of transparency, visible light transmissivity>92%, mist degree<1%.The metal level of making by chemical vapor deposition method has the ultraviolet feature of heat insulation.
(2), on metal level by magnetron sputtering method make 4 um every the infrared enhancement Layer of ultraviolet;
(3) the polyurethane glue-line that, is coated with 8 um on the corona surface of the first optical grade thin layer of 23 um is with compound every the infrared enhancement Layer of ultraviolet;
(4), then on the non-corona surface of the second optical grade thin layer, be coated with the installation glue-line of 8um, compound with it with the mould release membrance of 23um;
(5) finally on the non-corona surface of the first optical grade thin layer, be coated with the anti-scratch stain-proofing layer of 3um, obtain product described in the present embodiment, the anti-scratch ability of anti-scratch layer is more than 2H, and the every increase 1um of anti-scratch layer can improve 1H.
Embodiment 2:
A kind of anti-scratch antifouling solar energy thermal isolation film as shown in Figure 1, it comprises: the anti-scratch stain-proofing layer that thickness is 4um, the mould release membrance 8 that the second optical grade thin layer base material 6 that the metal level 5, the thickness that are 4um every the infrared enhancement Layer 4 of ultraviolet, thickness that the first optical grade thin layer base material 2 that thickness is 16um, polyurethane glue-line 3, the thickness that thickness is 8um are 2um is 23um, the installation glue-line 7 that thickness is 8um and thickness are 23um; Anti-scratch stain-proofing layer 1 in the present embodiment, every the infrared enhancement Layer 4 of ultraviolet, metal or metal oxide layer 5, adopt be acrylic resin, polyurethane glue-line 3 adopts polyurethane to make; What glue-line 7 employings were installed is silicone based resin.
The preparation method concrete steps of above-mentioned scratch resistant antifouling solar energy thermal isolation film are as follows:
(1), on the corona surface of the second optical grade thin layer of 23 um, by chemical vapor deposition legal system, make the metal level of 4 um; To the requirement of PET film substrate, be wherein the high grade of transparency, visible light transmissivity>92%, mist degree<1%.The metal level of making by chemical vapor deposition method has the ultraviolet feature of heat insulation.
(2), on metal level by magnetron sputtering method make 2 um every the infrared enhancement Layer of ultraviolet;
(3) the polyurethane glue-line that, is coated with 8 um on the corona surface of the first optical grade thin layer of 16 um is with compound every the infrared enhancement Layer of ultraviolet;
(4), then on the non-corona surface of the second optical grade thin layer, be coated with the installation glue-line of 8um, compound with it with the mould release membrance of 23um;
(5) finally on the non-corona surface of the first optical grade thin layer, be coated with the anti-scratch stain-proofing layer of 4um, obtain product described in the present embodiment, the anti-scratch ability of anti-scratch layer is more than 2H, and the every increase 1um of anti-scratch layer can improve 1H.
Embodiment 3:
A kind of anti-scratch antifouling solar energy thermal isolation film as shown in Figure 1, it comprises: the anti-scratch stain-proofing layer that thickness is 2um, the mould release membrance 8 that the second optical grade thin layer base material 6 that the metal level 5, the thickness that are 3um every the infrared enhancement Layer 4 of ultraviolet, thickness that the first optical grade thin layer base material 2 that thickness is 23um, polyurethane glue-line 3, the thickness that thickness is 4um are 3um is 23um, the installation glue-line 7 that thickness is 8um and thickness are 23um; What in the present embodiment, every the infrared enhancement Layer 4 of ultraviolet, metal or metal oxide layer 5, adopt is acrylic resin; Polyurethane glue-line 3 adopts polyurethane to make; What anti-scratch stain-proofing layer 1, installation glue-line 7 adopted is silicone based resin.
The preparation method concrete steps of above-mentioned scratch resistant antifouling solar energy thermal isolation film are as follows:
(1), on the corona surface of the second optical grade thin layer of 23 um, by chemical vapor deposition legal system, make the metal level of 3um; To the requirement of PET film substrate, be wherein the high grade of transparency, visible light transmissivity>92%, mist degree<1%.The metal level of making by chemical vapor deposition method has the ultraviolet feature of heat insulation.
(2), on metal level by magnetron sputtering method make 3 um every the infrared enhancement Layer of ultraviolet;
(3) the polyurethane glue-line that, is coated with 4 um on the corona surface of the first optical grade thin layer of 23um is with compound every the infrared enhancement Layer of ultraviolet;
(4), then on the non-corona surface of the second optical grade thin layer, be coated with the installation glue-line of 8um, compound with it with the mould release membrance of 23um;
(5) finally on the non-corona surface of the first optical grade thin layer, be coated with the anti-scratch stain-proofing layer of 2um, obtain product described in the present embodiment, the anti-scratch ability of anti-scratch layer is more than 2H, and the every increase 1um of anti-scratch layer can improve 1H.
Claims (7)
1. a scratch resistant antifouling solar energy thermal isolation film, is characterized in that: it comprises: anti-scratch stain-proofing layer (1), the first optical grade thin layer (2), polyurethane glue-line (3), every the infrared enhancement Layer of ultraviolet (4), metal or metal oxide layer (5), the second optical grade thin layer (6), glue-line (7) and mould release membrance (8) are installed;
On the corona surface of the second described optical grade thin layer (6), by chemical vapor deposition legal system, make metal or metal oxide layer (5), surface at metal or metal oxide layer (5) makes every the infrared enhancement Layer of ultraviolet (4) by magnetron sputtering method, on the corona surface of the first optical grade thin layer (2), be coated with polyurethane glue-line (3), this polyurethane glue-line (3) is with compound every the infrared enhancement Layer of ultraviolet (4); Then on the non-corona surface of the second optical grade thin layer (6), glue-line (7) is installed in coating, then uses mould release membrance (8) compound with installation glue-line (7); Finally on the non-corona surface of the first optical grade thin layer (2), be coated with anti-scratch stain-proofing layer (1), wherein, in the glue of described anti-scratch stain-proofing layer (1), containing UV reactive F is interfacial agent.
2. scratch resistant antifouling solar energy thermal isolation film according to claim 1, is characterized in that: described UV reactive F is that interfacial agent is selected from one or more in fluorinated acrylate, fluorochemical polyether.
3. scratch resistant antifouling solar energy thermal isolation film according to claim 1, it is characterized in that: described fluorinated acrylate is selected from Hexafluorobutyl mathacrylate, methacrylic acid 2, one or more in 2,2-trifluoro ethyl ester, dodecafluoroheptyl methacrylate, dodecafluorhe-ptylacrylate, methacrylic acid ten trifluoro monooctyl esters, acrylic acid ten trifluoro monooctyl esters.
4. scratch resistant antifouling solar energy thermal isolation film according to claim 1, is characterized in that: described fluorochemical polyether is selected from one or more in polyether-modified fluorine-containing dimethyl silicone polymer, fluorochemical polyether bisphosphate, fluorochemical polyether isocyanates.
5. according to the scratch resistant antifouling solar energy thermal isolation film described in claim 1 to 4 any one, it is characterized in that: the thickness of wherein said each rete, each glue-line is respectively:
Anti-scratch stain-proofing layer (1) 2 um～8 um
The first optical grade thin layer (2) 16 um～36 um
Polyurethane glue-line (3) 2 um～20 um
Every infrared enhancement Layer (4) 2 um～30um of ultraviolet
Metal or metal oxide layer (5) 2 um～30 um
The second optical grade thin layer (6) 16 um～36 um
Glue-line (7) 10 um～40 um are installed
Mould release membrance (8) 9 um～50 um.
6. scratch resistant antifouling solar energy thermal isolation film according to claim 5, is characterized in that: described anti-scratch stain-proofing layer (1), every the infrared enhancement Layer of ultraviolet (4), metal or metal oxide layer (5), what install that glue-line (7) adopts is all silicone based resin or acrylic resin.
7. scratch resistant antifouling solar energy thermal isolation film according to claim 5, it is characterized in that: the first optical grade thin layer (2), the second optical grade thin layer (6), mould release membrance (8) are PET film, and the light transmittance of PET film is being greater than 92%, and mist degree is less than 1%.
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| CN201210204965.3A CN103507370A (en) | 2012-06-20 | 2012-06-20 | Scratch-resistant stain-repellent solar heat insulation membrane |
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| CN201210204965.3A CN103507370A (en) | 2012-06-20 | 2012-06-20 | Scratch-resistant stain-repellent solar heat insulation membrane |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788698A (en) * | 2015-03-31 | 2015-07-22 | 苏州市鼎立包装有限公司 | Scratch-resistant protective film and preparation method thereof |
| CN105313651A (en) * | 2015-12-04 | 2016-02-10 | 太仓苏晟电气技术科技有限公司 | Scratch-resistant automobile door |
| CN108819414A (en) * | 2018-05-29 | 2018-11-16 | 广东旭坤新特材料科技有限公司 | A kind of selfreparing TPU protective film basement membrane and preparation method thereof |
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| JP2003334911A (en) * | 2002-05-21 | 2003-11-25 | Mitsubishi Polyester Film Copp | Display surface protecting film |
| JP2006120972A (en) * | 2004-10-25 | 2006-05-11 | Toppan Printing Co Ltd | Surface protection sheet for solar cell, and solar cell module |
| CN101114026A (en) * | 2006-07-24 | 2008-01-30 | 南亚塑胶工业股份有限公司 | Surface protective film for polarizer |
| CN101474901A (en) * | 2009-01-16 | 2009-07-08 | 中山市万丰胶粘电子有限公司 | Heat insulation film |
| CN101899249A (en) * | 2009-05-25 | 2010-12-01 | 上海复甲新型材料科技有限公司 | Transparent thermal insulation anti-ultraviolet coating and preparation method thereof |
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2012
- 2012-06-20 CN CN201210204965.3A patent/CN103507370A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003334911A (en) * | 2002-05-21 | 2003-11-25 | Mitsubishi Polyester Film Copp | Display surface protecting film |
| JP2006120972A (en) * | 2004-10-25 | 2006-05-11 | Toppan Printing Co Ltd | Surface protection sheet for solar cell, and solar cell module |
| CN101114026A (en) * | 2006-07-24 | 2008-01-30 | 南亚塑胶工业股份有限公司 | Surface protective film for polarizer |
| CN101474901A (en) * | 2009-01-16 | 2009-07-08 | 中山市万丰胶粘电子有限公司 | Heat insulation film |
| CN101899249A (en) * | 2009-05-25 | 2010-12-01 | 上海复甲新型材料科技有限公司 | Transparent thermal insulation anti-ultraviolet coating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788698A (en) * | 2015-03-31 | 2015-07-22 | 苏州市鼎立包装有限公司 | Scratch-resistant protective film and preparation method thereof |
| CN105313651A (en) * | 2015-12-04 | 2016-02-10 | 太仓苏晟电气技术科技有限公司 | Scratch-resistant automobile door |
| CN108819414A (en) * | 2018-05-29 | 2018-11-16 | 广东旭坤新特材料科技有限公司 | A kind of selfreparing TPU protective film basement membrane and preparation method thereof |
| CN108819414B (en) * | 2018-05-29 | 2020-09-11 | 广东旭坤新特材料科技有限公司 | Self-repairing TPU (thermoplastic polyurethane) protective film base film and preparation method thereof |
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Application publication date: 20140115 |