A kind of novel conductive mineral silica sheet drier and preparation method thereof
Technical field
The present invention relates to chemical material field, particularly, relate to a kind of novel conductive mineral silica sheet drier and preparation method thereof.
Background technology
Along with being widely used of drier, requiring drier volume less, and can better carve and close mutually with packing container; And requiring drier in use safe and reliable, moisture pick-up properties is stable, and can be reproduced Reusability; More require drier to there is good electric conductivity, can not play static.
What generally adopt in recent years is the drier such as packed silica gel, its major defect is: the drier such as silica gel must be packed again through gas permeability material nonwoven or paper etc., can not directly fit tightly with the packing of product that need to place drier, and can produce the situation that packed silica-gel desiccant drops and breaks, there is the possibility that causes secondary pollution product; And conventional pouch silica-gel desiccant put procedure can only manually be placed, can not realize continuous and automatic and throw in, thereby limit its Automation Industry process.The housing material that bagged dryer adopts, processes or reach and have electric conductivity at surface printing conductive ink, but electric conductivity is lower through antistatic surface.
Patent application CN03135587.0 discloses a kind of composite type zeolite drier, to take epidesmine as primary raw material, with the kaolin in clay mineral, or montmorillonite, or sepiolite etc., with with water-absorbing resins in starch grafted acrylate, or SPA, or the macromolecular material such as starch graft acrylamide, in 75~85: 10~15: the ratio of 5~10 (take gross weight as 100) mixes makes base-material, 0~5% calcite or the coal dust that add again base-material weight, or flyash is as pore creating material, after adding the waterglass of base-material weight 15~30% or epoxy resin together evenly to mix as binding agent, extrusion modling, sending into baker dries after moisture content, or cooling the input or acid of coming out of the stove, or alkali, or in sodium salt or ammonium salt solution, soak and implement modification, clean, dry, or again heat up and carry out high-temperature baking, make zeolite drier.
The shortcoming that above-mentioned technology contents exists is: its drier must carry out packing again with ventilative nonwoven or paper, just can be used in various moistureproof fields; And space injected volume is few, gross absorption will certainly be lower, and there is no electric conductivity, easily plays static.In prior art, conductive carbon fibre is not applied in drier, if can develop a kind of like this drier, certainly will will has huge application prospect and economic worth.
Summary of the invention
In order to solve problems of the prior art, one of object of the present invention is to provide a kind of novel conductive mineral silica sheet drier.
Another object of the present invention is to, a kind of preparation method of described novel conductive mineral silica sheet drier is provided.
Novel conductive mineral silica sheet drier provided by the invention, comprises the component of following weight percentage: conductive carbon fibre 2~10%, mineral silica drier powder 60~94%, macromolecular material 0.1~30%.
Novel conductive mineral silica sheet drier provided by the invention, preferably, comprises the component of following weight percentage: conductive carbon fibre 4.0~5.5%, mineral silica drier powder 65~90%, macromolecular material 8.5~27.0%.
The weight that above-mentioned percentage composition is each component accounts for the percentage of all components (conductive carbon fibre, mineral silica drier powder and macromolecular material etc.) gross weight.
Conductive carbon fibre of the present invention is high-strength conductive carbon fiber.
Wherein, described mineral silica drier powder is: the mixture of mineral and silica, wherein both weight ratios are (1~3): (1~3).
Preferably, in mineral silica drier powder, the weight ratio of mineral and silica is (7~10): (10~13).
Wherein, described mineral are natural minerals, i.e. the mineral of natural degradable; Preferably, described mineral are selected from: one or more in montmorillonite, bentonite and attapulgite clay.
Wherein, described silica is selected from: one or both in pore (A type) and gross porosity (Type B) silica gel, its wettability power is higher.
Wherein, described macromolecular material is selected from: low density polyethylene (LDPE) (LDPE), high density polyethylene (HDPE) (HDPE), polypropylene (PP), polystyrene (PS), PLA (PLA), hydroxypropyl methylcellulose (HPMC) and carboxymethyl cellulose (CMC) etc. one or more, preferred low density polyethylene (LDPE) (LDPE).Macromolecular material is Powdered.Add macromolecular material mainly to play dustproof effect.
The preparation method of novel conductive mineral silica sheet drier provided by the invention, comprises the following steps:
1) mineral silica drier powder is mixed in described ratio with conductive carbon fibre, macromolecular material;
2) mixed component is compressing, make the tablet of dimension size;
3), by the tablet drying of making, obtain electric conductivity mineral silica sheet drier.
The preparation method of novel conductive mineral silica sheet drier provided by the invention, further, comprises the following steps:
1) prepare tablet material: by mineral silica drier powder and conductive carbon fibre, macromolecular material mixes in described ratio;
2) compressing: mixed component is compressing through tablet press machine heating, make the tablet of dimension size;
3) activation: the tablet of making, through vacuum drying, is obtained to electric conductivity mineral silica sheet drier.
Wherein, step 2) in, the temperature of heating is: 60~120 ℃, and preferably 70~90 ℃.
Novel conductive mineral silica sheet drier provided by the invention, it is main is specificly:
One, can make the packing of product be closely linked, save greatly the useful space, and can realize continuous and automatic operation;
Two, there is electric conductivity and do not produce static, can activate by direct-electrifying;
Three, renewable and be reused;
Four, more can be consistent with the space of placing drier, space injected volume is high, and moisture pick-up properties temperature and hygroscopic capacity promote greatly;
Five, adopt raw material all harmless, safe and reliable; Environmentally safe, odorless, tasteless, non-corrosiveness.
Novel conductive mineral silica sheet drier provided by the invention, the a kind of of moisture protected dry drying prescription, employing conductive carbon fibre is conductive material, macromolecular material is binding agent, and mineral silica drier powder is main adsorbent etc., through mixing, in a certain size size mould compacting, form, make it there are various fixedly external forms, have sufficient mechanical strength, there is excellent conductive performance.
In a word, electric conductivity mineral silica sheet drier provided by the invention is compared with conventional pouch electric conductivity silica-gel desiccant in performance, and in same volume situation, electric conductivity is more obvious; And, can be consistent with usage space size, safety and environmental protection, can realize automated production, there is huge application prospect and economic worth.
The specific embodiment
Following examples are used for illustrating the present invention, but are not used for limiting the scope of the invention.
Unit of the present invention " part " can refer to: jin, kilogram, gram, kilogram, ton ... etc. unit of weight, according to practical condition, determine.
The NM operation of the present invention and technological parameter are the routine of this area and select, and material used is also for can purchase from the market available conventional material.
The specification of the low density polyethylene (LDPE) (LDPE) that the present invention is used is: the following powder of 200 order.
The present invention's conductive carbon fibre used is purchased from U.S. Ya Qi international corporation.
Embodiment 1: the preparation of mineral silica powder
The first step: natural minerals is purified
First purifying waste water of 80 parts of 5 parts of use of montmorillonite ore deposit soil stirred to fully immersion and more than 50 hours, treat that it fully expands, through 200 orders, sieve above, isolate bulky grain thing impurity ore deposit soil.
Second step: parcel
By the mineral of above-mentioned purification and 8 parts of input machine for cutting charge into pieces of pore (A type) silicon dioxide powder (particle diameter is more than 400 orders), grind more than 60 hours, mixed material, supercentrifuge centrifugal (rotating speed is more than 2000 revs/min), is removed to particle, make parcel liquid.
The 3rd step: dry
The parcel liquid making is concentrated, and vacuum drying, mineral silica drier powder obtained.
Embodiment 2: the preparation of mineral silica powder
The first step: natural minerals is purified
First 2 parts, montmorillonite ore deposit soil is stirred fully and soaked more than 50 hours with purifying waste water of 100 parts of 3 parts of use of attapulgite clay, treat that it fully expands, through 200 orders, sieve above, isolate bulky grain thing impurity ore deposit soil.
Second step: parcel
By 3 parts of the mineral of above-mentioned purification and pore (A type) silica whites (particle diameter is: particle diameter is more than 400 orders), 2 parts of gross porosity (Type B) silica whites drop into machine for cutting charge into pieces together, grind more than 60 hours, by mixed material supercentrifuge centrifugal (rotating speed is more than 2000 revs/min), remove particle, make parcel liquid.
The 3rd step: dry
The parcel liquid making is concentrated, and drying box is dry, makes mineral silica drier powder.
Embodiment 3: the preparation of electric conductivity mineral silica sheet drier
The first step: material is prepared
By 0.5 part of 10 parts, the mineral silica drier powder being made by embodiment 1 and conductive carbon fibre, 1 part, LDPE powder fully mixes.
Second step: compressing
Above-mentioned mixed material, through tablet press machine heating (temperature is 70 ℃), is made to type at mould inner pressure.
The 3rd step: activation
The tablet of making, through vacuum drying, is obtained to electric conductivity mineral silica sheet drier.
Embodiment 4: the preparation of electric conductivity mineral silica sheet drier
The first step: material is prepared
By 0.8 part of 10 parts, the mineral silica drier powder being made by embodiment 1 and conductive carbon fibre, 4 parts, LDPE powder fully mixes.
Second step: compressing
Above-mentioned mixed material, through tablet press machine heating (temperature is 90 ℃), is made to type at mould inner pressure.
The 3rd step: activation
The tablet of making, through vacuum drying, is obtained to electric conductivity mineral silica sheet drier.
Experimental example
Novel conductive mineral silica sheet drier of the present invention (product being made by embodiment 3), adopt the conventional method of this area to carry out performance test with the drier of selling on existing market (packed silica-gel desiccant), except functions/drying, electric conductivity contrast following (take place drier space 70.00 * 80.00 * 7.00mm be example):
As can be seen from the above table: novel conductive mineral silica sheet drier of the present invention is compared with existing packed silica-gel desiccant, more can be consistent with the space of placing drier; And the amount raising of placing drier in space is very large, total hygroscopic capacity has great raising; In addition, the electric conductivity of type mineral silica sheet drier of the present invention will be far superior to existing packed silica-gel desiccant.
Other embodiment and embodiment 3 effects are similar, but take embodiment 3 as excellent.
Although above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements, all belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.