CN103498227A - Cashmere fiber and Richcel fiber blended fabric - Google Patents
Cashmere fiber and Richcel fiber blended fabric Download PDFInfo
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- 239000000835 fiber Substances 0.000 title claims abstract description 70
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- 239000004744 fabric Substances 0.000 title claims abstract description 30
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- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 claims 1
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Abstract
Description
技术领域technical field
本发明涉及一种面料,尤其涉及一种羊绒纤维和丽赛纤维混纺的面料。The invention relates to a fabric, in particular to a fabric blended with cashmere fiber and Lisa fiber.
背景技术Background technique
羊绒是生长在山羊外表皮层,掩在山羊粗毛根部的一层薄薄的细绒,入冬寒冷时长出,抵御风寒,开春转暖后脱落,自然适应气候,属于稀有的特种动物纤维。羊绒之所以十分珍贵,不仅由于产量稀少(仅占世界动物纤维总产量的0.2%),更重要的是其优良的品质和特性,交易中以克论价,被人们认为是“纤维宝石”、“纤维皇后”,是目前人类能够利用的所有纺织原料都无法比拟的,因而又被称为“软黄金”。Cashmere is a thin layer of fine velvet that grows on the outer skin of goats and covers the roots of goats' coarse hair. It grows out when it is cold in winter to resist the wind and cold. It falls off after the warming of spring and naturally adapts to the climate. It is a rare special animal fiber. The reason why cashmere is very precious is not only due to the scarcity of output (accounting for only 0.2% of the world's total animal fiber production), but more importantly, its excellent quality and characteristics. "Fiber Queen" is incomparable to all the textile materials currently available to human beings, so it is also called "soft gold".
羊绒具有不规则的稀而深的卷曲,由鳞片层和皮质层组成,没有髓质层,鳞片密度约为60-70个/mm,纤维横截面近似圆形,直径比细羊毛还要细,平均细度多在14-16um,细度不匀率小,约为20%,长度一般为35-45mm,集纤细、轻薄、柔软、滑糯、保暖于一身。纤维强力适中,富有弹性,并具有一种天然柔和的色泽。Cashmere has irregular thin and deep curls, composed of scale layer and cortex layer, without medulla layer, the scale density is about 60-70/mm, the fiber cross section is approximately circular, and the diameter is thinner than fine wool. The average fineness is mostly 14-16um, the fineness unevenness is small, about 20%, and the length is generally 35-45mm. It is thin, light, soft, smooth and warm. The fibers are moderately strong, elastic and have a natural soft color.
丽赛纤维,又称Richcel纤维,是采用日本东洋纺专有技术及原料体系生产的波里诺西克Polynosic纤维,是具有优异综合性能的植物纤维素纤维。丽赛纤维原料源于日本进口的天然针叶树精制木浆,资源可再生,废弃物可自然降解,安全环保。丽赛纤维具有高强度、高湿模量、高聚合度和适当的伸度,吸湿性好,在性能上与Tencel纤维接近;而市场价格大大低于Tencel纤维,与Modal较为接近。丽赛纤维织物尺寸稳定性较好,收缩率较小,较耐洗、耐穿;色泽鲜艳,悬垂性好;丽赛纤维的耐碱性好,与棉混纺织物还可进行丝光处理,改善织物手感与光泽。因此,丽赛纤维既符合"可持续发展"的要求,又满足人们日益追求自然、舒适、美观和卫生保健的时尚需求,具有很好的市场前景。Richcel fiber, also known as Richcel fiber, is a Polynosic fiber produced by Japan Toyobo's proprietary technology and raw material system. It is a plant cellulose fiber with excellent comprehensive properties. The raw material of Lisai fiber comes from the refined wood pulp of natural coniferous trees imported from Japan. The resources are renewable, and the waste can be degraded naturally, which is safe and environmentally friendly. Lisai fiber has high strength, high wet modulus, high degree of polymerization and appropriate elongation, good hygroscopicity, and is close to Tencel fiber in performance; while the market price is much lower than Tencel fiber, and is closer to Modal. Lisai fiber fabric has better dimensional stability, less shrinkage, more washable and durable; bright color, good drape; Lisai fiber has good alkali resistance, and can be mercerized with cotton blended fabrics to improve fabric Feel and gloss. Therefore, Lisai fiber not only meets the requirements of "sustainable development", but also meets the fashion needs of people's increasing pursuit of nature, comfort, beauty and health care, and has a very good market prospect.
本发明试图通过提供一种新的混纺面料,将羊绒纤维与丽赛纤维混纺。The present invention attempts to blend cashmere fibers and Lisa fibers by providing a new blended fabric.
发明内容Contents of the invention
针对现有技术的不足,本发明所要解决的技术问题是提供一种羊绒纤维和丽赛纤维混纺的面料。Aiming at the deficiencies of the prior art, the technical problem to be solved by the present invention is to provide a fabric blended with cashmere fiber and Lisa fiber.
为解决上述技术问题,本发明通过以下技术方案来实现:In order to solve the problems of the technologies described above, the present invention is achieved through the following technical solutions:
一种羊绒纤维和丽赛纤维混纺的面料,由20-40wt%羊绒纤维和60-80wt%丽赛纤维混纺织造而成。A blended fabric of cashmere fiber and Lisa fiber is made of 20-40wt% cashmere fiber and 60-80wt% Lisa fiber.
优选地,Preferably,
一种羊绒纤维和丽赛纤维混纺的面料,由20-40wt%羊绒纤维和60-80wt%丽赛纤维混纺织造而成,再经过抗菌后整理而成。A cashmere fiber and Lisa fiber blended fabric is made of 20-40wt% cashmere fiber and 60-80wt% Lisai fiber blended fabric, and then finished after antibacterial finishing.
所述抗菌后整理步骤为,常温下在抗菌整理液中浸渍10-30分钟,所述抗菌整理液中抗菌整理剂用量为0.5-1.5%o.w.f,浴比为1:15-1:25。The antibacterial finishing step is to immerse in the antibacterial finishing solution at room temperature for 10-30 minutes, the amount of antibacterial finishing agent in the antibacterial finishing solution is 0.5-1.5% o.w.f, and the bath ratio is 1:15-1:25.
所述抗菌整理剂,由如下重量份的组分组成:硫酸鱼精蛋白5-15份、2,4,4’-三氯-2’-羟基二苯醚50-70份、十二烷基二甲基甜菜碱5-15份、聚六亚甲基双胍盐酸盐15-25份。将上述各组分搅拌混合均匀,即可制得所述抗菌整理剂。The antibacterial finishing agent is composed of the following components by weight: 5-15 parts of protamine sulfate, 50-70 parts of 2,4,4'-trichloro-2'-hydroxydiphenyl ether, 50-70 parts of dodecyl 5-15 parts of dimethyl betaine, 15-25 parts of polyhexamethylene biguanide hydrochloride. The antibacterial finishing agent can be prepared by stirring and mixing the above-mentioned components evenly.
具体的,在本发明中:Specifically, in the present invention:
硫酸鱼精蛋白,拼音名:Liusuan Yujingdanbai,英文名:ProtamineSulfate,书页号:中国药典2005年版二部-742,本品系自适宜的鱼类新鲜成熟精子中提取的一种碱性蛋白质的硫酸盐。按干燥品计,为白色或类白色粉末,无臭,有吸湿性,易溶于水,不溶于乙醇、氯仿或乙醚中。Protamine sulfate, pinyin name: Liusuan Yujingdanbai, English name: ProtamineSulfate, page number: Chinese Pharmacopoeia 2005 Edition II-742, this strain is a kind of basic protein sulfate extracted from fresh mature sperm of suitable fish . Calculated as dry product, it is white or off-white powder, odorless, hygroscopic, soluble in water, insoluble in ethanol, chloroform or ether.
2,4,4’-三氯-2’-羟基二苯醚,别名:玉洁新、三氯生,缩写DP300,英文名:5-chloro-2-(2,4-dichlorophenoxy),CAS号:3380-34-5。2,4,4'-Trichloro-2'-hydroxydiphenyl ether, alias: Yujiexin, Triclosan, abbreviated as DP300, English name: 5-chloro-2-(2,4-dichlorophenoxy), CAS number : 3380-34-5.
十二烷基二甲基甜菜碱,CAS号:683-10-3。Lauryl dimethyl betaine, CAS number: 683-10-3.
聚六亚甲基双胍盐酸盐,英文名:Poly(hexamethylenebiguanide)hydrochloride,CAS登录号:32289-58-0。Polyhexamethylenebiguanide hydrochloride, English name: Poly(hexamethylenebiguanide) hydrochloride, CAS accession number: 32289-58-0.
o.w.f,全称为On weight the fabric,纺织染整用语,纺织染整工艺中浓度以织物重量为基准,相对织物百分比。o.w.f, the full name is On weight the fabric, a term for textile dyeing and finishing. The concentration in the textile dyeing and finishing process is based on the weight of the fabric, relative to the percentage of the fabric.
浴比,liquor ratio,纺织染整用语,指浸渍方式中织物与染液的比值。Bath ratio, liquor ratio, a term used in textile dyeing and finishing, refers to the ratio of fabric to dye liquor in the dipping method.
需要说明的是,在本发明中如无特别解释说明,各原料均以含量100%计。It should be noted that, unless otherwise specified in the present invention, the content of each raw material is 100%.
在本发明中,突破性地将常用于医药、食品行业的原料硫酸鱼精蛋白应用于纺织抗菌处理,进一步的,本发明中首次将硫酸鱼精蛋白与抗菌剂2,4,4’-三氯-2’-羟基二苯醚、聚六亚甲基双胍盐酸盐复配使用,并在表面活性剂十二烷基二甲基甜菜碱的协同下,抗菌效果明显增效。In the present invention, protamine sulfate, a raw material commonly used in medicine and food industry, is applied to textile antibacterial treatment. Further, in the present invention, protamine sulfate and antibacterial agent 2, 4, 4'-tri Chloro-2'-hydroxydiphenyl ether and polyhexamethylene biguanide hydrochloride are used in combination, and under the synergy of surfactant dodecyl dimethyl betaine, the antibacterial effect is obviously enhanced.
相对于现有技术,本发明技术方案的显著进步主要体现为:本发明将羊绒纤维和丽赛纤维两种性能不同的纤维混合在一起,取长补短,面料纤细、轻薄、保暖并富有弹性,穿着舒适。进一步的,通过抗菌后整理,面料抑菌率高,从而能够有效保护人体健康。Compared with the prior art, the remarkable progress of the technical solution of the present invention is mainly reflected in the following: the present invention mixes cashmere fiber and Lisai fiber with different properties to complement each other, and the fabric is slender, light and thin, warm and elastic, and comfortable to wear . Furthermore, through antibacterial finishing, the fabric has a high antibacterial rate, which can effectively protect human health.
具体实施方式Detailed ways
实施例1Example 1
选用市售的羊绒纤维和丽赛纤维,质量比为30:70。Select commercially available cashmere fiber and Lisa fiber, and the mass ratio is 30:70.
将按上述配比称取的羊绒纤维开松预处理,在梳棉机上梳理成生条;将按上述配比称取的丽赛纤维开松预处理,在梳棉机上梳理成生条;然后将羊绒纤维生条和丽赛纤维生条在并条机上并合,制成熟条;在粗纱机上进行牵伸和加捻,最后在细纱机上进一步牵伸加捻,制成丽赛纤维和羊绒纤维混纺纱。再将丽赛纤维和羊绒纤维混纺纱采用大圆机纬编织造方法进行织造,最终制得羊绒纤维和丽赛纤维混纺的面料。The cashmere fiber weighed according to the above ratio is opened and pretreated, and carded into a raw sliver on the carding machine; the Lisa fiber weighed according to the above ratio is opened and pretreated, and carded into a raw sliver on the carding machine; Combining cashmere fiber raw sliver and Lisa fiber raw sliver on the drawing frame to make mature sliver; drafting and twisting on the roving frame, and finally further drafting and twisting on the spinning frame to make Lisa fiber and cashmere fiber blend spinning. Then, the blended yarn of the Lisai fiber and the cashmere fiber is woven by a large circular machine weft knitting method, and finally a fabric blended with the cashmere fiber and the Lisai fiber is obtained.
显然,上述的混纺纱及面料的制备工艺均为本行业的通用方法,为本领域普通技术人员所熟知。Obviously, the above-mentioned preparation techniques of blended yarns and fabrics are common methods in this industry and are well known to those skilled in the art.
实施例2Example 2
取部分实施例1所制得的羊绒纤维和丽赛纤维混纺的面料,进一步进行抗菌后整理,具体步骤为:Get some of the cashmere fibers and Lisai fiber blended fabrics prepared in Example 1, and further carry out antibacterial finishing. The specific steps are:
(1)抗菌整理剂的配置:(1) Configuration of antibacterial finishing agent:
按表1中实施例2对应的数据称取各原料,搅拌混合均匀,制得抗菌整理剂。According to the data corresponding to Example 2 in Table 1, each raw material was weighed, stirred and mixed evenly, and an antibacterial finishing agent was obtained.
(2)浸渍:(2) Dipping:
将抗菌整理剂溶解在水中,制得抗菌整理液;Dissolving the antibacterial finishing agent in water to prepare an antibacterial finishing solution;
再将羊绒纤维和丽赛纤维混纺的面料常温(18-25℃)下在抗菌整理液中浸渍20分钟,所述抗菌整理液中抗菌整理剂用量为1.0%o.w.f,浴比为1:20。Then immerse the cashmere fiber and Lisai fiber blended fabric in the antibacterial finishing solution at room temperature (18-25°C) for 20 minutes. The antibacterial finishing agent dosage in the antibacterial finishing solution is 1.0% o.w.f, and the bath ratio is 1:20.
(3)脱水;(3) Dehydration;
(4)烘干:在100℃温度下将织物烘干。(4) Drying: Dry the fabric at 100°C.
即可制得本发明的抗菌后处理之后的羊绒纤维和丽赛纤维混纺的面料。The cashmere fiber and Lisa fiber blended fabric after the antibacterial post-treatment of the present invention can be obtained.
实施例3Example 3
制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例3对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 3 in Table 1 was used to prepare the antibacterial finishing agent.
实施例4Example 4
制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例4对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 4 in Table 1 was used to prepare the antibacterial finishing agent.
实施例5Example 5
制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例5对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 5 in Table 1 was used to prepare the antibacterial finishing agent.
实施例6Example 6
制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例6对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 6 in Table 1 was used to prepare the antibacterial finishing agent.
表1:抗菌整理剂配方表单位:公斤Table 1: Antibacterial finishing agent formula table Unit: kg
测试例1test case 1
采用国家标准GB/T20944.3-2008《纺织品抗菌性能的评价第3部分:振荡法》进行抗菌性定量测试,采用耐洗色牢度试验机洗涤方法,测试水洗30次后的织物,测试结果见表2。The national standard GB/T20944.3-2008 "Evaluation of Antibacterial Properties of Textiles Part 3: Oscillating Method" was used for quantitative testing of antibacterial properties, and the washing method of washing color fastness test machine was used to test the fabric after washing 30 times. The test results See Table 2.
表2:水洗30次后抑菌率测试表Table 2: Antibacterial rate test table after washing 30 times
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