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CN103482904B - A kind of modified epoxy mortar resistant abrasion patching material - Google Patents

A kind of modified epoxy mortar resistant abrasion patching material Download PDF

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Publication number
CN103482904B
CN103482904B CN201310413242.9A CN201310413242A CN103482904B CN 103482904 B CN103482904 B CN 103482904B CN 201310413242 A CN201310413242 A CN 201310413242A CN 103482904 B CN103482904 B CN 103482904B
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component
solidifying agent
aggregate
orders
patching material
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CN103482904A (en
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万雄卫
徐盈
李北星
肖皓
邱富源
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Wuhan Jucheng Structure Group Co ltd
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WUDA JUCHENG STRUCTURE Co Ltd
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Abstract

A kind of modified epoxy mortar resistant abrasion patching material, this patching material comprises component A, B component, and the mass ratio of component A and B component is 4: 1, the composition of component A and weight ratio thereof are: epoxy resin 15 ~ 20, toughner 1.5 ~ 2, reactive thinner 1.5 ~ 3, abrasive aggregates 75 ~ 82, the composition of B component and weight ratio thereof are: solidifying agent 18 ~ 24, coupling agent 1 ~ 1.5, abrasive aggregates 75 ~ 80, abrasive aggregates is quartz sand graduation aggregate or silicon carbide graded aggregate, the particle diameter composition of this aggregate and mass ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=0 ~ 1: 1 ~ 2: 0 ~ 2: 0 ~ 1, solidifying agent is polyether monoamine solidifying agent.The present invention not only increases anti-abrasion strength and resistance to impact shock, and reduces curing reaction speed, avoids the appearance of the early stage tiny crack of epoxy mortar.

Description

A kind of modified epoxy mortar resistant abrasion patching material
Technical field
The present invention relates to a kind of concrete anti-abrasion patching material, be specifically related to a kind of modified epoxy mortar resistant abrasion patching material, be applicable to the resistant abrasion and the resistance to impact shock that improve epoxy mortar.
Background technology
In recent years, along with development of the West Regions and the enforcement of transferring electricity from the west to the east development strategy, China has built a collection of large-scale high-head power station, its earial drainage flow velocity all reaches 40-50m/s, earial drainage head is more than 150m, and it is construction of hydropower plant and operating knotty problem that high-velocity sediment-laden flow galls bad to the concrete punching of hydraulic structure flow-passing surface.High-velocity & sediment-laden flow can cause Surface layer's concrete big area to be degraded to the erosive wear of hydraulic concrete buildings flow-passing surface, cavitation corrosion effect, and serious then initiation catastrophic failure occurs, therefore always attention.To the splitting resistance of resistant abrasion material, resistant abrasion ability and fast easy act etc. all have higher requirement.
To the abrasion of ultrahigh-water head current and destruction and maintenance, the research of Chinese scholars has history decades, involved resistant abrasion description of materials is a lot, as steel plate, glass cermaic plate, cast iron plate lining protect, different modes buries rail pointing silicon powder concrete, fiber reinforced concrete, resin slurry (resin used has epoxy and modified epoxy, furane resin and other macromolecular material), sprayed concrete, silicon powder concrete, flyash abrasion resistance concrete etc. again underground.From the sixties in 20th century, domestic once by epoxy resin, furane resin, acrylate resin, unsaturated polyester resin mortar etc., for hydraulic structure resist containing sand current rush gall bad, wherein better with epoxy mortar effect, more with obtaining, up to now also in use.From the experience of prolonged application, people recognize; high water head current to after the washing away of hydraulic structure, ablation destruction; patching material can not pursue high strength simply; and the toughness of material should be improved; improve the ability of its opposing temperature, humidity change; improve its cohesive force etc. to substrate concrete, become the punching of concrete surface anti-high velocity flow and gall bad protective layer.
Chinese patent: application publication number is CN101423358A, publication date is the preparation method that the patent of invention on May 6th, 2009 discloses a kind of high impact resistant epoxy resin mortar, in this preparation method, the raw material of component A comprises polyurethane modified epoxy resin, quartz sand, thinner, softening agent, and quartz sand is that the coarse sand of 0.5 ~ 3mm and particle diameter mix by a certain percentage at 80 ~ 400 object fine sands by particle diameter, the raw material of B component comprises room temperature amine curing agent, quartz sand, thinner, and room temperature amine curing agent is diethylenetriamine, triethylene tetramine or low molecular polyamides.Although the cured article that this invention obtains has good resistance to compression, shearing resistance and resistance to impact shock, still have following defect:
1, the coarse sand selected in this invention and the grain diameter of fine sand differ greatly, particularly coarse sand, its particle diameter reaches 0.5 ~ 3mm, and obtained epoxy mortar is not easy to apply smooth in construction process, the covered effect of bonding base-material to quartz sand is poor, thus affects the etch resistant properties of epoxy mortar;
2, this invention is using diethylenetriamine, triethylene tetramine or low molecular polyamides as solidifying agent, and the use of such solidifying agent can cause curing reaction wayward because of excessive velocities, thus makes troubles to construction.
Summary of the invention
The object of the invention is to overcome the excessive problem affecting etch resistant properties, curing reaction excessive velocities of the aggregate size existed in prior art, provide a kind of aggregate size moderate and effectively can reduce the modified epoxy mortar resistant abrasion patching material of curing reaction speed.
For realizing above object, the invention provides following technical scheme:
A kind of modified epoxy mortar resistant abrasion patching material, this patching material comprises component A, B component, and the mass ratio of described component A and B component is 4: 1;
The composition of described component A and weight ratio thereof are: epoxy resin 15 ~ 20, toughner 1.5 ~ 2, reactive thinner 1.5 ~ 3, abrasive aggregates 75 ~ 82;
The composition of described B component and weight ratio thereof are: solidifying agent 18 ~ 24, coupling agent 1 ~ 1.5, abrasive aggregates 75 ~ 80;
Described abrasive aggregates is quartz sand graduation aggregate or silicon carbide graded aggregate, and the particle diameter composition of described quartz sand graduation aggregate or silicon carbide graded aggregate and mass ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=0 ~ 1: 1 ~ 2: 0 ~ 2: 0 ~ 1.
Described solidifying agent is polyether monoamine solidifying agent.
Described solidifying agent is polyetheramine solidifying agent T-403 or polyetheramine solidifying agent D-230.
Described epoxy resin is bisphenol A-type E44 epoxy resin or bisphenol A-type E51 epoxy resin.
Described toughner is liquid polysulfide rubber, liquid acrylonitrile butadiene rubber or liquid styrene butadiene rubber.
Described reactive thinner is one or more in benzyl glycidyl ether, butylglycidyl ether, glycidyl allyl ether.
Described coupling agent is APTES.
Compared with prior art, beneficial effect of the present invention is:
1, in a kind of modified epoxy mortar of the present invention resistant abrasion patching material, abrasive aggregates is quartz sand graduation aggregate or silicon carbide graded aggregate, and the particle diameter of quartz sand graduation aggregate or silicon carbide graded aggregate composition and weight ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=0 ~ 1: 1 ~ 2: 0 ~ 2: 0 ~ 1, on the one hand, the present invention adopts Young's modulus high, hardness is large, wear-resisting quartz sand or silicon carbide also carry out good grating, significantly improve anti-abrasion strength and the resistance to impact shock of epoxy mortar, on the other hand, the moderate in grain size of aggregate used, bonding base-material is better to its covered effect, can effectively avoid causing because aggregate size is too large the etch resistant properties of epoxy mortar lower and affect the abrasion resistance of epoxy mortar because aggregate size is too little, simultaneously, present invention employs the aggregate of four kinds of different-grain diameters, can need to regulate the composition of these aggregates and ratio according to intensity, use range is wider.Therefore, the present invention not only increases anti-abrasion strength and resistance to impact shock, and avoids because aggregate size is too large and affect etch resistant properties, and use range is wider.
2, the solidifying agent selected in a kind of modified epoxy mortar of the present invention resistant abrasion patching material is polyether monoamine solidifying agent, after the solidification of such solidifying agent, system reaction heat is lower, curing reaction speed is slower, the presetting period of epoxy resin cure is longer, effectively can reduce exothermic heat of reaction peak and the original volume cure shrinkage of curing system, avoid the appearance of the early stage tiny crack of epoxy mortar.Therefore, the present invention can reduce curing reaction speed, avoid the appearance of the early stage tiny crack of epoxy mortar.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
A kind of modified epoxy mortar resistant abrasion patching material, this patching material comprises component A, B component, and the mass ratio of described component A and B component is 4: 1;
The composition of described component A and weight ratio thereof are: epoxy resin 15 ~ 20, toughner 1.5 ~ 2, reactive thinner 1.5 ~ 3, abrasive aggregates 75 ~ 82;
The composition of described B component and weight ratio thereof are: solidifying agent 18 ~ 24, coupling agent 1 ~ 1.5, abrasive aggregates 75 ~ 80;
Described abrasive aggregates is quartz sand graduation aggregate or silicon carbide graded aggregate, and the particle diameter composition of described quartz sand graduation aggregate or silicon carbide graded aggregate and mass ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=0 ~ 1: 1 ~ 2: 0 ~ 2: 0 ~ 1.
Described solidifying agent is polyether monoamine solidifying agent.
Described solidifying agent is polyetheramine solidifying agent T-403 or polyetheramine solidifying agent D-230.
Described epoxy resin is bisphenol A-type E44 epoxy resin or bisphenol A-type E51 epoxy resin.
Described toughner is liquid polysulfide rubber, liquid acrylonitrile butadiene rubber or liquid styrene butadiene rubber.
Described reactive thinner is one or more in benzyl glycidyl ether, butylglycidyl ether, glycidyl allyl ether.
Described coupling agent is APTES.
Principle of the present invention is described as follows:
The present invention with the polyether monoamine solidifying agent of low viscous modified epoxy, low reaction heat for bonding base-material, take rubber elastomer as toughened system, with the high-wearing feature aggregate of certain grating for filler aggregate, be aided with multiple auxiliary agent, obtain the modified epoxy mortar resistant abrasion patching material with high compressive strength, high bond strength, high-impact-resistance wear-resistant, snappiness and toughness, high impact resistance.
Epoxy resin: present invention employs low viscous snappiness modified epoxy (bisphenol A-type E44 epoxy resin or bisphenol A-type E51 epoxy resin), it can carry out rational reduction when preparing epoxy resin to the hard section in polymer molecular structure and soft section, thus make cured article not only have good adhesive property, chemical mediator-resitant property, also there is high tenacity and high-elongation.
Solidifying agent: the solidifying agent that the present invention selects is polyether monoamine solidifying agent, after the solidification of such solidifying agent, system reaction heat is lower, curing reaction speed is slower, the presetting period of epoxy resin cure is longer, effectively can reduce exothermic heat of reaction peak and the original volume cure shrinkage of curing system, avoid the appearance of the early stage tiny crack of epoxy mortar, and without the need to using curing catalyst.
Toughner: the present invention is by liquid polysulfide rubber, liquid acrylonitrile butadiene rubber or liquid styrene butadiene rubber join epoxy curing agent system as toughner, in the curing process, toughner can form spheroidal particle, disperse phase is formed in cross linking of epoxy resin network external phase, namely " island structure " is formed, when being subject at a high speed containing sand current scour, in impact, under the comprehensive action of friction and cutting force, on the one hand, the particle of toughner originally consumes energy in material cracks process, on the other hand, " island structure " has transferred epoxy molecule network generation orientation, stretch, distortion, Voiding and produce many power consumption processes such as tiny crack, avoid the destruction of material, thus the fracture toughness property of material is increased, improve the resistant abrasion performance of material.
Abrasive aggregates: the present invention selects Young's modulus high, hardness is large, wear-resisting quartz sand or silicon carbide also carry out good grating, significantly improve anti-abrasion strength and the resistance to impact shock of epoxy mortar, wherein, the particle diameter composition of quartz sand graduation aggregate or silicon carbide graded aggregate and weight ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=0 ~ 1: 1 ~ 2: 0 ~ 2: 0 ~ 1, because the particle diameter of quartz sand graduation aggregate or silicon carbide graded aggregate is all between 10 ~ 200 orders, granularity is moderate, therefore etch resistant properties and the abrasion resistance of epoxy mortar can not be affected, simultaneously, the present invention has selected 10 ~ 20 orders, 20 ~ 40 orders, 40 ~ 70 orders, the aggregate of these four kinds of different-grain diameters of 100 ~ 200 orders, can regulate the composition of this aggregate and ratio according to the intensity needs of reality, use range is wider.
Embodiment 1:
A kind of modified epoxy mortar resistant abrasion patching material, this patching material comprises component A, B component, and the weight ratio of component A and B component is 4: 1, described component A composition and weight ratio be: epoxy resin 20, toughner 2, reactive thinner 3, abrasive aggregates 75, the composition of described B component and weight ratio thereof are: solidifying agent 24, coupling agent 1, abrasive aggregates 75, wherein, described solidifying agent is polyetheramine solidifying agent T-403, described abrasive aggregates is quartz sand graduation aggregate, the particle diameter composition of this aggregate and weight ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=1: 2: 2: 1, described epoxy resin is bisphenol A-type E44 epoxy resin or bisphenol A-type E51 epoxy resin, described toughner is liquid polysulfide rubber, liquid acrylonitrile butadiene rubber or liquid styrene butadiene rubber, described reactive thinner is benzyl glycidyl ether, butylglycidyl ether, one or more in glycidyl allyl ether, described coupling agent is APTES,
The preparation method of above-mentioned modified epoxy mortar resistant abrasion patching material comprises the following steps successively:
The preparation of component A: after epoxy resin and toughner, reactive thinner are stirred in required ratio, add abrasive aggregates, stir, obtain component A;
The preparation of B component: after solidifying agent, coupling agent are stirred in required ratio, add abrasive aggregates, stir, obtain B component;
The preparation of modified epoxy mortar resistant abrasion patching material: component A, B component are mixed in required ratio, can obtain modified epoxy mortar resistant abrasion patching material.
Obtained modified epoxy mortar resistant abrasion patching material carries out Mechanics Performance Testing with reference to " epoxy resin mortar technical regulation " DL/T5193-2004, result shows, tensile strength>=10.0MPa, ultimate compression strength>=90.0MPa, bending strength>=30.0MPa, with concrete adhesive tensile resistance intensity>=2.5MPa, punching mill intensity 3.563h/(g/cm 2), resistance to impact shock 32.4MPa.
Embodiment 2:
Step is with embodiment 1, unlike, described component A composition and weight ratio be: epoxy resin 15, toughner 1.5, reactive thinner 1.5, abrasive aggregates 82, the composition of described B component and weight ratio thereof are: solidifying agent 24, coupling agent 1, abrasive aggregates 75, wherein, described abrasive aggregates is quartz sand graduation aggregate, and the particle diameter composition of this aggregate and weight ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 order=1: 2: 1.
Obtained modified epoxy mortar resistant abrasion patching material carries out Mechanics Performance Testing with reference to " epoxy resin mortar technical regulation " DL/T5193-2004, result shows, tensile strength>=10.0MPa, ultimate compression strength>=90.0MPa, bending strength>=30.0MPa, with concrete adhesive tensile resistance intensity>=2.5MPa, punching mill intensity 3.863h/(g/cm 2), resistance to impact shock 39.8MPa.
Embodiment 3:
Step is with embodiment 1, unlike, described component A composition and weight ratio be: epoxy resin 15, toughner 1.5, reactive thinner 1.5, abrasive aggregates 85, the composition of described B component and weight ratio thereof are: solidifying agent 18, coupling agent 1.5, abrasive aggregates 80.5, wherein, described solidifying agent is polyetheramine solidifying agent D-230, described abrasive aggregates is silicon carbide graded aggregate, and the particle diameter composition of this aggregate and weight ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 order=1: 1: 2.
Obtained modified epoxy mortar resistant abrasion patching material carries out Mechanics Performance Testing with reference to " epoxy resin mortar technical regulation " DL/T5193-2004, result shows, tensile strength>=10.0MPa, ultimate compression strength>=90.0MPa, bending strength>=30.0MPa, with concrete adhesive tensile resistance intensity>=2.5MPa, punching mill intensity 3.274h/(g/cm 2), resistance to impact shock 36.5MPa.

Claims (4)

1. a modified epoxy mortar resistant abrasion patching material, is characterized in that:
This patching material comprises component A, B component, and the mass ratio of described component A and B component is 4: 1;
The composition of described component A and weight ratio thereof are: epoxy resin 15 ~ 20, toughner 1.5 ~ 2, reactive thinner 1.5 ~ 3, abrasive aggregates 75 ~ 82;
The composition of described B component and weight ratio thereof are: solidifying agent 18 ~ 24, coupling agent 1 ~ 1.5, abrasive aggregates 75 ~ 80;
Described abrasive aggregates is quartz sand graduation aggregate or silicon carbide graded aggregate, and the particle diameter composition of described quartz sand graduation aggregate or silicon carbide graded aggregate and mass ratio thereof are 10 ~ 20 orders: 20 ~ 40 orders: 40 ~ 70 orders: 100 ~ 200 order=0 ~ 1: 1 ~ 2: 0 ~ 2: 0 ~ 1;
Described solidifying agent is polyether monoamine solidifying agent;
Described epoxy resin is bisphenol A-type E44 epoxy resin or bisphenol A-type E51 epoxy resin;
Described toughner is liquid polysulfide rubber, liquid acrylonitrile butadiene rubber or liquid styrene butadiene rubber.
2. a kind of modified epoxy mortar resistant abrasion patching material according to claim 1, is characterized in that: described solidifying agent is polyetheramine solidifying agent T-403 or polyetheramine solidifying agent D-230.
3. a kind of modified epoxy mortar resistant abrasion patching material according to claim 1 and 2, is characterized in that: described reactive thinner is one or more in benzyl glycidyl ether, butylglycidyl ether, glycidyl allyl ether.
4. a kind of modified epoxy mortar resistant abrasion patching material according to claim 1 and 2, is characterized in that: described coupling agent is APTES.
CN201310413242.9A 2013-09-12 2013-09-12 A kind of modified epoxy mortar resistant abrasion patching material Active CN103482904B (en)

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Address after: No. 4, Wuda Science and Technology Park Road, Donghu Development Zone, Wuhan City, Hubei Province, 430223

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Patentee before: WUDA JUCHENG STRUCTURE Co.,Ltd.