CN103481599B - A kind of flexible decoration veneer - Google Patents
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Abstract
Description
技术领域 technical field
本发明属于木材加工行业,尤其涉及一种柔性装饰薄木。 The invention belongs to the wood processing industry, in particular to a flexible decorative veneer.
背景技术 Background technique
一般天然薄木或重组装饰薄木,尤其是微薄木都较脆、柔性不足、易开裂,不适用于异型构造面的装饰。柔性装饰薄木是在天然薄木或重组装饰薄木背面复合粘贴无纺布或牛皮纸等增强材料的可绕卷、柔韧性较好的装饰薄木。这样既增强了重组装饰单板的柔韧性,又增加了产品的整体厚度,节约了木材资源。该薄木可用于各类异型曲面的装饰贴面,也适合浅浮雕面的饰面,拓宽了传统薄木的应用范围。 General natural veneer or recombined decorative veneer, especially thin veneer is brittle, not flexible enough, and easy to crack, so it is not suitable for the decoration of special-shaped structural surfaces. Flexible decorative veneer is a reelable and flexible decorative veneer that is laminated with non-woven fabric or kraft paper and other reinforcing materials on the back of natural veneer or recombined decorative veneer. This not only enhances the flexibility of the recombined decorative veneer, but also increases the overall thickness of the product, saving wood resources. The veneer can be used for decorative veneering of various special-shaped curved surfaces, and is also suitable for veneering of bas-relief surfaces, which broadens the application range of traditional veneer.
现有技术木材加工行业常用的热压机为多层压机,而无纺布为布匹的卷筒状,因此需要将无纺布卷筒状展开,并根据薄木的长度裁切成片状,再按照常规的胶合板生产工艺进行施胶、粘贴、冷热压。由于无纺布进行辊筒施胶时,会卷进布胶机内,无法正常施胶,因此,有人采用喷胶方式进行施胶,如科技文献:《柔性人造装饰薄木制造工艺的研究》,李年存、向琴、杨灿明,中南林学院学报,2000年6月,第20卷第2期。 In the prior art, the hot press commonly used in the wood processing industry is a multi-layer press, and the non-woven fabric is in the form of a roll of cloth. Therefore, it is necessary to unroll the roll of the non-woven fabric and cut it into sheets according to the length of the veneer. Then, according to the conventional plywood production process, sizing, pasting, and hot and cold pressing are carried out. Since the non-woven fabric will be rolled into the gluing machine when the roller is sizing, it cannot be sizing normally. Therefore, some people use the glue spraying method to sizing, such as the scientific literature: "Research on the Manufacturing Process of Flexible Artificial Decorative Veneer", Li Niancun, Xiang Qin, Yang Canming, Journal of Central South Forestry University, June 2000, Volume 20, Issue 2.
上述文献采用固含量为55%(质量分数)的改性脲醛树脂胶为胶粘剂,并采用喷胶的方式进行施胶,存在胶粘剂成本高,需要改变常用辊涂施胶的工艺,操作要求高,易渗胶等缺陷。 The above literature uses modified urea-formaldehyde resin glue with a solid content of 55% (mass fraction) as the adhesive, and uses glue spraying for sizing. However, the cost of the adhesive is high, and the common roller coating sizing process needs to be changed, and the operation requirements are high. Easy to leak glue and other defects.
为此,在不改变施胶方式的前提下,采用将无纺布连续施胶的方式进行施胶,即先将无纺布展开,通过辊筒施胶后在布胶机的出口再卷筒,从而将无纺布拉紧绷直,避免卷进布胶机内。 For this reason, under the premise of not changing the sizing method, the method of continuously sizing the non-woven fabric is used for sizing, that is, the non-woven fabric is first unfolded, and after sizing by the roller, it is reeled at the exit of the gluing machine. , so that the non-woven fabric is stretched straight to avoid being rolled into the gluing machine.
上述工艺解决了无纺布施胶时卷进布胶机的问题,但是施胶后的无纺布卷筒时,胶粘剂会固化,使无纺布相互粘接,不能再次展开裁切成片状,不能进入下一道工序。因此,迫切需要一种能迅速表干,但不影响最终粘接强度的胶粘剂。 The above process solves the problem that the non-woven fabric is rolled into the glue machine when sizing, but when the non-woven fabric is rolled after sizing, the adhesive will be cured, so that the non-woven fabric is bonded to each other, and cannot be unfolded and cut into sheets again. , cannot enter the next process. Therefore, there is an urgent need for an adhesive that can dry quickly without affecting the final bond strength.
发明内容 Contents of the invention
为解决上述技术问题,本发明的目的是提供一种柔性装饰薄木,该方法采用一种胶粘剂,该胶粘剂具有迅速表干、粘接强度高、不易渗胶的特点,保证柔性装饰薄木的美观。 In order to solve the above technical problems, the object of the present invention is to provide a flexible decorative veneer. The method uses an adhesive, which has the characteristics of rapid surface drying, high bonding strength, and not easy to seep through, so as to ensure the appearance of the flexible decorative veneer.
为了实现上述的目的,本发明采用了以下的技术方案: In order to achieve the above object, the present invention adopts the following technical solutions:
一种柔性装饰薄木,该方法包括以下的步骤: A kind of flexible decorative veneer, the method comprises the following steps:
a、薄木整理:先对装饰薄木进行分等、分选; a. Veneer finishing: first classify and sort the decorative veneer;
b、调胶:将尿胶、白胶、面粉、木质素、阳离子表面活性剂五者按质量比进行混合,其质量配比为:尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:(40~60):(5~15):(5~15):(0.1~0.5);搅拌10~20分钟; B, glue adjustment: mix urine glue, white glue, flour, lignin, and cationic surfactant by mass ratio, and its mass ratio is: urine glue: white glue: flour: lignin: cationic surfactant =100:(40~60):(5~15):(5~15):(0.1~0.5); stir for 10~20 minutes;
c、施胶:对无纺布或牛皮纸进行滚筒施胶,施胶量控制在30~50g/m2; c. Sizing: Roller sizing of non-woven fabrics or kraft paper, the amount of sizing is controlled at 30-50g/m 2 ;
d、卷筒:将已施胶的无纺布或牛皮纸卷成筒状,便于裁剪; d. Roll: roll the glued non-woven fabric or kraft paper into a roll for easy cutting;
e、裁剪:将卷筒的无纺布或牛皮纸裁成所需长度规格; e. Cutting: Cut the roll of non-woven fabric or kraft paper into required length specifications;
f、铺装组合:将裁剪好的无纺布或牛皮纸和装饰薄木铺装组合成板坯; f. Pavement combination: combine the cut non-woven fabric or kraft paper and decorative veneer pavement into a slab;
g、热压:将上述板坯送入热压机进行热压,得到半成品; g, hot pressing: the above-mentioned slab is sent into a hot press for hot pressing to obtain a semi-finished product;
h、裁边分等打包:将上述半成品进行裁边,并按其外观质量进行分等,得到本产品,并打包入库。 h. Edge cutting and grading and packaging: Cut the above semi-finished products and grade them according to their appearance quality to obtain this product and pack it into the warehouse.
作为优选,所述的尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:(40~50):(5~10):(5~10):(0.1~0.2)。 Preferably, said urine glue: white glue: flour: lignin: cationic surfactant = 100: (40-50): (5-10): (5-10): (0.1-0.2).
作为优选,所述的尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:40:5:5:0.1。 As preferably, described urine glue: white glue: flour: lignin: cationic surfactant=100:40:5:5:0.1.
作为优选,所述的尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:(50~60):(10~15):(10~15):(0.2~0.5)。 Preferably, said urine glue: white glue: flour: lignin: cationic surfactant = 100: (50-60): (10-15): (10-15): (0.2-0.5).
作为优选,所述的尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:60:15:15:0.5。 As preferably, described urine glue: white glue: flour: lignin: cationic surfactant=100:60:15:15:0.5.
作为优选,所述的所述阳离子表面活性剂为十二烷基三甲基氯化铵或十六烷基二甲基苄基氯化铵。 Preferably, the cationic surfactant is dodecyltrimethylammonium chloride or cetyldimethylbenzylammonium chloride.
作为优选,所述的热压时温度为90~130℃,时间为30~120s,压力为0.7Mpa~1.1Mpa。 Preferably, during the hot pressing, the temperature is 90-130°C, the time is 30-120s, and the pressure is 0.7Mpa-1.1Mpa.
本发明由于采用了上述的技术方案,在采用的采用胶粘剂中木质素代替部分面粉,不仅能减少面粉的使用量,降低生产成本,而且能吸收胶粘剂中的部分游离甲醛,进一步降低柔性装饰薄木的甲醛释放量。阳离子表面活性剂具有化学稳定性良好,耐热、耐光、耐压、耐强酸强碱等特点,还具有优良的渗透性、乳化性、柔软性、抗静电性和杀菌等性能。阳离子表面活性剂的添加,不仅能使柔性装饰薄木的胶层具有一定的柔韧性,降低了胶层的脆性,避免柔性装饰薄木在使用过程中的破损,而且还能使柔性装饰薄木具有防霉、防腐的功能,延长了产品的使用寿命。采用上述胶粘剂配比,并且施胶量控制在30~50g/m2,在无纺布上施胶后易迅速表干,能将施好胶后的无纺布卷筒而不粘合起来,方便进入下一步工序;同时,热压成型后,胶水既不渗透至重组装饰单板上表面,也不渗透至无纺布下表面,不影响产品外观质量。本发明采用合理的胶粘剂配比及施胶量,解决了施胶后的无纺布卷筒时容易互相粘接,以及热压成型后产品表面的渗胶问题。 Due to the adoption of the above-mentioned technical scheme, the present invention uses lignin in the adhesive to replace part of the flour, which can not only reduce the amount of flour used, reduce production costs, but also absorb part of the free formaldehyde in the adhesive, further reducing the cost of flexible decorative veneer. Formaldehyde emission. Cationic surfactants have the characteristics of good chemical stability, heat resistance, light resistance, pressure resistance, strong acid and alkali resistance, etc., and also have excellent permeability, emulsification, softness, antistatic and bactericidal properties. The addition of cationic surfactants can not only make the adhesive layer of flexible decorative veneer have certain flexibility, reduce the brittleness of the adhesive layer, avoid the damage of flexible decorative veneer during use, but also make the flexible decorative veneer have mildew resistance. , anti-corrosion function, prolonging the service life of the product. Using the above adhesive ratio, and controlling the amount of sizing at 30-50g/m 2 , it is easy to dry quickly after sizing on the non-woven fabric, and the roll of non-woven fabric after gluing can be glued without bonding. It is convenient to enter the next process; at the same time, after hot pressing, the glue will neither penetrate into the upper surface of the restructured decorative veneer nor the lower surface of the non-woven fabric, which will not affect the appearance quality of the product. The invention adopts a reasonable adhesive ratio and sizing amount, and solves the problems of easy bonding of non-woven rolls after sizing and glue seepage on the surface of products after hot pressing.
采用本发明胶粘剂制得的产品达到国家标准Ⅱ类浸渍剥离试验要求,经(63±3)℃热水浸渍3h后,置于(63±3)℃干燥箱中干燥3h,胶层无剥离和分层现象。 The product prepared by using the adhesive of the present invention meets the requirements of the national standard II dipping and peeling test. After being soaked in hot water at (63±3)°C for 3 hours, it is placed in a drying oven at (63±3)°C for 3 hours, and the adhesive layer has no peeling and peeling. stratification phenomenon.
综上所述,本发明具有以下有益效果: In summary, the present invention has the following beneficial effects:
1、本发明具有迅速表干、粘接强度高、不易渗胶的特点; 1. The present invention has the characteristics of rapid surface drying, high bonding strength, and not easy to seep through;
2、本发明解决了柔性装饰薄木制造过程中,施胶后的无纺布卷筒时容易互相粘接的问题; 2. The present invention solves the problem that the non-woven rolls after gluing are easily bonded to each other during the manufacturing process of flexible decorative veneer;
3、本发明还解决了渗胶问题,保证柔性装饰薄木的美观。 3. The present invention also solves the problem of glue seepage and ensures the beauty of the flexible decorative veneer.
具体实施方式 Detailed ways
本具体实施例仅仅是对本发明的解释,其并不是对本发明的限制,本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改,但只要在本发明的权利要求范围内都受到专利法的保护。 This specific embodiment is only an explanation of the present invention, and it is not a limitation of the present invention. Those skilled in the art can make modifications to this embodiment without creative contribution as required after reading this specification, but as long as they are within the rights of the present invention All claims are protected by patent law.
实施例1Example 1
一种用于制造柔性装饰薄木的胶粘剂,该胶粘剂由尿胶、白胶、面粉、木质素、阳离子表面活性剂五者均匀混合而成,由于胶粘剂易受环境温度变化影响胶合强度,因此,在实际使用过程中,应当随季节变化调节胶粘剂配比。如:夏季,温度较高,胶粘剂固化较快,采用质量配比为:尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:40:5:5:0.1;而冬季温度较低,胶粘剂固化较慢,则采用质量配比为:尿胶:白胶:面粉:木质素:阳离子表面活性剂=100:60:15:15:0.5。上述的阳离子表面活性剂为十二烷基三甲基氯化铵或十六烷基二甲基苄基氯化铵。 An adhesive used to manufacture flexible decorative veneer, which is uniformly mixed with urine glue, white glue, flour, lignin, and cationic surfactants. Since the adhesive is easily affected by environmental temperature changes, the bonding strength is therefore, in In actual use, the adhesive ratio should be adjusted according to seasonal changes. For example: in summer, the temperature is higher, and the adhesive cures faster. The mass ratio is: urine glue: white glue: flour: lignin: cationic surfactant = 100:40:5:5:0.1; while the temperature in winter is lower , the adhesive solidifies slowly, and the mass ratio is: urine glue: white glue: flour: lignin: cationic surfactant=100:60:15:15:0.5. The above-mentioned cationic surfactant is lauryl trimethyl ammonium chloride or hexadecyl dimethyl benzyl ammonium chloride.
实施例2Example 2
使用本发明实施例1所述的胶粘剂制造柔性装饰薄木的工序如下: Use the adhesive described in the embodiment of the present invention 1 to manufacture the operation of flexible decorative veneer as follows:
a、薄木整理:先对装饰薄木进行分等、分选; a. Veneer finishing: first classify and sort the decorative veneer;
b、调胶:将尿胶、白胶、面粉、木质素、阳离子表面活性剂五者按质量比进行混合,搅拌10~20分钟; b. Glue adjustment: mix urine glue, white glue, flour, lignin, and cationic surfactant according to the mass ratio, and stir for 10 to 20 minutes;
c、施胶:对无纺布进行滚筒施胶,施胶量控制在30~50g/m2; c. Sizing: Roller sizing of non-woven fabrics, the amount of sizing is controlled at 30-50g/m 2 ;
d、卷筒:将已施胶的无纺布卷成筒状,便于裁剪; d. Roll: roll the non-woven fabric that has been glued into a roll for easy cutting;
e、裁剪:将卷筒的无纺布裁成所需长度规格; e. Cutting: Cut the non-woven fabric of the roll into the required length specification;
f、铺装组合:将裁剪好的无纺布和装饰薄木铺装组合成板坯; f. Pavement combination: combine the cut non-woven fabric and decorative veneer pavement into a slab;
g、热压:将上述板坯送入热压机进行热压,得到半成品,所述的热压时温度为90~130℃,时间为30~120s,压力为0.7Mpa~1.1Mpa; g. Hot pressing: send the above-mentioned slab into a hot pressing machine for hot pressing to obtain a semi-finished product. During the hot pressing, the temperature is 90-130°C, the time is 30-120s, and the pressure is 0.7Mpa-1.1Mpa;
h、裁边分等打包:将上述半成品进行裁边,并按其外观质量进行分等,得到本产品,并打包入库。 h. Edge cutting and grading and packaging: Cut the above semi-finished products and grade them according to their appearance quality to obtain this product and pack it into the warehouse.
采用本发明胶粘剂制得的产品达到国家标准Ⅱ类浸渍剥离试验要求,经(63±3)℃热水浸渍3h后,置于(63±3)℃干燥箱中干燥3h,胶层无剥离和分层现象。 The product prepared by using the adhesive of the present invention meets the requirements of the national standard II dipping and peeling test. After being soaked in hot water at (63±3)°C for 3 hours, it is placed in a drying oven at (63±3)°C for 3 hours, and the adhesive layer has no peeling and peeling. stratification phenomenon.
实施例3Example 3
使用本发明实施例1所述的胶粘剂制造柔性装饰薄木的工序如下: Use the adhesive described in the embodiment of the present invention 1 to manufacture the operation of flexible decorative veneer as follows:
a、薄木整理:先对装饰薄木进行分等、分选; a. Veneer finishing: first classify and sort the decorative veneer;
b、调胶:将尿胶、白胶、面粉、木质素、阳离子表面活性剂五者按质量比进行混合,搅拌10~20分钟; b. Glue adjustment: mix urine glue, white glue, flour, lignin, and cationic surfactant according to the mass ratio, and stir for 10 to 20 minutes;
c、施胶:对牛皮纸进行滚筒施胶,施胶量控制在30~50g/m2; c. Sizing: Roller sizing of kraft paper, the amount of sizing is controlled at 30-50g/m 2 ;
d、卷筒:将已施胶的牛皮纸卷成筒状,便于裁剪; d. Roll: roll the glued kraft paper into a roll for easy cutting;
e、裁剪:将卷筒的牛皮纸裁成所需长度规格; e. Cutting: Cut the roll of kraft paper into required length specifications;
f、铺装组合:将裁剪好的牛皮纸和装饰薄木铺装组合成板坯; f. Pavement combination: combine the cut kraft paper and decorative veneer pavement into a slab;
g、热压:将上述板坯送入热压机进行热压,得到半成品,所述的热压时温度为90~130℃,时间为30~120s,压力为0.7Mpa~1.1Mpa; g. Hot pressing: send the above-mentioned slab into a hot pressing machine for hot pressing to obtain a semi-finished product. During the hot pressing, the temperature is 90-130°C, the time is 30-120s, and the pressure is 0.7Mpa-1.1Mpa;
h、裁边分等打包:将上述半成品进行裁边,并按其外观质量进行分等,得到本产品,并打包入库。 h. Edge cutting and grading and packaging: Cut the above semi-finished products and grade them according to their appearance quality to obtain this product and pack it into the warehouse.
采用本发明胶粘剂制得的产品达到国家标准Ⅱ类浸渍剥离试验要求,经(63±3)℃热水浸渍3h后,置于(63±3)℃干燥箱中干燥3h,胶层无剥离和分层现象。 The product prepared by using the adhesive of the present invention meets the requirements of the national standard II dipping and peeling test. After being soaked in hot water at (63±3)°C for 3 hours, it is placed in a drying oven at (63±3)°C for 3 hours, and the adhesive layer has no peeling and peeling. stratification phenomenon.
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