[go: up one dir, main page]

CN103476994B - Water baffle system - Google Patents

Water baffle system Download PDF

Info

Publication number
CN103476994B
CN103476994B CN201280018233.3A CN201280018233A CN103476994B CN 103476994 B CN103476994 B CN 103476994B CN 201280018233 A CN201280018233 A CN 201280018233A CN 103476994 B CN103476994 B CN 103476994B
Authority
CN
China
Prior art keywords
fabric
barrier rib
water baffle
plastic body
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280018233.3A
Other languages
Chinese (zh)
Other versions
CN103476994A (en
Inventor
鲁洛夫·马里萨恩
迪特里克·维尼克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM IP Assets BV
Original Assignee
DSM IP Assets BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM IP Assets BV filed Critical DSM IP Assets BV
Publication of CN103476994A publication Critical patent/CN103476994A/en
Application granted granted Critical
Publication of CN103476994B publication Critical patent/CN103476994B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F7/00Devices affording protection against snow, sand drifts, side-wind effects, snowslides, avalanches or falling rocks; Anti-dazzle arrangements ; Sight-screens for roads, e.g. to mask accident site
    • E01F7/02Snow fences or similar devices, e.g. devices affording protection against sand drifts or side-wind effects
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B3/00Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
    • E02B3/04Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
    • E02B3/10Dams; Dykes; Sluice ways or other structures for dykes, dams, or the like
    • E02B3/102Permanently installed raisable dykes
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F7/00Devices affording protection against snow, sand drifts, side-wind effects, snowslides, avalanches or falling rocks; Anti-dazzle arrangements ; Sight-screens for roads, e.g. to mask accident site
    • E01F7/04Devices affording protection against snowslides, avalanches or falling rocks, e.g. avalanche preventing structures, galleries
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B15/00Cleaning or keeping clear the surface of open water; Apparatus therefor
    • E02B15/04Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
    • E02B15/08Devices for reducing the polluted area with or without additional devices for removing the material
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B15/00Cleaning or keeping clear the surface of open water; Apparatus therefor
    • E02B15/04Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
    • E02B15/08Devices for reducing the polluted area with or without additional devices for removing the material
    • E02B15/0814Devices for reducing the polluted area with or without additional devices for removing the material with underwater curtains
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B3/00Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
    • E02B3/04Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
    • E02B3/10Dams; Dykes; Sluice ways or other structures for dykes, dams, or the like
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B3/00Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
    • E02B3/04Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
    • E02B3/10Dams; Dykes; Sluice ways or other structures for dykes, dams, or the like
    • E02B3/102Permanently installed raisable dykes
    • E02B3/104Permanently installed raisable dykes with self-activating means

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Architecture (AREA)
  • Woven Fabrics (AREA)
  • Laminated Bodies (AREA)
  • Devices Affording Protection Of Roads Or Walls For Sound Insulation (AREA)

Abstract

The present invention relates to the water baffle system comprising barrier rib, for preventing material to the flowing of the side of the wall, wherein the barrier rib includes fabric, the fabric can prevent the infiltration of the fluid of the material and comprising high-strength polyolefin fiber.

Description

Water baffle system
Technical field
The present invention relates to the baffle system comprising barrier rib, it is used for preventing material to the flowing of the side of the wall, its Described in barrier rib include fabric.
Background technology
This baffle system is well known in the art, such as from US 4033137, it is disclosed that being used for accommodating The obstruct of oiliness leakage or other debris on the surface of water body.The obstruct can also include flat rectangular slab, the square Shape plate can be constituted by stretching in the impermeable fabric in rectangular shaped rim.
The content of the invention
However, known baffle system (such as presented above) can improve according to observations.Therefore, target of the invention The baffle system of improvement can be to provide and the obstruct system with suitable strength and/or mechanical stability is more specifically provided System.
The present invention provides the baffle system comprising barrier rib, for preventing material to the flowing of the side of the wall, wherein The barrier rib includes fabric, and the fabric can prevent the infiltration of the fluid of the material and comprising high-strength polyolefin fibre Dimension.
It has been observed that baffle system of the invention can prevent relative bulkrage (dust, rock, water, snow etc. Deng) flowing, and fault-free.Additionally, it has been observed that baffle system of the invention can maintain its original-shape, though temperature, Under the change of temperature and other environmental factors.Specifically, even if running into by material (such as those discussed above) miscarriage institute Raw multiple loads, baffle system of the invention can still maintain its original-shape.
Specific embodiment
In one embodiment, baffle system of the invention be used for preventing such as rock burst apart or snowslide in occur The flowing of rock or snow.Fabric for manufacturing the barrier rib of the system of the implementation method needs to prevent flowing and the snow of rock Flowing, but it is probably favourable some rocks or some wachtes is crossed rock wall for the reason for energy loss.This can be with Realized by using the fabric wherein with opening.
In another embodiment, baffle system of the invention is used for preventing the flowing of dust.
In further embodiment, baffle system of the invention is water baffle system, i.e., for preventing the flowing of water System.Preferably, the barrier rib that the system is included is comprising the fabric containing high-strength polyolefin fiber and is laminated to the fabric On forming the thermoplastic of waterproof barrier rib.
One advantage of baffle system of the invention can be its intensity and/or its resistance to tearing.It has been observed that even For example partly pierced through by floating object, sharp rock etc. when intercepting, the damage is still primarily retained in part.
In one preferred embodiment, baffle system of the invention is water baffle system, and it is included:
I. foundation structure, on sea bed to be protected or on ground;
Ii. be used for providing the floating object of buoyancy, wherein when the baffle system is not used, the floating object preferably by It is contained in the foundation structure or inside the foundation structure;
Iii. insert between foundation structure and floating object and connect the barrier rib of foundation structure and floating object;The barrier rib It is laminated comprising the fabric containing high-strength polyolefin fiber and preferably on the fabric to form the heat of waterproof barrier rib Plastic material;
Wherein when floating object is accommodated in the foundation structure or during foundation structure inside, the barrier rib is rolling over Folded mode is statically placed in the foundation structure or internal.Similar baffle system also from such as US 5154537, it is known that its It is fully incorporated herein by quoting.
Mooring device (Tiedown menas, such as rope, metal or synthesis chain or cable) can be connected simultaneously with barrier rib And be connected with the fixing point of (such as on the ground, sea bed or foundation structure on), by this way, water is applied on the wall Load is at least partly transferred to the device.
Another preferred embodiment in, baffle system of the invention is water baffle system, and it is used on flood Space of the horizontal barrier rib between the point at least two given intervals that be above the ground level is provided when rising, to prevent current direction institute The side of barrier rib is stated, the system is included:
I. shell structure, there is floating object to receive chamber and preferably at least one ground liquids access road for it, described to lead to Road has entrance and extends to from the top of the shell structure bottom of the chamber at the top of the housing, as a result ground liquid Body can fill the chamber when being allowed to;
Ii. the floating structure of the chamber, the size of the floating structure be adjusted to make its in the cavity from Bottom position (when anhydrous accumulation) in the chamber is to given level and upper and lower to upper position (when water rises) It is mobile;And
Iii. barrier rib, it is inserted between the floating structure and the chamber and connects floating structure with the chamber Room, wherein the barrier rib initially resides in horizon or following when the floating structure is in the nethermost position, and And when the floating structure position at an upper portion thereof, the barrier rib at least partly, preferably all higher than horizon.
Wherein described barrier rib is comprising the fabric containing high-strength polyolefin fiber and lamination on the fabric with formation The thermoplastic of waterproof barrier rib.Similar baffle system is also from such as US 5460462, it is known that it passes through to quote complete Portion is incorporated herein.
It has been observed that water baffle system of the invention is due to the flexible and thin cavity that may be accommodated in relatively smaller volume In, and also can fold in a compact fashion.In the case where protection is needed, can launch by within the relatively short time To dispose the system.Small size cavity comprising the obstruct can be used for storage, be built without interfering significantly with environment or surrounding Build, and during it may be included in structure, dike etc. on the bank.It can also be stored under water, for example with suitable distance away from The sea bed on bank, and do not reduce local water depth substantially, therefore ship movement possibility or coastal stress-relieving activity will not be damaged. But in a damaged condition, for example, notice tsunami temporarily, can be with arrangement baffle system of the invention and resistance of the invention Enough protections are provided every system.It has been observed that existing water baffle system is rigid and heavy, it is necessary to relatively large storage Cavity, thus may interfere with local building and other functions.However, water baffle system of the invention can mitigate this shortcoming.
According to the present invention, barrier rib includes high-strength polyolefin fiber.Fiber herein be interpreted as with length dimension and The slender bodies of lateral dimension (such as width and thickness), wherein length dimension is more much bigger than lateral dimension.Term fiber also includes Various implementation methods, such as silk thread, band, band, broadband, band and other analogs with rule or irregular cross section. Preferably, fiber has continuous length, has discontinuous length unlike chopped fiber.Yarn for the purpose of the present invention It is the slender bodies comprising multiple fibers.
In one preferred embodiment, polyolefine fiber is polyethylene fibre.When polyethylene fibre is HMW Polyethylene (HMWPE) fiber, more preferably super high molecular weight (UHMWPE) fiber when, can obtain good result.Polyethylene fiber Dimension can be by any technology as known in the art to manufacture, preferably by melt-spinning technology or gel spinning technique. If using melt-spinning technology, the polyethylene parent material manufactured for it preferably has 20000g/mol and 600000g/ Weight average molecular weight between mol, between more preferably 60000g/mol and 200000g/mol.One example of melt-spinning technology Disclosed in EP 1350868, it is incorporated herein by reference son.Most preferred polymer fiber is that the UHMWPE of gel spinning is fine Dimension, the trade name that for example DSM Dyneema are soldThose.When using gel spinning technique to manufacture When stating fiber, it is preferred to use the characteristic with preferably at least 3dl/g, more preferably at least 4dl/g, most preferably at least 5dl/g is glued Spend the UHMWPE of (IV).Preferably, IV is at most 40dl/g, more preferably up to 25dl/g, more preferably up to 15dl/g.It is excellent There is selection of land, UHMWPE every 100 C atoms to be less than 1 side chain less than 1 side chain, more preferably every 300 C atoms.It is preferred that Ground, gel spinning technique according to described in a large amount of publications manufactures UHMWPE fibers, and these publications include EP 0205960 A、EP 0213208 A1、US 4413110、GB 2042414 A、GB-A-2051667、EP 0200547 B1、EP 0472114 B1, WO 01/73173 A1, EP 1699954 and " Advanced Fibre Spinning Technology ", Ed.T.Nakajima,Woodhead Publ.Ltd(1994),ISBN 185573 182 7。
In a specific implementation, the polyolefine fiber according to used by the present invention has belt like shape, Huo Zhehuan Sentence is talked about, and the polyolefine fiber is polyolefm tape.Preferably described polyolefm tape is UHMWPE bands.For the present invention The band (or plane band) of purpose be cross-sectional aspect ratio (i.e. the ratio of width and thickness) preferably at least 5:1st, it is more excellent Selection of land at least 20:1st, even more preferably at least 100:1 and even more preferably still at least 1000:1 fiber.Band is preferred Ground has between 1mm and 600mm, between more preferably 1.5mm and 400mm, even more preferably still between 2mm and 300mm, also very To between the more preferably 5mm and 200mm and most preferably width between 10mm and 180mm.Band preferably has 10 μm And the thickness between 200 μm and between more preferably 15 μm and 100 μm.Cross-sectional aspect ratio herein is interpreted as width with thickness The ratio of degree.
Preferably, polyolefine fiber of the present invention has 0.5-20, more preferably 0.7-10, most preferably 1- Denier number (deniers) in the range of 5dpf.Yarn comprising the fiber preferably has 100-3000, more preferably Denier number in the range of 200-2500, most preferably 400-1000dtex.
High-strength polyolefin fiber herein is interpreted as having the polyolefin of for example, at least high tensile of 0.5GPa fine Dimension.The tensile strength of polyolefine fiber is preferably at least 1.2GPa, more preferably at least 2.5GPa, most preferably at least 3.5GPa.Preferably, polyolefine fiber is with preferably at least 1.2GPa, more preferably at least 2.5GPa, most preferably extremely The polyethylene fibre of the tensile strength of few 3.5GPa, more preferably UHMWPE fibers.With with like configurations but comprising by polyester, Other any systems of nylon or the fiber of aromatic polyamides manufacture are compared, and the baffle system comprising strong polyethylene fibres has more Good mechanical stability, weight is lighter, more solid.
Preferably, polyolefine fiber has preferably at least 30GPa, more preferably at least 50GPa, most preferably at least The stretch modulus of 60GPa.Preferably, polyolefine fiber is polyethylene fibre, more preferably UHMWPE fibers, wherein polyethylene fiber Dimension, the specifically stretch modulus of UHMWPE fibers are at least 50GPa, more preferably at least 60GPa, most preferably at least 80GPa. It has been observed that when according to the present invention using this high-strength polyethylene, more specifically this high intensity UHMWPE fibers, the present invention Baffle system can have good mechanical stability, good life-span, and can successfully bear sizable acting on External loads thereon.
In a preferred embodiment of the present invention, at least 80 mass % in the fiber that barrier rib is included, more preferably Ground at least 90 mass %, most preferably about 100 mass % are high-strength polyolefin fiber.It is highly preferred that the fibre that barrier rib is included At least 80 mass %, more preferably at least 90 mass % in dimension, most preferably 100 mass % are polyethylene fibre, more preferably Ground UHMWPE fibers.The fiber of residual mass % can be made up of other polymers fiber.It has been observed that by using comprising rising The barrier rib of the polyethylene fibre of quality %, the specifically wherein all of polymer fiber of use are all the obstruct of polyethylene fibre Wall, barrier rib of the invention can show good resistance, high-tear strength and the low weight degraded to sunlight and UV.
The high-strength polyolefin fiber included according to barrier rib used in the present invention forms fabric.The fabric can have There are known any construction in this area, such as woven (woven), knitting, weaving (plaited), braiding or nonwoven or its group Close.Knitting fabric can be that broadwise knitting (such as one side, reversible cloth) or warp-wise are knitting.One example of adhesive-bonded fabric It is felt fabric or fabric that wherein fiber is advanced in an essentially parallel fashion along a common aspect.Woven, knitting or nothing The other examples of yarn fabric and its manufacture method are described in " Handbook of Technical Textiles ", ISBN In 978-1-59124-651-0 the 4th, 5 and 6 chapters, the displosure is used as being incorporated herein by reference.The description of braided fabric and example are described In same Handbook Chapter 11, specifically in 11.4.1 sections, the disclosure of which is incorporated herein by reference.
Preferably, it is woven fabric according to fabric used in the present invention.Preferably, the woven fabric is long with per unit Degree is constructed with the weight of overall cross-sectional diameter very little.The preferred embodiment of woven fabric is knitted including plain (plain weave) Thing, burr braided fabric, basket braided fabric, twill weave fabric, square plain net eye braided fabric, brokentwlllweave (crow feet) Braided fabric and satin knit braided fabric, but can also use more complicated braided fabric, such as three-dimensional braided fabric.More preferably Ground, woven fabric is plain weave fabric, it is highly preferred that woven fabric is square plain net eye braided fabric.Preferably, for preparing The fiber of woven fabric is band, and more preferably they are the fibers with circular cross section, and the aspect ratio of the cross section is At most 4:1st, 2 are more preferably at most:1.
According to certain embodiments of the present invention, barrier rib can also include thermoplastic, particularly when of the invention When baffle system is used as water baffle system.However, it is preferred that for all of the embodiments of the present invention, barrier rib is comprising warm Plastic material.The non-limiting example of suitable thermoplastic includes polyolefin (such as low density polyethylene (LDPE) and high density Polyethylene), it is Ethyl vinylacetate, polyurethane, polyethylene kind, polyacrylic, polybutylene terephthalate (PBT) (PBT), poly- Acid amides, makrolon, or thermoplastic elastomer block copolymer, for example polyisoprene-polyethylene-butylene-polystyrene or Polystyrene-polyisoprene-polystyrene block copolymer.Other suitable thermoplastics are recited in such as WO 91/ In 12136 A1 (the 15-21 pages), it is incorporated herein by reference.Thermoplastic is in turn laminated to the fabric that barrier rib is included On, so that the fluid of the anti-such as material of water, snow, dust, rock etc. of the wall.Preferably, thermoplastic is plastic body. The plastic body is preferably the hypocrystalline copolymerization of ethene or propylene and one or more alpha-olefin comonomer of C2 to C12 Thing, and the plastic body has the 860 and 930kg/m measured according to ISO11833Between density
Preferably, barrier rib includes fabric, and wherein plastic body preferably impregnates the whole fabric.The dipping can be with Various forms and mode are carried out, such as by lamination or by making plastic body through the yarn of fabric by force in such as hot pressing And/or fiber.The side of the fabric for preparing impregnated is disclosed in such as US 5773373, US 6864195 and US 6054178 The example of method, these patents are incorporated herein by reference.These methods can be routinely (all according to the material for being used of the invention Such as fiber, plastic body) and change.
When plastic body has at most 0.6GPa, more preferably up to 0.4GPa, the most preferably at most stretching die of 0.2GPa During amount, the result that can be obtained.Preferably, the plastic body has at least 0.01GPa, more preferably at least 0.05GPa, most The preferably at least stretch modulus of 0.1GPa.
It has been observed that when use this impregnated fabric as baffle system of the invention barrier rib when, the system Mechanical stability improved.Specifically, under external loads the elongation of system and/or its with the time shrinkage factor most It is small.
A preferred example suitable for barrier rib of the invention is the barrier rib comprising woven fabric, described woven to knit Thing includes high-strength polyethylene fiber, more preferably high intensity UHMWPE fibers and the fabric impregnated of plastic body, the plasticity Body is ethene or propylene and one or more semi-crystalline co-polymers of the alpha-olefin comonomer of C2 to C12, and wherein described Plastic body has the 860 and 930kg/m measured according to ISO11833Between density.When baffle system of the invention is comprising this During barrier rib, the system can show enhanced tear resistance;Good processability;With excellent chemical resistance and fire resisting Property.Specifically, the impregnated woven fabric comprising polyethylene fibre and/or yarn shows excellent weight and strength ratio Example, they are lightweight and more solid than any impregnated fabric comprising such as polyester, nylon or aramid fibre.
One of the invention preferred embodiment in, barrier rib is included:
I () fabric, preferably woven fabric, it includes containing polyethylene fibre, the yarn of preferably UHMWPE fibers;
(ii) adhere to the plastomer layer at least one surface of the woven fabric, wherein the plastic body be ethene or Propylene and one or more semi-crystalline co-polymers of the alpha-olefin comonomer of C2 to C12, and wherein described plastic body has According to the 860 and 930kg/m that ISO1183 is measured3Between density.
The present inventors have noted that, when baffle system of the invention includes this barrier rib, the system is except can be with table Reveal outside above-mentioned advantage, appropriate anti-contracility can also be shown, especially in long-term use.It was additionally observed that the system weight Measure gently, with good tear resistance and fracture strength high.It was additionally observed that, when it is used in cold environment, the system System is caused damage (such as cracking etc.) influence smaller by low temperature.
Preferably, barrier rib is included:
I () woven fabric, it includes containing polyethylene fibre, the yarn of preferably UHMWPE fibers;
(ii) plastic body, the plastic body is with the Part I on surface for adhering to the woven fabric and impregnated in Part II between the yarn and/or fiber of the fabric, the Part II extend to the whole fabric and with it is described Part I bonds together;And wherein described plastic body is ethene or propylene and one or more alpha-olefin of C2 to C12 The semi-crystalline co-polymers of comonomer, and wherein described plastic body has the 860 and 930kg/m measured according to ISO11833It Between density.
It will be further noted that arrive, when plastomer layer adheres to two surfaces of woven fabric so as to be sealed the fabric, Baffle system of the invention is also wanted more preferable anti-contracility.Therefore, in one preferred embodiment, barrier rib bag Contain:
(i) woven fabric, it has a upper and lower surface, and comprising containing polyethylene fibre, preferably UHMWPE The yarn of fiber;
(ii) plastomer layer of the fabric is encapsulated, the plastomer layer has and adheres to first of the upper surface Point;Adhere to the Part III of the lower surface;And impregnated between the yarn and/or fiber of the fabric and extend whole The Part II of the individual fabric, the Part II is bonded in the Part I and Part III of the plastomer layer Together;Wherein described plastic body is that ethene or propylene and one or more hypocrystalline of the alpha-olefin comonomer of C2 to C12 are total to Polymers, and wherein described plastic body has the 860 and 930kg/m measured according to ISO11833Between density.
Preferably, the Part II impregnated between yarn and between fiber.The Part II of plastomer layer also prolongs The whole fabric is stretched in, this refers to lateral dimension of the plastic body along fabric and the vertical dimension along fabric is distributed in its table Between face.Preferably, impregnated, so that the Part II of plastomer layer is along longitudinal size a from table of fabric Face extends to surface corresponding thereto.
As used herein, " plastomer layer adheres to fabric face " is interpreted as plastic body by physics forceful grip (grip) fiber of the fabric for contacting.However, for the present invention, the actual surface for being chemically bound in fiber of plastic body Not necessarily.It has been observed that compared with other kinds of thermoplastic, the plastic body according to used by the present invention is in such as poly- second There is increased grasping on alkene fiber.In one preferred embodiment, the surface of polyethylene fibre is corrugated, with prominent Thing or hole or other irregular surface textures are played, so as to improve the grasping between plastic body and fiber.
" two parts for bonding together of plastomer layer " are understood herein to described partially fused turn into together Single main body, so that do not form line of demarcation between these portions preferably, and preferably in whole plastomer layer not There is mechanical performance or the essential difference of other physical properties.
Self-evidently, " upper surface " and " lower surface " is only used for distinctive two surfaces of identification woven fabric, and not Should be construed to woven fabric practically is defined into certain to place up or down.
Preferred woven fabric used according to the invention is with least 1.5, more preferably at least 2, most preferably at least 3 The fabric of coverage coefficient.Preferably, the coverage coefficient is at most 30, more preferably up to 20, most preferably at most 10.According to sight Examine, the use of this fabric causes the optimal dipping of woven fabric, make the amount of space that such as barrier rib is included or air pocket most It is small.It was additionally observed that, barrier rib evenly is obtained, machine of the baffle system of the invention with smaller localized variation is assigned in turn Tool performance and more preferable shape stability.For example the fiber can be passed through by making the plastic body of melting by force under elevated pressure And/or yarn realizes the dipping of plastic body.
Plastic body used according to the invention is plastic material, and it belongs to thermoplastic class.According to the present invention, the modeling Gonosome is the semicrystalline copolymers of ethene or propylene and the alpha-olefin comonomer of one or more of C2 to C12, the modeling The density of gonosome is 880-930kg/m3.It has been observed that when plastic body is prepared by single-point catalyst polymerization, it is preferably described When plastic body is metallocene-plastomer (that is, the plastic body for being prepared by metallocene single-site catalysts), comprising this plastic body Barrier rib shows good anti-contracility.Ethene be propylene copolymer in particularly preferred comonomer, and butylene, hexene It is the preferred alpha-olefin comonomer for ethylene copolymer and propylene copolymer with octene.
In one preferred embodiment, the plastic body is the thermoplastic copolymer of ethene or propylene, the copolymer Comprising one or more of with the 2-12 alpha-olefin of carbon atom (particularly ethene, isobutene, 1- butylene, 1- hexenes, 4- first Base -1- amylenes and 1- octenes) as comonomer.When the 'alpha '-olefin monomers conduct for using ethene and one or more of C3-C12 During comonomer, in copolymer the amount of comonomer generally between l-50 weight %, be preferably ranges between 5-35 weight % it Between.In the case of ethylene copolymer, preferred comonomer is 1- octenes, the amount of the comonomer between 5 weight % and Between 25 weight %, between more preferably 15 weight % and 20 weight %.In the case of propylene copolymer, the amount of comonomer, Particularly the amount of ethylene comonomer generally between l-50 weight %, between preferably 2-35 weight %, more preferably 5-20 Between weight %.When the density of plastic body is between 880-920kg/m3Between, be more preferably between 880-910kg/m3Between when, receive Contracting aspect will obtain good result.
When the DSC Peak melting points of the plastic body according to used by the present invention that ASTM D3418 are determined are between 70 DEG C and 120 DEG C Between, be preferably between 70 DEG C and 100 DEG C, be more preferably between when between 70 DEG C and 95 DEG C, can obtain more preferable anti-contracility.
The plastic body that is prepared by single-point catalyst polymerization, particularly metallocene-plastomer with by other polymerization techniques The difference of ethylene copolymer and propylene copolymer prepared by (such as Ziegler-Natta catalysis) is its specific density (specific density).The plastic body also because of narrower molecular weight distribution (Mw/Mn) and limited amount long chain branching and Other are differentiated it from, the value of wherein molecular weight distribution is preferably 1.5-3.Preferably, the quantity of long-chain branch is every 1000 Carbon atom at most 3.Can be used for according to the present invention with barrier rib and with metallocene type catalyst obtain it is suitable Plastic body is commercial mass production, for example respectively with trade (brand) name Exact, Exceed, Vistamaxx, Tafmer, Engage, Affinity and Versify are produced by DEXPlastomers, ExxonMobil, Mitsui and DOW.Plastic body, particularly cyclopentadienyl The explanation of plastic deformation body and the general introduction of its mechanical performance and physical property can be edited in such as Harutun G.Karian " Handbook of polypropylene and polypropylene composites " (ISBN 0-8247-4064- 5) found in the 7.2nd chapter, more specifically in its sub- chapters and sections 7.2.1;7.2.2;In 7.2.5 to 7.2.7, they are by drawing With being contained in this.
Can also use comprising the plastic body according to used by the present invention and other thermoplastics and/or even other plasticity The composition of body grade.At one preferred embodiment, the polyolefin comprising plastic body and functionalization used according to the invention Blend.Preferably, 1 weight %-99 weight %, more preferably of the amount of the polyolefin of functionalization between blend weight 2.5 weight %-50 weight %, more preferably 5 weight %-25 weight %.Preferably, the polyolefin of functionalization is by bifunctional monomer Carry out functionalization, the amount of the bifunctional monomer is between 0.1 weight %-10 weight %, more preferably 0.35 of the weight of polyolefin Weight %-5 weight %, most preferably 0.7 weight %-1.5 weight %.Preferably, the polyolefin for functionalization is also plasticity Body, more preferably described polyolefin is plastic body used according to the invention.Preferably, with bifunctional monomer (such as maleic acid Acid anhydride (MA) or vinyltrimethoxy silane (VTMOS)) will be Polyolefin Functionalized.The polyolefin of MA and VTMOS functionalizations is Commercially available product, and the functionalization of polyolefin can carry out according to procedures known in the art, such as in extruding During, using peroxide as initiator.Use the polyolefin of functionalization, the advantage of the preferably plastic body of functionalization It is that the mechanical stability of barrier rib used according to the invention can be improved.
When barrier rib used according to the invention includes fabric, preferably woven fabric, and wherein select plastic body Amount, the AD of the fabric to produce surface density (AD) used than wherein is high by least 20%, when being more preferably up to few 50% barrier rib, Good anti-contracility can be obtained.Preferably, the surface density (AD) of the barrier rib fabric more used than wherein, preferably woven fabric AD up to many 500%, more preferably up to many 400%, most preferably up to many 300%.When plastic body is sealed fabric (preferably Woven fabric) and by it is indicated above select the amount of plastic body when, obtain good result.AD is with kg/m2Represent, and It is by weighing certain area (0.01m2) weight and gained weight is obtained divided by the area of the sample.
Plastic body according to used by the present invention can also include the various fillers and/or additive for defining below.At one In preferred embodiment, barrier rib is comprising woven fabric as defined above, plastomer layer and optionally comprising fixed below The various fillers and/or additive that are added to plastic body of justice.It is preferable, however, that plastic body is free of any filler and/or addition Agent.It has been observed that when baffle system of the invention includes the barrier rib according to the implementation method, the system can show to shrink Reduce simultaneously solid and lightweight.Additionally, the barrier rib is easy to by thermal weld along joint seal, this will provide stronger Sealing, and cause save total time and cost.
The example of filler includes reinforcing material and non-reinforcing material, such as carbon black, calcium carbonate, clay, silica, mica, cunning Stone and glass.The example of additive is including stabilizer (such as UV stabilizer), pigment, antioxidant, fire retardant etc..Preferred resistance Combustion agent is including aluminum trihydrate, dehydration magnesium and ammonium polyphosphate etc..Preferably, the amount of fire retardant barrier rib of the invention is included 1-60 weight %, the more preferably 5-30 weight % of the amount of thermoplastic.Most preferred fire retardant be ammonium phosphate (for example Budenheim (Budit) and Clariant (Exolit) are provided).
The fabric of lamination can be prepared according to procedures known in the art.The example of methods described is in US 5773373 and US Disclosed in 6054178, these patents are incorporated herein by reference.Preferably, the fabric of lamination, the party are prepared by laminating method For example disclosed in US 4679519, the patent is incorporated herein by reference method, and methods described is according to material used in the present invention Expect and routinely change.
Preferably, the thickness of barrier rib is between 0.2mm and 10mm, more preferably between 0.3mm and 5mm.It is described The AD of barrier rib is preferably in 0.2kg/m2And 3kg/m2Between, more preferably in 0.2kg/m2And 2kg/m2Between.
When barrier rib is comprising the woven fabric encapsulated by plastic body, the fabric may be located at the center of the barrier rib Or offset from center.When fabric as much as possible positioned at barrier rib it is central when, the good result in terms of contraction can be obtained.
Preferably, the total shrinkage (average shrinkage ratio i.e. on the warp-wise of woven fabric and weft direction) of barrier rib is less than 1.5%th, more preferably less than 1.2%, even more preferably less than 1.0%, to be also even more preferably less than 0.8%, will also be even more Preferably smaller than 0.6%, more preferably less than 0.45%.Total shrinkage is public according to " method of testing " part institute behind file of the present invention The method opened is determined.Preferably, barrier rib is being less than 1%, more preferably less than 0.6% through upward shrinkage factor.Preferably, originally Shrinkage factor of the flexible sheet material of invention in broadwise is less than 1%, more preferably less than 0.5%.
The present invention, but not limited to this are further illustrated by the following examples.
Method of testing
IV:The characteristic of UHMWPE is determined according to method PTC-179 (Hercules Inc.Rev.1982 April 29) Viscosity (IV), test condition is:At 135 DEG C, in decahydronaphthalenes, dissolution time is 16 hours, and it is 2g/l solution to use consumption DBPC as antioxidant, the viscosity that the viscosity extrapolation that will be measured under various concentrations is obtained under zero-dose.
Coverage coefficient:By by the average number and single volume of single braided fabric yarn per cm on warp-wise and broadwise The square root of the line density (in terms of tex) of woven fabric yarn is multiplied and calculates the coverage coefficient of woven fabric divided by 10.It is single Braided fabric yarn can include produced monofilament, or it can include the multiple yarns for being produced, will Cheng Qian was woven The yarn is assembled into single braided fabric yarn.In the case of the latter, the line density of single braided fabric yarn is to be given birth to The summation of the line density of the yarn of product.Therefore, it can calculate coverage coefficient (CF) according to following formula:
Wherein m is the average number of single braided fabric yarn per cm, and p is to be assembled into being given birth to for braided fabric yarn The number of the yarn of product, t is the line density (in terms of tex) of produced yarn, and T be single braided fabric yarn line it is close Degree is (in terms of tex).
Dtex:The Dtex of fiber is measured by weighing 100 meters of fibers.Counted divided by 10 by by the weight in terms of milligram Calculate the dtex of fiber.
Shrinkage factor:By length be 0.4 meter and width is that 0.4 meter of square sample is placed in the roller of washing machine, In the case of in the absence of water, at about 23 DEG C of temperature and about 65% humidity, with 60 revs/min of rotating speed and 5 clay balls Rotate 72 hours together.The quality of each clay ball is 0.22Kg, and diameter is for about 50mm, is somebody's turn to do by the way that ball to be put into just be only capable of to accommodate The cotton bag of ball and the surface of each ball is covered by bafta.The size of sample before and after measurement processing, and its difference (being represented with %) is considered as the shrinkage factor of representative sample.
The tensile property of polymer fiber(i.e. intensity and modulus):Surveyed on polyfilament yarn according to the regulation of ASTM D885M It is fixed, use fiber, the crosshead speed of 50%/min and Fibre Grip D5618C types that nominal gauge length is 500mm The fixtures of Instron 2714.In order to calculate intensity, by measured tensile force, divided by fiber number, (fiber number is by weighing 10 meters long Fiber determines), its value is in units of GPa, it is assumed that the natural density of polymer such as UHMWPE is 0.97g/cm3To calculate.
The tensile property of polymeric tapes:Definition and surveyed on band 2mm wide at 25 DEG C according to the regulation of ASTM D882 Determine tensile strength and stretch modulus, use band, the crosshead speed of 50mm/min that nominal gauge length is 440mm.
Inorfil, specifically glass fibreTensile strength and modulus:Surveyed at 22 DEG C according to ASTM D4018-81 It is fixed.
The stretch modulus of thermoplastic:Determined at 25 DEG C according to ASTM D-638 (84).
Embodiment and contrast experiment
Embodiment
It is 0.193kg/m with AD2, thickness about 0.6mm, about 1.72 meters of width and comprising 880 dtex be referred to asThe basket braided fabric of the polyethylene yarn of SK 65 prepares barrier rib, the fabric impregnated of 0203。0203 is the plastic body from DEXPlastomers, and is have about 18% octane, density for 902kg/ m3And DSC Peak melting points are 95 DEG C of vinyl octane plastic body.Plastic body is melted and flowed out at a temperature of about 145 DEG C On the surface of fabric.
Apply the pressure of about 45bars, so that plastic body is impregnated into fabric at about 120 DEG C.
In order to coat two surfaces of woven fabric, said process is repeated.The barrier rib for being obtained has the thickness of about 0.8mm Degree, 0.550kg/m2AD and the space less than 40%.The AD of wall is that the AD280% of woven fabric is high.Plastomer layer is designed Into:
● one surface A D about 0.17kg/m of covering2Part I;
● Part II of the dipping through fabric between its yarn and fiber;
● another surface A D of covering is for about 0.175kg/m2Part III.
Result is shown in Table 1.
Sample Through upward shrinkage factor (%) Shrinkage factor (%) in broadwise Total shrinkage (%)
Embodiment 0.96 0.42 0.69

Claims (16)

1. a kind of water baffle system, it includes barrier rib, for preventing material to the flowing of the side of the wall, wherein the resistance Next door includes fabric, and the fabric can prevent the infiltration of the fluid of the material and comprising high-strength polyolefin fiber, described Fabric is impregnated with thermoplastic, and the thermoplastic is plastic body, and the plastic body is ethene or propylene and one kind Or the semi-crystalline co-polymers of the alpha-olefin comonomer of various C2 to C12, and the plastic body have measured according to ISO1183 860 and 930kg/m3Between density, to form waterproof barrier rib, wherein the water resistance is included every system:
I. foundation structure, on sea bed to be protected or on ground;
Ii. it is used for providing the floating object of buoyancy;
Iii. insert between the foundation structure and the floating object and connect the obstruct of the foundation structure and the floating object Wall;
Wherein when the baffle system is not used, floating object is accommodated in the foundation structure or inside the foundation structure, And the barrier rib is statically placed in the foundation structure or internal in a folded fashion.
2. water baffle system as claimed in claim 1, it provides the horizontal barrier rib that is above the ground level in flood rise, described Space of the barrier rib between the point at least two given intervals, to prevent the side of current direction barrier rib, the system bag Contain:
I. shell structure, there is floating object to receive chamber for it;
Ii. the floating structure of the chamber, the size of the floating structure is adjusted to make it in the cavity from anhydrous Bottom position during accumulation in the chamber is moved up and down to given level and to the upper position when water rises;And
Iii. barrier rib, it is inserted between the floating structure and the chamber and connects floating structure and the chamber, its In when the floating structure is in the nethermost position barrier rib initially reside in horizon or following, and work as institute State floating structure at an upper portion thereof position when, the barrier rib at least partly be higher than horizon;
Wherein described barrier rib is comprising the fabric containing high-strength polyolefin fiber and lamination on the fabric with formation The thermoplastic of waterproof barrier rib.
3. water baffle system as claimed in claim 2, it also includes at least one ground liquids access road, and the passage exists The top of the housing has entrance and the bottom of the chamber is extended to from shell structure top, so that ground liquids exist The chamber can be filled when being allowed to.
4. water baffle system as claimed in claim 1, wherein the polyolefine fiber is polyethylene fibre.
5. water baffle system as claimed in claim 1, wherein the polyolefine fiber is ultra-high molecular weight polyethylene (UHMWPE) fiber.
6. water baffle system as claimed in claim 1, wherein the polyolefine fiber has belt like shape.
7. water baffle system as claimed in claim 1, wherein the polyolefine fiber has at least tensile strength of 0.5GPa.
8. water baffle system as claimed in claim 1, wherein the polyolefine fiber has at least stretch modulus of 30GPa.
9. water baffle system as claimed in claim 1, wherein the fabric is selected from the group by constituting as follows:Woven fabric, pin Woven fabric, textile fabric, braided fabric, adhesive-bonded fabric with and combinations thereof.
10. water baffle system as claimed in claim 1, wherein the fabric is the woven fabric selected from following group, it is described Group is made up of plain weave fabric and square plain net eye braided fabric.
11. water baffle systems as claimed in claim 1, wherein the fabric and the modeling with the at most stretch modulus of 0.6GPa Gonosome is laminated.
12. water baffle systems as claimed in claim 1, wherein the fabric is with the woven of at least 1.5 coverage coefficient Fabric.
13. water baffle systems as claimed in claim 1, wherein the fabric is laminated with plastic body, the plastic body be comprising There is the 2-12 alpha-olefin of carbon atom as the ethene of comonomer or the thermoplastic copolymer of propylene for one or more.
14. water baffle systems as claimed in claim 1, wherein the fabric is laminated with plastic body, the plastic body be comprising One or more second as comonomer in ethene, isobutene, 1- butylene, 1- hexenes, 4-methyl-1-pentene and 1- octenes The thermoplastic copolymer of alkene or propylene.
15. water baffle systems as claimed in claim 1, wherein the fabric is woven fabric, the fabric and plastomer layer Merge and wherein select the amount of the plastic body to obtain surface density (AD) at least 20% resistance higher than the AD of the woven fabric Next door.
16. water baffle systems as claimed in claim 1, wherein the thickness of the barrier rib is 0.2mm-10mm.
CN201280018233.3A 2011-04-12 2012-04-10 Water baffle system Expired - Fee Related CN103476994B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11162076.1 2011-04-12
EP11162076 2011-04-12
PCT/EP2012/056461 WO2012140017A1 (en) 2011-04-12 2012-04-10 Barrier system

Publications (2)

Publication Number Publication Date
CN103476994A CN103476994A (en) 2013-12-25
CN103476994B true CN103476994B (en) 2017-07-07

Family

ID=44535925

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280018233.3A Expired - Fee Related CN103476994B (en) 2011-04-12 2012-04-10 Water baffle system

Country Status (5)

Country Link
US (1) US20140186118A1 (en)
EP (1) EP2697436A1 (en)
JP (1) JP6175705B2 (en)
CN (1) CN103476994B (en)
WO (1) WO2012140017A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9670635B1 (en) * 2016-01-22 2017-06-06 Viconic Sporting Llc System for managing rainfall
JP2018035567A (en) * 2016-08-31 2018-03-08 積水化学工業株式会社 Cutoff material, cutoff structure and cutoff method
US20180216869A1 (en) * 2017-02-01 2018-08-02 Nathan Allan Lipinski Defrost indicator
FR3093118B1 (en) * 2019-02-21 2021-02-19 C H A B Sheath formed by at least one circular knit for the realization of a reinforced concrete pile

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US495788A (en) * 1893-04-18 Louis debarle
US3456265A (en) * 1967-08-15 1969-07-22 Walter H Carnahan Swimming pools
US4033137A (en) 1973-07-12 1977-07-05 Geist James J Articulated floating barrier
IT1192624B (en) * 1978-07-28 1988-04-27 Colamussi Arturo MANEUVERABLE MOBILE BARRIER IN RUBBERIZED FABRIC WITH RECALL SYSTEM
NL177840C (en) 1979-02-08 1989-10-16 Stamicarbon METHOD FOR MANUFACTURING A POLYTHENE THREAD
NL177759B (en) 1979-06-27 1985-06-17 Stamicarbon METHOD OF MANUFACTURING A POLYTHYTHREAD, AND POLYTHYTHREAD THEREFORE OBTAINED
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4679519A (en) 1984-11-26 1987-07-14 Linville James C Laminated cloth construction
US4663101A (en) 1985-01-11 1987-05-05 Allied Corporation Shaped polyethylene articles of intermediate molecular weight and high modulus
WO1986004936A1 (en) 1985-02-15 1986-08-28 Toray Industries, Inc. Polyethylene multifilament yarn
JPH06102846B2 (en) 1985-05-01 1994-12-14 三井石油化学工業株式会社 Method for producing ultra-high molecular weight polyethylene stretched product
EP0205960B1 (en) * 1985-06-17 1990-10-24 AlliedSignal Inc. Very low creep, ultra high moduls, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber
NL9120011A (en) 1990-02-16 1992-12-01 Allied Signal Inc Ballistic-resistant thermosetting resin-impregnated fabric - wound into roll with interleaving separation film before curing resin
US5154537A (en) * 1991-05-28 1992-10-13 The United States Of America As Represented By The Secretary Of The Navy Barrier curtain
CA2113151A1 (en) * 1993-01-25 1994-07-26 Stacy W. Byrd Multi-layer waterproofing articles including a layer of water-soluble polymer and method
US5460462A (en) 1993-09-09 1995-10-24 Regan; Patrick Liquid and flood water barrier wall forming-apparatus
JPH0797809A (en) * 1993-09-29 1995-04-11 Sumitomo Electric Ind Ltd Fish path
JPH08120574A (en) * 1994-10-20 1996-05-14 Takao Shoji:Kk Work cloth and protective material using the same
WO1996026067A1 (en) 1995-02-21 1996-08-29 Serrot Corporation Fabric mesh reinforced monolithic thermoplastic membrane
US5773373A (en) 1996-06-18 1998-06-30 Reef Industries, Inc. Reinforced laminate with elastomeric tie layer
US6818091B1 (en) * 1997-10-24 2004-11-16 Jhrg, Llc Cut and puncture resistant laminated fabric
US6448359B1 (en) 2000-03-27 2002-09-10 Honeywell International Inc. High tenacity, high modulus filament
EP1350868B1 (en) 2000-12-11 2007-06-27 Toyo Boseki Kabushiki Kaisha High strength polyethylene fiber
JP4000513B2 (en) * 2002-05-31 2007-10-31 株式会社不動テトラ High tide prevention sluice
US6864195B2 (en) 2002-08-15 2005-03-08 Bfs Diversified Products, Llc Heat weldable roofing membrane
GB0314864D0 (en) * 2003-06-26 2003-07-30 Taylor Andrew C Flood barrier
RU2361021C2 (en) 2004-01-01 2009-07-10 ДСМ АйПи ЭССЕТС Б.В. Method of obtaining complex fibre from high-quality polyetylene
JP4322697B2 (en) * 2004-02-13 2009-09-02 功一 高野 Inundation prevention device
WO2006094552A1 (en) * 2005-03-03 2006-09-14 Dms V.O.F. Liquid-fillable barrier
GB2435664B (en) * 2006-03-03 2011-05-04 Meiklewall Scotland Ltd Barrier apparatus
US7449105B2 (en) * 2006-07-19 2008-11-11 Denny Hastings Flp 14 Water filtration and erosion control system
US7763556B2 (en) * 2007-01-24 2010-07-27 Honeywell International Inc. Hurricane resistant composites
JP2008184694A (en) * 2007-01-26 2008-08-14 Unitica Fibers Ltd Fiber aggregate for civil engineering works and construction
US7763555B2 (en) * 2007-08-27 2010-07-27 Honeywell International Inc. Hurricane resistant composites
GB2458941A (en) * 2008-04-04 2009-10-07 Ekspan Ltd Inflatable flood prevention barrier
DE102008036752A1 (en) * 2008-08-07 2010-02-11 Aleksej Limonow System for protection of flood, has barrier insurmountable for floodwater, which consists of two parallel collapsible walls in vertical direction

Also Published As

Publication number Publication date
JP2014517164A (en) 2014-07-17
CN103476994A (en) 2013-12-25
EP2697436A1 (en) 2014-02-19
US20140186118A1 (en) 2014-07-03
WO2012140017A1 (en) 2012-10-18
JP6175705B2 (en) 2017-08-09

Similar Documents

Publication Publication Date Title
CN103442882B (en) Inflation radome
CN102574377B (en) The preparation method and applications of flexible sheet material, the sheet material
CN103314460B (en) Flexible generator
CN103476994B (en) Water baffle system
CN104159730A (en) Composite panel
CN111542663B (en) Artificial turf system
CN106715785A (en) Space frame radome comprising a polymeric sheet

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170707

Termination date: 20190410