CN103474425B - The miniature flexible LED area array device of high uniformity of luminance and preparation method - Google Patents
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Abstract
Description
技术领域technical field
本发明属于发光显示技术领域,涉及一种新型微型柔性发光器件,具体地说是一种AlGaInP-LED柔性微器件及制作方法。The invention belongs to the technical field of light emitting display, and relates to a novel micro flexible light emitting device, in particular to an AlGaInP-LED flexible micro device and a manufacturing method.
背景技术Background technique
近年来,随着电子产业的发展,微型发光器件发展迅速。平面型LED微显示阵列相比传统发光器件具有很多不可比拟的优点,但由于其不能弯曲的特点很大程度上限制了其应用范围。OLED技术虽然有良好的应用前景,但相比于LED,仍有一些不足,例如在微小型器件方面,还存在一定问题,如发光亮度、均匀性、发光效率等不如LED,而最为突出的是寿命问题,这些问题会较大程度地限制OLED的应用和发展。随着科学技术的发展,对可以实现高分辨、明亮持久且轻薄并能应用在弯曲表面的微型柔性LED显示阵列的需求越来越迫切。In recent years, with the development of the electronic industry, micro light emitting devices have developed rapidly. Compared with traditional light-emitting devices, planar LED microdisplay arrays have many incomparable advantages, but their application range is largely limited due to their inflexibility. Although OLED technology has good application prospects, compared with LED, there are still some shortcomings. For example, there are still some problems in micro-miniature devices, such as luminous brightness, uniformity, and luminous efficiency. Lifespan issues, these issues will limit the application and development of OLED to a large extent. With the development of science and technology, there is an increasingly urgent demand for micro-flexible LED display arrays that can achieve high resolution, bright and durable, and are thin and light, and can be applied to curved surfaces.
发明内容Contents of the invention
本发明要解决的问题是提供基于石墨烯柔性电极的微型柔性LED显示器件,该器件具有柔性的金属电极和发光单元之间的柔性连接材料,具有易于弯曲和易于携带的特点。The problem to be solved by the present invention is to provide a micro-flexible LED display device based on graphene flexible electrodes, which has flexible connection materials between metal electrodes and light-emitting units, and is easy to bend and easy to carry.
高均匀性的微型柔性LED面阵器件,包括透光层、发光层、反射层、基片、上电极、上电极引线、下电极、下电极引线、柔性区域和微透镜;所述反射层上面依次为发光层、透光层、上电极和微透镜,反射层的下面为基片;所述透光层、发光层、反射层和基片的组成LED发光单元,多个LED发光单元均匀排布组成发光单元阵列;所述多个LED发光单元之间为柔性区域,柔性区域使各个发光单元依次连接并使LED发光单元阵列可弯曲;所述透光层的上表面排布有上电极,柔性材料的上表面排布有上电极引线,处于同一行的上电极与上电极引线依次相连接,在基片的下表面排布有下电极,处于同一列的下电极通过下电极引线连接;所述下电极和下电极引线组成的下引线列与上电极和上电极引线组成的上引线行在排列方向上异面垂直,所述上电极和上电极引线的材料为石墨烯。High uniformity miniature flexible LED area array device, including a light-transmitting layer, a light-emitting layer, a reflective layer, a substrate, an upper electrode, an upper electrode lead, a lower electrode, a lower electrode lead, a flexible region and a microlens; The light-emitting layer, the light-transmitting layer, the upper electrode and the micro-lens are in sequence, and the substrate is below the reflective layer; the light-transmitting layer, the light-emitting layer, the reflecting layer and the substrate are composed of an LED light-emitting unit, and a plurality of LED light-emitting units are evenly arranged. An array of light-emitting units is formed; among the plurality of LED light-emitting units is a flexible area, and the flexible area connects each light-emitting unit in sequence and makes the array of LED light-emitting units bendable; an upper electrode is arranged on the upper surface of the light-transmitting layer, The upper surface of the flexible material is arranged with upper electrode leads, the upper electrodes in the same row are connected to the upper electrode leads in turn, and the lower surface of the substrate is arranged with lower electrodes, and the lower electrodes in the same column are connected through the lower electrode leads; The lower lead column composed of the lower electrode and the lower electrode lead and the upper lead row composed of the upper electrode and the upper electrode lead are perpendicular to each other in the arrangement direction, and the material of the upper electrode and the upper electrode lead is graphene.
高均匀性的微型柔性LED面阵器件的制备方法,该方法由以下步骤实现:A method for preparing a micro-flexible LED area array device with high uniformity, the method is realized by the following steps:
步骤一、发光芯片的清洗及正面保护;首先,选择发光芯片,所述发光芯片由透光层、发光层、反射层和基片组成;然后,对发光芯片进行清洗,并在所述的发光芯片的透光层的上表面制备一层上保护膜;Step 1. Cleaning and front protection of the light-emitting chip; first, select the light-emitting chip, which is composed of a light-transmitting layer, a light-emitting layer, a reflective layer and a substrate; then, clean the light-emitting chip, and Prepare a layer of upper protective film on the upper surface of the light-transmitting layer of the chip;
步骤二、上隔离沟槽的制备;通过光刻和腐蚀上保护膜,露出柔性区域的窗口图形,即上隔离沟槽图形;在上保护膜和光刻胶的掩蔽下对发光芯片上表面进行湿法腐蚀或ICP刻蚀,去除柔性区域的发光芯片材料,形成一定深度的上隔离沟槽;Step 2, preparation of the upper isolation trench; through photolithography and etching of the upper protective film, the window pattern of the flexible area is exposed, that is, the upper isolation trench pattern; under the cover of the upper protective film and photoresist, the upper surface of the light-emitting chip is Wet etching or ICP etching removes the light-emitting chip material in the flexible area and forms an upper isolation trench with a certain depth;
步骤三、上隔离沟槽的填充;Step 3, filling the upper isolation trench;
步骤三一、在制备有上隔离沟槽的发光芯片的上表面涂覆柔性材料,并进行预固化;Step 31: Coating a flexible material on the upper surface of the light-emitting chip prepared with the upper isolation trench, and performing pre-curing;
步骤三二、通过光刻及腐蚀工艺去除透光层上表面的柔性材料,并通过去胶及再次腐蚀使所形成的填充材料上表面的形成凹陷形状;Step 32, removing the flexible material on the upper surface of the light-transmitting layer through photolithography and etching, and forming a concave shape on the upper surface of the formed filling material by removing glue and etching again;
步骤三三、完成柔性材料的完全固化,去除上保护膜;Step 33, complete the complete curing of the flexible material, and remove the upper protective film;
步骤四、在发光芯片的上表面进行石墨烯透明柔性上电极及上电极引线的制备;Step 4, preparing a graphene transparent and flexible upper electrode and upper electrode leads on the upper surface of the light-emitting chip;
步骤五、制备微透镜;在完成上电极和上电极引线的发光芯片上制备高粘附力的聚合物层,通过热熔法得到聚合物微透镜;Step 5, preparing a microlens; preparing a high-adhesion polymer layer on the light-emitting chip with the upper electrode and the upper electrode lead, and obtaining a polymer microlens by a hot-melt method;
步骤六、发光芯片的正面固定;采用粘接剂将发光芯片的上表面固定在上保护片上;Step 6, the front of the light-emitting chip is fixed; the upper surface of the light-emitting chip is fixed on the upper protective sheet with an adhesive;
步骤七、发光芯片的背面减薄;对发光芯片的基片的下表面进行减薄,然后进行抛光处理;Step 7, the back surface of the light-emitting chip is thinned; the lower surface of the substrate of the light-emitting chip is thinned, and then polished;
步骤八、发光芯片的像素分割,获得多个LED发光单元;Step 8, pixel segmentation of the light-emitting chip to obtain multiple LED light-emitting units;
步骤八一、在完成抛光的发光芯片的基片下表面制备下保护膜;Step 81, preparing a lower protective film on the lower surface of the polished light-emitting chip substrate;
步骤八二、通过双面对准光刻和腐蚀保护膜,露出柔性区域窗口;Step 82, exposing the flexible area window by aligning the photolithography and etching the protective film on both sides;
步骤八三、在下保护膜和光刻胶的掩蔽下对发光芯片的下表面进行刻蚀,完全去除柔性区域的发光芯片材料,实现发光芯片的像素分割,获得多个LED发光单元;Step 83: Etching the lower surface of the light-emitting chip under the cover of the lower protective film and photoresist, completely removing the material of the light-emitting chip in the flexible area, realizing pixel division of the light-emitting chip, and obtaining multiple LED light-emitting units;
步骤八四、去除下保护膜;Step 84, removing the lower protective film;
步骤九、制备下电极及下电极引线,在发光芯片的背面制备下电极及下电极引线,去除上保护片,制作电路引线,完成LED器件的制作。Step 9: Prepare the lower electrode and the lower electrode lead, prepare the lower electrode and the lower electrode lead on the back of the light-emitting chip, remove the upper protective sheet, make the circuit lead, and complete the production of the LED device.
本发明的有益效果:本发明微型柔性LED显示器件的工作过程是,电流从上电极注入,从下电极流出,在器件中形成电场,使得正负载流子在发光层复合发光。其中部分光向上经过透光层,从微透镜射出;部分光向下到达反射层,被反射层反射,穿过发光层、透光层,从微透镜射出。由于该发光器件的发光原理为p-n结内的载流子复合发光,具有二极管电流电压的非线性特性,发光亮度也随注入电流的大小具有非线性特性。本发明通过电路控制相素元的亮暗,实现发光显示。本发明提出的柔性器件由于具有柔性的电极结构和沟槽内的连接柔性材料,可以实现弯曲显示的功能,且这种器件的制作工艺简单易行。本发明提出的器件采用异面垂直的上、下电极,并采用柔性透明的石墨烯上电极,可以在理论上得到较高的发光效率,并且可以得到较为均匀的电流分布。Beneficial effects of the present invention: the working process of the miniature flexible LED display device of the present invention is that current is injected from the upper electrode and flows out from the lower electrode, forming an electric field in the device, so that positive load carriers recombine and emit light in the light-emitting layer. Part of the light goes upward through the light-transmitting layer and exits from the microlens; part of the light reaches down to the reflective layer, is reflected by the reflective layer, passes through the light-emitting layer and the light-transmitting layer, and exits from the microlens. Since the luminescence principle of the light-emitting device is the recombination of carriers in the p-n junction, it has the nonlinear characteristics of diode current and voltage, and the luminous brightness also has nonlinear characteristics with the magnitude of the injected current. The invention controls the brightness and darkness of the phase elements through a circuit to realize luminescent display. The flexible device proposed by the present invention can realize the function of bending display due to the flexible electrode structure and the connecting flexible material in the groove, and the manufacturing process of this device is simple and easy. The device proposed by the present invention adopts vertical upper and lower electrodes with different planes and a flexible and transparent graphene upper electrode, which can theoretically obtain higher luminous efficiency and more uniform current distribution.
附图说明Description of drawings
图1是本发明所述的高均匀性的微型柔性LED面阵器件的效果图。其中,图1a为器件的伸展状态,图1b为器件的弯曲状态。Fig. 1 is an effect diagram of the high-uniformity miniature flexible LED area array device described in the present invention. Among them, Fig. 1a is the stretched state of the device, and Fig. 1b is the bent state of the device.
图2中图2a为本发明所述的高均匀性的微型柔性LED面阵器件的主剖面图,图2b为本发明微型柔性LED显示器件的左剖面图。In Fig. 2, Fig. 2a is a main cross-sectional view of the highly uniform micro-flexible LED array device of the present invention, and Fig. 2b is a left-side cross-sectional view of the micro-flexible LED display device of the present invention.
图3为本发明所述的高均匀性的微型柔性LED面阵器件中采用方形发光单元的发光单元分布图。Fig. 3 is a distribution diagram of light-emitting units using square light-emitting units in the high-uniformity micro-flexible LED area array device of the present invention.
图4中图4a和图4b为本发明所述的高均匀性的微型柔性LED面阵器件中采用方形发光单元的两种上电极及上电极引线结构示意图;Fig. 4a and Fig. 4b in Fig. 4 are schematic diagrams of two kinds of upper electrodes and upper electrode lead structures using square light-emitting units in the high-uniformity micro-flexible LED area array device of the present invention;
图5中图5a至图5d为本发明所述的高均匀性的微型柔性LED面阵器件中采用方形发光单元的四种下电极及下电极引线结构示意图。Fig. 5a to Fig. 5d in Fig. 5 are schematic diagrams of four kinds of lower electrodes and lower electrode lead wire structures using square light-emitting units in the high-uniformity micro-flexible LED area array device according to the present invention.
图6为本发明所述的高均匀性的微型柔性LED面阵器件中采用圆形发光单元的发光单元分布图。Fig. 6 is a distribution diagram of light-emitting units using circular light-emitting units in the high-uniformity micro-flexible LED area array device of the present invention.
图7中图7a和图7b为本发明所述的高均匀性的微型柔性LED面阵器件中采用圆形发光单元的两种上电极及上电极引线结构示意图。Fig. 7a and Fig. 7b in Fig. 7 are schematic diagrams of two types of upper electrodes and upper electrode lead structures using circular light-emitting units in the high-uniformity micro-flexible LED area array device of the present invention.
图8中图8a至图8d为本发明所述的高均匀性的微型柔性LED面阵器件中采用圆形发光单元的四种下电极及下电极引线结构示意图。8a to 8d in FIG. 8 are schematic diagrams of four types of lower electrodes and lower electrode lead wire structures using circular light-emitting units in the high-uniformity micro-flexible LED area array device of the present invention.
图9中图9a至图9m为本发明所述的高均匀性的微型柔性LED面阵器件的制作方法的基本工艺步骤;其中,图9n和图9o为采用本发明的方法获得器件的左视剖面图,和正视剖面图。Figures 9a to 9m in Figure 9 are the basic process steps of the manufacturing method of the high-uniformity micro-flexible LED array device according to the present invention; among them, Figure 9n and Figure 9o are the left side views of the device obtained by the method of the present invention sectional view, and front sectional view.
图10为本发明所述的高均匀性的微型柔性LED面阵器件的另一种结构示意图。FIG. 10 is another structural schematic diagram of the high-uniformity miniature flexible LED array device of the present invention.
具体实施方式detailed description
具体实施方式一、结合图1至图8说明本实施方式,本实施方式所述的高均匀性的微型柔性LED面阵器件包括:透光层1、发光层2、反射层3、基片4、上电极5、上电极引线9、下电极6、下电极引线10、柔性区域7和微透镜8;反射层3的上面依次为发光层2、透光层1、上电极5和微透镜8,反射层3的下面是基片4。透光层1、发光层2、反射层3和基片4组成LED发光单元。LED发光单元均匀排布组成发光单元阵列。发光单元之间为柔性区域7,柔性区域7使各个发光单元依次连接并使整个LED发光单元阵列可弯曲。透光层1的上表面排布有上电极5,柔性区域7的上表面排布有上电极引线9,处于同一排的上电极5与上电极引线9依次相连接,在基片4的下表面排布有下电极6,在像素间的柔性材料接近下表面的区域排布有下电极引线10,处于同一列的下电极6与下电极引线10依次相连接,下电极6的形状为矩形、圆形、单条形、双条形或其它形状。下电极6与下电极引线10组成的下引线列与上电极5及上电极引线9组成的上引线排在方向上异面垂直。所述上电极5和上电极引线9的材料为石墨烯薄膜。Specific Embodiments 1. This embodiment is described in conjunction with FIGS. 1 to 8. The highly uniform micro-flexible LED area array device described in this embodiment includes: a light-transmitting layer 1, a light-emitting layer 2, a reflective layer 3, and a substrate 4 , upper electrode 5, upper electrode lead 9, lower electrode 6, lower electrode lead 10, flexible region 7 and microlens 8; above the reflective layer 3 are light emitting layer 2, light-transmitting layer 1, upper electrode 5 and microlens 8 , the reflective layer 3 is the substrate 4 below. The light-transmitting layer 1, the light-emitting layer 2, the reflective layer 3 and the substrate 4 form an LED light-emitting unit. The LED light-emitting units are uniformly arranged to form a light-emitting unit array. There is a flexible area 7 between the light emitting units, and the flexible area 7 connects each light emitting unit sequentially and makes the entire LED light emitting unit array bendable. The upper surface of the light-transmitting layer 1 is arranged with an upper electrode 5, and the upper surface of the flexible region 7 is arranged with an upper electrode lead 9. A lower electrode 6 is arranged on the surface, and a lower electrode lead 10 is arranged in the area where the flexible material between the pixels is close to the lower surface, and the lower electrodes 6 in the same row are connected with the lower electrode lead 10 in turn, and the shape of the lower electrode 6 is rectangular , circle, single bar, double bar or other shapes. The lower lead row composed of the lower electrode 6 and the lower electrode lead 10 and the upper lead row composed of the upper electrode 5 and the upper electrode lead 9 are perpendicular to each other in different directions. The material of the upper electrode 5 and the upper electrode lead 9 is a graphene film.
本实施方式所述的发光单元为正方形、矩形、圆形或其他形状。上电极5形状为回形、圆环形、单条形、双条形或其它形状。本实施方式中还包括位于LED发光单元的基片4下表面的柔性区域7,即背面柔性材料层,所述背面柔性材料层覆盖下电极6和下电极引线10。The light emitting unit described in this embodiment is square, rectangular, circular or other shapes. The shape of the upper electrode 5 is circular, circular, single strip, double strip or other shapes. This embodiment also includes a flexible area 7 located on the lower surface of the substrate 4 of the LED light-emitting unit, that is, the back flexible material layer, and the back flexible material layer covers the lower electrode 6 and the lower electrode lead 10 .
本实施方式所述的透光层1、发光层2、反射层3、基片4为由传统工艺制作的通用AlGaInPLED外延片材料。上电极5及上电极引线9的材料为石墨烯薄膜,下电极14、下电极引线15的材料为石墨烯,或为由Cr/Au、Ti/Pt/Au、Ti/Mo/Au、AuGeNi/Au、Al或Cu中的任意一种,或为由Cr/Au、Ti/Pt/Au、Ti/Mo/Au或AuGeNi/Au与Cu组成的复合膜,或为由Cr/Au、Ti/Pt/Au、Ti/Mo/Au或AuGeNi/Au与Au组成的复合膜。柔性区域7材料为聚酰亚胺或柔性环氧树脂或易涂覆成型的其它柔性材料,微透镜8材料为硬质环氧树脂或PDMS或其它高透过率材料。The light-transmitting layer 1 , light-emitting layer 2 , reflective layer 3 , and substrate 4 described in this embodiment are general-purpose AlGaInPLED epitaxial wafer materials produced by conventional techniques. The material of upper electrode 5 and upper electrode lead 9 is graphene thin film, and the material of lower electrode 14, lower electrode lead 15 is graphene, or is by Cr/Au, Ti/Pt/Au, Ti/Mo/Au, AuGeNi/ Any one of Au, Al or Cu, or a composite film composed of Cr/Au, Ti/Pt/Au, Ti/Mo/Au or AuGeNi/Au and Cu, or a composite film composed of Cr/Au, Ti/Pt /Au, Ti/Mo/Au or AuGeNi/Au and Au composite film. The material of the flexible area 7 is polyimide or flexible epoxy resin or other flexible materials that are easy to be coated and molded, and the material of the microlens 8 is hard epoxy resin or PDMS or other high transmittance materials.
具体实施方式二、结合图9和图10说明本实施方式,本实施方式所述的高均匀性的微型柔性LED面阵器件采用自上而下的制作方法,先制作正面结构,然后,再保护正面结构,制备背面结构。具体过程为:Specific Embodiment 2. This embodiment is described with reference to FIG. 9 and FIG. 10. The high-uniformity micro-flexible LED area array device described in this embodiment adopts a top-down manufacturing method, firstly fabricating the front structure, and then protecting For the front structure, prepare the back structure. The specific process is:
A.发光芯片的清洗及正面保护:A. Cleaning and front protection of light-emitting chips:
a)本发明使用的基质材料为发光芯片,所用的发光芯片由透光层、发光层、反射层和基片构成,如图9a所示。a) The matrix material used in the present invention is a light-emitting chip, and the light-emitting chip used is composed of a light-transmitting layer, a light-emitting layer, a reflective layer and a substrate, as shown in FIG. 9a.
b)进行发光芯片的清洗。然后在发光芯片的上表面,即透光层上表面制备一层上保护膜,如图9b所示。b) Cleaning the light-emitting chip. Then prepare a layer of upper protective film on the upper surface of the light-emitting chip, that is, the upper surface of the light-transmitting layer, as shown in FIG. 9b.
B.上隔离沟槽的制备:B. Preparation of upper isolation trench:
通过光刻和腐蚀上保护膜,露出柔性区域窗口图形,亦即上隔离沟槽图形。在上保护膜和光刻胶的掩蔽下对发光芯片上表面进行湿法腐蚀或ICP刻蚀,去除柔性区域的发光芯片材料,形成一定深度的上隔离沟槽,如图9c所示。Through photolithography and corrosion of the upper protective film, the window pattern of the flexible area is exposed, that is, the pattern of the upper isolation trench. Wet etching or ICP etching is performed on the upper surface of the light-emitting chip under the cover of the upper protective film and photoresist to remove the material of the light-emitting chip in the flexible region and form an upper isolation trench with a certain depth, as shown in FIG. 9c.
C.上隔离沟槽的填充:C. Filling of the upper isolation trench:
a)在制备有上隔离沟槽的发光芯片上表面涂覆柔性材料,并进行预固化,如图9d所示。a) Coating a flexible material on the upper surface of the light-emitting chip prepared with the upper isolation trench, and performing pre-curing, as shown in FIG. 9d.
b)通过光刻及腐蚀工艺去除透光层上表面的柔性材料。并通过去胶及再次腐蚀使所形成的填充材料上表面的形成凹陷形状,以便有利于附着在其上的上电极具有可弯曲性能。b) removing the flexible material on the upper surface of the light-transmitting layer through photolithography and etching processes. And the upper surface of the formed filling material is formed into a concave shape by removing glue and corroding again, so as to facilitate the upper electrode attached thereon to have a bendable property.
c)完成柔性材料的完全固化。c) Complete curing of the flexible material.
d)去除上保护膜,如图9e。d) Remove the upper protective film, as shown in Figure 9e.
D.石墨烯透明柔性上电极及上电极引线的制备:D. Preparation of graphene transparent and flexible upper electrode and upper electrode lead:
进行石墨烯材料的发光单元上柔性上电极引线和发光单元外柔性上电极引线的制作,如图9f所示。Fabricate flexible upper electrode leads on the light emitting unit of graphene material and flexible upper electrode leads outside the light emitting unit, as shown in FIG. 9f.
E.制备微透镜:E. Fabrication of microlenses:
在完成发光单元上上电极引线和发光单元外上电极引线的发光芯片上制备高粘附力的聚合物层,通过热熔法得到聚合物微透镜,如图9g所示。A polymer layer with high adhesion is prepared on the light-emitting chip with the upper electrode lead on the light-emitting unit and the upper electrode lead outside the light-emitting unit, and a polymer microlens is obtained by hot-melting, as shown in FIG. 9g.
F.发光芯片的正面固定:F. Fixation of the front side of the light-emitting chip:
为了对制备上部结构的发光芯片进行保护,将其用粘接剂固定在上保护片上,图9h为完成正面固定的发光芯片。In order to protect the light-emitting chip with the upper structure prepared, it is fixed on the upper protective sheet with an adhesive, and FIG. 9h shows the light-emitting chip with the front side fixed.
G.发光芯片的背面减薄,即对发光芯片的下表面进行减薄:对整个发光芯片的下表面进行减薄,减薄至所需厚度后,进行抛光处理,如图9i所示。G. Thinning the back surface of the light-emitting chip, that is, thinning the lower surface of the light-emitting chip: thinning the lower surface of the entire light-emitting chip to a required thickness, and then performing polishing treatment, as shown in FIG. 9i.
H.发光芯片的像素分割:H. Pixel segmentation of light-emitting chips:
a)在完成抛光的发光芯片背面制备下保护膜。a) Prepare a lower protective film on the back of the polished light-emitting chip.
b)通过双面对准光刻和腐蚀保护膜,露出柔性区域窗口,如图9j所示。b) By double-side alignment photolithography and etching the protective film, the flexible area window is exposed, as shown in Fig. 9j.
c)在下保护膜和光刻胶的掩蔽下对发光芯片上表面进行刻蚀,完全去除柔性区域的发光芯片材料,实现发光芯片的像素分割,如图9k所示。c) Etching the upper surface of the light-emitting chip under the mask of the lower protective film and the photoresist to completely remove the material of the light-emitting chip in the flexible region to realize pixel segmentation of the light-emitting chip, as shown in FIG. 9k.
d)去除下保护膜。d) Remove the lower protective film.
I.制备下电极及下电极引线:I. Preparation of lower electrode and lower electrode lead:
制备薄膜下电极及下电极引线;或厚膜下电极及下电极引线,如图9l所示。Prepare thin-film lower electrodes and lower electrode leads; or thick-film lower electrodes and lower electrode leads, as shown in FIG. 9l.
J.制备背面柔性材料:J. Preparation of back flexible material:
在做好下电极及下电极引线的基片下表面制备背面柔性材料,如图9m所示。A back flexible material is prepared on the lower surface of the substrate on which the lower electrode and the lower electrode leads are prepared, as shown in FIG. 9m.
K.去除上保护片,图9n为左视剖面图。图9o为正视剖面图。制作电路引线,完成器件制作。K. Remove the upper protective sheet, Fig. 9n is a cross-sectional view from the left. Figure 9o is a front sectional view. Make circuit leads to complete device fabrication.
结合图10说明本实施方式,图10a和10b分别为不含有背面柔性材料层的LED显示器件左剖面图和主剖面图。This embodiment will be described with reference to FIG. 10 . FIGS. 10 a and 10 b are a left sectional view and a main sectional view of an LED display device without a back flexible material layer, respectively.
具体实施方式三、本实施方式为具体实施方式二所述的高均匀性的微型柔性LED面阵器件的制备方法的实施例:具体方法为:Specific implementation mode three. This implementation mode is an example of the preparation method of the highly uniform miniature flexible LED area array device described in the specific implementation mode two: the specific method is:
A.发光芯片的清洗及正面保护:A. Cleaning and front protection of light-emitting chips:
a)本发明使用的发光芯片为AlGaInP-LED外延片,由透光层、发光层、反射层和基片构成,发光芯片的厚度在200μm~1000μm。a) The light-emitting chip used in the present invention is an AlGaInP-LED epitaxial wafer, which is composed of a light-transmitting layer, a light-emitting layer, a reflective layer and a substrate, and the thickness of the light-emitting chip is 200 μm to 1000 μm.
b)上保护膜材料为二氧化硅或氮化硅或二氧化硅与氮化硅组成的复合膜或金属或有机材料或无机材料或其它能起到保护作用的薄膜材料。保护膜制备方法为电子束蒸发或射频溅射或磁控溅射或溶胶凝胶法或其它薄膜生长方法。b) The material of the upper protective film is silicon dioxide or silicon nitride or a composite film composed of silicon dioxide and silicon nitride or metal or organic material or inorganic material or other film materials that can play a protective role. The preparation method of the protective film is electron beam evaporation, radio frequency sputtering, magnetron sputtering, sol-gel method or other film growth methods.
B.上隔离沟槽的制备:B. Preparation of upper isolation trench:
a)通过光刻工艺在上保护膜上形成柔性区域光刻胶窗口图形,亦即上隔离沟槽图形。a) Forming a photoresist window pattern in the flexible region, that is, an upper isolation trench pattern, on the upper protective film through a photolithography process.
b)在光刻胶的保护下通过干法刻蚀或湿法腐蚀工艺得到保护膜的上隔离沟槽图形。光刻胶厚度为0.2μm-15μm。b) obtaining the upper isolation groove pattern of the protective film by dry etching or wet etching under the protection of the photoresist. The thickness of the photoresist is 0.2 μm-15 μm.
c)在保护膜和光刻胶的掩蔽下对发光芯片上表面进行湿法腐蚀或ICP刻蚀,刻蚀深度为将透光层、发光层、反射层刻蚀透,并刻蚀基片至一定深度;上隔离沟槽的深度为100~300μm。c) Under the cover of the protective film and photoresist, perform wet etching or ICP etching on the upper surface of the light-emitting chip. A certain depth; the depth of the upper isolation trench is 100-300 μm.
C.上隔离沟槽的填充:C. Filling of the upper isolation trench:
a)在发光芯片上表面涂覆的柔性材料即像素连接材料为聚酰亚胺或柔性环氧树脂或聚二甲基硅氧烷(PDMS)或其它可涂覆成膜的柔性有机材料。预固化方式为加热固化或常温固化。a) The flexible material coated on the surface of the light-emitting chip, that is, the pixel connection material is polyimide or flexible epoxy resin or polydimethylsiloxane (PDMS) or other flexible organic materials that can be coated to form a film. The pre-curing method is heat curing or room temperature curing.
b)通过光刻及湿法腐蚀工艺去除透光层上表面的柔性材料。b) removing the flexible material on the upper surface of the light-transmitting layer by photolithography and wet etching.
c)去胶,并用腐蚀剂或特定溶剂进行二次腐蚀,使所形成的填充材料上表面的形成凹陷形状。c) Removing the glue, and performing secondary etching with an etchant or a specific solvent, so that the upper surface of the formed filling material is formed into a concave shape.
d)完成柔性材料的完全固化。d) Complete curing of the flexible material is achieved.
e)用湿法腐蚀或干法刻蚀去除上保护膜。e) removing the upper protective film by wet etching or dry etching.
D.石墨烯透明柔性上电极及上电极引线的制备:采用化学气相沉积技术或液相电化学沉积技术或将石墨烯的水分散液旋涂技术与光刻、掩膜或腐蚀技术相结合在已完成C步骤的发光芯片上表面制备柔性石墨烯薄膜上电极及上电极引线。D. Preparation of graphene transparent and flexible upper electrode and upper electrode lead: use chemical vapor deposition technology or liquid phase electrochemical deposition technology or combine graphene aqueous dispersion spin-coating technology with photolithography, masking or corrosion technology The upper surface of the light-emitting chip that has completed step C is prepared with a flexible graphene film upper electrode and upper electrode leads.
E.制备微透镜;在完成发光单元上上电极引线和发光单元外上电极引线的发光芯片上涂覆一层聚合物胶体,具体的厚度根据设计和工艺实验决定;对聚合物胶体进行紫外固化或热固化,得到具有较高粘附力的聚合物层;在固化后的聚合物上旋涂一定厚度的光刻胶,前烘、曝光、显影后,采用热熔法制作光刻胶微透镜;再采用反应离子刻蚀将光刻胶微透镜转移至前述的聚合物上,得到聚合物微透镜。聚合物透镜材料为聚酰亚胺或环氧树脂或SU-8光刻胶。E. Preparation of microlenses; coating a layer of polymer colloid on the light-emitting chip that has completed the upper electrode lead of the light-emitting unit and the outer upper electrode lead of the light-emitting unit, and the specific thickness is determined according to the design and process experiments; UV-curing the polymer colloid or thermal curing to obtain a polymer layer with high adhesion; spin-coat a certain thickness of photoresist on the cured polymer, and after pre-baking, exposure, and development, use the hot-melt method to make photoresist microlenses ; Reactive ion etching is used to transfer the photoresist microlens to the aforementioned polymer to obtain the polymer microlens. Polymer lens material is polyimide or epoxy or SU-8 photoresist.
F.发光芯片的正面固定:粘接剂材料为光刻胶或热固化胶或紫外固化胶或其它粘接材料。上保护片的材料为硅或玻璃或石英或陶瓷或铝或钛或其他无机材料或有机材料或金属材料。F. Fixing the front side of the light-emitting chip: the adhesive material is photoresist or heat curing glue or ultraviolet curing glue or other bonding materials. The material of the upper protective sheet is silicon or glass or quartz or ceramics or aluminum or titanium or other inorganic materials or organic materials or metal materials.
G.发光芯片的下表面减薄:采用机械减薄及抛光或化学减薄及抛光或机械与化学方法相结合对发光芯片的下表面进行减薄和抛光处理,减薄后的发光芯片为20~300μm。G. Thinning of the lower surface of the light-emitting chip: the lower surface of the light-emitting chip is thinned and polished by mechanical thinning and polishing or chemical thinning and polishing or a combination of mechanical and chemical methods. The light-emitting chip after thinning is 20 ~300μm.
H.发光芯片的像素分割:H. Pixel segmentation of light-emitting chips:
a)下保护膜材料为二氧化硅或氮化硅或二氧化硅与氮化硅组成的复合膜或金属或有机材料或无机材料或其它能起到保护作用的薄膜材料。保护膜制备方法为电子束蒸发或射频溅射或磁控溅射或溶胶凝胶法或其它薄膜生长方法。a) The material of the lower protective film is silicon dioxide or silicon nitride or a composite film composed of silicon dioxide and silicon nitride or metal or organic material or inorganic material or other film materials that can play a protective role. The preparation method of the protective film is electron beam evaporation, radio frequency sputtering, magnetron sputtering, sol-gel method or other film growth methods.
b)通过双面对准光刻工艺在下保护膜上形成柔性区域光刻胶窗口图形。b) forming a photoresist window pattern in the flexible region on the lower protective film through a double-side alignment photolithography process.
c)在光刻胶的保护下通过干法刻蚀或湿法腐蚀工艺得到下保护膜的窗口图形。光刻胶厚度为0.2μm-15μm。c) obtaining the window pattern of the lower protective film by dry etching or wet etching under the protection of the photoresist. The thickness of the photoresist is 0.2 μm-15 μm.
d)在保护膜和光刻胶的掩蔽下对发光芯片上表面进行湿法腐蚀或ICP刻蚀,实现发光芯片的像素分割。d) performing wet etching or ICP etching on the upper surface of the light-emitting chip under the mask of the protective film and the photoresist to realize pixel division of the light-emitting chip.
e)用湿法腐蚀或干法刻蚀去除下保护膜。e) The lower protective film is removed by wet etching or dry etching.
I.制备下电极及下电极引线:通过lift-off工艺或镀膜-光刻-腐蚀工艺制备薄膜下电极及下电极引线,或通过厚胶光刻、蒸镀及电铸加厚等工艺制备厚膜下电极及下电极引线。I. Prepare the lower electrode and the lower electrode lead: prepare the thin film lower electrode and the lower electrode lead by the lift-off process or the coating-lithography-corrosion process, or prepare the thick film by photolithography, evaporation and electroforming. Membrane lower electrode and lower electrode leads.
所述下电极及下电极引线的材料为Cr/Au或Ti/Pt/Au或Ti/Mo/Au或AuGeNi/Au或Al或Cu,或由Cr/Au或Ti/Pt/Au或Ti/Mo/Au或AuGeNi/Au与Cu或Au组成的复合膜。薄膜蒸镀方式为电子束蒸发或射频溅射或磁控溅射。The material of the lower electrode and the lower electrode lead is Cr/Au or Ti/Pt/Au or Ti/Mo/Au or AuGeNi/Au or Al or Cu, or made of Cr/Au or Ti/Pt/Au or Ti/Mo Composite film composed of /Au or AuGeNi/Au and Cu or Au. The thin film evaporation method is electron beam evaporation or radio frequency sputtering or magnetron sputtering.
制备厚膜下电极及下电极引线具体有两种方法:一、首先进行厚胶光刻得到与下电极图形相反的厚光刻胶图形,再蒸镀下电极薄膜,下电极选用Au或AuGeNi/Au或Ti/Pt/Au或Ti/Mo/Au或其它与基片具有良好欧姆接触特性的金属。剥离后,进行电铸,使电极加厚。电铸材料与蒸镀的薄膜材料相同或不同。There are two specific methods for preparing the thick-film lower electrode and the lower electrode leads: 1. First, perform thick photolithography to obtain a thick photoresist pattern opposite to the pattern of the lower electrode, and then vapor-deposit the lower electrode film. The lower electrode is selected from Au or AuGeNi/ Au or Ti/Pt/Au or Ti/Mo/Au or other metals with good ohmic contact characteristics with the substrate. After stripping, electroforming is performed to thicken the electrode. The electroformed material is the same or different from the evaporated film material.
二、厚膜下电极及下电极引线还可以采用以下工艺:首先蒸镀下电极薄膜,下电极选用Au或AuGeNi/Au或Ti/Pt/Au或Ti/Mo/Au或其它与基片具有良好欧姆接触特性的金属。然后进行厚胶光刻得到与下电极图形相反的厚光刻胶图形。电铸使电极加厚,电铸材料与蒸镀的薄膜材料相同或不同。最后,去除厚光刻胶得到厚膜电极。2. The thick-film lower electrode and lower electrode leads can also adopt the following process: first, evaporate the lower electrode film, and use Au or AuGeNi/Au or Ti/Pt/Au or Ti/Mo/Au for the lower electrode or other materials that have good compatibility with the substrate. Metals with ohmic contact properties. Then perform thick resist photolithography to obtain a thick photoresist pattern opposite to that of the lower electrode. Electroforming makes the electrode thicker, and the electroforming material is the same or different from the evaporated film material. Finally, the thick photoresist is removed to obtain thick film electrodes.
J.制备背面柔性材料:在已制备下电极及下电极引线的基片下表面旋转涂覆或喷涂所需厚度的柔性材料涂料,然后进行固化,形成背面柔性材料层。背面柔性材料层的材料为聚酰亚胺或柔性环氧树脂或聚二甲基硅氧烷(PDMS)或其它可涂覆成膜的柔性有机材料。J. Preparation of flexible material on the back surface: Spin coating or spraying a flexible material coating with a required thickness on the lower surface of the substrate on which the lower electrodes and lower electrode leads have been prepared, and then curing to form a flexible material layer on the back. The material of the back flexible material layer is polyimide or flexible epoxy resin or polydimethylsiloxane (PDMS) or other flexible organic materials that can be coated to form a film.
K.去除上保护片,保护片及粘接剂用湿法或干法去除。K. Remove the upper protective sheet, and remove the protective sheet and adhesive with wet or dry methods.
本发明采用了无机主动发光二极管芯片制备柔性微显示器件,结构简单、牢固、响应快;并克服了有机发光器件寿命短和驱动电流低而限制光输出强度的问题,从而提供一种自发光、体积小、功耗低并基于高亮度发光芯片的可弯曲的柔性微显示器件及其制备方法。这种可弯曲的柔性微显示器件可以应用到医疗器械、微型传感器件制造等多个领域。The invention adopts the inorganic active light-emitting diode chip to prepare the flexible micro-display device, which has a simple structure, firmness, and fast response; and overcomes the problems of the short life of the organic light-emitting device and the low driving current that limit the light output intensity, thereby providing a self-luminous, A bendable and flexible micro-display device based on a high-brightness light-emitting chip with small volume and low power consumption and a preparation method thereof. This bendable and flexible microdisplay device can be applied to many fields such as medical equipment and micro sensor device manufacturing.
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