CN103469557A - Method for finishing ultraviolet-proof antibacterial fabric - Google Patents
Method for finishing ultraviolet-proof antibacterial fabric Download PDFInfo
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- CN103469557A CN103469557A CN2013103655941A CN201310365594A CN103469557A CN 103469557 A CN103469557 A CN 103469557A CN 2013103655941 A CN2013103655941 A CN 2013103655941A CN 201310365594 A CN201310365594 A CN 201310365594A CN 103469557 A CN103469557 A CN 103469557A
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- fabric
- antiultraviolet
- finishing agent
- ultraviolet
- antibacterial finishing
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 34
- 239000004744 fabric Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002803 maceration Methods 0.000 claims abstract description 12
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 7
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000007822 coupling agent Substances 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- 230000003115 biocidal effect Effects 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 6
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims description 4
- 230000002421 anti-septic effect Effects 0.000 claims description 4
- JXQJXXUBPMVRNX-UHFFFAOYSA-N butyl carbamodithioate;nickel Chemical compound [Ni].CCCCSC(N)=S JXQJXXUBPMVRNX-UHFFFAOYSA-N 0.000 claims description 4
- 235000021050 feed intake Nutrition 0.000 claims description 4
- 150000002357 guanidines Chemical class 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 claims description 3
- 229940123208 Biguanide Drugs 0.000 claims description 3
- 239000005766 Dodine Substances 0.000 claims description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003242 anti bacterial agent Substances 0.000 abstract 1
- MMUFAGXJPKNAHT-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1 MMUFAGXJPKNAHT-UHFFFAOYSA-N 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 230000000845 anti-microbial effect Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 230000006750 UV protection Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000002062 proliferating effect Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 208000007442 rickets Diseases 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a method for finishing an ultraviolet-proof antibacterial fabric. The method comprises the following steps: enabling a fabric to pass through a roll groove, adding a maceration liquid containing an ultraviolet-proof antibacterial finishing agent to the fabric at 80-95 DGE C at the same time, controlling a padding speed to be at 20-25m/minute, and then keeping the fabric at a constant temperature for 0.5-2 hours, wherein the constant temperature is between 115 and 130 DEG C; after the temperature of the fabric is reduced to the room temperature, using neutralizing agent water to wash the fabric until the pH value is 6.5-6.8, and drying the fabric. The ultraviolet-proof antibacterial finishing agent is prepared from the following components in parts by weight: silicon dioxide, zeolite, 2,4-dihydroxy benaophenonel, N,N-di-n-butyl dithiocarbamate nickel, guanidine antibacterial agent, 2,4,4'-trichlorine-2'-hydroxyl diphenyl ether, 8-hydroxyquinoline copper, aluminum zirconium acid ester coupling agent and sodium polyacrylate dispersant. Through the adoption of the method, the fabric has ultraviolet-proof and antibacterial functions, is high in durability, and is no-toxic and safe.
Description
Technical field
The present invention relates to a kind of method for sorting of antiultraviolet antibiotic facing material.
Background technology
In general, suitable ultraviolet ray is useful to human body, and it can promote the synthetic of vitamin D, rickets is had to inhibitory action, and have sterilization.But in recent years; because the chlorofluorination hydrocarbon compound in fluorine Lyons and so on is discharged in human being's production and life in large quantities; the umbrella that makes the earth is that atmosphere is destroyed day by day; at terrestrial pole and overhead, China Qinghai-Tibet Platean, the ozone cavity has appearred particularly; the guard circle of the earth is that the ozone layer attenuation is thinning; the amount of ultraviolet irradiation that arrives ground increases, and irradiates because of excessive ultraviolet ray the disease caused and gets more and more.Generally, human body skin can be accepted ultraviolet safe amount of radiation every day should be in 20kJ/m2, and the amount of radiation that ultraviolet ray arrives ground about 40-60kJ/m2 during the cloudy day, about 80-100kJ/m2 during fine day, can reach 100-200kJ/m2 during scorching sun in hot summer days, common dress material generally in 50% left and right, does not reach requirement of shelter to ultraviolet screening rate far away.In addition, long-term ultraviolet ray irradiation also can cause fading of textiles and aging.Therefore, be necessary textiles is carried out to anti-ultraviolet finishing.
When illumination is mapped on object, a part is reflected by body surface; Part is absorbed by object; Other see through object.Fiber and goods with ultraviolet protection function, when UV-irradiation, except the hole of a part from fabric wherein sees through (its transit dose is looked the differences such as the tissue of fabric and thickness), not not reflected by ultra-violet protecting agent of other, selectively absorbed exactly, and become heat energy to discharge its power conversion, to reach the ultraviolet purpose of minimizing.Strictly say, can be by the material of ultraviolet reflection ultraviolet light screener, to ultraviolet ray have strong selective absorb and can carry out power conversion and the material of transit dose that reduces it ultra-violet absorber.But in fact shielding exists with absorption simultaneously, and they have improved the ultraviolet protection function of fiber and textiles from different approach.
The kinds of fibers difference, its ultraviolet ray transmissivity is also different.The natural fabrics such as cotton, real silk are low to ultraviolet absorbability, thereby uvioresistant line poor performance, and wherein fabric is the most meable fabric of ultraviolet ray.
Anti-ultraviolet finishing agent commonly used divides inorganic and organic two large classes at present.Antiultraviolet antibacterial finishing agent commonly used is metal, metal oxide and its esters, for example TiO mostly
2, ZnO, Al
2o
3, kaolin, talcum powder, carbon black, iron oxide, lead monoxide and CaCO
3deng.Inorganic anti-ultraviolet finishing agent and fabric fibre binding ability are poor.Organic anti-ultraviolet finishing agent is mainly absorb ultraviolet ray and carry out power conversion, ultraviolet ray is become to low-energy heat energy or the shorter electromagnetic wave of wavelength, thereby reach the purpose of ultra-violet radiation resisting.Generally there is conjugated structure or hydrogen bond.Such anti-ultraviolet finishing agent has certain toxicity.
The textiles of some and human body close contact in use, inevitably can stain bacterium.Because common textiles there is no bactericidal action, therefore itself also can become various pathogenic bacteria prolific " hotbed ", again the flora imbalance on human body skin surface is played to the effect of adding fuel to the flames conversely.In addition, the bacterium of contamination on textiles, when it obtains the rapid breeding of nutrition, can metabolism or decomposite the volatile compound of various lower fatty acids, ammonia and other irritant stinks, add the secretion of bacterium itself and the corrupt smell of the dead bones of the body, make textiles produce various disgusting smells, affect health.
Antibacterial finishing agent generally is divided into three kinds of mineral-type, organic and natural products classes.The mineral-type antibacterial finishing agent has the advantages such as pollution-free, safe, but poor durability often, repeatedly after the washing, antibacterial effect weakens greatly.CN102493181A discloses a kind of manufacture method of antibiotic fabric, it utilizes the radio frequency reaction magnetron sputtering technique that the nanometer silver antimicrobial particle is covered on the general fibre fabric, obtain antibiotic fabric, the film that the nanometer silver antimicrobial particle forms covers on fiber uniformly, be combined preferably with fiber, strengthened the service life of antibiotic fabric.But higher to equipment requirement, production cost is high.The general durability of organic antibacterial finishing agent is strong, but certain toxicity is often arranged.Natural products class antibacterial finishing agent natural environmental-protective, but general cost is higher.
Therefore, develop and a kind ofly there is antiultraviolet and antibiotic simultaneously, and be that non-toxic and safe, the antiultraviolet antibiotic facing material that has again excellent durability become important research topic.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of method for sorting of antiultraviolet antibiotic facing material, the above-mentioned defect existed to overcome prior art.
For solving the problems of the technologies described above, the method for sorting of antiultraviolet antibiotic facing material of the present invention, it comprises the steps: fabric is passed through to groove, adds the maceration extract that contains the antiultraviolet antibacterial finishing agent under 80-95 ℃, pads the speed of a motor vehicle and is controlled at 20-50 m/min; Then constant temperature 0.5-2 hour between 115-130 ℃; Being down to after normal temperature and being washed to the pH value with neutralizer is 6.5-6.8, dries and obtains described antiultraviolet antibiotic facing material;
Described antiultraviolet antibacterial finishing agent is comprised of the component of following weight portion:
The antiultraviolet antibacterial finishing agent can adopt general mixed method, preferably adopts following method preparation:
By 2,4-dihydroxy benaophenonel, N, N-second, n-butyl dithiocarbamate nickel, zeolite, guanidine class antiseptic, 2,4, the chloro-2'-dihydroxy diphenyl ether of 4'-tri-and copper 8-quinolinolate mix, then slowly add silica, Aluminum zirconium coupling agent and Sodium Polyacrylate dispersant, feed intake in 1-2 hour complete, continue to mix 30-50 minute simultaneously.
As a kind of preferred version, the particle diameter of described silica is the 0.05-0.12 micron.
Preferably, described guanidine class antiseptic is selected from dodine, 1,6-bis-(4'-chlorobenzene biguanides) hexane or hexamethylene.
Preferably, the described maceration extract that contains the antiultraviolet antibacterial finishing agent is that the antiultraviolet antibacterial finishing agent adds water and is made into mass content and is not less than 15% mixture; Preferably be made into the mixture of mass content 35-50%.
Preferably, described Sodium Polyacrylate dispersant preferred viscosities 300-350mPas.
The present invention organically combines anti-ultraviolet finishing agent and antibacterial finishing agent, and selected specific auxiliary agent is composited, and has the functional advantage of two kinds of finishing agents concurrently, can with the fabric strong bonded, durability is strong, and fabric is had to good anti-ultraviolet and antibacterial action, non-toxic and safe.
The specific embodiment
Embodiment 1
The preparation of the maceration extract that contains the antiultraviolet antibacterial finishing agent:
By 2,4-dihydroxy benaophenonel 10 grams, N, N-second, n-butyl dithiocarbamate nickel 25 grams, zeolite 6 grams, dodine 5 grams, 2,4, chloro-2'-dihydroxy diphenyl ether 10 grams of 4'-tri-and copper 8-quinolinolate 0.5 gram mix, then slowly add silica 60 grams, Aluminum zirconium coupling agent 3 grams and Sodium Polyacrylate dispersant 0.9 gram that particle diameter is 0.10 micron, feed intake in 1 hour complete, continue to mix 30 minutes simultaneously.The antiultraviolet antibacterial finishing agent adds water and is mixed with the maceration extract that mass content is 40%.
The arrangement of antiultraviolet antibiotic facing material:
Fabric, by groove, is added to the maceration extract that contains the antiultraviolet antibacterial finishing agent under 95 ℃, pad the speed of a motor vehicle and be controlled at 20 m/mins; Then constant temperature 2 hours between 115 ℃; Being down to after normal temperature and being washed to the pH value with neutralizer is 6.5, dries and obtains described antiultraviolet antibiotic facing material.
Embodiment 2
The preparation of the maceration extract that contains the antiultraviolet antibacterial finishing agent:
By 2,4-dihydroxy benaophenonel 15 grams, N, N-second, n-butyl dithiocarbamate nickel 20 grams, zeolite 5 grams, 1,6-bis-(4'-chlorobenzene biguanides) hexane 3 grams, 2, chloro-2'-dihydroxy diphenyl ether 15 grams of 4,4'-tri-and copper 8-quinolinolate 1 gram mix, and then slowly add silica 80 grams, Aluminum zirconium coupling agent 1 gram and Sodium Polyacrylate dispersant 1.2 grams that particle diameter is 0.06 micron simultaneously, feed intake in 1 hour complete, continue to mix 50 minutes.The antiultraviolet antibacterial finishing agent adds water and is mixed with the maceration extract that mass content is 35%.
The arrangement of antiultraviolet antibiotic facing material:
Fabric, by groove, is added to the maceration extract that contains the antiultraviolet antibacterial finishing agent under 80 ℃ simultaneously, pad the speed of a motor vehicle and be controlled at 50 m/mins; Then by fabric constant temperature 0.5 hour between 130 ℃; Being down to after normal temperature and being washed to the pH value with neutralizer is 6.8, dries and obtains described antiultraviolet antibiotic facing material.
Application Example
1, durability
Fabric use is contained to the ratio of the neutral detergent of 1 grams per liter with fabric and the detergent solution of 1:50, about 60 ℃ washings 30 minutes, about 60 ℃ dryings after centrifuge dewatering.Wash respectively as stated above 5 times, 30 times.
2, ultraviolet resistance
Method according to standard GB/T-T18830-2002 " evaluation of UV-proof Property of Textiles " is measured the anti-ultraviolet property of fabric under different wash conditions, and result is as follows:
Anti-ultraviolet property after the different washing times of table 1
In table, a means that b means to wash 5 times without the fabric of washing, and c means to wash 30 times.
3, anti-microbial property
Method according to national standard GB/T 20944.1-2007 " the evaluation part 1 of antibacterial textile performance: agar diffusion method " is measured the anti-microbial property of fabric under different wash conditions, and result is as follows:
Anti-microbial property after the different washing times of table 1
In table, a means that b means to wash 5 times without the fabric of washing, and c means to wash 30 times.
Visible, the fabric antiultraviolet that the inventive method is made and antibacterial effect are all very excellent, and have good wash durability, through repeatedly after washing, still having good antiultraviolet and anti-microbial property.
Claims (7)
1. the method for sorting of antiultraviolet antibiotic facing material, is characterized in that, comprises the steps: fabric is passed through to groove, adds the maceration extract that contains the antiultraviolet antibacterial finishing agent under 80-95 ℃, pads the speed of a motor vehicle and be controlled at 20-50 m/min; Then constant temperature 0.5-2 hour between 115-130 ℃; Being down to after normal temperature and being washed to the pH value with neutralizer is 6.5-6.8, dries and obtains described antiultraviolet antibiotic facing material;
Described antiultraviolet antibacterial finishing agent is comprised of the component of following weight portion:
2. method according to claim 1, it is characterized in that, described antiultraviolet antibacterial finishing agent adopts following method preparation: by 2,4-dihydroxy benaophenonel, N, N-second, n-butyl dithiocarbamate nickel, zeolite, guanidine class antiseptic, 2,4, the chloro-2'-dihydroxy diphenyl ether of 4'-tri-and copper 8-quinolinolate mix, then slowly add silica, Aluminum zirconium coupling agent and Sodium Polyacrylate dispersant, feed intake in 1-2 hour complete, continue to mix 30-50 minute simultaneously.
3. method according to claim 1, is characterized in that, the particle diameter of described silica is the 0.05-0.12 micron.
4. method according to claim 1, is characterized in that, described guanidine class antiseptic is selected from dodine, 1,6-bis-(4'-chlorobenzene biguanides) hexane or hexamethylene.
5. method according to claim 1, is characterized in that, described Sodium Polyacrylate dispersant viscosity 300-350mPas.
6. method according to claim 1, is characterized in that, the described maceration extract that contains the antiultraviolet antibacterial finishing agent is that the antiultraviolet antibacterial finishing agent adds water and is made into mass content and is not less than 15% mixture.
7. method according to claim 6, is characterized in that, the described maceration extract that contains the antiultraviolet antibacterial finishing agent is that the antiultraviolet antibacterial finishing agent adds water and is made into the mixture that mass content is 35-50%.
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| CN2013103655941A CN103469557A (en) | 2013-08-21 | 2013-08-21 | Method for finishing ultraviolet-proof antibacterial fabric |
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|---|---|---|---|
| CN2013103655941A CN103469557A (en) | 2013-08-21 | 2013-08-21 | Method for finishing ultraviolet-proof antibacterial fabric |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105350321A (en) * | 2015-12-16 | 2016-02-24 | 常熟市华博毛纺织有限公司 | Dyeing and finishing process for compound material |
| CN105350305A (en) * | 2015-12-16 | 2016-02-24 | 常熟市华博毛纺织有限公司 | Finishing process of shirt fabric |
| CN105421072A (en) * | 2015-12-22 | 2016-03-23 | 常熟市博凡针纺织有限公司 | Dyeing and finishing process of polar fleece |
| CN105506990A (en) * | 2015-12-16 | 2016-04-20 | 常熟市华博毛纺织有限公司 | Garment material finishing process |
| CN105603727A (en) * | 2016-01-08 | 2016-05-25 | 湖州市千金丝织厂 | Novel anti-ultraviolet antibacterial finishing agent and preparing method thereof |
| CN106702717A (en) * | 2017-01-17 | 2017-05-24 | 瑞投（上海）服饰科技有限公司 | Anti-ultraviolet women clothing and preparation method thereof |
| CN107724070A (en) * | 2017-10-20 | 2018-02-23 | 浙江剑利美针织服饰有限公司 | A kind of graphene fabric and preparation method thereof |
| CN108729216A (en) * | 2018-05-29 | 2018-11-02 | 安徽英士博纺织发展有限公司 | A kind of rapid-curing cutback clothing fabric anti-ultraviolet finishing liquid |
| CN109457466A (en) * | 2018-11-15 | 2019-03-12 | 李宁 | Functionalized carbon nano-tube and its application in antistatic antibiotic fabric finishing liquor |
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| CN1546755A (en) * | 2003-12-01 | 2004-11-17 | 中国人民解放军总后勤部军需装备研究 | Processing method for durable antibiotic deodorant fibre fabric |
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| CN109457466A (en) * | 2018-11-15 | 2019-03-12 | 李宁 | Functionalized carbon nano-tube and its application in antistatic antibiotic fabric finishing liquor |
| CN109457466B (en) * | 2018-11-15 | 2021-06-08 | 浪达网络科技(浙江)有限公司 | Functionalized carbon nanotube and application thereof in antistatic and antibacterial fabric finishing liquid |
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