CN103467774A - Composition applicable to surface flame retardance of rigid polyurethane foam insulation board - Google Patents
Composition applicable to surface flame retardance of rigid polyurethane foam insulation board Download PDFInfo
- Publication number
- CN103467774A CN103467774A CN2013104355107A CN201310435510A CN103467774A CN 103467774 A CN103467774 A CN 103467774A CN 2013104355107 A CN2013104355107 A CN 2013104355107A CN 201310435510 A CN201310435510 A CN 201310435510A CN 103467774 A CN103467774 A CN 103467774A
- Authority
- CN
- China
- Prior art keywords
- flame retardant
- insulation board
- foam insulation
- mass
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 6
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 6
- 239000003063 flame retardant Substances 0.000 claims abstract description 57
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000853 adhesive Substances 0.000 claims abstract description 16
- 230000001070 adhesive effect Effects 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229920002635 polyurethane Polymers 0.000 claims description 28
- 239000004814 polyurethane Substances 0.000 claims description 28
- 239000006260 foam Substances 0.000 claims description 27
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 12
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 12
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 12
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 12
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 12
- 229920000877 Melamine resin Polymers 0.000 claims description 11
- 239000007921 spray Substances 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004831 Hot glue Substances 0.000 claims description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000299 Nylon 12 Polymers 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 239000011206 ternary composite Substances 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 239000010455 vermiculite Substances 0.000 claims description 2
- 229910052902 vermiculite Inorganic materials 0.000 claims description 2
- 235000019354 vermiculite Nutrition 0.000 claims description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 238000013329 compounding Methods 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000012774 insulation material Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000003111 delayed effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
技术领域technical field
本发明涉及一种由膨胀型阻燃剂与固态阻燃剂复配的具有高效阻燃特性的组合物，属于利用多种材料复配组合的方式取得具有阻燃性能材料的技术领域。The invention relates to a composition with high-efficiency flame-retardant properties compounded by an intumescent flame retardant and a solid flame retardant, and belongs to the technical field of obtaining materials with flame-retardant properties by compounding and combining various materials.
背景技术Background technique
硬质聚氨酯泡沫(RPUF)由于导热系数低、抗压强度高、质轻、粘结性好、易于加工等一系列优点，因此在建筑墙体节能保温领域具有广泛的应用；采用聚氨酯等高分子泡沫塑料替代传统无机保温材料广泛用于建筑领域已成为各国持续发展经济、节约能源的重要措施之一。Due to a series of advantages such as low thermal conductivity, high compressive strength, light weight, good adhesion, and easy processing, rigid polyurethane foam (RPUF) has a wide range of applications in the field of energy-saving and thermal insulation of building walls; polymers such as polyurethane are used It has become one of the important measures for sustainable economic development and energy conservation in various countries to replace traditional inorganic thermal insulation materials with foam plastics and widely used in the construction field.
聚氨酯硬泡保温板自身暴露在热源或火源下极易燃烧，且火焰传播速度非常快，其LOI值仅为19.2％，因此，该材料在建筑领域进一步应用时需要大力提高其阻燃性能。Polyurethane rigid foam insulation board itself is very easy to burn when exposed to heat or fire, and the flame spreads very fast, and its LOI value is only 19.2%. Therefore, the further application of this material in the construction field needs to greatly improve its flame retardancy.
目前，解决聚氨酯硬泡保温板易燃问题的两种主要途径为：一、通过使用阻燃剂对保温板芯材进行阻燃改性；二、通过使用有机或无机阻燃剂对保温板表面做阻燃处理。At present, there are two main ways to solve the flammability problem of polyurethane rigid foam insulation boards: first, by using flame retardants to modify the core material of insulation boards; Do flame retardant treatment.
例如，专利申请号201220017493.6公开了一种六面包覆型阻燃聚氨酯保温复合板，其特点在于它的六面是由阻燃水泥基界面毡包覆的，具有较好的表面阻燃性能；类似地，201020232569.8公开了一种防水保温防火装饰一体板，同样对表面做了阻燃处理。For example, patent application number 201220017493.6 discloses a six-sided coated flame-retardant polyurethane thermal insulation composite board, which is characterized in that its six sides are covered by flame-retardant cement-based interface felt, which has good surface flame-retardant properties; Similarly, 201020232569.8 discloses a waterproof, thermal, fireproof and decorative integrated board, which also has flame-retardant treatment on the surface.
本发明主要通过对保温板表面用阻燃涂层做阻燃处理来解决聚氨酯硬泡表面易燃的问题。The invention mainly solves the problem that the polyurethane hard foam surface is flammable by performing flame-retardant treatment on the surface of the insulation board with a flame-retardant coating.
发明内容Contents of the invention
本发明采用膨胀型阻燃剂与固态阻燃剂复配，与液态胶粘剂充分混合后，涂敷于聚氨酯硬泡保温板表面来制备防火涂层。The invention adopts compounding of intumescent flame retardant and solid flame retardant, fully mixed with liquid adhesive, and then coating on the surface of polyurethane rigid foam insulation board to prepare fireproof coating.
所用原料：聚氨酯硬泡保温板、膨胀型阻燃剂(工业级)、固态阻燃剂(工业级)、液态胶粘剂(工业级)。Raw materials used: polyurethane rigid foam insulation board, intumescent flame retardant (industrial grade), solid flame retardant (industrial grade), liquid adhesive (industrial grade).
为了更进一步地说明本发明的技术方案，列出了如下的详细内容：In order to further illustrate the technical scheme of the present invention, the following details are listed:
所述的液态胶粘剂为羧甲基纤维素钠、尼龙12、聚乙烯醇缩甲醛胶、乙烯-乙酸乙烯共聚物热熔胶、丙烯酸酯乳液胶粘剂中的一种。The liquid adhesive is one of sodium carboxymethylcellulose, nylon 12, polyvinyl formal adhesive, ethylene-vinyl acetate copolymer hot melt adhesive, and acrylate emulsion adhesive.
所述的膨胀型阻燃剂为聚磷酸铵／季戊四醇／三聚氰胺三元复合阻燃剂、可膨胀石墨、蛭石中的一种或几种。The intumescent flame retardant is one or more of ammonium polyphosphate/pentaerythritol/melamine ternary composite flame retardant, expandable graphite, and vermiculite.
较好地，所述的膨胀型阻燃剂含聚磷酸铵／季戊四醇／三聚氰胺时，聚磷酸铵：季戊四醇：三聚氰胺=10-80质量份：5-40质量份：5-50质量份。Preferably, when the intumescent flame retardant contains ammonium polyphosphate/pentaerythritol/melamine, ammonium polyphosphate: pentaerythritol: melamine=10-80 parts by mass: 5-40 parts by mass: 5-50 parts by mass.
所述的固态阻燃剂为氢氧化镁、氢氧化铝、红磷、磷酸三苯酯中的一种或几种。The solid flame retardant is one or more of magnesium hydroxide, aluminum hydroxide, red phosphorus, and triphenyl phosphate.
本发明的具体制备方法为：Concrete preparation method of the present invention is:
取液态胶粘剂100质量份，添加膨胀型阻燃剂10-100质量份，添加固态阻燃剂0-100质量份。Take 100 parts by mass of liquid adhesive, add 10-100 parts by mass of intumescent flame retardant, and add 0-100 parts by mass of solid flame retardant.
根据上述的组合物配制比例，先将膨胀型阻燃剂、固态阻燃剂与液态胶粘剂在室温下充分搅拌2-60分钟，得到混合均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度0.1-2毫米，最后在烘箱中恒温保持0.1小时-12小时，固化完成后，得到具有阻燃表面的聚氨酯硬泡保温板。According to the above-mentioned composition ratio, first fully stir the intumescent flame retardant, solid flame retardant and liquid adhesive at room temperature for 2-60 minutes to obtain a uniformly mixed mixture, and then apply the mixture to the surface of the polyurethane rigid foam insulation board Spraying is carried out, and the thickness of the coating is controlled to 0.1-2 mm, and finally kept at a constant temperature in an oven for 0.1-12 hours. After curing, a polyurethane rigid foam insulation board with a flame-retardant surface is obtained.
利用本发明方法，可以综合膨胀型阻燃剂受热后膨胀与固态阻燃剂受热后分解所产生的双重阻隔作用，能够在很大程度上抑制外界热量向芯材部分的传递，因此，可以实现聚氨酯硬泡保温板表面的阻燃；使用本发明涂层厚度在0.1毫米时，采用酒精灯点燃时，聚氨酯硬泡保温材料点燃时间推迟35分钟；涂层厚度在1.0毫米时，采用酒精灯点燃时，聚氨酯硬泡保温材料点燃时间推迟2小时以上。Utilizing the method of the present invention, the double barrier function produced by the thermal expansion of the intumescent flame retardant and the thermal decomposition of the solid flame retardant can be integrated, and the transfer of external heat to the core material can be suppressed to a large extent. Therefore, it can realize The flame retardancy of the surface of the polyurethane rigid foam insulation board; when the coating thickness of the present invention is 0.1 mm, when the alcohol lamp is used to ignite, the ignition time of the polyurethane rigid foam insulation material is delayed by 35 minutes; when the coating thickness is 1.0 mm, the alcohol lamp is used to ignite At this time, the ignition time of polyurethane rigid foam insulation materials is delayed by more than 2 hours.
具体实施方式Detailed ways
实施例1称取丙烯酸酯乳液胶粘剂100质量份，添加膨胀型阻燃剂：聚磷酸铵20质量份、季戊四醇10质量份、三聚氰胺15质量份，添加氢氧化镁20质量份，在室温下充分搅拌10分钟，以得到均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度，最后在烘箱中恒温保持0.5小时，取出测厚为0.5毫米，采用酒精灯点燃时，聚氨酯硬泡保温材料点燃时间推迟1小时以上。Example 1 Weigh 100 parts by mass of acrylate emulsion adhesive, add intumescent flame retardant: 20 parts by mass of ammonium polyphosphate, 10 parts by mass of pentaerythritol, 15 parts by mass of melamine, add 20 parts by mass of magnesium hydroxide, and fully stir at room temperature 10 minutes to obtain a uniform mixture, and then spray the mixture on the surface of the polyurethane rigid foam insulation board to control the thickness of the coating, and finally keep the temperature in the oven for 0.5 hours, take it out and measure the thickness as 0.5mm, and use an alcohol lamp to light it , The ignition time of polyurethane rigid foam insulation materials is delayed by more than 1 hour.
实施例2称取丙烯酸酯乳液胶粘剂100质量份，添加膨胀型阻燃剂：聚磷酸铵20质量份、季戊四醇10质量份、三聚氰胺15质量份，添加氢氧化铝20质量份，在室温下充分搅拌10分钟，以得到均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度，最后在烘箱中恒温保持0.5小时，取出测厚为0.3毫米，采用酒精灯点燃时，聚氨酯硬泡保温材料点燃时间推迟48分钟以上。Example 2 Weigh 100 parts by mass of acrylate emulsion adhesive, add intumescent flame retardant: 20 parts by mass of ammonium polyphosphate, 10 parts by mass of pentaerythritol, 15 parts by mass of melamine, add 20 parts by mass of aluminum hydroxide, and fully stir at room temperature 10 minutes to get a uniform mixture, and then spray the mixture on the surface of the polyurethane rigid foam insulation board to control the thickness of the coating, and finally keep the temperature in the oven for 0.5 hours, take it out and measure the thickness as 0.3 mm, and use an alcohol lamp to light it , The ignition time of polyurethane rigid foam insulation materials is delayed by more than 48 minutes.
实施例3称取丙烯酸酯乳液胶粘剂100质量份，添加膨胀型阻燃剂：聚磷酸铵20质量份、季戊四醇10质量份、三聚氰胺15质量份，添加氢氧化镁20质量份，在室温下充分搅拌10分钟，以得到均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度，最后在烘箱中恒温保持0.5小时，取出测厚为0.5毫米，在700℃下灼烧10秒，表面增加的厚度为0.8毫米。Example 3 Weigh 100 parts by mass of acrylate emulsion adhesive, add intumescent flame retardant: 20 parts by mass of ammonium polyphosphate, 10 parts by mass of pentaerythritol, 15 parts by mass of melamine, add 20 parts by mass of magnesium hydroxide, and fully stir at room temperature 10 minutes to obtain a uniform mixture, and then spray the mixture on the surface of the polyurethane rigid foam insulation board to control the thickness of the coating, and finally keep it in the oven for 0.5 hours at a constant temperature, take it out to measure the thickness of 0.5 mm, and burn it at 700 ° C After burning for 10 seconds, the thickness of the surface increased by 0.8 mm.
实施例4称取聚乙烯醇缩甲醛胶100质量份，添加膨胀型阻燃剂：聚磷酸铵30质量份、季戊四醇10质量份、三聚氰胺20质量份，添加氢氧化铝25质量份，在室温下充分搅拌10分钟，以得到均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度，最后在烘箱中恒温保持0.5小时，取出测厚为0.5毫米，在500℃下灼烧10秒，表面增加的厚度为0.6毫米。Example 4 Weigh 100 parts by mass of polyvinyl formal glue, add intumescent flame retardant: 30 parts by mass of ammonium polyphosphate, 10 parts by mass of pentaerythritol, 20 parts by mass of melamine, add 25 parts by mass of aluminum hydroxide, at room temperature Fully stir for 10 minutes to obtain a uniform mixture, and then spray the mixture on the surface of the polyurethane rigid foam insulation board to control the thickness of the coating, and finally keep it in the oven for 0.5 hours at a constant temperature, take it out and measure the thickness as 0.5mm, and test it at 500°C Under burning for 10 seconds, the thickness of the surface increased by 0.6 mm.
实施例5称取聚乙烯醇缩甲醛胶100质量份，添加膨胀型阻燃剂：聚磷酸铵30质量份、季戊四醇10质量份、三聚氰胺20质量份，添加氢氧化铝25质量份，在室温下充分搅拌10分钟，以得到均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度，最后在烘箱中恒温保持0.5小时，取出测厚为0.5毫米，在600℃下灼烧10秒，表面增加的厚度为0.9毫米。Example 5 Weigh 100 parts by mass of polyvinyl formal glue, add intumescent flame retardant: 30 parts by mass of ammonium polyphosphate, 10 parts by mass of pentaerythritol, 20 parts by mass of melamine, add 25 parts by mass of aluminum hydroxide, at room temperature Fully stir for 10 minutes to obtain a uniform mixture, and then spray the mixture on the surface of the polyurethane rigid foam insulation board to control the thickness of the coating, and finally keep it in the oven for 0.5 hours at a constant temperature, take it out and measure the thickness as 0.5 mm, at 600 ° C Under burning for 10 seconds, the thickness of the surface increased by 0.9 mm.
实施例6称取聚乙烯醇缩甲醛胶100质量份，添加膨胀型阻燃剂：聚磷酸铵30质量份、季戊四醇10质量份、三聚氰胺20质量份，添加氢氧化镁25质量份，在室温下充分搅拌10分钟，以得到均匀的混合物，再将该混合物对聚氨酯硬泡保温板表面进行喷涂，控制涂层的厚度，最后在烘箱中恒温保持0.5小时，取出测厚为0.5毫米，在700℃下灼烧10秒，表面增加的厚度为1.3毫米。Example 6 Weigh 100 parts by mass of polyvinyl formal glue, add intumescent flame retardant: 30 parts by mass of ammonium polyphosphate, 10 parts by mass of pentaerythritol, 20 parts by mass of melamine, add 25 parts by mass of magnesium hydroxide, at room temperature Fully stir for 10 minutes to obtain a uniform mixture, and then spray the mixture on the surface of the polyurethane rigid foam insulation board to control the thickness of the coating, and finally keep it in the oven for 0.5 hours at a constant temperature, take it out and measure the thickness of 0.5 mm, at 700 ° C Under burning for 10 seconds, the thickness of the surface increased by 1.3 mm.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013104355107A CN103467774A (en) | 2013-09-24 | 2013-09-24 | Composition applicable to surface flame retardance of rigid polyurethane foam insulation board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013104355107A CN103467774A (en) | 2013-09-24 | 2013-09-24 | Composition applicable to surface flame retardance of rigid polyurethane foam insulation board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103467774A true CN103467774A (en) | 2013-12-25 |
Family
ID=49792829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013104355107A Pending CN103467774A (en) | 2013-09-24 | 2013-09-24 | Composition applicable to surface flame retardance of rigid polyurethane foam insulation board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103467774A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277519A (en) * | 2014-10-28 | 2015-01-14 | 成都纳硕科技有限公司 | Ultraviolet curable antifouling flame-retardant coating for plastic circuit board |
| CN104788640A (en) * | 2015-04-28 | 2015-07-22 | 南通苏东新型外墙保温板有限公司 | Preparation method of flame-retardant hard foam polyurethane |
| CN107043529A (en) * | 2017-03-21 | 2017-08-15 | 王正恒 | A kind of flame-retardant composite insulation and its preparation method and application |
| CN110591424A (en) * | 2019-10-29 | 2019-12-20 | 中国民航大学 | Preparation method of aluminum phosphate gum-based halogen-free high-expansion flame-retardant heat-insulating fireproof coating |
| CN113943443A (en) * | 2020-07-15 | 2022-01-18 | 中关村人居环境工程与材料研究院 | Film-coated flame-retardant thermal-insulation material and preparation method thereof |
| CN116041823A (en) * | 2022-12-29 | 2023-05-02 | 金旸（厦门）新材料科技有限公司 | Halogen-free intumescent flame-retardant antistatic thermoplastic elastomer composite foaming material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102585756A (en) * | 2011-11-30 | 2012-07-18 | 江苏欣安新材料技术有限公司 | Water-based high-expansion fireproof sealant |
| US20120256143A1 (en) * | 2011-04-11 | 2012-10-11 | Crosslink Technology, Inc. | Fire Resistant Coating |
-
2013
- 2013-09-24 CN CN2013104355107A patent/CN103467774A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120256143A1 (en) * | 2011-04-11 | 2012-10-11 | Crosslink Technology, Inc. | Fire Resistant Coating |
| CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102585756A (en) * | 2011-11-30 | 2012-07-18 | 江苏欣安新材料技术有限公司 | Water-based high-expansion fireproof sealant |
Non-Patent Citations (1)
| Title |
|---|
| 曾军等: "膨胀型阻燃剂在涤纶织物涂层中的应用性能", 《高分子材料科学与工程》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277519A (en) * | 2014-10-28 | 2015-01-14 | 成都纳硕科技有限公司 | Ultraviolet curable antifouling flame-retardant coating for plastic circuit board |
| CN104788640A (en) * | 2015-04-28 | 2015-07-22 | 南通苏东新型外墙保温板有限公司 | Preparation method of flame-retardant hard foam polyurethane |
| CN107043529A (en) * | 2017-03-21 | 2017-08-15 | 王正恒 | A kind of flame-retardant composite insulation and its preparation method and application |
| CN110591424A (en) * | 2019-10-29 | 2019-12-20 | 中国民航大学 | Preparation method of aluminum phosphate gum-based halogen-free high-expansion flame-retardant heat-insulating fireproof coating |
| CN110591424B (en) * | 2019-10-29 | 2021-07-06 | 中国民航大学 | A kind of preparation method of aluminum phosphate glue-based halogen-free high-expansion flame-retardant heat-insulating fire-retardant coating |
| CN113943443A (en) * | 2020-07-15 | 2022-01-18 | 中关村人居环境工程与材料研究院 | Film-coated flame-retardant thermal-insulation material and preparation method thereof |
| CN116041823A (en) * | 2022-12-29 | 2023-05-02 | 金旸（厦门）新材料科技有限公司 | Halogen-free intumescent flame-retardant antistatic thermoplastic elastomer composite foaming material and preparation method thereof |
| CN116041823B (en) * | 2022-12-29 | 2023-11-03 | 金旸（厦门）新材料科技有限公司 | Halogen-free intumescent flame-retardant antistatic thermoplastic elastomer composite foaming material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103497557A (en) | Flame-retardant hard polyurethane foam | |
| CN103467774A (en) | Composition applicable to surface flame retardance of rigid polyurethane foam insulation board | |
| CN109021837B (en) | Fireproof heat-preservation adhesive | |
| CN102320782B (en) | Composite fireproof coating of rice husk ash and metakaolin base polymer and preparation method thereof | |
| CN101429001A (en) | Energy-saving environment-friendly fireproof thermal-insulation composite material | |
| CN104086913A (en) | Flame-retardant EPS (expandable polystyrene) foam thermal-insulation board and preparation method thereof | |
| CN105694648B (en) | The resistance to fire-proof and explosion-proof coating of hydro carbons | |
| CN102276215A (en) | Fireproof and flame-retarding interface agent for organic thermal-insulation material | |
| CN102493566A (en) | Flame-retardant expandable polystyrene (EPS) insulation board and preparation method thereof | |
| CN102443185B (en) | Organic fire-proof warm-keeping particles, and preparation process and application thereof | |
| CN101798195B (en) | Thermosetting resin base fire retardant module | |
| CN106633151A (en) | Fireproof and flame retardant surface treating agent for foam insulating material and preparation method of surface treating agent | |
| CN103979860A (en) | Waterproof lightweight partition plate and manufacturing method thereof | |
| CN103601463A (en) | Magnesium cement inorganic heat insulation material and preparation method thereof | |
| CN106188918B (en) | A kind of fire-retardant heat insulation plate and its preparation method and application | |
| CN103911025A (en) | Water-based fireproof coating | |
| CN106752143B (en) | A kind of calcined diatomite non-intumescent fireproof coating | |
| CN105174897A (en) | Flame-retardant external wall thermal insulation material and preparation method thereof | |
| CN103131288A (en) | Fire retardant coating and preparation method thereof | |
| CN103387362A (en) | Flame-retardant polymer cement paper and preparation method thereof | |
| CN104556923A (en) | Flame-retardant and aging-resistant composite heat-preservation material, as well as preparation method and application thereof | |
| CN104844131A (en) | Flame-retardant heat insulating material | |
| CN102584122A (en) | Building heat preservation mortar | |
| CN108237609A (en) | A kind of gypsum-base self-adjusting wet suspended ceiling decoration material | |
| CN108003832B (en) | Environmentally friendly adhesive and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20131225 |