[go: up one dir, main page]

CN103465436A - Method for manufacturing fiber reinforced product with combination mechanism - Google Patents

Method for manufacturing fiber reinforced product with combination mechanism Download PDF

Info

Publication number
CN103465436A
CN103465436A CN2012101885361A CN201210188536A CN103465436A CN 103465436 A CN103465436 A CN 103465436A CN 2012101885361 A CN2012101885361 A CN 2012101885361A CN 201210188536 A CN201210188536 A CN 201210188536A CN 103465436 A CN103465436 A CN 103465436A
Authority
CN
China
Prior art keywords
fiber
semi
finished product
reinforced
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2012101885361A
Other languages
Chinese (zh)
Other versions
CN103465436B (en
Inventor
陈美玉
刘志隆
张义忠
洪光辉
张砚钧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Advanced International Multitech Co Ltd
Original Assignee
Advanced International Multitech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advanced International Multitech Co Ltd filed Critical Advanced International Multitech Co Ltd
Priority to CN201210188536.1A priority Critical patent/CN103465436B/en
Publication of CN103465436A publication Critical patent/CN103465436A/en
Application granted granted Critical
Publication of CN103465436B publication Critical patent/CN103465436B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Diaphragms For Electromechanical Transducers (AREA)
  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

A method of manufacturing a fiber-reinforced product having a bonding mechanism, comprising the steps of: stacking a plurality of fiber reinforced materials impregnated with thermosetting resin and a thermosetting polymer membrane into a composite substrate; (B) placing the composite substrate in a hot-pressing mould to be hot-pressed into a semi-finished product, wherein the semi-finished product comprises an intermediate layer formed by the thermosetting polymer membrane and a body which is connected with the intermediate layer and is formed by the fiber reinforced material; (C) coating an adhesive on the intermediate layer to form an adhesive layer; (D) and placing the semi-finished product in a forming die to form a combining mechanism combined with the adhesive layer. By matching the medium layer with the adhesion layer, the bonding force between the semi-finished product and the bonding mechanism can be improved, and the semi-finished product can be effectively prevented from being broken or peeled off under the action of external force.

Description

具结合机构的纤维强化产品的制造方法Method for manufacturing fiber-reinforced product with bonding mechanism

技术领域 technical field

本发明涉及一种纤维强化产品的制造方法,特别是涉及一种具结合机构的纤维强化产品的制造方法。The invention relates to a method for manufacturing a fiber-reinforced product, in particular to a method for manufacturing a fiber-reinforced product with a bonding mechanism.

背景技术 Background technique

随着工业技术与生活水平的提升,人们对于各式产品的要求也愈来愈高,不只要求价格便宜与实用性,还更进一步要求美观、质轻,及使用寿命长等功能。With the improvement of industrial technology and living standards, people have higher and higher requirements for various products. They not only require low price and practicality, but also further require functions such as beauty, light weight, and long service life.

因此,近年来,日常生活中以高强度且质轻的纤维强化材料所制成的产品愈来愈多,又以碳纤维强化材料的产品最为常见,但是,众所周知,碳纤维复合材料大多以热压方式成型,因此多用于制造如:板状、管状或柱状等断面均一的产品,若要成型出具有较复杂的特征结构的产品,往往需要分别成型后,再以人工方式利用机械力(例如:销、铆钉、螺丝等)或黏合剂相互结合,如此,不但尺寸精度差且费时费工。Therefore, in recent years, more and more products are made of high-strength and light-weight fiber-reinforced materials in daily life, and products made of carbon fiber-reinforced materials are the most common. Forming, so it is mostly used to manufacture products with uniform cross-section such as plate, tube or column. If you want to form products with more complex characteristic structures, you often need to form them separately, and then use mechanical force manually (for example: pin , rivets, screws, etc.) or adhesives are combined with each other, so that not only poor dimensional accuracy but also time-consuming and labor-intensive.

为克服上述缺点,相关业者研发出如日本第2010-046939号「一体成型成品的制造方法」,主要是将一含有热塑性树脂且端部成锥状的纤维强化复合材料板置于一模具中,利用射包成型技术将附着件射出成型于该纤维强化复合材料板上。In order to overcome the above-mentioned shortcomings, related companies have developed such as Japanese No. 2010-046939 "Manufacturing Method of Integral Molded Products", which mainly involves placing a fiber-reinforced composite material plate containing thermoplastic resin and tapered at the end into a mold. The attachment part is injection-molded on the fiber-reinforced composite material board by using the injection molding technique.

但是,热塑性树脂的强度与刚性较差,造成该附着件与该纤维强化复合材料板的结合力不足,而容易因外力而发生断裂或剥离。However, the thermoplastic resin has poor strength and rigidity, which results in insufficient bonding force between the attachment part and the fiber-reinforced composite material board, and is prone to breakage or peeling due to external force.

发明内容 Contents of the invention

本发明的目的在于提供一种结合力较为稳定的具结合机构的纤维强化产品的制造方法。The purpose of the present invention is to provide a method for manufacturing a fiber-reinforced product with a bonding mechanism with relatively stable bonding force.

本发具结合机构的纤维强化产品的制造方法,包含下列步骤:(A)将数个含浸热固性树脂的纤维强化材料与一个热固性高分子膜片堆叠成为一个复合基材,该热固性高分子膜片是选自聚醚类或聚酰胺高分子材料所制成,(B)将该复合基材置于一个热压模具中热压成为一半成品,该半成品包括一个由该热固性高分子膜片所形成的中介层,及一个与该中介层相连接且由所述纤维强化材料形成的本体,(C)在该中介层上涂覆黏着剂以形成一个黏着层,(D)将该半成品置于一个成型模具中,利用射出成型技术将热塑性高分子材料充填于该成型模具中,以成型出一个与该黏着层相互结合的结合机构,进而获得一具结合机构的纤维强化产品。The method for manufacturing a fiber-reinforced product with a combination mechanism includes the following steps: (A) stacking several fiber-reinforced materials impregnated with a thermosetting resin and a thermosetting polymer membrane to form a composite substrate, and the thermosetting polymer membrane It is made of polyether or polyamide polymer materials. (B) Place the composite base material in a hot pressing mold and heat press it into a semi-finished product. The semi-finished product includes a thermosetting polymer film. an intermediate layer, and a body connected to the intermediate layer and formed of the fiber reinforced material, (C) coating the adhesive on the intermediate layer to form an adhesive layer, (D) placing the semi-finished product in a In the forming mold, the injection molding technology is used to fill the thermoplastic polymer material into the forming mold to form a bonding mechanism combined with the adhesive layer, thereby obtaining a fiber-reinforced product with a bonding mechanism.

本发明具结合机构的纤维强化产品的制造方法,该步骤(B)中的该半成品的本体具有相反的一个第一表面与一个第二表面,及一个环绕该第一表面与该第二表面的周缘的环绕面,该中介层是包覆该第二表面与该环绕面。In the method for manufacturing a fiber-reinforced product with a bonding mechanism of the present invention, the body of the semi-finished product in step (B) has a first surface and a second surface opposite to each other, and a ring surrounding the first surface and the second surface. The surrounding surface of the periphery, the intermediary layer covers the second surface and the surrounding surface.

本发明具结合机构的纤维强化产品的制造方法,该步骤(B)中的该半成品的本体具有相反的一个第一表面与一个第二表面,及一个环绕该第一表面与该第二表面的周缘的环绕面,该中介层是环绕该环绕面。In the method for manufacturing a fiber-reinforced product with a bonding mechanism of the present invention, the body of the semi-finished product in step (B) has a first surface and a second surface opposite to each other, and a ring surrounding the first surface and the second surface. A surrounding surface of the periphery, the interposer surrounds the surrounding surface.

本发明具结合机构的纤维强化产品的制造方法,该步骤(A)中所述含浸热固性树脂的纤维强化材料是含浸环氧树脂的碳纤维预浸布,该热固性高分子膜片是聚氨基甲酸酯所制成。The method for manufacturing a fiber-reinforced product with a bonding mechanism of the present invention, the fiber-reinforced material impregnated with a thermosetting resin in the step (A) is a carbon fiber prepreg impregnated with an epoxy resin, and the thermosetting polymer membrane is polyurethane made from esters.

本发明的有益效果在于:利用由热固性高分子膜片所形成的中介层,以确实包着由所述纤维强化材料形成的本体,而提供足够的强度与刚性,配合黏着剂所形成的黏着层,不但能提升该半成品与该结合机构间的结合力与稳定性,还能有效避免受外力作用而发生断裂或剥离。The beneficial effect of the present invention lies in: using the intermediary layer formed by the thermosetting polymer film to surely wrap the body formed by the fiber reinforced material to provide sufficient strength and rigidity, and to cooperate with the adhesive layer formed by the adhesive , not only can improve the bonding force and stability between the semi-finished product and the bonding mechanism, but also can effectively prevent fracture or peeling due to external force.

附图说明 Description of drawings

图1是一流程图,说明本发明具结合机构的纤维强化产品的制造方法的较佳实施例。Fig. 1 is a flow chart illustrating a preferred embodiment of the method of manufacturing a fiber-reinforced product with bonding mechanism of the present invention.

图2是一示意图,辅助说明图1。FIG. 2 is a schematic diagram to assist in explaining FIG. 1 .

具体实施方式 Detailed ways

下面结合附图及实施例对本发明进行详细说明。The present invention will be described in detail below in conjunction with the accompanying drawings and embodiments.

参阅图1、2,本发明具结合机构的纤维强化产品的制造方法的一较佳实施例,首先,是如步骤21所示,将数个含浸热固性树脂的纤维强化材料31与一个热固性高分子膜片32堆叠成为一个复合基材33,该热固性高分子膜片32是选自聚醚类(Polyethers)或聚酰胺类(polyamide)高分子材料所制成。Referring to Figures 1 and 2, a preferred embodiment of the method for manufacturing a fiber-reinforced product with a bonding mechanism in the present invention, first, as shown in step 21, several fiber-reinforced materials 31 impregnated with thermosetting resin and a thermosetting polymer The membranes 32 are stacked to form a composite substrate 33 , and the thermosetting polymer membrane 32 is made of polyethers or polyamide polymer materials.

于本较佳实施例中,所述含浸热固性树脂的纤维强化材料31是含浸环氧树脂的碳纤维预浸布,该热固性高分子膜片32是聚氨基甲酸酯(polyurethane,PU)所制成。In this preferred embodiment, the fiber reinforced material 31 impregnated with thermosetting resin is a carbon fiber prepreg cloth impregnated with epoxy resin, and the thermosetting polymer membrane 32 is made of polyurethane (PU) .

接着,如步骤22所示,将该复合基材33置于一个热压模具200中热压成为一个半成品34,该半成品34包括一个由该热固性高分子膜片32所形成的中介层341,及一个位在该中介层341内且由所述纤维强化材料31形成的本体342。其中,该半成品34的本体342具有相反的一个第一表面343与一个第二表面344,及一个环绕该第一表面343与该第二表面344周缘的环绕面345,该中介层341是包覆该第二表面344与该环绕面345。Next, as shown in step 22, the composite substrate 33 is placed in a hot pressing mold 200 and heat-pressed to form a semi-finished product 34, the semi-finished product 34 includes an intermediary layer 341 formed by the thermosetting polymer film 32, and A body 342 is located in the intermediate layer 341 and formed by the fiber reinforced material 31 . Wherein, the body 342 of the semi-finished product 34 has an opposite first surface 343 and a second surface 344, and a surrounding surface 345 surrounding the periphery of the first surface 343 and the second surface 344, and the intermediary layer 341 is a coating The second surface 344 and the surrounding surface 345 .

在此要特别说明的是,于本较佳实施例中,该中介层341是包覆该第二表面344与该环绕面345,在实际应用上,能够通过热压模具200的设计,或是改变该热固性高分子膜片32与所述纤维强化材料31的堆叠方式,而使该中介层341只包覆该环绕面345,依然可达成相同的功效。It should be noted here that in this preferred embodiment, the intermediary layer 341 covers the second surface 344 and the surrounding surface 345. In practical applications, it can be achieved through the design of the hot pressing mold 200, or Changing the stacking method of the thermosetting polymer film 32 and the fiber reinforced material 31 so that the intermediary layer 341 only covers the surrounding surface 345 can still achieve the same effect.

然后,如步骤23所示,在该半成品34的中介层341上涂覆黏着剂以形成一个黏着层346。最后,如步骤24所示,将该半成品34置于一个成型模具201中,利用射出成型技术将热塑性高分子材料充填于该成型模具201中,以成型出一个与该黏着层346相互结合的结合机构35,进而获得一个具结合机构35的纤维强化产品36。Then, as shown in step 23 , an adhesive is coated on the intermediate layer 341 of the semi-finished product 34 to form an adhesive layer 346 . Finally, as shown in step 24, the semi-finished product 34 is placed in a forming mold 201, and the thermoplastic polymer material is filled in the forming mold 201 by using injection molding technology to form a combination with the adhesive layer 346. mechanism 35, and then obtain a fiber-reinforced product 36 with a bonding mechanism 35.

利用将该热固性高分子膜片32与所述纤维强化材料31堆叠成为该复合基材33,并经热压成为该半成品34,使由该热固性高分子膜片32所形成的中介层341,能确实包着该由所述纤维强化材料31形成的本体342,借由强度与刚性较热塑性树脂佳的热固性高分子膜片32所形成的中介层341,以及涂覆于中介层341上的黏着层346,来结合以热塑性高分子材料射出成型的结合机构35,不但能够提升该结合机构35与该半成品34间的结合力与稳定性,还能提供足够的强度与刚性,避免该半成品34与该结合机构35受外力而容易发生断裂或剥离。By stacking the thermosetting polymer film 32 and the fiber reinforcement material 31 to form the composite base material 33, and then heat pressing to form the semi-finished product 34, the interlayer 341 formed by the thermosetting polymer film 32 can be The main body 342 formed by the fiber-reinforced material 31 is indeed wrapped, the interlayer 341 formed by the thermosetting polymer film 32 with better strength and rigidity than thermoplastic resin, and the adhesive layer coated on the intermediary layer 341 346, to combine the bonding mechanism 35 injection-molded with thermoplastic polymer materials, not only can improve the bonding force and stability between the bonding mechanism 35 and the semi-finished product 34, but also provide sufficient strength and rigidity to avoid the semi-finished product 34 and the semi-finished product 34. The coupling mechanism 35 is easily broken or peeled off due to external force.

综上所述,本发明具结合机构的纤维强化产品的制造方法,将该热固性高分子膜片32与所述纤维强化材料31堆叠成为该复合基材33,并经热压成为该半成品34,使由该热固性高分子膜片32所形成的中介层341,能确实包着该由所述纤维强化材料31形成的本体342,以提供足够的强度与刚性,配合黏着剂所形成的黏着层346,不但能提升该半成品34与该结合机构35间的结合力与稳定性,还能有效避免受外力作用而发生断裂或剥离,所以确实能达成本发明的目的。To sum up, the method for manufacturing a fiber-reinforced product with a bonding mechanism of the present invention includes stacking the thermosetting polymer membrane 32 and the fiber-reinforced material 31 to form the composite base material 33, and heat-pressing to form the semi-finished product 34, The intermediary layer 341 formed by the thermosetting polymer film 32 can definitely wrap the body 342 formed by the fiber reinforced material 31 to provide sufficient strength and rigidity, and cooperate with the adhesive layer 346 formed by the adhesive , not only can improve the bonding force and stability between the semi-finished product 34 and the bonding mechanism 35, but also effectively avoid fracture or peeling due to external force, so the purpose of the present invention can indeed be achieved.

Claims (4)

1.一种具结合机构的纤维强化产品的制造方法,其特征在于:1. A method of manufacturing a fiber-reinforced product with a bonding mechanism, characterized in that: 该制造方法包含下列步骤:(A)将数个含浸热固性树脂的纤维强化材料与一个热固性高分子膜片堆叠成为一个复合基材,该热固性高分子膜片是选自聚醚类或聚酰胺高分子材料所制成,(B)将该复合基材置于一个热压模具中热压成为一半成品,该半成品包括一个由该热固性高分子膜片所形成的中介层,及一个与该中介层相连接且由所述纤维强化材料形成的本体,(C)在该中介层上涂覆黏着剂以形成一个黏着层,(D)将该半成品置于一个成型模具中,利用射出成型技术将热塑性高分子材料充填于该成型模具中,以成型出一个与该黏着层相互结合的结合机构,进而获得一具结合机构的纤维强化产品。The manufacturing method includes the following steps: (A) stacking several fiber reinforced materials impregnated with thermosetting resin and a thermosetting polymer membrane to form a composite substrate, the thermosetting polymer membrane is selected from polyether or polyamide high (B) placing the composite base material in a hot-pressing mold and hot-pressing it into a semi-finished product, the semi-finished product includes an intermediary layer formed by the thermosetting polymer film, and an interlayer with the intermediary layer connected and formed of said fiber-reinforced material, (C) applying an adhesive to the intermediary layer to form an adhesive layer, (D) placing the semi-finished product in a forming mold, and injecting the thermoplastic The polymer material is filled in the forming mold to form a combination mechanism combined with the adhesive layer to obtain a fiber-reinforced product with a combination mechanism. 2.根据权利要求1所述具结合机构的纤维强化产品的制造方法,其特征在于:该步骤(B)中的该半成品的本体具有相反的一个第一表面与一个第二表面,及一个环绕该第一表面与该第二表面的周缘的环绕面,该中介层是包覆该第二表面与该环绕面。2. The method for manufacturing a fiber-reinforced product with a bonding mechanism according to claim 1, wherein the body of the semi-finished product in the step (B) has a first surface and a second surface opposite to each other, and a surrounding The surrounding surface of the first surface and the periphery of the second surface, the intermediary layer covers the second surface and the surrounding surface. 3.根据权利要求1所述具结合机构的纤维强化产品的制造方法,其特征在于:该步骤(B)中的该半成品的本体具有相反的一个第一表面与一个第二表面,及一个环绕该第一表面与该第二表面的周缘的环绕面,该中介层是环绕该环绕面。3. The method for manufacturing a fiber-reinforced product with a bonding mechanism according to claim 1, characterized in that: the body of the semi-finished product in the step (B) has a first surface and a second surface opposite, and a surrounding The surrounding surface of the first surface and the periphery of the second surface, the intermediary layer surrounds the surrounding surface. 4.根据权利要求1至3项中任一所述具结合机构的纤维强化产品的制造方法,特征在于:该步骤(A)中所述含浸热固性树脂的纤维强化材料是含浸环氧树脂的碳纤维预浸布,该热固性高分子膜片是由聚氨基甲酸酯所制成。4. The method for manufacturing a fiber-reinforced product with a bonding mechanism according to any one of claims 1 to 3, characterized in that: the fiber-reinforced material impregnated with thermosetting resin in the step (A) is carbon fiber impregnated with epoxy resin Prepreg, the thermosetting polymer film is made of polyurethane.
CN201210188536.1A 2012-06-08 2012-06-08 Method for manufacturing fiber-reinforced product with bonding mechanism Expired - Fee Related CN103465436B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210188536.1A CN103465436B (en) 2012-06-08 2012-06-08 Method for manufacturing fiber-reinforced product with bonding mechanism

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210188536.1A CN103465436B (en) 2012-06-08 2012-06-08 Method for manufacturing fiber-reinforced product with bonding mechanism

Publications (2)

Publication Number Publication Date
CN103465436A true CN103465436A (en) 2013-12-25
CN103465436B CN103465436B (en) 2015-11-04

Family

ID=49790593

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210188536.1A Expired - Fee Related CN103465436B (en) 2012-06-08 2012-06-08 Method for manufacturing fiber-reinforced product with bonding mechanism

Country Status (1)

Country Link
CN (1) CN103465436B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10695991B2 (en) 2014-11-25 2020-06-30 Volkswagen Aktiengesellschaft Process arrangement and method for producing a fiber-reinforced plastic component
US11004792B2 (en) 2018-09-28 2021-05-11 Intel Corporation Microelectronic device including fiber-containing build-up layers

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6143540A (en) * 1984-08-06 1986-03-03 Mazda Motor Corp Manufacture of frp parts
EP0650822A2 (en) * 1993-10-29 1995-05-03 Toyota Jidosha Kabushiki Kaisha A method of forming a product integrally with a surface layer and the product itself
WO2003061941A1 (en) * 2002-01-22 2003-07-31 Weidmann Plastics Technology Ag Method for producing an adhesive moulded body, and a moulded body produced according to said method
CN101224618A (en) * 2007-01-17 2008-07-23 梁徽湖 Injection molding device and method for combined film
JP2010046939A (en) * 2008-08-22 2010-03-04 Toray Ind Inc Method for producing integrated molding

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6143540A (en) * 1984-08-06 1986-03-03 Mazda Motor Corp Manufacture of frp parts
EP0650822A2 (en) * 1993-10-29 1995-05-03 Toyota Jidosha Kabushiki Kaisha A method of forming a product integrally with a surface layer and the product itself
WO2003061941A1 (en) * 2002-01-22 2003-07-31 Weidmann Plastics Technology Ag Method for producing an adhesive moulded body, and a moulded body produced according to said method
CN101224618A (en) * 2007-01-17 2008-07-23 梁徽湖 Injection molding device and method for combined film
JP2010046939A (en) * 2008-08-22 2010-03-04 Toray Ind Inc Method for producing integrated molding

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10695991B2 (en) 2014-11-25 2020-06-30 Volkswagen Aktiengesellschaft Process arrangement and method for producing a fiber-reinforced plastic component
US11004792B2 (en) 2018-09-28 2021-05-11 Intel Corporation Microelectronic device including fiber-containing build-up layers
US11664313B2 (en) 2018-09-28 2023-05-30 Intel Corporation Microelectronic device including fiber-containing build-up layers

Also Published As

Publication number Publication date
CN103465436B (en) 2015-11-04

Similar Documents

Publication Publication Date Title
GB2448951B (en) Manufacture of fibre-reinforced composite moulding
WO2009016552A3 (en) A method of manufacturing a curved element made of composite material
WO2013008720A1 (en) Thermoplastic resin pre-preg, molded preform and molded composite using same, and method for producing molded preform and molded composite
CN102626974A (en) Carbon fiber shell processing technology
CN103465436B (en) Method for manufacturing fiber-reinforced product with bonding mechanism
TWI447025B (en) Method for manufacturing fiber reinforced products with bonding mechanism
CN201350707Y (en) Continuous reinforced fiber laminate structure
CN114554761B (en) A method for preparing a shell, a shell and an electronic device
TWI429534B (en) Method for manufacturing fiber reinforced shell
TWI457234B (en) Shell
KR101144768B1 (en) Manufacturing Method for Composite Sandwiches
WO2013099993A1 (en) Injection molded article using prepreg, and production method for injection molded article
CN102922832A (en) Fabrication method of fiber reinforced shell
CN203457450U (en) Multilayer board 3C product shell
CN103802269A (en) Injection molding method of carbon plate composite material and product thereof
TWI496692B (en) The forming method of three - dimensional fiber shell
TW202212113A (en) Method for manufacturing composite material product which is time-saving and labor-saving and has better bonding strength
CN220784955U (en) Apparatus for producing composite board
CN102442040A (en) Forming method of fiber product and finished product thereof
CN104441592A (en) Forming method of fiber shell
TW202220833A (en) A production method of a fiber composite material
CN103171061B (en) Method of manufacturing an angled fiber reinforced shell
CN104669634A (en) Forming method of fiber shell
CN204471676U (en) An aluminum substrate for making molds
CN101486881A (en) Reinforcing material for composite material structure unit interface and adding method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20151104

Termination date: 20210608