CN103464305B - Noble metals beneficiation agent and preparation method and application thereof - Google Patents
Noble metals beneficiation agent and preparation method and application thereof Download PDFInfo
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- CN103464305B CN103464305B CN201310401606.1A CN201310401606A CN103464305B CN 103464305 B CN103464305 B CN 103464305B CN 201310401606 A CN201310401606 A CN 201310401606A CN 103464305 B CN103464305 B CN 103464305B
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- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 60
- 239000000276 potassium ferrocyanide Substances 0.000 claims abstract description 15
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 claims abstract description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004202 carbamide Substances 0.000 claims abstract description 13
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 29
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 21
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 20
- 229910052737 gold Inorganic materials 0.000 claims description 20
- 239000010931 gold Substances 0.000 claims description 20
- 238000005660 chlorination reaction Methods 0.000 claims description 14
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 9
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 9
- 239000004571 lime Substances 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- AAJRIJBGDLLRAE-UHFFFAOYSA-M sodium;butoxymethanedithioate Chemical group [Na+].CCCCOC([S-])=S AAJRIJBGDLLRAE-UHFFFAOYSA-M 0.000 claims description 6
- 238000007796 conventional method Methods 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 229910000906 Bronze Inorganic materials 0.000 claims description 3
- 239000010974 bronze Substances 0.000 claims description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940072033 potash Drugs 0.000 claims description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 3
- 235000015320 potassium carbonate Nutrition 0.000 claims description 3
- OMKVZYFAGQKILB-UHFFFAOYSA-M potassium;butoxymethanedithioate Chemical compound [K+].CCCCOC([S-])=S OMKVZYFAGQKILB-UHFFFAOYSA-M 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 239000000284 extract Substances 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 6
- 239000011780 sodium chloride Substances 0.000 abstract description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000003814 drug Substances 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- -1 thiocarbamic acid ester Chemical class 0.000 description 2
- 239000012991 xanthate Substances 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 description 1
- 239000000264 sodium ferrocyanide Substances 0.000 description 1
- GTSHREYGKSITGK-UHFFFAOYSA-N sodium ferrocyanide Chemical compound [Na+].[Na+].[Na+].[Na+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] GTSHREYGKSITGK-UHFFFAOYSA-N 0.000 description 1
- 235000012247 sodium ferrocyanide Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses noble metals beneficiation agent. The noble metals beneficiation agent is characterized by containing 6-12 parts of alkali hydroxide, 8-16 parts of alkali carbonate, 20-40 parts of urea, 12-20 parts of potassium ferrocyanide, 4-8 parts of sodium chloride cynanide, and 2-5 parts of butyl xanthate. A preparation method of the noble metals beneficiation agent includes: proportionally mixing well the alkali hydroxide, the alkali carbonate, the urea and the potassium ferrocyanide, heating to 600-1000 DEG C to keep material molten for 1-2h, cooling to the room temperature, crushing, and evenly mixing the crushed material with the sodium chloride cynanide and the butyl xanthate so as to obtain the noble metals beneficiation agent. The invention further discloses an application method of the noble metals beneficiation agent.
Description
Technical field
The present invention relates to the oxide of a kind of noble metal mineral dressing additive, particularly gold, silver and copper or/and the dressing agent and its preparation method and application of sulfide.
Background technology
Along with improving constantly of people's living standard, the demand of gold expanded rapidly, only have continuous searching, develop new gold mineral product resource, the pursuit of people to U.S. could be met.But along with the exhaustion of high-grade gold deposits, and consider economy and environment protection problem, the process of poor value must be studied, leach a difficult problem.Chinese patent title: a kind of mineral dressing additive for gold mine and preparation method thereof, Application Number (patent): 201010553418.7, open (bulletin) number: CN102166545A, application (patent right) people: fault is bright, disclose a kind of additive that can process low-grade gold, this additive has advantages such as leaching the rate of recovery is high, environmental protection, but this dressing agent can only be applicable to Precious metal oxidation ore deposit, very poor to the leaching effect of noble metal sulphide ore, and often the oxide ore of noble metal and sulphide ore are symbiosis, this causes the waste of the resource of noble metal unavoidably.Also the dressing agent report being applicable to noble metal sulphide ore is had, as Chinese patent title: noble metal and nonferrous metal sulfide mineral composite chemical for floatating, Application Number (patent): the CN99113384.6 applying date: 1999.10.29, open (bulletin) number: CN1294032, open (bulletin) day: 2001.05.09, application (patent right) people: Shenyang Mining and Metallurgical Industry Inst., address: south, Tiexi District, Shenyang City, Liaoning Province No. 70, nine Road invention (design) people: Han Shushan makes a summary: noble metal and nonferrous metal sulfide mineral floating agent field, contain: dialkyl dithiophosphate 30%-60%, dialkyl thiocarbamic acid ester 8%-14%, mixed fatty alcohol 8%-24%, aromatic naphtha 4%-8%, sodium carboxymethylcellulose 0%-30%, water 15%-36%, it is little that this invention has consumption, cost is low, medicament interpolation system is easy, good improvement can be had to metal recovery index.But this dressing agent is made up of organic chemical reagent, price, and toxicity is high, has pollution to environment.
Summary of the invention
The object of the invention is openly a kind of dressing agent being applicable to Precious metal oxidation ore deposit and sulphide ore, this dressing agent is all made up of low toxicity or even nontoxic inorganic compound, and cost is low, environmentally friendly; Present invention also discloses preparation method and the using method of this dressing agent.
The solution of the present invention is:
Precious metal ore agent, comprises the raw material of following parts by weight:
Alkali metal hydroxide 6 ~ 12;
Alkali carbonate 8 ~ 16;
Urea 20 ~ 40;
Potassium ferrocyanide 12 ~ 20;
Chlorination hydroxyl sodium salt 4 ~ 8;
Butyl xanthate, 2 ~ 5;
Described alkali metal hydroxide is NaOH or potassium hydroxide or their mixture;
Described alkali carbonate is the composition of any one or they in sodium carbonate, potash, sodium acid carbonate or saleratus.
Described potassium ferrocyanide chemical name is potassium ferrocyanide (chemical formula K
4[Fe(CN)
6] 3H
2o), sodium ferrocyanide (chemical formula Na
4[Fe(CN)
6] 3H
2o), pale yellow crystals is the complex that iron and cyanogen are formed.Mainly for the manufacture of paint, ink, pigment, pharmacy, metal heat treatmet, salt anticaking agent, food additives and steel and iron industry and rub leather etc.
Described chlorination hydroxyl sodium salt, chemicals popular name: gold ore agent, chemical classes English name: Sodium chloride cynanide, chemical molecular formula: Na
3cNOHCl, be a kind of New Gold dressing agent, can be applicable to noble metal sulphide ore, cost is low, and toxicity is little.
Described butyl xanthate is sodium n-butyl-xanthate C
4h
9oCSSNa or potassium butyl xanthate C
4h
9oCSSK can be normal-butyl xanthates, also can be isobutyl group xanthates.
The production method of noble metal dressing agent of the present invention: alkali metal hydroxide, alkali carbonate, urea and potassium ferrocyanide are proportionally, mix, then 600 ~ 1000 DEG C are heated to, material is made to keep 1 ~ 2h in the molten state, be cooled to normal temperature, mix with chlorination hydroxyl sodium salt and butyl xanthate after pulverizing, obtain noble metal dressing agent.
The using method of described noble metal dressing agent is: by the water-soluble solution of noble metal dressing agent, and according to the dose of 50 grams ~ 250 grams, ore per ton, add in breeze and soak, extraction time is 5 ~ 20 hours.
The using method of noble metal dressing agent of the present invention, lime can also be added and admix use, method is: will add dressing agent of the present invention after ore grinding, ore per ton adds dressing agent 50 grams ~ 250 grams, ore per ton adds 20 ~ 30 kilograms, lime, and per kilogram noble metal dressing agent adds water in advance 200 kilograms and dissolves, and mixes with breeze, lime, the peak period of ore extraction time is 5 ~ 12 hours, then by conventional method gold recovering silver-bearing copper.
Outstanding substantive distinguishing features and the significant progress of noble metal dressing agent of the present invention are:
1. can be widely used in the production in noble metal mine, immersion, the heap of the oxide ore of such as gold, silver and bronze, the sulphide ore of gold, silver and bronze drench, the industrial production industries such as plating can also be used in, substitute the medicine of hypertoxic Cymag, compared with the nontoxic cyaniding medicine that other are all, have that the property of medicine is stable, medicine environmental protection, the advantages such as cost is lower.
2. noble metal dressing agent toxicity of the present invention is low, and security is high.
3 add chlorination hydroxyl sodium salt and butyl xanthate, collecting agent can also be made, its collecting ability is stronger, it is the collecting agent being applicable to copper, lead, zinc, Ni sulphide mine, special in the complicated ore containing a small amount of sulphide ore, such as to the sulphide ore raw material containing partial oxidation copper, lead ore, its collecting ability is strong.
Detailed description of the invention
Embodiment 1
Get NaOH 8kg, sodium carbonate 12kg, urea 24kg and potassium ferrocyanide 14kg, mixes, be heated to 600-1000 DEG C, after molten state, be incubated 1h, be cooled to room temperature, pulverize, add 5kg chlorination hydroxyl sodium salt, 1kg potassium butyl xanthate mixes, obtain noble metal dressing agent.
Embodiment 2
Get potassium hydroxide 10kg, potash 14kg, urea 30kg and potassium ferrocyanide 16kg, mixes, is heated to 600-1000 DEG C, is incubated 1.5h, is cooled to room temperature, pulverize, add 6kg chlorination hydroxyl sodium salt, 2kg sodium n-butyl-xanthate C after molten state
4h
9oCSSNa, mixes, and obtains noble metal dressing agent.
Embodiment 3
Get potassium hydroxide 6kg, sodium acid carbonate 16kg, urea 36kg and potassium ferrocyanide 18kg, mixes, is heated to 600-1000 DEG C, is incubated 1.5h, is cooled to room temperature, pulverize, add 7kg chlorination hydroxyl sodium salt, 2kg sodium n-butyl-xanthate C after molten state
4h
9oCSSNa, to mix, obtain noble metal dressing agent.
Embodiment 4
Get potassium hydroxide 12kg, saleratus 8kg, urea 20kg and potassium ferrocyanide 12kg, mixes, is heated to 600-1000 DEG C, is incubated 2h, is cooled to room temperature, pulverize, add 4kg chlorination hydroxyl sodium salt, mix, obtain noble metal dressing agent after molten state.
Embodiment 5
Get NaOH 12kg, sodium acid carbonate 10kg, urea 40kg and potassium ferrocyanide 20kg, mixes, be heated to 600-1000 DEG C, after molten state, be incubated 2h, be cooled to room temperature, pulverize, add 8kg chlorination hydroxyl sodium salt, 3kg sodium isobutyl xanthan, mix, obtain noble metal dressing agent.
Embodiment 6
Get potassium hydroxide 6kg, sodium acid carbonate 16kg, urea 32kg and potassium ferrocyanide 18kg, mixes, is heated to 600-1000 DEG C, is incubated 1.5h, is cooled to room temperature, pulverize, add 6kg chlorination hydroxyl sodium salt, 5kg sodium n-butyl-xanthate C after molten state
4h
9oCSSNa, to mix, obtain noble metal dressing agent.
Use embodiment 1
Get 20 tons containing the gold certain Oxidized Gold Ore of 3.4 grams/ton and the aurosulfo ore of 0.56 gram/ton, add water and lime under agitation after pulverizing, then add the present invention 1000 grammes per square metre metal dressing agent, soak 20 hours, the liquid active carbon adsorption that then will leach, obtains 60.4 grams of gold after roasting, refinement.
Use embodiment 2
Get 20 tons of breezes containing gold 3.2 grams/ton, the breeze that argentiferous is 30.6 grams/ton, add the present invention 5000 grammes per square metre metal dressing agent, heavy metal dressing agent adds water in advance 200 kilograms and dissolves, mix with breeze, 400kg lime, soak 12 hours, then reclaimed by conventional method, obtain 46.4 grams of metallic gold, 517.7 grams of argents.
Use embodiment 3
Get ore deposit silver oxide and the silver sulfide ore of 20 tons of argentiferous 50.4 grams/ton, the present invention 2500 grammes per square metre metal dressing agent is added after pulverizing, heavy metal dressing agent adds water in advance 200 kilograms and dissolves, mix with breeze, 500kg lime, soak 5 hours, then reclaimed by conventional method, obtain 826.6 grams of argents.
Use embodiment 4
Get 20 tons of argentiferous 30.4 grams/ton, the ore that cupric is 60 grams/ton, the present invention 4000 grammes per square metre metal dressing agent is added after pulverizing, heavy metal dressing agent adds water in advance 200 kilograms and dissolves, mix with breeze, 560kg lime, soak 15 hours, then reclaimed by conventional method, obtain 522.9 grams of argents, 1026.4 grams of copper.
Comparative example
Get NaOH 8kg, sodium carbonate 12kg, urea 24kg and potassium ferrocyanide 14kg, mixes, is heated to 600-1000 DEG C, is incubated 1h, is cooled to room temperature, pulverize, obtain dressing agent A after molten state.
The noble metal dressing agent obtained by dressing agent A and embodiment 2 contains the breeze of gold 3.2 grams/ton to 20 tons, and the breeze that argentiferous is 30.6 grams/ton, leaches under similarity condition, and the noble metal dressing agent of embodiment 2 obtains 46.4 grams of metallic gold, 517.7 grams of silver; Dressing agent A obtains 44.2 grams of metallic gold, 503.4 grams of silver; This is because the noble metal dressing agent that embodiment 2 obtains contains chlorination hydroxyl sodium salt and sodium n-butyl-xanthate, it can leach the noble metal in noble metal sulphide, and therefore the yield of noble metal is high.
The noble metal dressing agent that other embodiment is produced also has good leaching rate to the precious metal ore containing sulfide.
Claims (5)
1. a noble metal dressing agent, is characterized in that, comprises the raw material of following parts by weight:
Alkali metal hydroxide 6 ~ 12;
Alkali carbonate 8 ~ 16;
Urea 20 ~ 40;
Potassium ferrocyanide 12 ~ 20;
Chlorination hydroxyl sodium salt 4 ~ 8;
Butyl xanthate 2 ~ 5;
Described alkali metal hydroxide is NaOH or potassium hydroxide or their mixture;
Described alkali carbonate is the composition of any one or they in sodium carbonate, potash, sodium acid carbonate or saleratus;
Described chlorination hydroxyl sodium salt chemical formula is Na
3cNOHCl;
Described butyl xanthate is sodium n-butyl-xanthate or potassium butyl xanthate.
2. the production method of noble metal dressing agent according to claim 1, it is characterized in that, alkali metal hydroxide, alkali carbonate, urea and potassium ferrocyanide are proportionally, mix, then be heated to 600 ~ 1000 DEG C, make material keep 1 ~ 2h in the molten state, be cooled to normal temperature, mix with chlorination hydroxyl sodium salt and butyl xanthate after pulverizing, obtain noble metal dressing agent.
3. the using method of noble metal dressing agent according to claim 1, is characterized in that, by the water-soluble solution of noble metal dressing agent, according to the dose of 50 grams ~ 250 grams, ore per ton, add in breeze and soak, extraction time is 5 ~ 20 hours.
4. the using method of noble metal dressing agent according to claim 1, it is characterized in that, noble metal dressing agent will be added after ore grinding, ore per ton adds noble metal dressing agent 50 grams ~ 250 grams, ore per ton adds 20 ~ 30 kilograms, lime, and per kilogram noble metal dressing agent adds water in advance 200 kilograms and dissolves, and mixes with breeze, lime, the peak period of ore extraction time is 5 ~ 12 hours, then by conventional method gold recovering silver-bearing copper.
5. noble metal dressing agent according to claim 1 at the oxide of gold, silver and copper or/and sulfide extracts the application in gold, silver and bronze.
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| CN103861232B (en) * | 2014-03-21 | 2017-05-24 | 南京市环境保护科学研究院 | Stabilization chemical agent and processing method for processing nickel-containing dead catalyst |
| CN103981374B (en) * | 2014-05-19 | 2015-11-18 | 中国科学院兰州化学物理研究所 | A kind of environmentally friendly cyanate soaks the synthetic method of golden agent |
| CN108435438B (en) * | 2018-05-11 | 2020-10-09 | 西安建筑科技大学 | A kind of copper suppression inhibitor, preparation method and copper-bearing mineral flotation method |
| CN111926185A (en) * | 2020-07-09 | 2020-11-13 | 福建闽航电子有限公司 | Recycling process of precious metal |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0476078B1 (en) * | 1990-02-23 | 1994-09-07 | Cra Services Limited | Extraction and recovery of gold |
| CN102121067A (en) * | 2010-12-15 | 2011-07-13 | 广西富皇矿业有限公司 | Nuisanceless oredressing additive as well as preparation method and application thereof |
| CN102166545A (en) * | 2010-11-22 | 2011-08-31 | 阙明 | Mineral dressing additive for gold mine and preparation method thereof |
| CN102321807A (en) * | 2011-07-13 | 2012-01-18 | 广西富皇矿业有限公司 | Production and using method of environmentally-friendly noble metal mineral processing reagent |
-
2013
- 2013-09-06 CN CN201310401606.1A patent/CN103464305B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0476078B1 (en) * | 1990-02-23 | 1994-09-07 | Cra Services Limited | Extraction and recovery of gold |
| CN102166545A (en) * | 2010-11-22 | 2011-08-31 | 阙明 | Mineral dressing additive for gold mine and preparation method thereof |
| CN102121067A (en) * | 2010-12-15 | 2011-07-13 | 广西富皇矿业有限公司 | Nuisanceless oredressing additive as well as preparation method and application thereof |
| CN102321807A (en) * | 2011-07-13 | 2012-01-18 | 广西富皇矿业有限公司 | Production and using method of environmentally-friendly noble metal mineral processing reagent |
Non-Patent Citations (1)
| Title |
|---|
| 国内外金银综合回收研究的进展;巫汉泉;《矿产综合利用》;19841231(第1期);41-46页 * |
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