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CN103408808A - Automobile paste high-expansion vibration-reduction and sound-insulation rubber and manufacturing process thereof - Google Patents

Automobile paste high-expansion vibration-reduction and sound-insulation rubber and manufacturing process thereof Download PDF

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Publication number
CN103408808A
CN103408808A CN2013103353424A CN201310335342A CN103408808A CN 103408808 A CN103408808 A CN 103408808A CN 2013103353424 A CN2013103353424 A CN 2013103353424A CN 201310335342 A CN201310335342 A CN 201310335342A CN 103408808 A CN103408808 A CN 103408808A
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agent
rubber
automobile
add
sound
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CN103408808B (en
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李林森
夏振飞
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Shaanxi Baoguang Xinke Automotive Parts Co ltd
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Tianjin Jingda Bokwang Automobile Parts Co Ltd
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Abstract

The invention provides automobile paste high-expansion vibration-reduction and sound-insulation rubber and a manufacturing process thereof. Butadiene rubber, EVA, liquid butyronitrile, rubber oil, epoxy resin, polyisobutene, nano activated calcium carbonate, a foaming agent, sulfur, an accelerating agent, a rust inhibitor, a vulcanizing agent, a plasticizer and a tackifier are selected and used, and a pressure kneader is used for mixing the dispersed materials. The rubber is spread on corresponding parts of steel plates in an automobile body welding workshop by a glue spreading pump; the rubber passes through a painting shop after automobile body welding, is heated with an electrophoretic paint drying line to foam to fill up an entire cavity, and achieves the effects of vibration reduction, sound insulation, dust separation and dust prevention.

Description

Automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof
Technical field
The present invention relates to the automotive material technical field, re-entrant portion for the two block plates formation of three columns of automobile, or between ceiling outside plate and stiffening web, also can be used in vehicle body due to the position, gap produced between the rear inner and outer plates of welding, relate in particular to automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof.
Background technology
Car industry is in order to pursue the automobile of peace and quiet, comfortable, environmental protection, will cut off the noise that all re-entrant portions of vehicle body bring, the noise and the dust that bring from outside air of A, B, a C3 column particularly, these cavitys and column again can not be in the workshop shutoff that is welded, when vehicle body was crossed pre-treatment and electrophoresis line body, liquid will be from these cavity inflow and outflows, if shutoff after having crossed pre-treatment and electrophoresis line body, cavity is soldered, and material can't be put into cavity.The past people require lower to the car load comfortableness, a lot of cars do not focus on processing this problem, and along with the raising that client requires car comfort, car load factory more and more pays close attention to this problem.At present, automobile industry designer is widely used two kinds, the first is expansive niggerhead material after heating, and the second is the paste material of two components, although this bi-material can have certain effect, but defect is separately arranged respectively, the first material is bulk material, and the technique more complicated is not easy to automatic production and automated construction, and the quality guaranteed period is shorter, is unfavorable for long-distance transport and uses.The second material is two-component materials, needs special preparation of construction, and cost is higher, and Flame Retardancy is poor, is unfavorable for that big area is used on automobile.How just can overcome the above problems, and just can construction operation with common gluing pump in auto vendor.
Summary of the invention
In order to overcome the problem of prior art, the invention provides automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof, the smooth gluing of the enough common gluing pumps of energy, rate of expansion reaches the standard-required of current bulk material, reduce production cost and construction cost, overcome the disadvantage of this bi-material of current automobile industry use.
Technical scheme of the present invention is: automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof, select cis-1,4-polybutadiene rubber, EVA, nitrile (HTBN), rubber oil, epoxy resin, polyisobutene, nm-class active calcium carbonate, whipping agent, sulphur, promotor, rust-preventive agent, vulcanizing agent, softening agent, tackifier to use the pressurization kneader, the blending dispersion material is below the weight ratio of this material:
Figure BSA0000093423930000021
Manufacturing process steps is as follows: the first step: proportioning was put in Banbury mixer to banburying 10 minutes by cis-1,4-polybutadiene rubber and EVA, puts into rubber oil minutes for three times, make it softening, material mixing is even, without small-particle;
Second step: the material mixed is put in kneader, added nitrile (HTBN), mediated 10 minutes in kneader, then drop into nm-class active calcium carbonate, mediated 5 minutes, divide and slowly put into polyisobutene 3 times, guarantee that kneading process is without fine particle;
The 3rd step: when the kneader temperature is reduced to below 40 ℃, add whipping agent, sulphur, promotor, rust-preventive agent, vulcanizing agent, add softening agent to mediate evenly after mixing;
The 4th step: the viscosity according to product, add tackifier, adjust viscosity, viscosity is adjusted to 1000-1600 ten thousand CP (0.5RPM);
The 5th step: then vacuum 1 hour is packaged into the specification quantity of regulation.
The invention has the beneficial effects as follows: be convenient to the automatic production of auto vendor, the material phenomenon of not trickling, and can meet the performance requriements of the overseas assembling of domestic production.
Embodiment
Automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof, by cis-1,4-polybutadiene rubber, EVA, nitrile (HTBN), rubber oil, epoxy resin, polyisobutene, nm-class active calcium carbonate, whipping agent, sulphur, promotor, rust-preventive agent, vulcanizing agent, softening agent, tackifier, use the pressurization kneader, the blending dispersion material is below the weight ratio of this material:
Figure BSA0000093423930000031
Manufacturing process steps is as follows: the first step: proportioning was put in Banbury mixer to banburying 10 minutes by cis-1,4-polybutadiene rubber and EVA, puts into rubber oil minutes for three times, make it softening, material mixing is even, without small-particle;
Second step: the material mixed is put in kneader, added nitrile (HTBN), mediated 10 minutes in kneader, then drop into nm-class active calcium carbonate, mediated 5 minutes, divide and slowly put into polyisobutene 3 times, guarantee that kneading process is without fine particle;
The 3rd step: when the kneader temperature is reduced to below 40 ℃, add whipping agent, sulphur, promotor, rust-preventive agent, vulcanizing agent, add softening agent to mediate evenly after mixing;
The 4th step: the viscosity according to product, add tackifier, adjust viscosity, viscosity is adjusted to 1000-1600 ten thousand CP (0.5RPM);
The 5th step: then vacuum 1 hour is packaged into the specification quantity of regulation.
Corresponding site at car body welding shop steel plate is smeared this material with gluing pump, and after car body welding, along with the electrophoresis baking finish line, the post-foaming that is heated, fill full whole cavity through painting hall, plays vibration damping, dust-separation, dustproof effect.The present invention adds rust-preventive agent, guarantee on the rear adhesive surface of material foaming not get rusty phenomenon, the use of nano modified material and softening agent by good operability, make the paste material be convenient to smear, difficult drop-off again after smearing, and high rate of expansion reaches the standard-required of current bulk material, production cost and construction cost have been reduced.

Claims (2)

1. automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof, by cis-1,4-polybutadiene rubber, EVA, nitrile (HTBN), rubber oil, epoxy resin, polyisobutene, nm-class active calcium carbonate, whipping agent, sulphur, promotor, rust-preventive agent, vulcanizing agent, softening agent, tackifier, formed, it is characterized in that the weight ratio of material is:
Figure FSA0000093423920000011
2. automobile paste high expansion shock-absorption sound-insulation glue and manufacture craft thereof according to claim 1, it is characterized in that manufacturing process steps is as follows: the first step: proportioning was put in Banbury mixer to banburying 10 minutes by cis-1,4-polybutadiene rubber and EVA, divide and put into rubber oil three times, make it softening, material mixing is even, without small-particle, second step: the material mixed is put in kneader, add nitrile (HTBN), in kneader, mediated 10 minutes, drop into again nm-class active calcium carbonate, mediated 5 minutes, divide and slowly put into polyisobutene 3 times, guarantee that kneading process is without fine particle, the 3rd step: when the kneader temperature is reduced to below 40 ℃, add whipping agent, sulphur, promotor, rust-preventive agent, vulcanizing agent, after mixing, add softening agent to mediate evenly, the 4th step: according to the viscosity of product, add tackifier, adjust viscosity, viscosity is adjusted to 1000-1600 ten thousand CP (0.5RPM), the 5th step: vacuum 1 hour, then be packaged into the specification quantity of regulation.
CN201310335342.4A 2013-08-05 2013-08-05 Automobile paste height expansion shock-absorption sound-insulation glue and manufacture craft thereof Active CN103408808B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086856A (en) * 2015-08-31 2015-11-25 北京龙苑伟业新材料有限公司 Preformed automobile-damping expandable rubber belt with good oil surface construction and preparation method therefor
CN105175816A (en) * 2015-09-09 2015-12-23 北京龙苑伟业新材料有限公司 High-strength low-hardness damping rubber and preparation method thereof
CN106280037A (en) * 2016-08-09 2017-01-04 深圳市前海龙达新能源有限公司 A kind of modified rubber oil additive, preparation method and modified rubber oil thereof
CN106633635A (en) * 2016-11-07 2017-05-10 北京汽车股份有限公司 Foaming composition and cavity structure reinforcing structure
CN106750863A (en) * 2016-12-19 2017-05-31 钦州市科学技术开发中心 A kind of expandable cavity agent and preparation method thereof of automobile
CN110885656A (en) * 2019-12-16 2020-03-17 芜湖海程橡塑有限公司 Amorphous sealant for vehicles and preparation method thereof
CN111073068A (en) * 2019-12-25 2020-04-28 浙江世泰实业有限公司 Butadiene rubber dust cover and preparation method thereof
US10899109B2 (en) 2019-03-11 2021-01-26 Honda Motor Co., Ltd. Multi-material joint and method of making thereof
CN113717427A (en) * 2021-09-24 2021-11-30 海南必凯水性新材料有限公司 Spot-welding foaming sealant material for passenger car and preparation method and application thereof
CN113896970A (en) * 2021-11-17 2022-01-07 安徽江淮安驰汽车有限公司 Expansion shock insulation glue for body-in-white and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6369741A (en) * 1986-09-12 1988-03-29 タツタ電線株式会社 Flexible sound isolator
CN101735497A (en) * 2009-12-09 2010-06-16 浙江仕峰实业有限公司 Physical foaming ethane-butadiene rubber composite capable of being injected and crosslinked, as well as preparation method, product and processing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6369741A (en) * 1986-09-12 1988-03-29 タツタ電線株式会社 Flexible sound isolator
CN101735497A (en) * 2009-12-09 2010-06-16 浙江仕峰实业有限公司 Physical foaming ethane-butadiene rubber composite capable of being injected and crosslinked, as well as preparation method, product and processing method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086856A (en) * 2015-08-31 2015-11-25 北京龙苑伟业新材料有限公司 Preformed automobile-damping expandable rubber belt with good oil surface construction and preparation method therefor
CN105175816A (en) * 2015-09-09 2015-12-23 北京龙苑伟业新材料有限公司 High-strength low-hardness damping rubber and preparation method thereof
CN106280037A (en) * 2016-08-09 2017-01-04 深圳市前海龙达新能源有限公司 A kind of modified rubber oil additive, preparation method and modified rubber oil thereof
CN106280037B (en) * 2016-08-09 2018-10-16 深圳市前海龙达新能源有限公司 A kind of modified rubber oil additive, preparation method and its modified rubber oil
CN106633635A (en) * 2016-11-07 2017-05-10 北京汽车股份有限公司 Foaming composition and cavity structure reinforcing structure
CN106750863A (en) * 2016-12-19 2017-05-31 钦州市科学技术开发中心 A kind of expandable cavity agent and preparation method thereof of automobile
US10899109B2 (en) 2019-03-11 2021-01-26 Honda Motor Co., Ltd. Multi-material joint and method of making thereof
CN110885656A (en) * 2019-12-16 2020-03-17 芜湖海程橡塑有限公司 Amorphous sealant for vehicles and preparation method thereof
CN111073068A (en) * 2019-12-25 2020-04-28 浙江世泰实业有限公司 Butadiene rubber dust cover and preparation method thereof
CN113717427A (en) * 2021-09-24 2021-11-30 海南必凯水性新材料有限公司 Spot-welding foaming sealant material for passenger car and preparation method and application thereof
CN113896970A (en) * 2021-11-17 2022-01-07 安徽江淮安驰汽车有限公司 Expansion shock insulation glue for body-in-white and preparation method thereof

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Address after: 301700 No. 1 Guwang Road, Jingbin Industrial Park, Wuqing District, Tianjin

Patentee after: PAUL LIGHT (TIANJIN) AUTO PARTS CO.,LTD.

Address before: 301712 Tianjin Keihin Industrial Park of Wuqing District ancient road, No. 1

Patentee before: TIANJIN JINGDA BAOGUANG AUTOMOTIVE PARTS CO.,LTD.

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Effective date of registration: 20240307

Address after: 721000 Xiqin Road, Dongguan Science and Technology Industrial Park, Baoji City, Shaanxi Province

Patentee after: Shaanxi Baoguang Xinke Automotive Parts Co.,Ltd.

Country or region after: China

Address before: 301700 No.1 Guwang Road, Jingbin Industrial Park, Wuqing District, Tianjin

Patentee before: PAUL LIGHT (TIANJIN) AUTO PARTS CO.,LTD.

Country or region before: China