CN103387288A - Improved UCT sewage treatment plant - Google Patents
Improved UCT sewage treatment plant Download PDFInfo
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- CN103387288A CN103387288A CN2013102731789A CN201310273178A CN103387288A CN 103387288 A CN103387288 A CN 103387288A CN 2013102731789 A CN2013102731789 A CN 2013102731789A CN 201310273178 A CN201310273178 A CN 201310273178A CN 103387288 A CN103387288 A CN 103387288A
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Abstract
Description
技术领域technical field
本发明属于环境工程技术领域,具体为一种新型的改进的UCT污水处理装置。The invention belongs to the technical field of environmental engineering, in particular to a novel and improved UCT sewage treatment device.
背景技术Background technique
人们对于环境的日益重视,使得污水排放标准不断提高,且这些污水排放标准都受到法律的保护和社会舆论的监督。在我国,氮和磷污染物是最主要的污染物之一,他们的排放都受到了严格的监督和限制。A2/O工艺在理论上具有较好的污染物去除效果,且污泥沉降性能良好,能量消耗少。A2/O工艺通过硝化反硝化过程可以脱除大量的氮污染物,通过交替厌氧好氧和缺氧的过程,聚磷菌可以过量吸收和释放磷以去除磷污染物。但是A2/O工艺的弊端在于回流污泥中硝酸盐氮进入厌氧池,破坏厌氧池的厌氧状态而影响系统的磷污染物去除率。于是针对以上问题人们开发出了UCT工艺。UCT工艺是一种在我国使用较为广泛的污水处理工艺,其以较高的性价比,较为稳定的处理效果,得到了国内很多污水处理厂的青睐。但是现有的UCT工艺处理效果也还有许多值得改进的地方,究其原因是回流污泥中存在大量的溶解氧和硝酸盐氮,他们都会回流到UCT反应器的缺氧区从而影响缺氧区的反应效果。磷污染物的去除也受到了影响,因为回流污泥中含有大量的硝酸盐氮营养元素,他们会促使缺氧区中非聚磷菌的生长。People pay more and more attention to the environment, which leads to continuous improvement of sewage discharge standards, and these sewage discharge standards are protected by law and supervised by public opinion. In my country, nitrogen and phosphorus pollutants are one of the most important pollutants, and their discharge has been strictly supervised and restricted. Theoretically, the A2/O process has a good pollutant removal effect, and has good sludge settling performance and low energy consumption. The A2/O process can remove a large amount of nitrogen pollutants through nitrification and denitrification process, and through the process of alternating anaerobic aerobic and anoxic processes, phosphorus accumulating bacteria can absorb and release phosphorus excessively to remove phosphorus pollutants. However, the disadvantage of the A2/O process is that the nitrate nitrogen in the return sludge enters the anaerobic tank, destroying the anaerobic state of the anaerobic tank and affecting the removal rate of phosphorus pollutants in the system. So in response to the above problems, people developed the UCT process. The UCT process is a sewage treatment process that is widely used in my country. It has been favored by many domestic sewage treatment plants for its high cost performance and relatively stable treatment effect. However, the treatment effect of the existing UCT process still has many areas worth improving. The reason is that there are a large amount of dissolved oxygen and nitrate nitrogen in the return sludge, and they will all flow back to the anoxic zone of the UCT reactor to affect the anoxic process. area response. The removal of phosphorus pollutants was also affected because the return sludge contains a large amount of nitrate nitrogen nutrients, which can promote the growth of non-phosphorus accumulating bacteria in the anoxic zone.
发明内容Contents of the invention
本发明的目的在于提供一种改进的UCT污水处理装置,它可避免现有UCT因回流污泥中存在大量的溶解氧和硝酸盐氮,而对缺氧区的脱氮除磷效果造成不良影响。The purpose of the present invention is to provide an improved UCT sewage treatment device, which can avoid the existing UCT from causing adverse effects on the denitrification and phosphorus removal in the anoxic zone due to the presence of a large amount of dissolved oxygen and nitrate nitrogen in the return sludge .
本发明的技术方案是:一种改进的UCT污水处理装置,按污水处理顺序包括依次相连通的厌氧反应器、缺氧反应器、好氧反应器、澄清池,厌氧反应器与缺氧反应器之间,以及缺氧反应器与好氧反应器之间分别设有内回流管,其特征在于:经澄清池后的回流污泥与好氧反应器连通。The technical scheme of the present invention is: a kind of improved UCT sewage treatment device, comprises anaerobic reactor, anoxic reactor, aerobic reactor, clarifier, anaerobic reactor connected with anoxic Internal return pipes are provided between the reactors, and between the anoxic reactor and the aerobic reactor, and the feature is that the return sludge after passing through the clarification tank is connected with the aerobic reactor.
有益效果:本发明回流污泥中存在大量的溶解氧进入好氧区,可以促进好氧区中微生物对于COD的降解,同时回流污泥中存在大量的硝酸盐氮进入好氧区,可以在一定程度上促进好氧区中微生物的脱氮效果。本发明对于市政污水有很好的处理效果。Beneficial effects: a large amount of dissolved oxygen in the return sludge of the present invention enters the aerobic zone, which can promote the degradation of COD by microorganisms in the aerobic zone, and at the same time, a large amount of nitrate nitrogen in the return sludge enters the aerobic zone, which can Promote the denitrification effect of microorganisms in the aerobic zone to a certain extent. The invention has good treatment effect on municipal sewage.
附图说明Description of drawings
图1:本发明装置构成示意图;Fig. 1: Schematic diagram of the structure of the device of the present invention;
图2:水力停留时间与污染物去除率关系线,其中a:COD和TP,b:TN、NH4+-N和KN;Figure 2: The relationship between hydraulic retention time and pollutant removal rate, where a: COD and TP, b: TN, NH4+-N and KN;
图3:水力停留时间与污染物比去除率关系线,其中a:COD和TP,b:TN、NH4+-N和KN。Figure 3: The relationship between hydraulic retention time and specific removal rate of pollutants, where a: COD and TP, b: TN, NH4+-N and KN.
具体实施方式Detailed ways
下面通过实施例对本发明进行详细的说明:The present invention is described in detail below by embodiment:
实施例Example
图1是本发明中所用的改进后的UCT处理过程。在改进的UCT处理过程中,回流的污泥进入到了好氧区中,从而避免了溶解氧(DO)对于缺氧和厌氧区的影响。用于中试实验的装置的总容积是128L,其厌氧反应器10L,缺氧反应器26L,好氧反应器90L,澄清池2L(图1)。Fig. 1 is the improved UCT process used in the present invention. During the improved UCT treatment, the returned sludge enters the aerobic zone, thereby avoiding the influence of dissolved oxygen (DO) on the anoxic and anaerobic zones. The total volume of the device used for the pilot test is 128L, with an anaerobic reactor of 10L, anoxic reactor of 26L, aerobic reactor of 90L, and a clarifier of 2L (Fig. 1).
(1)入流市政污水的性质如表1所示。在整个实验周期中,每4天测试一次进水、出水和污泥的各项指标,总共有36组数据。所有的污染物测试都是按照American Public HealthAssociation(APHA)的标准进行的。悬浮固体量(SS)和溶解氧(DO)分别使用Surface Scatter7sc device(HACH,USA)和Z LLIGS-14device(HACH,USA)进行测量。pH值和温度则使用HACH GLIPH/ORP device(HACH,USA)来测量。生活污水的pH和DO每天都要测量,其典型的pH值的范围是6.0到7.6,DO则一直保持在1mg L-1以上(表1)。(1) The properties of inflowing municipal sewage are shown in Table 1. During the whole experiment period, the indicators of influent, effluent and sludge were tested every 4 days, with a total of 36 sets of data. All pollutant tests are conducted in accordance with the standards of the American Public Health Association (APHA). Suspended solids (SS) and dissolved oxygen (DO) were measured using Surface Scatter7sc device (HACH, USA) and Z LLIGS-14device (HACH, USA), respectively. pH and temperature were measured using HACH GLIPH/ORP device (HACH, USA). The pH and DO of domestic sewage were measured daily, with typical pH values ranging from 6.0 to 7.6 and DO consistently above 1 mg L-1 (Table 1).
表1:UCT进水性质(mg L-1)Table 1: UCT influent properties (mg L-1)
(2)如图2a所示,UCT可以保持很高的COD去除率,其最高可以在水力停留时间15h(第三阶段,81-120天,21-30组数据)时达到96%,然而比降解速率则表现出先升后降的趋势,其最大值在水力停留时间15h达到了8.80×10-3h-1(图3a)。在活性污泥法过程中,COD去除率和水力停留时间总是成正比的,然而在本实验中,最高的COD去除率并没有出现在最大的水力停留时间24h。究其原因,可能是因为在较长的水力停留时间条件下(如19h或者24h),水流在厌氧、好氧、缺氧和澄清池中的流动速率,以及好氧到缺氧和缺氧到厌氧的内回流速率,以及澄清池到缺氧的污泥回流量,都会有不同程度的减缓和减少,这样好氧区域的好氧细菌的数量就可能较少,从而影响COD污染的降解。(2) As shown in Figure 2a, UCT can maintain a high COD removal rate, which can reach up to 96% when the hydraulic retention time is 15h (the third stage, 81-120 days, 21-30 sets of data), but compared with The degradation rate showed a trend of increasing first and then decreasing, and its maximum value reached 8.80×10-3h-1 at the hydraulic retention time of 15h (Fig. 3a). In the process of activated sludge process, COD removal rate and hydraulic retention time are always proportional, but in this experiment, the highest COD removal rate did not appear in the maximum hydraulic retention time of 24h. The reason may be that under longer hydraulic retention time conditions (such as 19h or 24h), the flow rate of water flow in anaerobic, aerobic, anoxic and clarifier tanks, and aerobic to anoxic and anoxic The internal reflux rate to anaerobic, and the sludge reflux from clarifier to anoxic will be slowed down and reduced to varying degrees, so that the number of aerobic bacteria in the aerobic area may be less, thus affecting the degradation of COD pollution .
(3)图2a中总磷(TP)的去除率是先升后降,去除率在19h(第二阶段,41-80天,11-20组数据)时达到最大值85%。TP的比去除率在整个实验过程中始终保持在低水平上,变化不大,在水力停留时间19h时达到最大值2.90×10-3h-1(图3a)。在第一阶段TP平均去除率仅为54%,但是在第二和第三阶段上升到79%和72%,第四阶段则又突然下降到49%。这说明最优的水力停留时间是介于19到15小时之间的,这和聚磷菌的世代时间刚好吻合。因此,19h确定为最佳的TP去除水力停留时间。(3) The removal rate of total phosphorus (TP) in Figure 2a first increased and then decreased, and the removal rate reached a maximum of 85% at 19 hours (the second stage, 41-80 days, 11-20 group data). The specific removal rate of TP remained at a low level throughout the experiment, with little change, and reached a maximum value of 2.90×10-3h-1 at a hydraulic retention time of 19h (Fig. 3a). The average removal rate of TP in the first stage was only 54%, but it rose to 79% and 72% in the second and third stages, and suddenly dropped to 49% in the fourth stage. This shows that the optimal hydraulic retention time is between 19 and 15 hours, which coincides with the generation time of PAO. Therefore, 19h was determined as the optimal hydraulic retention time for TP removal.
图2b中,总氮(TN)、氨氮(NH4+-N)和凯氏氮(KN)的去除率正比于水力停留时间和污染物去除率。水力停留时间24h(第一阶段,140天,数据组1-10)时TN、NH4+-N和KN分别达到最大去除率72%、76%和78%。而他们的比去除率则是和污染物去除率的变化趋势一致(图2b和图3b),在水力停留时间24h时分别达到最大值1.70×10-3、1.85×10-3和2.05×10-3h-1。In Fig. 2b, the removal rates of total nitrogen (TN), ammonia nitrogen (NH4+-N) and Kjeldahl nitrogen (KN) are proportional to the hydraulic retention time and pollutant removal rate. When the hydraulic retention time was 24h (first stage, 140 days, data set 1-10), TN, NH4+-N and KN reached the maximum removal rates of 72%, 76% and 78%, respectively. Their specific removal rates are consistent with the variation trends of pollutant removal rates (Fig. 2b and Fig. 3b), and reach the maximum values of 1.70×10-3, 1.85×10-3 and 2.05×10 respectively at the hydraulic retention time of 24h -3h-1.
综上所述,TN、NH4+-N和KN的去除率在第一阶段和第二阶段总是要大于第四阶段的,因此本研究结果表明在水力停留时间较长时,UCT装置对于含氮污染物具有较高的去除率。In summary, the removal rates of TN, NH4+-N and KN in the first and second stages are always greater than those in the fourth stage, so the results of this study show that when the hydraulic retention time is long, the UCT unit is more effective for nitrogen-containing Pollutants have a high removal rate.
(4)本发明所述的改进后的UCT工艺对于城市生活污水的净化已经达到了较好的效果,但是其在污泥的絮凝沉降性能以及NH4+-N和COD的去除方面还有待改进。最优水力停留时间为19h,此时COD、TP、TN、NH4+-N和KN的去除率分别可以达到96%、85%、72%、76%和78%。(4) The improved UCT process of the present invention has achieved a good effect on the purification of urban domestic sewage, but it still needs to be improved in terms of sludge flocculation and sedimentation performance and removal of NH4+-N and COD. The optimal hydraulic retention time is 19h, and the removal rates of COD, TP, TN, NH4+-N and KN can reach 96%, 85%, 72%, 76% and 78% respectively.
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CN1416407A (en) * | 2000-03-08 | 2003-05-07 | 京好工程综合建筑士事务所 | Appts. and method for purifying wastewater |
KR100419431B1 (en) * | 2002-02-28 | 2004-02-18 | 삼성엔지니어링 주식회사 | Wastewater treatment apparatus and method for removing nitrogen and phosphorus |
CN1903745A (en) * | 2006-08-15 | 2007-01-31 | 北京工业大学 | Improved UCT technology and device |
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CN1416407A (en) * | 2000-03-08 | 2003-05-07 | 京好工程综合建筑士事务所 | Appts. and method for purifying wastewater |
KR100419431B1 (en) * | 2002-02-28 | 2004-02-18 | 삼성엔지니어링 주식회사 | Wastewater treatment apparatus and method for removing nitrogen and phosphorus |
CN1903745A (en) * | 2006-08-15 | 2007-01-31 | 北京工业大学 | Improved UCT technology and device |
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Application publication date: 20131113 |