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CN103373204B - A kind of sealing strip on outer side of car window and preparation method thereof - Google Patents

A kind of sealing strip on outer side of car window and preparation method thereof Download PDF

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CN103373204B
CN103373204B CN201210123355.0A CN201210123355A CN103373204B CN 103373204 B CN103373204 B CN 103373204B CN 201210123355 A CN201210123355 A CN 201210123355A CN 103373204 B CN103373204 B CN 103373204B
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sealing strip
skeleton
acrylonitrile
butadiene
matrix
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CN103373204A (en
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李宁
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BYD Co Ltd
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BYD Co Ltd
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Abstract

The invention provides a kind of sealing strip on outer side of car window, described sealing strip includes skeleton and matrix, described skeleton is the alloy plastic of chliorinated polyvinyl chloride and acrylonitrile butadient styrene, and its outward appearance is strip, and its section is in being similar to reverse U-shaped structure;Described reverse U-shaped structure is divided into top and the first sidepiece near glass for vehicle window and the second sidepiece away from glass for vehicle window;Described matrix is polrvinyl chloride, and described matrix is coated on around described skeleton, and is provided with the first projection on the outside matrix of the first sidepiece, and the described first protruding side contacted with glass for vehicle window is provided with flannelette;The inner base of described first sidepiece and door panel contact position are provided with burr and present invention also offers the preparation method of this sealing strip.The adhesion sealing sky of the present invention is good, and the method is simple, eliminates the step of existing technique furnishing steel band of model, decreases operation.

Description

A kind of sealing strip on outer side of car window and preparation method thereof
Technical field
The invention belongs to weather strip for automobile field, relate to a kind of sealing strip on outer side of car window and preparation method thereof.
Background technology
Along with improving constantly of the national economic development, business prosperity and living standards of the people, automobile quantity increases day by day.The lightweight of automobile is increasingly paid attention to by each big automotive giant.The sealing property of motor-vehicle glass window is one of important document affecting car mass.Sealing strip can ensure that the sealing between glass pane and the structural member of vehicle so that is possible to prevent the environmental effect such as rainwater, dust and/or wind to enter vehicle interior.Sealing strip especially for glass of movable window has some special requirements, these windows whether can fairly linearly (horizontal or vertical) mobile, the most collapsible or can non-linearly move (the most rotatable).These requirements include high resiliency and the life-span of sealing member, the presentation quality of sealing strip and the obvious stability about environmental effect.Currently used motor-vehicle glass window sealing strip, all using metal as skeleton, because metal hardness is high, can meet requirement, but metal is heavier, so can increase the weight of automobile, and the preparation process of metallic framework is more complicated.
In order to solve the problems referred to above, applicant of the present invention discloses a kind of sealing strip on outer side of car window in the patent of Application No. CN201110327255.5, described sealing strip includes skeleton and matrix, described skeleton is chliorinated polyvinyl chloride, its outward appearance is strip, and its section is in being similar to reverse U-shaped structure;Described reverse U-shaped structure is divided into top and the first sidepiece near glass for vehicle window and the second sidepiece away from glass for vehicle window;Described matrix is polrvinyl chloride, and described matrix is coated on around described skeleton, and is provided with the first projection on the outside matrix of the first sidepiece, and the described first protruding side contacted with glass for vehicle window is provided with flannelette;The inner base of described first sidepiece and door panel contact position are provided with burr.This patent solves vehicle weight and the problem of preparation process complexity, but its impact resistance is poor.
Summary of the invention
The present invention solves the impact resistance difference technical problem of existing window sealing strip, it is provided that window sealing strip that a kind of impact resistance is good and preparation method thereof.
The invention provides a kind of sealing strip on outer side of car window, described sealing strip includes skeleton and matrix, described skeleton is the alloy plastic of chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer, and its outward appearance is strip, and its section is in being similar to reverse U-shaped structure;Described reverse U-shaped structure is divided into top and the first sidepiece near glass for vehicle window and the second sidepiece away from glass for vehicle window;Described matrix is polrvinyl chloride, and described matrix is coated on around described skeleton, and is provided with the first projection on the outside matrix of the first sidepiece, and the described first protruding side contacted with glass for vehicle window is provided with flannelette;The inner base of described first sidepiece and door panel contact position are provided with burr.
Present invention also offers the preparation method of a kind of window sealing strip, the method is the alloy plastic and polrvinyl chloride compound extrusion moulding formed with acrylonitrile-butadiene-styrene copolymer by chliorinated polyvinyl chloride, wherein said polrvinyl chloride is coated with the alloy plastic that chliorinated polyvinyl chloride is formed with acrylonitrile-butadiene-styrene copolymer completely, then flannelette is pasted onto the first protruding side contacted with glass for vehicle window, high temperature by flannelette bottom glue melt bonding with the soft-sided of PVC base system, it is fully cured stickup after the sizing of overboard stock mould and the cooling in water.
The sealing strip of the present invention is by the compound extruded of the alloy plastic skeleton of the chliorinated polyvinyl chloride of high rigidity and acrylonitrile-butadiene-styrene copolymer with the plastic material of PVC matrix, it is ensured that product while satisfied assembling, difficult drop-off, it is ensured that intensity.Replace steel band as skeleton with the alloy plastic of chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer, not only like CPVC the most lightweight (weight of CPVC is the 1/5 of steel), substantially increase the lightweight of automobile.And also the same with CPVC it is resistant to most acid, alkali, salt, there are good chemical resistance, heat-resisting aspect to be also significantly better than other plastics, all significantly improve using temperature (higher 35-40 than polyvinyl chloride resin), intensity, the performance such as heat-resisting, fire-retardant.Owing to CPVC processing temperature is higher and scope is narrower, the tendency of the HCL that thermal decomposition is released increases, and the highest and CPVC self the impact strength of the requirement to former and material molding technology is poor.And ABS mixes generation concurrent mixture as a kind of anti-impact modifier with CPVC, the impact strength of CPVC can be improved, improve its elongation at break, reduce its melt viscosity and Vicat softening point, improve its toughness.ABS resin can also effectively reduce the counter balance torque of CPVC/ABS alloy, improves the mobility of co-mixing system, makes concurrent mixture be more easy to plasticizing, thus improves the processing characteristics of CPVC.In terms of processing identical with PVC product processing mode, only need to change some processing conditionss on processing equipment can process, and more important advantage is the reduction of operation, improves efficiency.
Accompanying drawing explanation
Fig. 1 is the sectional schematic diagram of the window sealing strip of the present invention.
Fig. 2 is equipment schematic diagram used in method of testing.
Detailed description of the invention
In order to make technical problem solved by the invention, technical scheme and beneficial effect clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The invention provides a kind of sealing strip on outer side of car window, described sealing strip includes skeleton and matrix, described skeleton is the alloy plastic of chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer, and its outward appearance is strip, and its section is in being similar to reverse U-shaped structure;Described reverse U-shaped structure is divided into top and the first sidepiece near glass for vehicle window and the second sidepiece away from glass for vehicle window;Described matrix is polrvinyl chloride, and described matrix is coated on around described skeleton, and is provided with the first projection on the outside matrix of the first sidepiece, and the described first protruding side contacted with glass for vehicle window is provided with flannelette;The inner base of described first sidepiece and door panel contact position are provided with burr.
Chliorinated polyvinyl chloride is identical with the major part of the component of polrvinyl chloride, can well stick together, it is not easy to come off.ABS resin can also effectively reduce the counter balance torque of CPVC/ABS alloy, improves the mobility of co-mixing system, makes concurrent mixture be more easy to plasticizing, thus improves the processing characteristics of CPVC.And chliorinated polyvinyl chloride and ABS are light than metal, the weight of automobile can be alleviated.
According to sealing strip on outer side of car window provided by the present invention, it is preferable that in the alloy plastic of described chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer, the mol ratio of chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer is 2.7-3.35:1.Along with the increase of ABS consumption, the minimum plasticization temperature of CPVC/ABS alloy is greatly lowered, and the minimum plasticization temperature of pure CPVC is 186 DEG C, and when adding 25 parts, (i.e. CPVC and ABS proportion of composing is 3:1, and during ABS, the minimum plasticization temperature of alloy is reduced to 166 DEG C;Reduction amplitude reaches 20 DEG C, adds ABS and the processing temperature of CPVC can be greatly lowered, improve its processing characteristics.Owing to the heat resistance of ABS resin itself is good, when its consumption is less than 25 parts, the vicat softening point temperature of alloy is affected little;But when ABS consumption is more than after 25 parts, and the vicat softening point temperature of alloy drastically declines, to ABS consumption be 40 parts time, downward trend just slows down, and illustrate after ABS consumption is more than 25 parts, with the increase of ABS consumption, the heat resistance variation of alloy.
According to sealing strip on outer side of car window provided by the present invention, in order to be able to make higher and minimizing skeleton as far as possible the thickness of intensity of skeleton, it is preferable that the thickness of described skeleton is 0.5-0.8mm.
According to sealing strip on outer side of car window provided by the present invention, but at the resistance of assembling, little to assemble later withdrawal force big in order to make sealing strip, it is preferable that the thickness of described burr is 0.8-1.2 Mm, a length of 3.5-4.5 mm;Described burr and skeleton are 130-150 ° in the angle of installation direction.
Described installation direction refers to be installed to sealing strip the direction of glass outer side, the i.e. opening direction of reverse U-shaped structure.
According to sealing strip on outer side of car window provided by the present invention, in order to make, first is protruding and glass has better seal and adhesion, it is preferable that the thickness of described first projection is 2.3-2.7 Mm, a length of 13.5-14.5 mm;Described first projection is 115-125 ° with skeleton in the angle of installation direction.
According to sealing strip on outer side of car window provided by the present invention, it is preferable that being additionally provided with the second projection on the half of matrix of glass for vehicle window, described second projection is positioned at the first convex upper portion;The outward appearance that described second projection can make sealing strip is more attractive.In order to enable the second projection less and glass contact, it is highly preferred that described second projection thickness is 1.8-2.2 Mm, a length of 12.5-13.5 mm;Described second projection is 115-125 ° with skeleton in the angle of installation direction.
Preferably, density 1.45-1.58g/cm of described chliorinated polyvinyl chloride3
Preferably, described chliorinated polyvinyl chloride chlorinity be 63-69%.The chlorinity of CPVC high 5-10 the point than PVC.The biggest improve material heat-resisting, acidproof, alkaline-resisting, salt tolerant, be the performance of oxidant.
Below in conjunction with the accompanying drawings the sealing strip of the present invention is described in detail.As shown in Figure 1, this sealing strip includes skeleton 1 and matrix 2, described skeleton 1 is chliorinated polyvinyl chloride and the alloy plastic of acrylonitrile-butadiene-styrene copolymer formation, its outward appearance is strip, its section is in being similar to reverse U-shaped structure, and described reverse U-shaped structure is divided into top 11 and the first sidepiece 12 near glass for vehicle window and the second sidepiece 13 away from glass for vehicle window;Matrix 2 is polrvinyl chloride, and described matrix 2 is coated on around described skeleton 1, and is provided with the first projection 21 on the outside matrix 2 of the first sidepiece 12, and the described first protruding 21 side contacted with glass for vehicle window is provided with flannelette 22;Inner base 2 and the door panel contact position of described first sidepiece 12 are provided with burr 23.Being additionally provided with the second projection 24 on the matrix 2 of the first sidepiece 12, the second projection 24 is positioned at the first protruding 21 tops.
The invention provides the preparation method of a kind of window sealing strip, the method is the alloy plastic and polrvinyl chloride compound extrusion moulding formed with acrylonitrile-butadiene-styrene copolymer by chliorinated polyvinyl chloride, wherein said polrvinyl chloride is coated with the alloy plastic that chliorinated polyvinyl chloride is formed with acrylonitrile-butadiene-styrene copolymer completely, then flannelette is pasted onto the first protruding side contacted with glass for vehicle window, high temperature by flannelette bottom glue melt bonding with the soft-sided of PVC base system, it is fully cured stickup after the sizing of overboard stock mould and the cooling in water.
Preferably, alloy plastic and the raw material that the method for polrvinyl chloride compound extrusion moulding is alloy plastic and the polrvinyl chloride formed with acrylonitrile-butadiene-styrene copolymer by chliorinated polyvinyl chloride that described chliorinated polyvinyl chloride is formed with acrylonitrile-butadiene-styrene copolymer are separately added into two extruders, and the zone heating temperature of chliorinated polyvinyl chloride is 150-170 DEG C;The antipyretic temperature of segmentation of polrvinyl chloride is 105-115 DEG C.
Preferably, then the method for described stickup flannelette for being pasted together flannelette with sample through being positioned on extrusion die while extrusion molding.
Preferably, the alloy plastic that described polrvinyl chloride and acrylonitrile-butadiene-styrene copolymer are formed is to be obtained according to the ratio that mol ratio is 2.7-3.35:1 is mixing with acrylonitrile-butadiene-styrene copolymer by polrvinyl chloride.
The present invention provides the alloy plastic of a kind of CPVC Yu ABS and the compound extruded window sealing strip technology of PVC, eliminates the step of existing technique furnishing steel band of model, decreases operation.Improve the impact strength of CPVC, improve its elongation at break, reduce its melt viscosity and Vicat softening point, improve its toughness.ABS resin can also effectively reduce the counter balance torque of CPVC/ABS alloy, improves the mobility of co-mixing system, makes concurrent mixture be more easy to plasticizing, thus improves the processing characteristics of CPVC.Save cost, improve production efficiency.
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
The total amount of the alloy plastic of chliorinated polyvinyl chloride (CPVC) and acrylonitrile-butadiene-styrene copolymer (ABS) is 100 parts, and wherein ABS consumption is 12.5 parts;The raw material of chliorinated polyvinyl chloride (CPVC) and the alloy plastic of acrylonitrile-butadiene-styrene copolymer (ABS) and polrvinyl chloride is separately added into two extruders extrusion molding, and the zone heating temperature of CPVC/ABS is about 185 DEG C;The zone heating temperature of polrvinyl chloride is 110 DEG C.Wherein said polrvinyl chloride complete clad alloy plastic skeleton, then flannelette is pasted onto the first protruding side contacted with glass for vehicle window, high temperature by flannelette bottom glue melt bonding with the soft-sided of PVC matrix, after the sizing of overboard stock mould and the cooling in water, be fully cured stickup prepare sealing strip A1.The raw material of chliorinated polyvinyl chloride and polrvinyl chloride is separately added into two extruders extrusion molding, and the zone heating temperature of chliorinated polyvinyl chloride is 160 DEG C;The antipyretic temperature of segmentation of polrvinyl chloride is 110 DEG C.Wherein said polrvinyl chloride is coated with chliorinated polyvinyl chloride completely, then flannelette is pasted onto the first protruding side contacted with glass for vehicle window, high temperature by flannelette bottom glue melt bonding with the soft-sided of PVC matrix, after the sizing of overboard stock mould and the cooling in water, be fully cured stickup prepare sealing strip A1.The thickness of skeleton is 0.6mm;The thickness of burr is 1.0mm, a length of 4.0mm, and angle is 140 °.The thickness of the first projection is 2.5mm, a length of 14mm, and angle is 120 °.Being provided with the second projection on the half of matrix of glass for vehicle window, described second projection thickness is 2.0mm, a length of 13mm, and angle is 120 °.
Embodiment 2
Sealing strip A2 is prepared according to the method for embodiment 1.Difference is: ABS consumption is 25 parts;Not having the second projection, the thickness of skeleton is 0.5cm;The thickness of burr is 0.8mm, a length of 3.5mm, and angle is 130 °.The thickness of the first projection is 2.3mm, a length of 13.5mm, and angle is 115 °.
Embodiment 3
Sealing strip A3 is prepared according to the method for embodiment 1.Difference is: ABS consumption is 37.5 parts;The thickness of skeleton is 0.8mm;The thickness of burr is 1.2mm, a length of 4.5mm, and angle is 150 °.The thickness of the first projection is 2.7mm, a length of 14.5mm, and angle is 125 °.Being provided with the second projection on the half of matrix of glass for vehicle window, described second projection thickness is 2.2mm, a length of 13.5mm, and angle is 125 °.
Embodiment 4
Sealing strip A4 is prepared according to the method for embodiment 1.Difference is: ABS consumption is 50 parts.
Embodiment 5
Sealing strip A5 is prepared according to the method for embodiment 1.Difference is: ABS consumption is 7.5 parts.
Comparative example 1
Sealing strip B1 is prepared according to the method for embodiment 1.Difference is: do not contain ABS.
Method of testing: impact strength
Test machine: universal tensile testing machine.
Test sample: sealing strip A1-A5 and B1 is parked at least 3h.
Test content: sealing strip impact strength, makes sealing strip matrix fracture in hands impact, measures the merit consumed when sample fractures, and record the breakdown strength of anti-impact force effect.
The length of sample: 100mm.
Method of testing: be placed on tool and be fixed on the lower end (in Fig. 2, the distance between two fulcrums 4 is 70mm) of testing machine by removing the first protruding and the second projection sealing strip matrix 3 such as Fig. 2 with blade, it is pressed downward against along the central point of sealing strip matrix by the hammer 5 of termination fillet in the upper end of testing machine, record the data of display after fractureing to matrix, the results are shown in Table 1.
Table 1
Sealing strip kind Average impact strength (J/m)
A1 490
A2 627
A3 515
A4 435
A5 340
B1 98
From table 1 it follows that the peel strength of the former sealing strip more than comparative example of the impact strength of the sealing strip of the present invention, illustrate that the adhesion of the sealing strip of the present invention is good, and the method is simple, eliminates the step of existing technique furnishing steel band of model, decreases operation.

Claims (9)

1. a sealing strip on outer side of car window, it is characterized in that, described sealing strip includes skeleton and matrix, described skeleton is the alloy plastic of chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer, in the alloy plastic of described chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer, the weight ratio of chliorinated polyvinyl chloride and acrylonitrile-butadiene-styrene copolymer is 3:1, its outward appearance is strip, and its section is in being similar to reverse U-shaped structure;Described reverse U-shaped structure is divided into top and the first sidepiece near glass for vehicle window and the second sidepiece away from glass for vehicle window;Described matrix is polrvinyl chloride, and described matrix is coated on around described skeleton, and is provided with the first projection on the outside matrix of the first sidepiece, and the described first protruding side contacted with glass for vehicle window is provided with flannelette;The inner base of described first sidepiece and door panel contact position are provided with burr.
Sealing strip the most according to claim 1, it is characterised in that the thickness of described skeleton is 0.5-0.8mm.
Sealing strip the most according to claim 1, it is characterised in that the thickness of described burr is 0.8-1.2 mm, a length of 3.5-4.5 mm;Described burr and skeleton are 130-150 ° in the angle of installation direction.
Sealing strip the most according to claim 1, it is characterised in that the thickness of described first projection is 2.3-2.7 mm, a length of 13.5-14.5 mm;Described first projection is 115-125 ° with skeleton in the angle of installation direction.
Sealing strip the most according to claim 1, it is characterised in that being additionally provided with the second projection on the half of matrix of glass for vehicle window, described second projection is positioned at the first convex upper portion;Described second projection thickness is 1.8-2.2 mm, a length of 12.5-13.5 mm;Described second projection is 115-125 ° with skeleton in the angle of installation direction.
6. the preparation method of the window sealing strip described in a claim 1, it is characterized in that, the method is the alloy plastic and polrvinyl chloride compound extrusion moulding formed with acrylonitrile-butadiene-styrene copolymer by chliorinated polyvinyl chloride, wherein said polrvinyl chloride is coated with the alloy plastic that chliorinated polyvinyl chloride is formed with acrylonitrile-butadiene-styrene copolymer completely, then flannelette is pasted onto the first protruding side contacted with glass for vehicle window, high temperature by flannelette bottom glue melt bonding with the soft-sided of PVC base system, it is fully cured stickup after the sizing of overboard stock mould and the cooling in water.
Method the most according to claim 6, it is characterized in that, alloy plastic and the raw material that the method for polrvinyl chloride compound extrusion moulding is alloy plastic and the polrvinyl chloride formed with acrylonitrile-butadiene-styrene copolymer by chliorinated polyvinyl chloride that described chliorinated polyvinyl chloride is formed with acrylonitrile-butadiene-styrene copolymer are separately added into two extruders, and the zone heating temperature of chliorinated polyvinyl chloride is 150-170 DEG C;The antipyretic temperature of segmentation of polrvinyl chloride is 105-115 DEG C.
Method the most according to claim 6, it is characterised in that then the method for described stickup flannelette for being pasted together flannelette with sample through being positioned on extrusion die while extrusion molding.
Method the most according to claim 6, it is characterized in that, the alloy plastic that described polrvinyl chloride and acrylonitrile-butadiene-styrene copolymer are formed is to be obtained according to the ratio that weight ratio is 3:1 is mixing with acrylonitrile-butadiene-styrene copolymer by polrvinyl chloride.
CN201210123355.0A 2012-04-25 2012-04-25 A kind of sealing strip on outer side of car window and preparation method thereof Active CN103373204B (en)

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* Cited by examiner, † Cited by third party
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JP6662205B2 (en) * 2015-07-31 2020-03-11 Agc株式会社 Automotive belt line sound insulation structure and automotive door glass
CN108116198A (en) * 2016-11-28 2018-06-05 长城汽车股份有限公司 Water is cut and automobile door glass jacking system
CN109421494A (en) * 2017-08-24 2019-03-05 江苏锋驰汽车车身制造有限公司 A kind of vehicle window sealing structure
US11828365B2 (en) * 2021-07-28 2023-11-28 Rivian Ip Holdings, Llc Low profile outer belt seal with improved retention

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JP2001097045A (en) * 1999-09-30 2001-04-10 Toyoda Gosei Co Ltd Vehicular seal component
CN1729113A (en) * 2002-12-19 2006-02-01 梅策勒汽车外形系统有限责任公司 Sealing devices especially for sealing automotive window panes
CN101439657A (en) * 2007-11-22 2009-05-27 东海兴业株式会社 Belt molding for vehicles
JP2012071651A (en) * 2010-09-28 2012-04-12 Sekisui Chem Co Ltd Molding for automobile

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JP2001097045A (en) * 1999-09-30 2001-04-10 Toyoda Gosei Co Ltd Vehicular seal component
CN1729113A (en) * 2002-12-19 2006-02-01 梅策勒汽车外形系统有限责任公司 Sealing devices especially for sealing automotive window panes
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