CN103371177A - Herbicide composition containing methyl sulcotrione and glyphosate - Google Patents
Herbicide composition containing methyl sulcotrione and glyphosate Download PDFInfo
- Publication number
- CN103371177A CN103371177A CN2012101294376A CN201210129437A CN103371177A CN 103371177 A CN103371177 A CN 103371177A CN 2012101294376 A CN2012101294376 A CN 2012101294376A CN 201210129437 A CN201210129437 A CN 201210129437A CN 103371177 A CN103371177 A CN 103371177A
- Authority
- CN
- China
- Prior art keywords
- glyphosate
- mesotrione
- agent
- acid
- dispersant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 methyl sulcotrione Chemical compound 0.000 title claims abstract description 77
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 58
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000005562 Glyphosate Substances 0.000 title claims abstract description 47
- 229940097068 glyphosate Drugs 0.000 title claims abstract description 47
- 239000004009 herbicide Substances 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000005618 Sulcotrione Substances 0.000 title abstract 2
- 241000196324 Embryophyta Species 0.000 claims abstract description 39
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 21
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 20
- 235000005822 corn Nutrition 0.000 claims abstract description 20
- 239000005578 Mesotrione Substances 0.000 claims description 50
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 claims description 50
- 239000002253 acid Substances 0.000 claims description 22
- 239000002270 dispersing agent Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000000080 wetting agent Substances 0.000 claims description 19
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 15
- 239000011230 binding agent Substances 0.000 claims description 13
- 239000013530 defoamer Substances 0.000 claims description 13
- 239000007884 disintegrant Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- PDYXIVPKOMYDOK-UHFFFAOYSA-N Glyphosate-monoammonium Chemical compound [NH4+].OC(=O)CNCP(O)([O-])=O PDYXIVPKOMYDOK-UHFFFAOYSA-N 0.000 claims description 6
- 239000007900 aqueous suspension Substances 0.000 claims description 6
- 239000007938 effervescent tablet Substances 0.000 claims description 6
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000003826 tablet Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 208000003643 Callosities Diseases 0.000 claims description 3
- 206010020649 Hyperkeratosis Diseases 0.000 claims description 3
- VDCHTAFVUAPYGO-UHFFFAOYSA-N n-methylmethanamine;2-(phosphonomethylamino)acetic acid Chemical compound CNC.OC(=O)CNCP(O)(O)=O VDCHTAFVUAPYGO-UHFFFAOYSA-N 0.000 claims description 3
- LIOPHZNMBKHGAV-UHFFFAOYSA-M potassium;2-(phosphonomethylamino)acetate Chemical compound [K+].OC(=O)CNCP(O)([O-])=O LIOPHZNMBKHGAV-UHFFFAOYSA-M 0.000 claims description 3
- YWICANUUQPYHOW-UHFFFAOYSA-M sodium;2-(phosphonomethylamino)acetate Chemical compound [Na+].OP(O)(=O)CNCC([O-])=O YWICANUUQPYHOW-UHFFFAOYSA-M 0.000 claims description 3
- 230000009261 transgenic effect Effects 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- 244000045561 useful plants Species 0.000 claims description 2
- 241000209149 Zea Species 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 230000000361 pesticidal effect Effects 0.000 claims 2
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 240000008042 Zea mays Species 0.000 abstract description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 102
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 72
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 32
- 239000007859 condensation product Substances 0.000 description 24
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 18
- 229910052938 sodium sulfate Inorganic materials 0.000 description 15
- 235000011152 sodium sulphate Nutrition 0.000 description 15
- 239000011734 sodium Substances 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 13
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 12
- 229910019142 PO4 Inorganic materials 0.000 description 12
- 229920001400 block copolymer Polymers 0.000 description 12
- 230000018044 dehydration Effects 0.000 description 12
- 238000006297 dehydration reaction Methods 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 235000021317 phosphate Nutrition 0.000 description 12
- 229910021653 sulphate ion Inorganic materials 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 239000002518 antifoaming agent Substances 0.000 description 10
- 229920001296 polysiloxane Polymers 0.000 description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 10
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 10
- 230000003449 preventive effect Effects 0.000 description 10
- 239000005995 Aluminium silicate Substances 0.000 description 9
- 235000012211 aluminium silicate Nutrition 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 9
- 108010010803 Gelatin Proteins 0.000 description 8
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 7
- 244000215068 Acacia senegal Species 0.000 description 6
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 229920000084 Gum arabic Polymers 0.000 description 6
- 229920001732 Lignosulfonate Polymers 0.000 description 6
- 235000010489 acacia gum Nutrition 0.000 description 6
- 239000000205 acacia gum Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 6
- 235000011130 ammonium sulphate Nutrition 0.000 description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
- 125000001624 naphthyl group Chemical group 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 6
- 229920005646 polycarboxylate Polymers 0.000 description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 6
- 150000003871 sulfonates Chemical class 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 239000008101 lactose Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 240000001592 Amaranthus caudatus Species 0.000 description 3
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 240000003173 Drymaria cordata Species 0.000 description 3
- 244000058871 Echinochloa crus-galli Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 3
- 235000012735 amaranth Nutrition 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 240000006995 Abutilon theophrasti Species 0.000 description 2
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 2
- 241001645380 Bassia scoparia Species 0.000 description 2
- 244000178993 Brassica juncea Species 0.000 description 2
- 235000005855 Brassica juncea var. subintegrifolia Nutrition 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005586 Nicosulfuron Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FKUYMLZIRPABFK-UHFFFAOYSA-N Plastoquinone 9 Natural products CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1=CC(=O)C(C)=C(C)C1=O FKUYMLZIRPABFK-UHFFFAOYSA-N 0.000 description 2
- 241000205407 Polygonum Species 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 241001251949 Xanthium sibiricum Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 239000004178 amaranth Substances 0.000 description 2
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 2
- FKUYMLZIRPABFK-IQSNHBBHSA-N plastoquinone-9 Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC1=CC(=O)C(C)=C(C)C1=O FKUYMLZIRPABFK-IQSNHBBHSA-N 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000015424 sodium Nutrition 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- FGRBYDKOBBBPOI-UHFFFAOYSA-N 10,10-dioxo-2-[4-(N-phenylanilino)phenyl]thioxanthen-9-one Chemical compound O=C1c2ccccc2S(=O)(=O)c2ccc(cc12)-c1ccc(cc1)N(c1ccccc1)c1ccccc1 FGRBYDKOBBBPOI-UHFFFAOYSA-N 0.000 description 1
- TVEXGJYMHHTVKP-UHFFFAOYSA-N 6-oxabicyclo[3.2.1]oct-3-en-7-one Chemical compound C1C2C(=O)OC1C=CC2 TVEXGJYMHHTVKP-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 102000016680 Dioxygenases Human genes 0.000 description 1
- 108010028143 Dioxygenases Proteins 0.000 description 1
- 241001057636 Dracaena deremensis Species 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 240000000275 Persicaria hydropiper Species 0.000 description 1
- 235000017337 Persicaria hydropiper Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 241000482268 Zea mays subsp. mays Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000001851 biosynthetic effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 235000021466 carotenoid Nutrition 0.000 description 1
- 150000001747 carotenoids Chemical class 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 244000144980 herd Species 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000000442 meristematic effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 108010001545 phytoene dehydrogenase Proteins 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a herbicide composition containing methyl sulcotrione and glyphosate. The composition is mainly used for preventing and removing weed, in particular weed in corn fields.
Description
Technical field:
The present invention relates to a kind of herbicidal composition that contains mesotrione and glyphosate, be mainly used in management of weeds, particularly corn field weed.
Background technology:
Along with the adjustment of the structure of agricultural production, herding had become the emphasis of agricultural development already, and the livestock breeding fast development constantly increases the demand of high quality grass feed.Because field corn mainly is to obtain higher biological yield by high-density planting, choose reasonable and use weed killer herbicide are particularly important.China's corn field herbicide is with atrazine, Acetochlor, nicosulfuron, 2 at present, more than 10 kinds such as 4-drips are main, wherein long residual effect weed killer herbicide atrazine, Acetochlor consumption are excessive, exist huge hidden danger, Patent expiry product nicosulfuron is single preemergence herbicide, although drug effect is better, because production capacity is expanded rapidly, price continues to drop, and increase magnitude of export is slowed down.China's corn field is badly in need of the short residual effect kind of development and cauline leaf treatment agent and herbicide after seedling, has the new herbicides of super-high-efficient, low toxicity characteristics will become market mainstream kind.
Mesotrione is the new three ketones weed killer herbicide of Zeneca farmingization company exploitation, and former medicine is brown or faint yellow solid, and chemical name is 2-(4-mesyl-2-nitro-benzoyl) cyclohexane-1, the 3-diketone.As interior absorption corn field broad spectrum type weed killer herbicide, mesotrione can be used for before the corn field bud or the bud rear defence removes annual broadleaf weed and some grassy weeds, belong to weeds, summer cypress, Polygonum weeds, leaf mustard, barnyard grass, chickweed, lady's-grass etc. such as piemarker, Siberian cocklebur, thorn amaranth, multitude, not only to corn safety, and to environment, succession crop safety.The mechanism of action is for suppressing the activity of PHPPA dioxygenase (HPPD), HPPD can be converted into plastoquinone with the amino acid TYR, plastoquinone is the co-factor of phytoene desaturase, it is the biosynthetic key enzyme of carotenoid, use 3～5 days implants meristematic tissue of mesotrione the yellow symptom to occur and cause withered spot thereupon, spread all over whole strain plant behind the fortnight.Mesotrione with its broad weed-killing spectrum, active high, miscibilty strong, to succession crop safety, use flexibly, Environmental compatibility is strong etc., and characteristics have than great development in China is worth and promotes the use of preferably prospect.
Glyphosate is to inhale steriland herbicide in a kind of broad spectrum activity by About Monsanto Chemicals exploitation, and conductivity is extremely strong, and the green parts by weeds absorbs, and conducts to complete stool, and the photosynthesis that hinders plant causes death.Can effectively prevent and treat one, biennial unifacial leaf grassy weed, especially extremely strong to the underground organization destructive power of perennial dark root weeds, can reach the general agricultural machinery degree of depth that is beyond one's reach, farming, woods, herd, be widely used aspect the gardening.Along with the increase of glyphosate tolerant transgenic corns cultivated area, the economic worth of glyphosate further manifests, mesotrione and glyphosate composite, not only can enlarge the herbicide spectrum, reduce farmer's burdens, and it is single effectively to solve the corn field medication, easily produces the problem of resistance.
Summary of the invention:
The various salt of mesotrione and glyphosate make up in certain proportion among the present invention; in the hope of a kind of efficient, low-residual of further invention, low cost and grassy weed and broad leaved weed there are the herbicidal composition of better preventive effect; this herbicidal composition can enlarge the herbicide spectrum, improve herbicidal effect; reduce poisoning; protection of the environment is brought considerable economic benefit for the peasant simultaneously.
Mesotrione and glyphosate herbicidal composition are mainly used in management of weeds, particularly corn field weed.Wherein glyphosate exists with in ammonium glyphosate, glyphosate potassium, sodium glyphosate, glyphosate isopropyl amine salt, the glyphosate dimethylamine salt one or more.
Mesotrione (nitre sulphur ketone, Mesotrione), chemical name is 2-(4-mesyl-2-nitro-benzoyl) cyclohexane-1, the 3-diketone, structural formula is
Glyphosate (glyphosate), chemical name: the N-phosphono-methyl-glycine, structural formula is
The present invention further comprises a kind of Herbicidal combinations preparation that comprises mesotrione and glyphosate, active ingredient mesotrione wherein: the mass ratio of glyphosate is 1: 99～99: 1, more preferably 1: 20～10: 1, add an amount of auxiliary agent or carrier, can be mixed with aqueous suspension agent, water dispersible granules, aqueous dispersion tablets, effervescent tablet, wetting powder, granule.
Active ingredient shared compositing range in preparation is 5%～95% in the described Herbicidal combinations preparation, is preferably 30%～80%
Technical scheme of the present invention realizes with following proposal:
A kind of mesotrione and glyphosate herbicidal composition aqueous suspension agent form (by mass percentage %) by following raw material
Mesotrione: 0.1%-99%
Glyphosate salt (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Antifreezing agent: 0.1%-10%
Thickener: 0.05%-5%
Defoamer: 0.05%-5%
The surplus water is supplied.
Used dispersant is naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, polycarboxylate, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy based phosphates, lignosulfonates, gelatin, gum Arabic, carboxymethyl cellulose, polyoxyethylene alcohol, polyvinylpyrrolidone, Sodium Polyacrylate, polyethylene glycol can be wherein one or more.
Used wetting agent is aliphatic alcohol sulfate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfate, alkylnaphthalene sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, alkyl amide sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, dehydration sorbic alcohol fatty acid ester, dehydration sorbic alcohol fatty acid ester polyoxyethylene agent ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, alkylphenol formaldehyde condensation product polyoxyethylene ether can be wherein one or more.
Used antifreezing agent is ethylene glycol, glycerine, can be wherein one or more.
Thickener is that xanthans, aluminium-magnesium silicate, white carbon, carboxymethyl cellulose can be wherein one or more.
Defoamer is: silicone defoaming agent
A kind of mesotrione and glyphosate herbicidal composition water dispersible granules form (by mass percentage %) by following raw material
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Defoamer: 0.05%-1%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier
Used dispersant is naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, polycarboxylate, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy based phosphates, lignosulfonates, gelatin, gum Arabic, carboxymethyl cellulose, polyoxyethylene alcohol, polyvinylpyrrolidone, Sodium Polyacrylate, polyethylene glycol can be wherein one or more.
Used wetting agent is aliphatic alcohol sulfate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfate, alkylnaphthalene sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, alkyl amide sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, dehydration sorbic alcohol fatty acid ester, dehydration sorbic alcohol fatty acid ester polyoxyethylene agent ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, alkylphenol formaldehyde condensation product polyoxyethylene ether can be wherein one or more.
Used disintegrant is urea, sodium chloride, sodium sulphate, sodium carbonate, polyvinylpyrrolidone, sodium alginate, sodium carboxymethyl starch, ammonium sulfate, can be wherein one or more.
Used carrier is potter's clay, attapulgite, kaolin, bentonite, gypsum, diatomite, precipitated silicate calcium, precipitated calcium carbonate, white carbon, silica gel, alkaline lignin, can be wherein one or more.
Used defoamer is: silicone defoaming agent
Used binding agent is: water
A kind of mesotrione and glyphosate herbicidal composition aqueous dispersion tablets form (by mass percentage %) by following raw material
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier
Used dispersant is naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, polycarboxylate, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy based phosphates, lignosulfonates, gelatin, gum Arabic, carboxymethyl cellulose, polyoxyethylene alcohol, polyvinylpyrrolidone, Sodium Polyacrylate, polyethylene glycol can be wherein one or more.
Used wetting agent is aliphatic alcohol sulfate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfate, alkylnaphthalene sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, alkyl amide sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, dehydration sorbic alcohol fatty acid ester, dehydration sorbic alcohol fatty acid ester polyoxyethylene agent ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, alkylphenol formaldehyde condensation product polyoxyethylene ether can be wherein one or more.
Used disintegrant is calcium chloride, sodium sulphate, ammonium sulfate, and polyethyl acrylate can be wherein one or more.
Used carrier is kaolin, bentonite, anhydrous sodium sulfate, precipitated calcium carbonate, sawdust etc., can be wherein one or more.
Used binding agent is: gelatin, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, starch, dextrin, lactose can be wherein one or more.
A kind of mesotrione and glyphosate herbicidal composition effervescent tablet form (by mass percentage %) by following raw material
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier
Used dispersant is naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, polycarboxylate, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy based phosphates, lignosulfonates, gelatin, gum Arabic, carboxymethyl cellulose, polyoxyethylene alcohol, polyvinylpyrrolidone, Sodium Polyacrylate, polyethylene glycol can be wherein one or more.
Used wetting agent is aliphatic alcohol sulfate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfate, alkylnaphthalene sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, alkyl amide sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, dehydration sorbic alcohol fatty acid ester, dehydration sorbic alcohol fatty acid ester polyoxyethylene agent ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, alkylphenol formaldehyde condensation product polyoxyethylene ether can be wherein one or more.
Used disintegrant is citric acid, tartaric acid, succinic acid, adipic acid, phosphoric acid, sodium bicarbonate, sodium carbonate etc., can be wherein one or more.
Used carrier is kaolin, bentonite, anhydrous sodium sulfate, precipitated calcium carbonate, sawdust etc., can be wherein one or more.
Used binding agent is: gelatin, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, starch, dextrin, lactose can be wherein one or more.
A kind of mesotrione and glyphosate herbicidal composite wettable powder form (by mass percentage %) by following raw material
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Defoamer: 0.05%-1%
Surplus is supplied with carrier.
Used dispersant is naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, polycarboxylate, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy based phosphates, lignosulfonates, gelatin, gum Arabic, carboxymethyl cellulose, polyoxyethylene alcohol, polyvinylpyrrolidone, Sodium Polyacrylate, polyethylene glycol can be wherein one or more.
Used wetting agent is aliphatic alcohol sulfate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfate, alkylnaphthalene sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, alkyl amide sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, dehydration sorbic alcohol fatty acid ester, dehydration sorbic alcohol fatty acid ester polyoxyethylene agent ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, alkylphenol formaldehyde condensation product polyoxyethylene ether can be wherein one or more.
Used carrier is potter's clay, attapulgite, kaolin, bentonite, gypsum, diatomite, precipitated silicate calcium, precipitated calcium carbonate, white carbon, silica gel, alkaline lignin, can be wherein one or more.
Defoamer is silicone defoaming agent
A kind of mesotrione and glyphosate herbicidal composition granule form (by mass percentage %) by following raw material
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Defoamer: 0.05%-1%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier
Used dispersant is naphthalene or alkyl naphthalene formaldehyde condensate sulfonates, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, polycarboxylate, fatty alcohol ethylene oxide adduct phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy based phosphates, lignosulfonates, gelatin, gum Arabic, carboxymethyl cellulose, polyoxyethylene alcohol, polyvinylpyrrolidone, Sodium Polyacrylate, polyethylene glycol can be wherein one or more.
Used wetting agent is aliphatic alcohol sulfate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfate, alkylnaphthalene sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, alkyl amide sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, dehydration sorbic alcohol fatty acid ester, dehydration sorbic alcohol fatty acid ester polyoxyethylene agent ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, alkylphenol formaldehyde condensation product polyoxyethylene ether can be wherein one or more.
Used disintegrant is urea, sodium chloride, sodium sulphate, sodium carbonate, polyvinylpyrrolidone, sodium alginate, sodium carboxymethyl starch, ammonium sulfate, can be wherein one or more.
Used carrier is potter's clay, attapulgite, kaolin, bentonite, gypsum, diatomite, precipitated silicate calcium, precipitated calcium carbonate, white carbon, silica gel, alkaline lignin, can be wherein one or more.
Used defoamer is: silicone defoaming agent
Used binding agent is: water
The present invention also comprises the method for utilizing above-mentioned Herbicidal combinations management of weeds and dogstail, and the method comprises with the mesotrione of synergy effective dose and glyphosate composite weedicide processing useful plants, its seed or transplants or its cultivation area.
Can be the transgenic corns of corn, especially resistance glyphosate with weed killer herbicide management of weeds of the present invention and the crop that not damaged by above-mentioned weed killer herbicide.
The weeds that are mainly used in preventing and kill off comprise: prevent and kill off annual broadleaf weed and some grassy weeds, belong to weeds, summer cypress, Polygonum weeds, leaf mustard, barnyard grass, chickweed, lady's-grass etc. such as piemarker, Siberian cocklebur, thorn amaranth, multitude;
Herbicidal composition of the present invention is applicable to upper conventional all application processes used of agricultural, for example preemergence application, postemergence application and seed dressing when being used for management of weeds.The consumption of weed killer herbicide is generally being that the active component total amount is counted 100～3500g/ha.
The invention will be further described below in conjunction with example
1 one kinds of mesotriones of example and glyphosate herbicidal composition aqueous suspension agent
Mesotrione: 15
Glyphosate isopropyl ammonium salt (in acid): 30
Sodium alkyl sulfate: 3
NNO：4
Xanthans: 0.16
Aluminium-magnesium silicate: 0.5
Silicone defoaming agent: 0.2
The surplus water is supplied 100g.
2 one kinds of mesotriones of example and glyphosate herbicidal composition aqueous suspension agent
Mesotrione: 15
Glyphosate isopropyl ammonium salt (in acid): 5
Sodium alkyl sulfate: 5
NNO：4
Xanthans: 0.16
Aluminium-magnesium silicate: 0.5
Silicone defoaming agent: 0.2
The surplus water is supplied 100g.
3 one kinds of mesotriones of example and glyphosate herbicidal composition water dispersible granules
Mesotrione: 35
Ammonium glyphosate (in acid): 20
Sodium alkyl sulfate: 4
Alkyl benzene calcium sulfonate: 3
Ammonium sulfate: 3.5
Silicone defoaming agent: 0.2
Surplus complements to 100g with kaolin.
4 one kinds of mesotriones of example and glyphosate herbicidal composition water dispersible granules
Mesotrione: 5
Ammonium glyphosate (in acid): 60
Sodium alkyl sulfate: 5
Alkyl benzene calcium sulfonate: 3
Ammonium sulfate: 3.5
Silicone defoaming agent: 0.2
Surplus complements to 100g with kaolin.
5 one kinds of mesotriones of example and glyphosate herbicidal composition granule
Mesotrione: 1
Glyphosate potassium (in acid): 77
OP-10：1
Dispersing agent MF: 2
Urea: 1
Silicone defoaming agent: 0.1
Surplus complements to 100g with kaolin
6 one kinds of mesotriones of example and glyphosate herbicidal composite wettable powder
Mesotrione: 40
Sodium glyphosate (in acid): 25
Sodium lignin sulfonate: 5.5
Sodium alkyl sulfate: 3
Silicone defoaming agent: 0.1
Surplus complements to 100g with diatomite.
7 one kinds of mesotriones of example and glyphosate herbicidal composition aqueous dispersion tablets
Mesotrione: 29
Glyphosate dimethylamine salt (in acid): 25
Sodium lignin sulfonate: 5
Pull open powder: 3.5
Ammonium sulfate: 2.5
Surplus complements to 100g with kaolin.
8 one kinds of mesotriones of example and glyphosate herbicidal composition effervescent tablet
Mesotrione: 35
Ammonium glyphosate (in acid): 20
Sodium lignin sulfonate: 2
Citric acid: 9
Sodium carbonate: 10
Surplus complements to 100g with lactose.
9 one kinds of mesotriones of example and glyphosate herbicidal composition effervescent tablet
Mesotrione: 45
Ammonium glyphosate (in acid): 7
Sodium lignin sulfonate: 2
Citric acid: 9
Sodium carbonate: 10
Surplus complements to 100g with lactose.
Biological Examples 1 mesotrione glyphosate herbicidal composition is to the corn field weed field control effectiveness test
1. experimental scheme
11 processing are established in test altogether, example 1, example 2, example 3, example 4, example 5, example 6, example 7, example 8, example 9, (farming reaches contrast medicament 41% glyphosate isopropylamine salt water solution, Monsanto Company produces), 15% mesotrione suspending agent (production of Dandong, Liaoning city agricultural chemicals head factory), and establish a blank.Each is processed and repeats each residential quarter area 20m 4 times
2
2. weeds investigation
Dispenser the previous day, every residential quarter is decided 4 squares, every some 0.25m2, i.e. 1m at random
2/ residential quarter, the weeds radix in investigating at every.Preventive effect is counted in the 15th day investigation weeds strain after dispenser, preventive effect and fresh weight preventive effect are counted in investigation strain in 30 days.
3. crop safety sex investigation
After the dispenser, observe medicament corn is had or not poisoning, estimate reagent agent to the safety of corn
4. experimental result
(1) safety
After the dispenser, chemicals treatment district corn plant height, Ye Se and blank district are basically identical, show that reagent agent is to corn safety.
(2) weeds preventive effect
Herbicidal effect is seen attached list, can find out that from subordinate list 15% mesotrione suspending agent is on the low side to the preventive effect of grassy weed such as lady's-grass, barnyard grass etc., and to preventive effects such as broad leaved weed such as chickweed, polygonum flaccidum, thorn amaranths all more than 80%, 41% glyphosate isopropylamine salt water solution to the preventive effect of grassy weed and broad leaved weed about 90%.And the mesotrione that the present invention relates to and glyphosate herbicidal composition have preferably control efficiency to grassy weed and broad-leaved section weeds, and all more than 95%, herbicidal effect is better than glyphosate and mesotrione single dose to the preventive effect of corn field weed.
Subordinate list 1 is weeds radix (unit: strain/m experimental field
2)
3 one kinds of mesotrione glyphosate herbicidals of subordinate list composition is to corn field weed 30d fresh weight preventive effect (unit: g/m
2)
Claims (17)
1. the Herbicidal combinations of a controlling weeds and dogstail is characterized in that being comprised of mesotrione and glyphosate salt compounds.
2. composition according to claim 1 is characterized in that described glyphosate salt is one or more existence in ammonium glyphosate, glyphosate potassium, sodium glyphosate, glyphosate isopropyl amine salt, the glyphosate dimethylamine salt.
3. composition according to claim 1 and 2 is characterized in that the mass ratio of mesotrione and glyphosate salt compounds (take acid) is 1: 99-99: 1.
4. described composition according to claim 3, the mass ratio that it is characterized in that mesotrione and glyphosate salt compounds is 1: 20～10: 1.
5. a weed killer herbicide is characterized in that, it is comprised of acceptable auxiliary material in each described Herbicidal combinations of claim 1 to 4 and the pesticidal preparations, and the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 5%～95%.
6. weed killer herbicide according to claim 5 is characterized in that, the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 30%～90%.
7. weed killer herbicide according to claim 5 is characterized in that, it is aqueous suspension agent, water dispersible granules, aqueous dispersion tablets, effervescent tablet, wetting powder and granule.
8. weed killer herbicide according to claim 5 is characterized in that acceptable auxiliary material in the described pesticidal preparations comprises one or more the mixture in wetting agent, dispersant, disintegrant, emulsifier, binding agent, defoamer, thickener, stabilizing agent, antifreezing agent, preservative, volume, the carrier etc.
9. aqueous suspension agent according to claim 7 is characterized in that comprising following composition:
Mesotrione: 0.1%-99%
Glyphosate salt (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Antifreezing agent: 0.1%-10%
Thickener: 0.05%-5%
Defoamer: 0.05%-5%
The surplus water is supplied.
10. water dispersible granules according to claim 7 is characterized in that comprising following composition:
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Defoamer: 0.05%-1%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier.
11. aqueous dispersion tablets according to claim 7 is characterized in that comprising following composition:
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier.
12. effervescent tablet according to claim 7 is characterized in that comprising following composition:
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier.
13. wetting powder according to claim 7 is characterized in that comprising following composition:
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Defoamer: 0.05%-1%
Surplus is supplied with carrier.
14. granule according to claim 7 is characterized in that comprising following composition:
Mesotrione: 0.1%-99%
Glyphosate (in acid): 0.1%-99%
Dispersant: 0.1%-10%
Wetting agent: 0.1%-8%
Disintegrant: 0.1%-10%
Defoamer: 0.05%-1%
Binding agent: 0.1%-10%
Its surplus is supplied with carrier.
15. the method for a management of weeds and dogstail comprises with herbicide treatment useful plants crop claimed in claim 5, its seed of weed killer herbicide synergy effective dose or transplants or its cultivation area.
16. method according to claim 15 is characterized in that the consumption of described weed killer herbicide is equivalent to the active component total amount of 100～3500g/ha.
17. method according to claim 15 is characterized in that described crop is corn, especially the transgenic corns of resistance glyphosate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101294376A CN103371177A (en) | 2012-04-24 | 2012-04-24 | Herbicide composition containing methyl sulcotrione and glyphosate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101294376A CN103371177A (en) | 2012-04-24 | 2012-04-24 | Herbicide composition containing methyl sulcotrione and glyphosate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103371177A true CN103371177A (en) | 2013-10-30 |
Family
ID=49457498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101294376A Pending CN103371177A (en) | 2012-04-24 | 2012-04-24 | Herbicide composition containing methyl sulcotrione and glyphosate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103371177A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105532723A (en) * | 2016-02-01 | 2016-05-04 | 陕西上格之路生物科学有限公司 | Weeding composition containing saflufenacil |
| CN109819998A (en) * | 2019-03-21 | 2019-05-31 | 河南瀚斯作物保护有限公司 | It is a kind of containing glyphosate, Quizalotop-ethyl, mesotrione Herbicidal combinations |
| GB2555462B (en) * | 2016-10-31 | 2021-07-07 | Rotam Agrochem Int Co Ltd | Herbicidal composition comprising mesotrione |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1315832A (en) * | 1998-08-13 | 2001-10-03 | 阿温提斯作物科学有限公司 | Herbicidal composition for tolerant or resistant rice crops |
| CN1897811A (en) * | 2003-12-05 | 2007-01-17 | 辛根塔参与股份公司 | Submicron mesotrione compositions |
| WO2009141367A2 (en) * | 2008-05-21 | 2009-11-26 | Basf Se | Herbicidal composition comprising glyphosate, glufosinate or their salts |
-
2012
- 2012-04-24 CN CN2012101294376A patent/CN103371177A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1315832A (en) * | 1998-08-13 | 2001-10-03 | 阿温提斯作物科学有限公司 | Herbicidal composition for tolerant or resistant rice crops |
| CN1897811A (en) * | 2003-12-05 | 2007-01-17 | 辛根塔参与股份公司 | Submicron mesotrione compositions |
| WO2009141367A2 (en) * | 2008-05-21 | 2009-11-26 | Basf Se | Herbicidal composition comprising glyphosate, glufosinate or their salts |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105532723A (en) * | 2016-02-01 | 2016-05-04 | 陕西上格之路生物科学有限公司 | Weeding composition containing saflufenacil |
| GB2555462B (en) * | 2016-10-31 | 2021-07-07 | Rotam Agrochem Int Co Ltd | Herbicidal composition comprising mesotrione |
| CN109819998A (en) * | 2019-03-21 | 2019-05-31 | 河南瀚斯作物保护有限公司 | It is a kind of containing glyphosate, Quizalotop-ethyl, mesotrione Herbicidal combinations |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR112020022805A2 (en) | liquid suspension composition, granular composition, composition preparation processes and method for improving plant health or yield | |
| CN103609566B (en) | A kind of Herbicidal combinations containing mesotrione and amicarbazone | |
| CN102696630A (en) | Weeding composition and preparation thereof | |
| CN103749480A (en) | Paddy field herbicide composition and application | |
| CN102763658A (en) | Safety herbicide for corn field | |
| CN104521993B (en) | 1,2,3-thiadiazoles-5-formamidine new herbicides containing three azacyclo-s | |
| CN101946792A (en) | Azoxystrobin-prochloraz complex bactericide and application thereof | |
| CN102845446A (en) | Herbicidal composition containing bensulfuron methyl and butachlorfor for paddy field | |
| CN104872162B (en) | A kind of cornfield weeding composition containing topramezone | |
| CN104115835A (en) | Herbicide composition | |
| CN104186513A (en) | Herbicidal composition and preparation thereof | |
| CN101911948B (en) | Cinosulfuron-containing herbicide composition | |
| CN103371177A (en) | Herbicide composition containing methyl sulcotrione and glyphosate | |
| CN103518780A (en) | Novel herbicide | |
| CN104255738A (en) | Sugarcane field herbicide composition and application thereof | |
| CN104273135B (en) | Containing compound herbicide and the application thereof of clethodim, benazolin and isopropyl methoxalamine | |
| US9642371B2 (en) | Compositions and methods comprising colletotrichum for controlling plant species | |
| CN101336632A (en) | Composite synergistic herbicide for controlling weeds in cornfield | |
| CN107318865A (en) | The composition pesticide of captan and furametpyr compounding | |
| CN104542695B (en) | A kind of containing methylsulfonyl bacterium azoles and the complex composition of toxic fluoride phosphate and preparation | |
| CN105638697B (en) | Composition pesticide and its application containing methoxy acrylic bactericide | |
| CN106561700A (en) | Paddy direct sowing field ternary weeding composition | |
| CN102388899B (en) | Herbicide composition and preparation method thereof | |
| CN102365959B (en) | Wheatland weeding composition and preparation thereof | |
| CN106472519A (en) | A kind of rice direct seeding field ternary weeding composition containing cyhalofop-butyl |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20131030 |