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CN103351585B - Antibacterial and antistatic polyester resin slice - Google Patents

Antibacterial and antistatic polyester resin slice Download PDF

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Publication number
CN103351585B
CN103351585B CN201310283183.8A CN201310283183A CN103351585B CN 103351585 B CN103351585 B CN 103351585B CN 201310283183 A CN201310283183 A CN 201310283183A CN 103351585 B CN103351585 B CN 103351585B
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Prior art keywords
antibacterial
antistatic
polyester resin
parts
additives
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Expired - Fee Related
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CN201310283183.8A
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CN103351585A (en
Inventor
邵峰
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Changshu Hulian Printing & Dyeing Co Ltd
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Changshu Hulian Printing & Dyeing Co Ltd
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Abstract

本发明涉及一种抗菌抗静电涤纶树脂切片,以重量份计,所述的抗菌抗静电涤纶树脂切片的原料配方如下:PET切片75~85份、抗菌添加剂5~15份、抗静电添加剂0.5~5份、增塑剂5~10份,其中所述的PET切片分子量为25000~50000,所述的增塑剂为邻苯二甲酸二丁酯、邻苯二甲酸二异丙酯、邻苯二甲酸二戊酯中的一种。由于上述技术方案运用,本发明具有下列优点:在涤纶树脂切片原料中同时加入抗菌添加剂和抗静电添加剂,使得涤纶树脂切片同时具有抗菌、抗静电性能,利用该涤纶树脂切片制备的纺织品被赋予永久的抗菌、抗静电性能,能满足人们对纺织品日益增长的要求。The invention relates to an antibacterial and antistatic polyester resin slice. The raw material formula of the antibacterial and antistatic polyester resin slice is as follows: 75 to 85 parts of PET slices, 5 to 15 parts of antibacterial additives, and 0.5 to 15 parts of antistatic additives. 5 parts, 5~10 parts of plasticizer, wherein the molecular weight of the PET chips is 25000~50000, and the plasticizer is dibutyl phthalate, diisopropyl phthalate, phthalate One of dipyl formate. Due to the application of the above-mentioned technical scheme, the present invention has the following advantages: antibacterial additives and antistatic additives are added to the polyester resin chip raw materials at the same time, so that the polyester resin chip has antibacterial and antistatic properties at the same time, and the textiles prepared by using the polyester resin chip are endowed with permanent Excellent antibacterial and antistatic properties can meet people's increasing requirements for textiles.

Description

一种抗菌抗静电涤纶树脂切片A kind of antibacterial and antistatic polyester resin chip

技术领域 technical field

本发明属于纺丝原料领域,具体地涉及一种抗菌抗静电涤纶树脂切片。 The invention belongs to the field of spinning raw materials, and in particular relates to an antibacterial and antistatic polyester resin chip.

背景技术 Background technique

随着生活水平的不断改善,人们对纺织产品的要求也不断提高,具有抗紫外、抗菌、吸臭、抗静电、红外保暖等特殊性能的纺织品越来越能引起人们的关注。 With the continuous improvement of living standards, people's requirements for textile products are also constantly improving. Textiles with special properties such as anti-ultraviolet, antibacterial, odor absorption, antistatic, and infrared warmth are attracting more and more people's attention.

为了使纺织品具有上述性能,工程师们设计了两种方法:一种是在聚酯熔体中添加各种纳米材料,然后纺丝形成纤维,接着将纤维纺织成布料;另一种是将纺织形成的织物浸入含有纳米粒子前驱体的溶液中,通过调节溶液的pH值和温度,使得纳米粒子附着于织物上。其中通过后一种方法制备的纺织品在使用过程中会由于纳米粒子的逐渐流失而失去其赋予的特殊性能,而前一种方法可以赋予纺织品永久的特殊性能,因而被大范围推广使用。 In order to make textiles have the above properties, engineers have designed two methods: one is to add various nanomaterials to polyester melt, and then spin to form fibers, and then weave the fibers into cloth; The fabric is immersed in the solution containing the nanoparticle precursor, and the nanoparticle is attached to the fabric by adjusting the pH value and temperature of the solution. Among them, the textiles prepared by the latter method will lose their special properties due to the gradual loss of nanoparticles during use, while the former method can endow textiles with permanent special properties, so it is widely used.

例如,申请公布号为CN102702692A的中国发明专利公开了一种抗菌多孔聚酯切片及其制备和加工POY长丝、DTY丝的方法,并且制备的PET聚酯切片具有良好的抗菌效果。然而,用该PET聚酯切片纺成的纤维丝在使用过程中不可避免的会累积静电,不利于人类身体健康。 For example, the Chinese invention patent application publication number CN102702692A discloses an antibacterial porous polyester chip and its method for preparing and processing POY filaments and DTY filaments, and the prepared PET polyester chip has good antibacterial effect. However, the filaments spun from the PET polyester chips will inevitably accumulate static electricity during use, which is not conducive to human health.

发明内容 Contents of the invention

本发明目的是为了克服现有技术的不足而提供一种能够同时抗菌、抗静电的涤纶树脂切片。 The object of the present invention is to provide a polyester resin chip capable of antibacterial and antistatic in order to overcome the deficiencies of the prior art.

为达到上述目的,本发明所采用的技术方案为:一种抗菌抗静电涤纶树脂切片,以重量份计,所述的抗菌抗静电涤纶树脂切片的原料配方如下:PET切片75~85份、抗菌添加剂5~15份、抗静电添加剂0.5~5份、增塑剂5~10份,其中所述的PET切片分子量为25000~50000,所述的增塑剂为邻苯二甲酸二丁酯、邻苯二甲酸二异丙酯、邻苯二甲酸二戊酯中的一种。 In order to achieve the above object, the technical solution adopted in the present invention is: a kind of antibacterial antistatic polyester resin slice, in parts by weight, the raw material formula of described antibacterial antistatic polyester resin slice is as follows: PET slice 75~85 parts, antibacterial 5-15 parts of additives, 0.5-5 parts of antistatic additives, 5-10 parts of plasticizers, wherein the molecular weight of the PET chips is 25000-50000, and the plasticizers are dibutyl phthalate, ortho One of diisopropyl phthalate and dipentyl phthalate.

优化地,所述的抗菌添加剂为以二氧化硅为载体表面负载有银纳米粒子的粉体。 Optimally, the antibacterial additive is a powder with silver nanoparticles loaded on the surface of silica as a carrier.

进一步地,所述的银与二氧化硅的质量比为1:1~5。 Further, the mass ratio of silver to silicon dioxide is 1:1-5.

优化地,所述的抗静电添加剂为纳米二氧化钛。 Optimally, the antistatic additive is nano titanium dioxide.

进一步地,所述的纳米二氧化钛粒径为50~200nm。 Further, the particle size of the nano-titanium dioxide is 50-200nm.

由于上述技术方案运用,本发明与现有技术相比具有下列优点:在涤纶树脂切片原料中同时加入抗菌添加剂和抗静电添加剂,使得涤纶树脂切片同时具有抗菌、抗静电性能,因此利用该涤纶树脂切片制备的纺织品被赋予永久的抗菌、抗静电性能,满足人们对纺织品日益增长的要求。 Due to the application of the above-mentioned technical scheme, the present invention has the following advantages compared with the prior art: adding antibacterial additives and antistatic additives to the raw materials of polyester resin slices simultaneously, so that polyester resin slices have antibacterial and antistatic properties at the same time, so using the polyester resin The textiles prepared by slicing are endowed with permanent antibacterial and antistatic properties, meeting people's increasing requirements for textiles.

具体实施方式 Detailed ways

以下结合实施例对本发明作进一步详细描述。 The present invention is described in further detail below in conjunction with embodiment.

实施例1-3 Example 1-3

实施例1-3的抗菌抗静电涤纶树脂切片原料配方、抗菌性能、抗静电性能见表1: The antibacterial and antistatic polyester resin slice raw material formula of embodiment 1-3, antibacterial performance, antistatic performance are shown in Table 1:

表1 实施例1-3的抗菌抗静电涤纶树脂切片原料配方以及抗菌性和抗静电性检测结果 Table 1 Antibacterial and antistatic polyester resin slice raw material formula and antibacterial and antistatic test results of embodiment 1-3

上述实施例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围之内。 The above-mentioned embodiments are only to illustrate the technical concept and characteristics of the present invention, and the purpose is to enable those skilled in the art to understand the content of the present invention and implement it accordingly, and not to limit the protection scope of the present invention. All equivalent changes or modifications made according to the spirit of the present invention shall fall within the protection scope of the present invention.

Claims (1)

1.一种抗菌抗静电涤纶树脂切片,其特征在于:以重量份计,所述的抗菌抗静电涤纶树脂切片的原料配方如下:PET切片75~85份、抗菌添加剂5~15份、抗静电添加剂0.5~5份、增塑剂5~10份,其中所述的PET切片分子量为25000~50000,所述的增塑剂为邻苯二甲酸二丁酯、邻苯二甲酸二异丙酯、邻苯二甲酸二戊酯中的一种;所述的抗菌添加剂为以二氧化硅为载体表面负载有银纳米粒子的粉体;所述的银与二氧化硅的质量比为1:1~5;所述的抗静电添加剂为纳米二氧化钛;所述的纳米二氧化钛粒径为50~200nm。 1. an antibacterial and antistatic polyester resin slice, is characterized in that: in parts by weight, the raw material formula of described antibacterial and antistatic polyester resin slice is as follows: PET slice 75~85 parts, antibacterial additive 5~15 parts, antistatic 0.5-5 parts of additives, 5-10 parts of plasticizers, wherein the molecular weight of the PET chips is 25000-50000, and the plasticizers are dibutyl phthalate, diisopropyl phthalate, One of dipentyl phthalate; the antibacterial additive is a powder with silica as the carrier surface loaded with silver nanoparticles; the mass ratio of silver to silica is 1:1~ 5. The antistatic additive is nano-titanium dioxide; the particle size of the nano-titanium dioxide is 50-200nm.
CN201310283183.8A 2013-07-08 2013-07-08 Antibacterial and antistatic polyester resin slice Expired - Fee Related CN103351585B (en)

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104451950A (en) * 2014-12-23 2015-03-25 常熟市云燕化纤有限公司 Composite anti-electrostatic fiber
CN105542404A (en) * 2016-01-18 2016-05-04 苏州法斯特信息科技有限公司 Novel anti-static textile material and preparation method thereof
CN105838044B (en) * 2016-05-05 2017-11-03 长兴宝福织造有限公司 A kind of preparation method of multifunctional terylene resin slicer
CN105862159B (en) * 2016-05-05 2018-04-20 长兴宝福织造有限公司 A kind of preparation method of uvioresistant, antistatic superfine denier polyester fiber
CN106343639B (en) * 2016-11-01 2018-06-05 江苏昌邦安防科技股份有限公司 Anti-skidding anti-static glove
CN108976723A (en) * 2018-06-20 2018-12-11 安徽江淮汽车集团股份有限公司 A kind of PBT composite and preparation method thereof
CN110373745B (en) * 2019-08-23 2022-03-11 温州大学 High-strength blended spinning polyester fiber and high-strength clothing material
CN110552080A (en) * 2019-09-04 2019-12-10 浙江迈实科技有限公司 Slice spinning method for photocatalyst chemical fiber
CN112342637A (en) * 2020-11-09 2021-02-09 李东靖 Antibacterial anti-static textile fabric and preparation method thereof
CN116005288A (en) * 2022-12-09 2023-04-25 罗莱生活科技股份有限公司 Antibacterial antistatic polyester fiber and preparation method and application thereof

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CN101263826A (en) * 2007-03-14 2008-09-17 范翔 Silver ion antimicrobial agent and dry method production process
CN102040828A (en) * 2009-10-26 2011-05-04 杜邦兴达(无锡)单丝有限公司 Antibacterial composition, antibacterial brush filament and preparation method thereof
CN102371743A (en) * 2011-08-29 2012-03-14 合肥乐凯科技产业有限公司 Antistatic polyester film and preparation method thereof
CN102702692A (en) * 2012-05-23 2012-10-03 常熟市阳光针织布业有限公司 Antimicrobial porous polyester chip and method for preparing and processing POY filament yarns and DTY yarns

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1763275A (en) * 2004-10-21 2006-04-26 天津石油化工公司化纤厂 Method for manufacturing fire retardant-antistatic polyester fiber
CN101263826A (en) * 2007-03-14 2008-09-17 范翔 Silver ion antimicrobial agent and dry method production process
CN102040828A (en) * 2009-10-26 2011-05-04 杜邦兴达(无锡)单丝有限公司 Antibacterial composition, antibacterial brush filament and preparation method thereof
CN102371743A (en) * 2011-08-29 2012-03-14 合肥乐凯科技产业有限公司 Antistatic polyester film and preparation method thereof
CN102702692A (en) * 2012-05-23 2012-10-03 常熟市阳光针织布业有限公司 Antimicrobial porous polyester chip and method for preparing and processing POY filament yarns and DTY yarns

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