CN103343453A - Super pretty flame-retardant textile fabric and manufacturing method thereof - Google Patents
Super pretty flame-retardant textile fabric and manufacturing method thereof Download PDFInfo
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- CN103343453A CN103343453A CN201310297374XA CN201310297374A CN103343453A CN 103343453 A CN103343453 A CN 103343453A CN 201310297374X A CN201310297374X A CN 201310297374XA CN 201310297374 A CN201310297374 A CN 201310297374A CN 103343453 A CN103343453 A CN 103343453A
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- 239000004744 fabric Substances 0.000 title claims abstract description 52
- 239000003063 flame retardant Substances 0.000 title claims abstract description 45
- 239000004753 textile Substances 0.000 title claims abstract description 27
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 77
- 239000002344 surface layer Substances 0.000 claims abstract description 49
- 229920000742 Cotton Polymers 0.000 claims abstract description 44
- 239000011347 resin Substances 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 239000002184 metal Substances 0.000 claims abstract description 23
- 229920000728 polyester Polymers 0.000 claims abstract description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 16
- 239000010439 graphite Substances 0.000 claims abstract description 16
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 16
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 16
- 230000000979 retarding effect Effects 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 6
- 238000009941 weaving Methods 0.000 claims abstract description 4
- 239000004952 Polyamide Substances 0.000 claims description 33
- 229920002647 polyamide Polymers 0.000 claims description 33
- 239000000243 solution Substances 0.000 claims description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 16
- 239000003292 glue Substances 0.000 claims description 15
- 229910052698 phosphorus Inorganic materials 0.000 claims description 15
- 239000011574 phosphorus Substances 0.000 claims description 15
- -1 phosphorus compound Chemical class 0.000 claims description 15
- 239000010410 layer Substances 0.000 claims description 13
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 10
- 239000004115 Sodium Silicate Substances 0.000 claims description 10
- 239000004411 aluminium Substances 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 239000003610 charcoal Substances 0.000 claims description 10
- FBPXRCLDUZKJLC-UHFFFAOYSA-N dioxosilane;oxomagnesium Chemical compound [Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FBPXRCLDUZKJLC-UHFFFAOYSA-N 0.000 claims description 10
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 10
- 239000004575 stone Substances 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 239000011787 zinc oxide Substances 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 9
- 239000003814 drug Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 6
- 239000012080 ambient air Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000009954 braiding Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 230000035699 permeability Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 229920006052 Chinlon® Polymers 0.000 abstract 2
- 230000008033 biological extinction Effects 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 150000003018 phosphorus compounds Chemical class 0.000 abstract 1
- 230000006378 damage Effects 0.000 description 5
- 238000003892 spreading Methods 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 206010021143 Hypoxia Diseases 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007954 hypoxia Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 210000000689 upper leg Anatomy 0.000 description 1
Landscapes
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
The invention relates to a super pretty flame-retardant textile fabric and a manufacturing method of the super pretty flame-retardant textile fabric. The fabric comprises three surface layers, wherein the surface layers are adhered by flame-retardant high-temperature mold resin adhesive, the surface layer is woven by warps and wefts in an up and down staggered manner, the warps and wefts are soaked in a special flame-retardant chemical solution before being woven, the warp comprises fiber metal filament, brocade cotton, polyester filament yarn and 20D chinlon extinction FDY (polyester filament yarn) filament yarn; the weft comprises cotton, linen, silk and 20D chinlon extinction FDY filament yarn, the cross section of each warp yarn and the cross section of each weft yarn are pressed to flat rectangles before weaving to beneficially improve the stiffness of the fabric, the warp and weft materials are soaked in the flame-retardant chemical solution to perform functions of retarding flame and preventing the fire spread, graphite and phosphorus compounds and metal oxide sprayed on the fabric perform a surface flame retardant function, the fabric is tightly woven and the air permeability of the fabric is very bad, so that the flame retardant effect of the fabric can be improved; and the manufacturing method of the fabric is simple, and a plurality of warps or wefts are connected in parallel to improve the stiffness and the air impermeability of the fabric.
Description
Technical field
The present invention relates to super very fire-retardant textile cloth and manufacture method thereof, it is a kind of textile cloth that can prevent the fire spreading burning, adopts specific chemical agent soak-out material, and specific doubling method is made, and belongs to textiles and method field of manufacturing thereof.
Background technology
Textile cloth extensively exists and is applied in our everyone life, and the clothes of the overwhelming majority, family's curtain etc. all use textile cloth.Present urbanization construction, the life that makes people is crypto set more, no matter handles official business or lives, a lot of people live in the same building, and number of floor levels is bigger usually, and people more rely on the elevator and go downstairs, understanding for escape way is very few, generally lacks knowledge on fire fighting, the experience of almost not escaping.During breaking out of fire, people usually can be very terrified, and escape way stops up, and personnel are difficult in time evacuate; cause great personnel's injury, property is difficult to save from damage, so the injury of fire is extremely big; how to prevent fire, and after the fire generation, it is very important how to eliminate fire.At present, that people do not have is special, can be the easily portable fire service inventory that can be used for, and present a lot of chemical agent fire, electric fire, coal gas fire, all be not suitable for fire-fighting by water, so, for normal work and life, do not have people's fire extinguishing that article can group, fire hydrant also will regularly replace, and is often ignored by people or forgets.
Summary of the invention
In order to solve the problem of above-mentioned existence; the invention discloses a kind of super very fire-retardant textile cloth and manufacture method thereof; this textile cloth can effectively stop fire spreading; be placed on family or office space, easy to use, bedding is on fire; after fire burns down this textile cloth; automatically extinguish, can not spread, convenient handy; can effectively avoid bigger fire damage; safe and reliable, this textile cloth can be fitted in the inflammable thing surface for bedding or adhesion simultaneously, and the inflammable thing catching fire is intact; automatically extinguish; around can not spreading to, effectively fire damage is dropped to minimumly, be conducive to protect substantially people's safety of life and property.
Super very fire-retardant textile cloth, comprise 3 aspect layers, bonding with glue between surface layer, surface layer is formed by warp thread and weft yarn up and down weaving, warp thread and weft yarn are placed on before braiding in the specific fire retardant chemistry liquid medicine and soak, warp thread comprises fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament, and weft yarn comprises cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament.
The thickness of described individual layer surface layer is 1.5 ~ 2.5mm, and the space between the mutual bonding adjacent surface layer is less than 0.02mm, and the warp thread of bonding adjacent surface layer is vertical mutually with weft yarn mutually, and two-layer at least warp thread or weft yarn are arranged on the cross section of surface layer.
The upper and lower surface of described surface layer all is coated with fire retardant, and the active ingredient of fire retardant is graphite and phosphorus compound, metal oxide.
The bonding glue that uses of described surface layer is inflaming retarding high-temperature resin mould glue.
The active ingredient of described specific fire retardant chemistry liquid medicine comprises: vinyl acetate, titanium dioxide, float stone, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, powdery fluorocarbon resin, furane resins, charcoal end.
The part by weight of the fibre metal silk in the described warp thread, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament is: 1:3:5:8, the part by weight of the cotton in the weft yarn, fiber crops, silk and 20D polyamide fibre delustring FDY long filament is: 1:3:4:8.
Make the method for super very fire-retardant textile cloth, may further comprise the steps:
(1) according to weight proportion: vinyl acetate 65 ~ 70%, titanium dioxide 1 ~ 3%, float stone 3 ~ 5%, zinc oxide 1 ~ 3%, SODIUM SILICATE 1 ~ 3%, moisture Petimin aluminium 2 ~ 3%, powdery fluorocarbon resin 5 ~ 7%, furane resins 7 ~ 8%, charcoal end 8 ~ 11%, take by weighing each composition, at first vinyl acetate is dissolved in the ethanol, dilution factor reaches 1:4 ~ 7, treat the ethanolic solution cooling of vinyl acetate, fluid temperature is no more than 5 ℃, in environment temperature is no more than 25 ℃ environment, float stone and charcoal end are joined in the ethanolic solution of vinyl acetate, and be cooled to fluid temperature and be no more than 5 ℃, shake up, again with titanium dioxide, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, powdery fluorocarbon resin and furane resins are cooled to natural temperature, shake up, be cooled to fluid temperature and be no more than 5 ℃, stand-by;
(2) fibre metal silk, brocade cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk are immersed in step (1) the gained solution and soak at least 13 hours;
(3) the fibre metal silk after will soaking, brocade cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk taking-up, grouping according to type separates, scatters, and be suspended on the gentle breeze that wind speed is 5 ~ 5.4m/s, ambient air temperature is transferred to no wind environment with moisture less than 10% warp thread or weft material in 27 ~ 30 ℃ environment;
(4) be that 1:3:5:8 gets fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament according to weight ratio, and it is the vertical combing of each composition is neat, parallel combining, twist then and rub with the hands, fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament spiral are twisted and are twisted into a strand, and the rectangle that rope is placed on two butt joints flattens in the mould, to restrict and flatten, the cross section of rope is rectangle, and obtain warp thread, the length of rectangle: wide is 2 ~ 3:1;
(5) be that 1:3:4:8 gets cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament according to weight ratio, and it is the vertical combing of each composition is neat, parallel combining, twist then and rub with the hands, cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament spiral are twisted and are twisted into a strand, and the rectangle that rope is placed on two butt joints flattens in the mould, to restrict and flatten, the cross section of rope is rectangle, and obtain weft yarn, the length of rectangle: wide is 2 ~ 3:1;
(6) get 8 on the warp thread that step (4) obtains, the left and right sides, the long limit contiguous concatenation of rectangle forms single layer warp, gets 8 of the weft yarns that step (5) obtains, the left and right sides, the long limit contiguous concatenation of rectangle, formation individual layer weft yarn;
(7) warp thread is vertical with weft yarn, and the pattern that weft yarn obtains with step (6) splicing penetrates the adjacent pattern warp thread that obtains with step (6) splicing up and down, and the warp thread of the pattern that obtains with step (6) splicing runs through successively with weft yarn and interweaves the formation surface layer;
(8) the even aqueous solution of graphite spraying and phosphorus compound, metal oxide on two surfaces of the surface layer of step (7) gained, and will be the gentle breeze of 5 ~ 5.4m/s at wind speed, ambient air temperature is in 27 ~ 30 ℃ environment, up to the facing surface drying;
(9) surface layer one side surface of step (8) gained is coated inflaming retarding high-temperature resin mould glue, fit mutually with another surface layer, and evenly give 3 ~ 4 kilograms power extruding, solidify fully up to flame-retardant glue.
The process for preparation of the solution of graphite and phosphorus compound, metal oxide is in the described step (8), getting graphite is dissolved in the water, be stirred to even dispersion, solution is cooled to the normal temperature state, adds ice cube in solution, add phosphorus compound again, constantly stir in the process that adds, be cooled to normal temperature, add metal oxide, cool off, shake up, the mol ratio of the solution that graphite and phosphorus compound, metal oxide dissolving are mixed with is 3:2:4.
The middle warp thread of described step (7) and weft yarn run through and interweave closely, and the interstitial gap between the adjacent warp thread is not more than 0.05mm, and the space between the adjacent weft is not more than 0.05m, and warp thread is vertical mutually in weft yarn.
Be used in the described step (9) extruding two mutually the temperature of the extruding story surface layer contact surface of bonding surface layer be lower than 4 ℃.
The present invention, the original material of cloth is the fibre metal silk, brocade is cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk, distribution is dispersed in warp thread in weft yarn, can satisfy the hardness deflection demand of surface layer, the fibre metal silk improves the toughness of surface layer simultaneously, reduce wearing and tearing, increase the service life, before processing, be placed in the fire retardant chemistry medicament and soak, the fire retardant chemistry medicament infilters the fibre metal silk, brocade is cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, in the silk, under fired state, the fibre metal silk, brocade is cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, the vinyl acetate that silk contains, titanium dioxide, float stone, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, the powdery fluorocarbon resin, furane resins, the charcoal end, stop fire spreading, only in the fire location burning, fire can not spread from fire location fire towards periphery.When catching fire, only need this cloth is covered the surface that catches fire, fire burns is intact to be extinguished automatically, can not spread; simultaneously, cloth of the present invention can be made clothes, for fire fighter's dress; can protect the fire fighter well, in fire fighting, health can not burnt by fire spread.Cloth of the present invention surface is coated with fire retardant, improves the flame retardant effect of cloth, increases the thickness of cloth, reduces the gas permeability of cloth, when cloth covers fiery going up, makes the oxygen flow of fiery surrounding environment logical obstructed, accelerates fire and extinguishes.The manufacture method of this cloth, simple relatively, warp thread and weft yarn are formed thigh respectively and are come knitted or woven fabrics, increase the thickness of cloth, the air-vent on cloth surface is less less, autologous density is big, and the multilayer cloth adheres to, and the lining of part air-vent covers, permeability is poorer, during use, when covering fiery going up, the gas permeability of cloth is poor, make or environmental hypoxia on every side, the fire retardant on cloth surface increases difficulty on fire, reduces the rate of propagation of fire, integrates, cloth of the present invention is when being used for putting out fire, can play good effect, and this cloth, can be placed on family or any office space, floor space is little, easy to use, and can be not expired, people improved greatly at home or the sense of security of office.
The present invention, warp thread and weft yarn are holded up the long limit of cross section, and 8 are side by side, the surface layer of braiding gained, thickness is big, and deflection is big, but the space also can be big slightly, by 3 aspect layers, can remedy the space on the surface layer effectively, and the overall air permeability of cloth can be reduced.
The specific embodiment
Below in conjunction with the specific embodiment, further illustrate the present invention.
This super very fire-retardant textile cloth, comprise 3 aspect layers, bonding with glue between surface layer, surface layer is formed by warp thread and weft yarn up and down weaving, warp thread and weft yarn are placed on before braiding in the specific fire retardant chemistry liquid medicine and soak, warp thread comprises fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament, and weft yarn comprises cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament.
The thickness of described individual layer surface layer is 1.5 ~ 2.5mm, and the space between the mutual bonding adjacent surface layer is less than 0.02mm, and the warp thread of bonding adjacent surface layer is vertical mutually with weft yarn mutually, and two-layer at least warp thread or weft yarn are arranged on the cross section of surface layer.
The upper and lower surface of described surface layer all is coated with fire retardant, and the active ingredient of fire retardant is graphite and phosphorus compound, metal oxide.
The bonding glue that uses of described surface layer is inflaming retarding high-temperature resin mould glue.
The active ingredient of described specific fire retardant chemistry liquid medicine comprises: vinyl acetate, titanium dioxide, float stone, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, powdery fluorocarbon resin, furane resins, charcoal end.
The part by weight of the fibre metal silk in the described warp thread, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament is: 1:3:5:8, the part by weight of the cotton in the weft yarn, fiber crops, silk and 20D polyamide fibre delustring FDY long filament is: 1:3:4:8.
Make the method for super very fire-retardant textile cloth, may further comprise the steps:
(1) according to weight proportion: vinyl acetate 65 ~ 70%, titanium dioxide 1 ~ 3%, float stone 3 ~ 5%, zinc oxide 1 ~ 3%, SODIUM SILICATE 1 ~ 3%, moisture Petimin aluminium 2 ~ 3%, powdery fluorocarbon resin 5 ~ 7%, furane resins 7 ~ 8%, charcoal end 8 ~ 11%, take by weighing each composition, at first vinyl acetate is dissolved in the ethanol, dilution factor reaches 1:4 ~ 7, treat the ethanolic solution cooling of vinyl acetate, fluid temperature is no more than 5 ℃, in environment temperature is no more than 25 ℃ environment, float stone and charcoal end are joined in the ethanolic solution of vinyl acetate, and be cooled to fluid temperature and be no more than 5 ℃, shake up, again with titanium dioxide, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, powdery fluorocarbon resin and furane resins are cooled to natural temperature, shake up, be cooled to fluid temperature and be no more than 5 ℃, stand-by;
(2) fibre metal silk, brocade cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk are immersed in step (1) the gained solution and soak at least 13 hours;
(3) the fibre metal silk after will soaking, brocade cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk taking-up, grouping according to type separates, scatters, and be suspended on the gentle breeze that wind speed is 5 ~ 5.4m/s, ambient air temperature is transferred to no wind environment with moisture less than 10% warp thread or weft material in 27 ~ 30 ℃ environment;
(4) be that 1:3:5:8 gets fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament according to weight ratio, and it is the vertical combing of each composition is neat, parallel combining, twist then and rub with the hands, fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament spiral are twisted and are twisted into a strand, and the rectangle that rope is placed on two butt joints flattens in the mould, to restrict and flatten, the cross section of rope is rectangle, and obtain warp thread, the length of rectangle: wide is 2 ~ 3:1;
(5) be that 1:3:4:8 gets cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament according to weight ratio, and it is the vertical combing of each composition is neat, parallel combining, twist then and rub with the hands, cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament spiral are twisted and are twisted into a strand, and the rectangle that rope is placed on two butt joints flattens in the mould, to restrict and flatten, the cross section of rope is rectangle, and obtain weft yarn, the length of rectangle: wide is 2 ~ 3:1;
(6) get 8 on the warp thread that step (4) obtains, the left and right sides, the long limit contiguous concatenation of rectangle forms single layer warp, gets 8 of the weft yarns that step (5) obtains, the left and right sides, the long limit contiguous concatenation of rectangle, formation individual layer weft yarn;
(7) warp thread is vertical with weft yarn, and the pattern that weft yarn obtains with step (6) splicing penetrates the adjacent pattern warp thread that obtains with step (6) splicing up and down, and the warp thread of the pattern that obtains with step (6) splicing runs through successively with weft yarn and interweaves the formation surface layer;
(8) the even aqueous solution of graphite spraying and phosphorus compound, metal oxide on two surfaces of the surface layer of step (7) gained, and will be the gentle breeze of 5 ~ 5.4m/s at wind speed, ambient air temperature is in 27 ~ 30 ℃ environment, up to the facing surface drying;
(9) surface layer one side surface of step (8) gained is coated inflaming retarding high-temperature resin mould glue, fit mutually with another surface layer, and evenly give 3 ~ 4 kilograms power extruding, solidify fully up to flame-retardant glue.
The process for preparation of the solution of graphite and phosphorus compound, metal oxide is in the described step (8), getting graphite is dissolved in the water, be stirred to even dispersion, solution is cooled to the normal temperature state, adds ice cube in solution, add phosphorus compound again, constantly stir in the process that adds, be cooled to normal temperature, add metal oxide, cool off, shake up, the mol ratio of the solution that graphite and phosphorus compound, metal oxide dissolving are mixed with is 3:2:4.
The middle warp thread of described step (7) and weft yarn run through and interweave closely, and the interstitial gap between the adjacent warp thread is not more than 0.05mm, and the space between the adjacent weft is not more than 0.05m, and warp thread is vertical mutually in weft yarn.
Be used in the described step (9) extruding two mutually the temperature of the extruding story surface layer contact surface of bonding surface layer be lower than 4 ℃.
This preparation method, be pressed into not rectangular shape of cross section with twisting the warp thread or the weft yarn that are twisted into rope, follow in the knitted or woven fabrics process, many warp thread or weft yarn merge and use, increase the stability that is connected and fixed of warp thread and weft yarn, and, on unit are, voidage reduces, and increases the content of fire retardant in the cloth.
The disclosed technological means of the present invention program is not limited only to the disclosed technological means of above-mentioned technological means, also comprises the technical scheme of being made up of above technical characterictic any combination.
Claims (10)
1. surpass very fire-retardant textile cloth, it is characterized in that comprising 3 aspect layers, bonding with glue between surface layer, surface layer is formed by warp thread and weft yarn up and down weaving, warp thread and weft yarn are placed on before braiding in the specific fire retardant chemistry liquid medicine and soak, warp thread comprises fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament, and weft yarn comprises cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament.
2. super very fire-retardant textile cloth according to claim 1, the thickness that it is characterized in that described individual layer surface layer is 1.5 ~ 2.5mm, space between the mutual bonding adjacent surface layer is less than 0.02mm, the warp thread of bonding adjacent surface layer is vertical mutually with weft yarn mutually, and two-layer at least warp thread or weft yarn are arranged on the cross section of surface layer.
3. super very fire-retardant textile cloth according to claim 1 is characterized in that the upper and lower surface of described surface layer all is coated with fire retardant, and the active ingredient of fire retardant is graphite and phosphorus compound, metal oxide.
4. super very fire-retardant textile cloth according to claim 1 is characterized in that the bonding glue that uses of described surface layer is inflaming retarding high-temperature resin mould glue.
5. super very fire-retardant textile cloth according to claim 1 is characterized in that the active ingredient of described specific fire retardant chemistry liquid medicine comprises: vinyl acetate, titanium dioxide, float stone, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, powdery fluorocarbon resin, furane resins, charcoal end.
6. super very fire-retardant textile cloth according to claim 1, the part by weight that it is characterized in that fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament in the described warp thread is: 1:3:5:8, the part by weight of the cotton in the weft yarn, fiber crops, silk and 20D polyamide fibre delustring FDY long filament is: 1:3:4:8.
7. make the method for the described super very fire-retardant textile cloth of claim 1-6, it is characterized in that, may further comprise the steps:
(1) according to weight proportion: vinyl acetate 65 ~ 70%, titanium dioxide 1 ~ 3%, float stone 3 ~ 5%, zinc oxide 1 ~ 3%, SODIUM SILICATE 1 ~ 3%, moisture Petimin aluminium 2 ~ 3%, powdery fluorocarbon resin 5 ~ 7%, furane resins 7 ~ 8%, charcoal end 8 ~ 11%, take by weighing each composition, at first vinyl acetate is dissolved in the ethanol, dilution factor reaches 1:4 ~ 7, treat the ethanolic solution cooling of vinyl acetate, fluid temperature is no more than 5 ℃, in environment temperature is no more than 25 ℃ environment, float stone and charcoal end are joined in the ethanolic solution of vinyl acetate, and be cooled to fluid temperature and be no more than 5 ℃, shake up, again with titanium dioxide, zinc oxide, SODIUM SILICATE, moisture Petimin aluminium, powdery fluorocarbon resin and furane resins are cooled to natural temperature, shake up, be cooled to fluid temperature and be no more than 5 ℃, each composition dissolves fully at ethanolic solution, and is stand-by;
(2) fibre metal silk, brocade cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk are immersed in step (1) the gained solution and soak at least 13 hours;
(3) the fibre metal silk after will soaking, brocade cotton, polyester filament, 20D polyamide fibre delustring FDY long filament, cotton, fiber crops, silk taking-up, grouping according to type separates, scatters, and be suspended on the gentle breeze that wind speed is 5 ~ 5.4m/s, ambient air temperature is transferred to no wind environment with moisture less than 10% warp thread or weft material in 27 ~ 30 ℃ environment;
(4) be that 1:3:5:8 gets fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament according to weight ratio, and it is the vertical combing of each composition is neat, parallel combining, twist then and rub with the hands, fibre metal silk, brocade cotton, polyester filament and 20D polyamide fibre delustring FDY long filament spiral are twisted and are twisted into a strand, and the rectangle that rope is placed on two butt joints flattens in the mould, to restrict and flatten, the cross section of rope is rectangle, and obtain warp thread, the length of rectangle: wide is 2 ~ 3:1;
(5) be that 1:3:4:8 gets cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament according to weight ratio, and it is the vertical combing of each composition is neat, parallel combining, twist then and rub with the hands, cotton, fiber crops, silk and 20D polyamide fibre delustring FDY long filament spiral are twisted and are twisted into a strand, and the rectangle that rope is placed on two butt joints flattens in the mould, to restrict and flatten, the cross section of rope is rectangle, and obtain weft yarn, the length of rectangle: wide is 2 ~ 3:1;
(6) get 8 on the warp thread that step (4) obtains, the left and right sides, the long limit contiguous concatenation of rectangle forms single layer warp, gets 8 of the weft yarns that step (5) obtains, the left and right sides, the long limit contiguous concatenation of rectangle, formation individual layer weft yarn;
(7) warp thread is vertical with weft yarn, and the pattern that weft yarn obtains with step (6) splicing penetrates the adjacent pattern warp thread that obtains with step (6) splicing up and down, and the warp thread of the pattern that obtains with step (6) splicing runs through successively with weft yarn and interweaves the formation surface layer;
(8) the even aqueous solution of graphite spraying and phosphorus compound, metal oxide on two surfaces of the surface layer of step (7) gained, and will be the gentle breeze of 5 ~ 5.4m/s at wind speed, ambient air temperature is in 27 ~ 30 ℃ environment, up to the facing surface drying;
(9) surface layer one side surface of step (8) gained is coated inflaming retarding high-temperature resin mould glue, fit mutually with another surface layer, and evenly give 3 ~ 4 kilograms power extruding, solidify fully up to flame-retardant glue.
8. the manufacture method of super very fire-retardant textile cloth according to claim 7, the process for preparation that it is characterized in that the solution of the middle graphite of described step (8) and phosphorus compound, metal oxide is, getting graphite is dissolved in the water, be stirred to even dispersion, solution is cooled to the normal temperature state, in solution, add ice cube, add phosphorus compound again, constantly stir in the process that adds, be cooled to normal temperature, add metal oxide, cool off, shake up, the mol ratio of the solution that graphite and phosphorus compound, metal oxide dissolving are mixed with is 3:2:4.
9. the manufacture method of super very fire-retardant textile cloth according to claim 7, it is characterized in that in the described step (7) warp thread and weft yarn run through interweave tight, interstitial gap between the adjacent warp thread is not more than 0.05mm, space between the adjacent weft is not more than 0.05m, and warp thread is vertical mutually in weft yarn.
10. the manufacture method of super very fire-retardant textile cloth according to claim 7, it is characterized in that being used in the described step (9) extruding two mutually the temperature of the extruding story surface layer contact surface of bonding surface layer be lower than 4 ℃.
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| CN104088153A (en) * | 2014-06-25 | 2014-10-08 | 浙江金汇特材料有限公司 | Manufacturing method for multifunctional industry cloth |
| CN106087418A (en) * | 2016-05-17 | 2016-11-09 | 温州职业技术学院 | The garment material of water proof fire retardant |
| CN108998983A (en) * | 2018-07-03 | 2018-12-14 | 威海惠高生物科技有限公司 | A kind of fire-retardant jacquard weave cloth of full terylene and its preparation process |
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Application publication date: 20131009 |