CN103337209B - Can start assemble organic solar batteries teaching aid - Google Patents
Can start assemble organic solar batteries teaching aid Download PDFInfo
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- CN103337209B CN103337209B CN201310221674.XA CN201310221674A CN103337209B CN 103337209 B CN103337209 B CN 103337209B CN 201310221674 A CN201310221674 A CN 201310221674A CN 103337209 B CN103337209 B CN 103337209B
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- solar batteries
- organic solar
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- organic
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- 238000013086 organic photovoltaic Methods 0.000 claims abstract description 23
- 239000004020 conductor Substances 0.000 claims abstract description 8
- 239000007769 metal material Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 27
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical group C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 6
- 229910003472 fullerene Inorganic materials 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910003437 indium oxide Inorganic materials 0.000 claims description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 3
- 229960002796 polystyrene sulfonate Drugs 0.000 claims description 3
- 239000011970 polystyrene sulfonate Substances 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 241001597008 Nomeidae Species 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000001338 self-assembly Methods 0.000 abstract description 2
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 10
- 239000011521 glass Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 6
- 238000012856 packing Methods 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000003990 capacitor Substances 0.000 description 3
- 229920000123 polythiophene Polymers 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
Abstract
The invention discloses a kind of organic solar batteries teaching aid of starting to assemble.Described teaching aid comprises control circuit, the power supply be located on described control circuit, electrical appliance and organic solar batteries plate; Described organic solar batteries plate is made up of the negative electrode superposed successively, organic photovoltaic active layer and anode; Described anode is made up of transparent conductive material, and described negative electrode is made up of metal material.The teaching aid of organic solar batteries provided by the invention, the advantages such as organic solar batteries is flexible, the low easily a large amount of preparations of cost are given full play to, and what overcome sun power teaching aid in the past can not self assembly, thus improve user especially adolescent student colony, for the structure of organic solar batteries and the learning initiative of principle of work, fully demonstrate the thought of teaching through lively activities.
Description
Technical field
The present invention relates to a kind of organic solar batteries teaching aid of starting to assemble.
Background technology
In order to improve user especially adolescent student colony, for the structure of organic solar batteries device and the learning initiative of principle of work, devise the teaching aid comprising organic solar batteries that this can do it yourself to assemble, fully demonstrate the thought of teaching through lively activities.There is limited evidence currently of adopts organic solar batteries device as teaching aid, the solar cell teaching aid structure be disclosed in patent of invention CN102054385A and patent CN102654950A in the teaching aid of solar-energy photo-voltaic cell is comparatively complicated, is not easy to user oneself and carries out assembling and operating.Visible sun power teaching aid or educational toy etc. on market in addition, adopts traditional inorganic photovoltaic cell more, and organic solar batteries is easily prepared in a large number, relative price is cheap, soft etc., and premium properties does not also play a role in teaching aid field.
Summary of the invention
The object of this invention is to provide a kind of organic solar batteries teaching aid of starting to assemble, teaching aid structure provided by the invention simply, is easily assembled, and can be used as teaching aid and be applied in the extracurricular interest study of classroom instruction or student;
A kind of organic solar batteries teaching aid of starting to assemble provided by the present invention, it comprises control circuit, the power supply be located on described control circuit, electrical appliance and organic solar batteries plate;
Described organic solar batteries plate is made up of the negative electrode superposed successively, organic photovoltaic active layer and anode;
Described anode is made up of transparent conductive material, and described negative electrode is made up of metal material.
In above-mentioned organic solar batteries teaching aid, the thickness of described organic photovoltaic active layer can be 50nm ~ 500 μm.
In above-mentioned organic solar batteries teaching aid, in described anode, described transparent conductive material is located on transparent base, as being located at above unorganic glass, organic glass and transparent membrane etc.
In above-mentioned organic solar batteries teaching aid, in above-mentioned organic solar batteries teaching aid, the organic film, organic glass, unorganic glass etc. of the optional self-induced transparency of described transparent base.
Conductive coating materials can be the zinc paste of the tin oxide of doping, the indium oxide of doping or doping, as the tin indium oxide (ITO) of tin dope;
Described metal material can be aluminium, calcium, magnesium, nickel, silver or the metal such as golden.
In above-mentioned organic solar batteries teaching aid, described organic photovoltaic active layer can be individual layer photovoltaic material layer or heterojunction photovoltaic material layer.
In above-mentioned organic solar batteries teaching aid, described heterojunction photovoltaic material layer can be double layer heterojunction layer or bulk-heterojunction layer.
In above-mentioned organic solar batteries teaching aid, the electron donor material of described heterojunction photovoltaic material layer can be the micromolecular compound or polymkeric substance with conjugated structure, as polystyrene support, polythiophene and narrow band gap polymkeric substance etc.;
The electron acceptor material of described heterojunction photovoltaic material layer can be fullerene etc.
In above-mentioned organic solar batteries teaching aid, described organic photovoltaic active layer and decorative layer (improve photoelectric transformation efficiency, extend battery) can be provided with between described anode and described negative electrode, described decorative layer can by poly-3,4-ethylene dioxythiophene/poly styrene sulfonate, LiF, ZnO and TiO
2make.
In above-mentioned organic solar batteries teaching aid, described organic photovoltaic active layer can be provided with charge transport layer, and described charge transport layer is made up of NiO, can improve the electricity conversion of Thin film conductive rate and solar cell.
In above-mentioned organic solar batteries teaching aid, described electrical appliance can be luminescent device, heater members, electric device or display device, and described solar panel produces electric energy under visible light to drive described electrical appliance work.
The teaching aid of organic solar batteries provided by the invention, the advantages such as organic solar batteries is flexible, the low easily a large amount of preparations of cost are given full play to, and what overcome sun power teaching aid in the past can not self assembly, thus improve user especially adolescent student colony, for the structure of organic solar batteries and the learning initiative of principle of work, fully demonstrate the thought of teaching through lively activities.In addition, the distinguishing feature of teaching aid provided by the invention sun power teaching aid different from the past is that user can according to instructions direct, assemble voluntarily fast, convenient and safely, assembling process user can be more deep understand the principle of work of solar cell device and structure.
Accompanying drawing explanation
Fig. 1 is the structural representation of the solar panel of organic solar batteries teaching aid of the present invention;
Fig. 2 is the structural representation of organic solar batteries teaching aid of the present invention; In Fig. 3 embodiment 2, organic solar batteries drives the photo of the teaching aid of bulb luminescence;
In Fig. 4 embodiment 3, organic solar batteries drives the photo of the teaching aid of small fan;
In Fig. 5 embodiment 4, organic solar batteries drives the photo of the teaching aid of electrochromic variable color.
In figure, each mark is as follows: 1 transparent base, 2 anodes, 3 organic photovoltaic active layers, 4 negative electrodes, 1 transparent base, 5 packing washers, 6 organic solar batteries plates, 7 power supplys, 8 electrical appliances.
Embodiment
The experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, all can obtain from commercial channels.
Embodiment 1, organic solar batteries teaching aid
As shown in Figure 2, provided by the invention can the organic solar batteries teaching aid of assembled by hand comprise control circuit, the power supply 7 be located on this control circuit, electrical appliance 8 and organic solar batteries plate 6; Wherein, organic solar batteries plate 6 is made up of the negative electrode 4 superposed successively, organic photovoltaic active layer 3 and anode 2, and anode 2 is made up of transparent conductive material, and negative electrode 4 is by metal material system; The thickness of organic photovoltaic active layer 3 is 50nm ~ 500 μm.As shown in Figure 1, anode 2 and negative electrode 4 are located on transparent base 1.In use, the superficial layer of transparent base 1 all attaches one deck gasket seal 5.
In organic solar batteries teaching aid provided by the invention, transparent conductive material can select the tin oxide, the indium oxide of doping or the zinc paste of doping that adulterate, as the tin indium oxide (ITO) of tin dope; Metal material can select aluminium, calcium, magnesium, silver or the metal such as golden.Transparent base wherein can be unorganic glass, organic glass and transparent membrane etc.
Organic photovoltaic active layer in organic solar batteries teaching aid provided by the invention can be individual layer photovoltaic material layer or heterojunction photovoltaic material layer, wherein heterojunction photovoltaic material layer can be double layer heterojunction layer or bulk-heterojunction layer, as heterojunction photovoltaic material layer, the electron donor material of heterojunction photovoltaic material layer can be the micromolecular compound or polymkeric substance with conjugated structure, as polystyrene support, polythiophene and narrow band gap polymkeric substance etc., and the electron acceptor material of heterojunction photovoltaic material layer can be fullerene etc.
In organic solar batteries teaching aid provided by the invention, can be provided with decorative layer at organic photovoltaic active layer 4 and between anode 2 and negative electrode 3, it can by poly-3,4-ethylene dioxythiophene/poly styrene sulfonate, LiF, ZnO and TiO
2make.And can be provided with charge transport layer on organic photovoltaic active layer 5, it specifically can be made up of NiO.
Embodiment 2, organic solar batteries teaching aid of the present invention is utilized to drive bulb luminous
According to Fig. 1 and embodiment 1 assembling solar cell panel, the solar panel formed after each assembling parts is of a size of 10cm × 10cm.Specifically be made up of following material under upper: transparent base, anode, organic photovoltaic active layer, negative electrode, transparent base, packing washer, wherein transparent base selects organic glass, negative electrode selects aluminium, tin indium oxide (ITO) film of anode selection tin dope, organic photovoltaic active layer selects polystyrene support and fullerene, and its thickness is 500 μm.
As shown in Figure 3, the solar panel of above-mentioned assembling being accessed one has in the simple straight circuit of miniature bulb and capacitor, under being placed in sunlight.After connecting circuit, miniature bulb can normal luminous.After taking indoor a period of time, after connecting circuit, luminescent device still can be luminous.
Embodiment 3, organic solar batteries teaching aid drive fan of the present invention is utilized to rotate
According to Fig. 1 and embodiment 1 assembling solar cell panel, the solar panel formed after each assembling parts is of a size of 15cm × 15cm.Specifically be made up of following material under upper: packing washer, transparent base, anode, organic photovoltaic active layer, negative electrode and packing washer, wherein transparent base selects organic film, negative electrode selects magnesium, tin indium oxide (ITO) film of anode selection tin dope, organic photovoltaic active layer selects polythiophene and fullerene, and its thickness is 50nm.
As shown in Figure 4, the solar panel of above-mentioned assembling being accessed one has in the simple straight circuit of small fan and capacitor, under being placed in sunlight.After connecting circuit, small fan can normal rotation.After taking indoor a period of time, after connecting circuit, small fan still can rotate.
Embodiment 4, organic solar batteries teaching aid of the present invention is utilized to drive controllable color variable color
According to Fig. 1 and embodiment 1 assembling solar cell panel, the solar panel formed after each assembling parts is of a size of 15cm × 15cm.Specifically be made up of following material under upper: packing washer, transparent base, anode, organic photovoltaic active layer, negative electrode and packing washer, wherein transparent base selects organic glass, negative electrode selects calcium, tin indium oxide (ITO) film of anode selection tin dope, organic photovoltaic active layer selects polystyrene support and fullerene, and its thickness is 500nm.
As shown in Figure 5, the solar panel of above-mentioned assembling being accessed one has in the simple straight circuit of electrochromic and capacitor, under being placed in sunlight.Electrochromic can change the change showing as color or transmittance by response voltage.After connecting circuit, electrochromic can present the change of obvious color or transmittance change.After taking indoor a period of time, after connecting circuit, electrochromic still response voltage change can present color or transmittance change.
Above embodiment just understands method of the present invention, principle of work and design philosophy for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can do some improvement and modification to the present invention, these improve and modify also in the protection domain of this patent requirement.
Claims (9)
1. can start assemble an organic solar batteries teaching aid, it is characterized in that: described teaching aid comprises control circuit, the power supply be located on described control circuit, electrical appliance and organic solar batteries plate;
Described organic solar batteries plate is made up of the negative electrode superposed successively, organic photovoltaic active layer and anode;
Described anode is made up of transparent conductive material, and described negative electrode is made up of metal material;
Described transparent conductive material is the tin oxide, the indium oxide of doping or the zinc paste of doping that adulterate;
Described metal material is aluminium, calcium, magnesium, nickel, silver or golden.
2. organic solar batteries teaching aid according to claim 1, is characterized in that: the thickness of described organic photovoltaic active layer is 50nm ~ 500 μm.
3. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described organic solar batteries plate also comprises transparent base, and described transparent conductive material is located on transparent base.
4. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described organic photovoltaic active layer is individual layer photovoltaic material layer or heterojunction photovoltaic material layer.
5. organic solar batteries teaching aid according to claim 4, is characterized in that: described heterojunction photovoltaic material layer is double layer heterojunction layer or bulk-heterojunction layer.
6. organic solar batteries teaching aid according to claim 5, is characterized in that: the electron donor material of described heterojunction photovoltaic material layer is micromolecular compound or the polymkeric substance with conjugated structure;
The electron acceptor material of described heterojunction photovoltaic material layer is fullerene or imido derivant.
7. organic solar batteries teaching aid according to claim 1 and 2, it is characterized in that: described organic photovoltaic active layer and be provided with decorative layer between described anode and described negative electrode, described decorative layer is by gathering 3,4-ethylene dioxythiophene/poly styrene sulfonate, LiF, ZnO and TiO
2make.
8. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described organic photovoltaic active layer is provided with charge transport layer, and described charge transport layer is made up of NiO.
9. organic solar batteries teaching aid according to claim 1 and 2, is characterized in that: described electrical appliance is luminescent device, heater members, electric device or display device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310221674.XA CN103337209B (en) | 2013-06-05 | 2013-06-05 | Can start assemble organic solar batteries teaching aid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310221674.XA CN103337209B (en) | 2013-06-05 | 2013-06-05 | Can start assemble organic solar batteries teaching aid |
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| Publication Number | Publication Date |
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| CN103337209A CN103337209A (en) | 2013-10-02 |
| CN103337209B true CN103337209B (en) | 2016-04-13 |
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| CN201310221674.XA Active CN103337209B (en) | 2013-06-05 | 2013-06-05 | Can start assemble organic solar batteries teaching aid |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103531062A (en) * | 2013-10-16 | 2014-01-22 | 北京博如德工程技术研究有限公司 | PLED (polymer light emitting diode) teaching aid capable of being manually assembled |
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