CN103319948A - Environment-friendly quick-drying type thermosetting printing ink - Google Patents
Environment-friendly quick-drying type thermosetting printing ink Download PDFInfo
- Publication number
- CN103319948A CN103319948A CN201310241878XA CN201310241878A CN103319948A CN 103319948 A CN103319948 A CN 103319948A CN 201310241878X A CN201310241878X A CN 201310241878XA CN 201310241878 A CN201310241878 A CN 201310241878A CN 103319948 A CN103319948 A CN 103319948A
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- Prior art keywords
- parts
- environment
- printing ink
- environmental protection
- type heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920001187 thermosetting polymer Polymers 0.000 title abstract description 6
- 238000001035 drying Methods 0.000 title abstract 5
- 230000007613 environmental effect Effects 0.000 claims abstract description 14
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 16
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 16
- 239000003381 stabilizer Substances 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 10
- -1 polyethylene Polymers 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 239000000344 soap Substances 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002274 desiccant Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000012760 heat stabilizer Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses environment-friendly quick-drying type thermosetting printing ink. The environment-friendly quick-drying type thermosetting printing ink comprises the following raw materials in parts by weight: 20-60 parts of waterborne polyurethane resin, 10-20 parts of plasticizer, 1-10 parts of thickener, 1-10 parts of heat stabilizer, 2-5 parts of dispersant and 1-2 parts of drying agent. The raw materials are matched according to a reasonable proportion to prepare the environment-friendly quick-drying type thermosetting printing ink with long storage time and good stability, and the environment-friendly quick-drying type thermosetting printing ink has the advantages of easiness in curing under a low-temperature environment, no pollution, no harm to human bodies, safety and environmental friendliness.
Description
Technical field
The present invention relates to a kind of printing ink, relate in particular to a kind of environmental protection quick-dry type heat-set ink.
Background technology
Heat-set ink has had both the advantage of water slurry, rubber cement and conventional solvent type printing ink, as a kind of non-solvent printing in textiles coating, can print multiple wire mark technological effect at any cloth look, therefore obtains quoting more and more widely at Printing Industry.
The printed coating of heat-set ink must could solidify through high bake, forms fine and close filming.The curing temperature of common thermosetting is up to 180 ~ 190 ℃, and storing time reaches 90 ~ 180 seconds.But as printing in textiles coating, most textiless are subject to that the baking of excessive temperature easily is out of shape, variable color.Therefore, the curing temperature of control heat-set ink is the key that promotes ink performance.
Summary of the invention
The technical problem that solves:For the deficiencies in the prior art, the invention provides a kind of environmental protection quick-dry type heat-set ink, its period of storage length, good stability, easily curing and pollution-free, safety and environmental protection.
Technical scheme:The invention provides a kind of environmental protection quick-dry type heat-set ink, its raw material by following parts by weight forms: 20 ~ 60 parts of waterborne polyurethane resins, 10 ~ 20 parts in softening agent, 1 ~ 10 part of thickening material, 1 ~ 10 part of thermo-stabilizer, 2 ~ 5 parts of dispersion agents, siccative 1-2 part.
Described softening agent is one or more the combination in dioctyl phthalate (DOP), dibutyl phthalate or the trioctyl trimellitate.
Described thickening material is a kind of or combination in aerosil, the organobentonite.
Described thermo-stabilizer is selected the Ca/Zn one package stabilizer; Described dispersion agent is selected polyethylene wax; Described siccative is selected the soap of the metals such as cobalt or manganese.
Beneficial effect:Because the present invention has adopted technique scheme, the environmental protection quick-dry type heat-set ink period of storage that makes is longer, and stability is better, can solidify fully under 120 ~ 130 ℃ of environment, has avoided stock because adverse consequencess such as high bake after strain, variable colors.Simultaneously, printing ink is pollution-free, and is harmless, and environmental-protecting performance is good.
Embodiment
Mode below by embodiment further specifies the present invention, but therefore the present invention is not confined to following embodiment.
Embodiment 1
20 parts of waterborne polyurethane resins
10 parts of dioctyl phthalate (DOP)s
1 part of aerosil
1 part of Ca/Zn one package stabilizer
2 parts of polyethylene waxs
1 part of the soap of cobalt metal
First with stirring at low speed in 10 parts of adding stirrers of dioctyl phthalate (DOP), the 1 part of middling speed of soap that adds successively subsequently 20 parts of waterborne polyurethane resins, 1 part of Ca/Zn one package stabilizer, 1 part of aerosil, 2 parts of polyethylene waxs, cobalt metal stirs, and carries out milled processed after mixing and namely gets product.
Embodiment 2
40 parts of waterborne polyurethane resins
15 parts of dioctyl phthalate (DOP)s
5 parts of aerosils
5 parts of Ca/Zn one package stabilizers
4 parts of polyethylene waxs
1 part of the soap of cobalt metal
First with stirring at low speed in 15 parts of adding stirrers of dioctyl phthalate (DOP), the 1 part of middling speed of soap that adds successively subsequently 40 parts of waterborne polyurethane resins, 5 parts of Ca/Zn one package stabilizers, 5 parts of aerosils, 4 parts of polyethylene waxs, cobalt metal stirs, and carries out milled processed after mixing and namely gets product.
Embodiment 3
60 parts of waterborne polyurethane resins
20 parts of dioctyl phthalate (DOP)s
10 parts of aerosils
10 parts of Ca/Zn one package stabilizers
5 parts of polyethylene waxs
2 parts of the soaps of manganese metal
First with stirring at low speed in 20 parts of adding stirrers of dioctyl phthalate (DOP), the 2 parts of middling speeds of soap that add successively subsequently 60 parts of waterborne polyurethane resins, 10 parts of Ca/Zn one package stabilizers, 10 parts of aerosils, 5 parts of polyethylene waxs, manganese metal stir, and carry out milled processed after mixing and namely get product.
Embodiment 4
40 parts of waterborne polyurethane resins
15 parts of dibutyl phthalates
5 parts of aerosils
5 parts of Ca/Zn one package stabilizers
4 parts of polyethylene waxs
1 part of the soap of manganese metal
First with stirring at low speed in 15 parts of adding stirrers of dibutyl phthalate, the 1 part of middling speed of soap that adds successively subsequently 40 parts of waterborne polyurethane resins, 5 parts of Ca/Zn one package stabilizers, 5 parts of aerosils, 4 parts of polyethylene waxs, cobalt, manganese metal stirs, and carries out milled processed after mixing and namely gets product.
Test the set time of the environmental protection quick-dry type heat-set ink of the various embodiments described above, and test-results is as follows:
Claims (6)
1. an environmental protection quick-dry type heat-set ink is characterized in that being comprised of the raw material of following parts by weight: 20 ~ 60 parts of waterborne polyurethane resins, 10 ~ 20 parts in softening agent, 1 ~ 10 part of thickening material, 1 ~ 10 part of thermo-stabilizer, 2 ~ 5 parts of dispersion agents, siccative 1-2 part.
2. a kind of environmental protection quick-dry type heat-set ink according to claim 1 is characterized in that described softening agent is one or more the combination in dioctyl phthalate (DOP), dibutyl phthalate or the trioctyl trimellitate.
3. a kind of environmental protection quick-dry type heat-set ink according to claim 1 is characterized in that described thickening material is a kind of or combination in aerosil, the organobentonite.
4. a kind of environmental protection quick-dry type heat-set ink according to claim 1 is characterized in that described thermo-stabilizer selects the Ca/Zn one package stabilizer.
5. a kind of environmental protection quick-dry type heat-set ink according to claim 1 is characterized in that described dispersion agent selects polyethylene wax.
6. a kind of environmental protection quick-dry type heat-set ink according to claim 1 is characterized in that described siccative selects the soap of cobalt or manganese metal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310241878XA CN103319948A (en) | 2013-06-19 | 2013-06-19 | Environment-friendly quick-drying type thermosetting printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310241878XA CN103319948A (en) | 2013-06-19 | 2013-06-19 | Environment-friendly quick-drying type thermosetting printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103319948A true CN103319948A (en) | 2013-09-25 |
Family
ID=49189010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310241878XA Withdrawn CN103319948A (en) | 2013-06-19 | 2013-06-19 | Environment-friendly quick-drying type thermosetting printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103319948A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086611A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | Rapidly-used easily-dried ink |
| CN105131732A (en) * | 2015-08-13 | 2015-12-09 | 蚌埠市时代电子有限公司 | Long-acting led heat-dissipating coating material and preparation method thereof |
| CN106318023A (en) * | 2016-08-19 | 2017-01-11 | 苏州市博来特油墨有限公司 | Environment-friendly and quick-drying water-based ink |
| CN107337959A (en) * | 2017-08-29 | 2017-11-10 | 昆山大世界油墨涂料有限公司 | A kind of environmental printing ink |
| CN108264798A (en) * | 2016-12-30 | 2018-07-10 | 怡凌股份有限公司 | Thermosetting ink and method for manufacturing film using the same |
| CN111978783A (en) * | 2020-08-14 | 2020-11-24 | 龙利得智能科技股份有限公司 | Environment-friendly printing ink for carton printing and preparation process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002280A (en) * | 2009-09-01 | 2011-04-06 | 尚盟运动用品(惠阳)有限公司 | Low-temperature quick-drying type thermosetting ink |
| US20110234726A1 (en) * | 2010-03-26 | 2011-09-29 | Seiko Epson Corporation | Ink jet recording method |
-
2013
- 2013-06-19 CN CN201310241878XA patent/CN103319948A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002280A (en) * | 2009-09-01 | 2011-04-06 | 尚盟运动用品(惠阳)有限公司 | Low-temperature quick-drying type thermosetting ink |
| US20110234726A1 (en) * | 2010-03-26 | 2011-09-29 | Seiko Epson Corporation | Ink jet recording method |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131732A (en) * | 2015-08-13 | 2015-12-09 | 蚌埠市时代电子有限公司 | Long-acting led heat-dissipating coating material and preparation method thereof |
| CN105086611A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | Rapidly-used easily-dried ink |
| CN106318023A (en) * | 2016-08-19 | 2017-01-11 | 苏州市博来特油墨有限公司 | Environment-friendly and quick-drying water-based ink |
| CN108264798A (en) * | 2016-12-30 | 2018-07-10 | 怡凌股份有限公司 | Thermosetting ink and method for manufacturing film using the same |
| CN107337959A (en) * | 2017-08-29 | 2017-11-10 | 昆山大世界油墨涂料有限公司 | A kind of environmental printing ink |
| CN111978783A (en) * | 2020-08-14 | 2020-11-24 | 龙利得智能科技股份有限公司 | Environment-friendly printing ink for carton printing and preparation process thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20130925 |