CN103293196B - A kind of Automatic control system of anaerobic ammonium oxidation technology and method thereof - Google Patents
A kind of Automatic control system of anaerobic ammonium oxidation technology and method thereof Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 9
- 230000003647 oxidation Effects 0.000 title claims abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 title claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000000523 sample Substances 0.000 claims abstract description 27
- 238000004458 analytical method Methods 0.000 claims abstract description 18
- 230000001105 regulatory effect Effects 0.000 claims abstract description 16
- 238000012806 monitoring device Methods 0.000 claims abstract description 11
- 238000007405 data analysis Methods 0.000 claims 1
- 238000013480 data collection Methods 0.000 claims 1
- 238000012544 monitoring process Methods 0.000 abstract description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 4
- 229910021529 ammonia Inorganic materials 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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Abstract
一种厌氧氨氧化工艺自动控制系统及其方法,所述的自动控制系统包括反应器本体、流量监测装置、流量自动调节阀、带有控制面板的数据采集分析调控器、进水口电导率探头和出水口电导率探头,流量自动调节阀经流量监测装置与反应器本体相连;数据采集分析调控器分别与流量监测装置、流量自动调节阀、进出水口电导率探头相连;利用本发明控制系统采用的方法,步骤如下:1)进出水口处电导率为输入变量,进水流量为受控变量,进出水电导率的差值Δκ为目标值,在控制面板上设定Δκ上下限;2)Δκ大于上限值时增加进水流量;Δκ小于下限值时减小进水流量。本发明有益效果:工艺在线自动监测;调控及时并避免工艺超负荷运行;操作简单,易于构建。
An anaerobic ammonia oxidation process automatic control system and method thereof, the automatic control system includes a reactor body, a flow monitoring device, an automatic flow regulating valve, a data acquisition and analysis regulator with a control panel, and a water inlet conductivity probe and the water outlet conductivity probe, the flow automatic regulating valve is connected with the reactor body through the flow monitoring device; the data acquisition and analysis regulator is respectively connected with the flow monitoring device, the flow automatic regulating valve, and the water inlet and outlet conductivity probe; The method, the steps are as follows: 1) The conductivity at the water inlet and outlet is the input variable, the inflow flow is the controlled variable, the difference between the inflow and outflow conductivity Δκ is the target value, and the upper and lower limits of Δκ are set on the control panel; 2) Δκ Increase the water flow when it is greater than the upper limit; decrease the water flow when Δκ is less than the lower limit. The beneficial effects of the invention include: on-line automatic monitoring of the process; timely regulation and avoiding the overload operation of the process; simple operation and easy construction.
Description
技术领域technical field
本发明涉及一种厌氧氨氧化工艺自动控制系统及其方法。The invention relates to an automatic control system and method for an anaerobic ammonium oxidation process.
背景技术Background technique
厌氧氨氧化是一种新型生物脱氮工艺,能够在厌氧条件下以氨为电子供体将亚硝酸盐还原为氮气,实现两种氮素污染物的同时脱除。相比于传统生物脱氮工艺,厌氧氨氧化具有脱氮效果好,无需氧气和外加有机碳源,运行成本低等优点,工业应用前景广阔。然而,实际废水中污染物浓度波动以及重金属等抑制物质的存在,成为厌氧氨氧化工艺长期高效稳定运行的障碍。氨氮、亚硝态氮和硝态氮等指标的测定步骤较为繁琐,不能及时反馈厌氧氨氧化工艺的运行情况。此外,亚硝酸盐在线传感器尚处于开发阶段,且亚硝酸盐在线监测系统复杂,较难推广。若出现厌氧氨氧化抑制问题而未能及时检出,进而采取有效措施进行过程调控,则厌氧氨氧化工艺的运行性能将会下降,而且工艺受扰后恢复耗时较长。相反,若厌氧氨氧化工艺脱氮性能良好而未增加进水负荷,厌氧氨氧化工艺潜能同样不能得到挖掘。由此,实现厌氧氨氧化工艺的在线监测和自动控制显得尤为必要。Anaerobic ammonium oxidation is a new biological nitrogen removal process, which can reduce nitrite to nitrogen under anaerobic conditions with ammonia as an electron donor, and realize the simultaneous removal of two nitrogen pollutants. Compared with the traditional biological denitrification process, anaerobic ammonium oxidation has the advantages of good denitrification effect, no need for oxygen and external organic carbon source, low operating cost, etc., and has broad prospects for industrial application. However, the fluctuation of pollutant concentration in actual wastewater and the presence of inhibitory substances such as heavy metals have become obstacles to the long-term efficient and stable operation of the anammox process. The determination steps of indicators such as ammonia nitrogen, nitrite nitrogen and nitrate nitrogen are relatively cumbersome, and the operation status of the anammox process cannot be fed back in time. In addition, the nitrite online sensor is still in the development stage, and the nitrite online monitoring system is complicated and difficult to promote. If the anammox inhibition problem occurs and cannot be detected in time, and then effective measures are taken to regulate the process, the operation performance of the anammox process will decline, and it will take a long time to recover after the process is disturbed. On the contrary, if the nitrogen removal performance of the anammox process is good without increasing the influent load, the potential of the anammox process cannot be tapped. Therefore, it is particularly necessary to realize the on-line monitoring and automatic control of the anammox process.
根据厌氧氨氧化反应式,每去除1摩尔氨氮,大约消耗2.19摩尔的离子,使得厌氧氨氧化出水中电导率小于进水电导率。由此,进出水电导率变化可有效指示厌氧氨氧化反应进程,指示反应器承载负荷的饱和度。According to the anaerobic ammonium oxidation reaction formula, for every mole of ammonia nitrogen removed, about 2.19 moles of ions are consumed, so that the conductivity of the anaerobic ammonium oxidation effluent is smaller than that of the influent water. Therefore, the change in the conductivity of the influent and effluent water can effectively indicate the progress of the anammox reaction and the saturation of the reactor load.
发明内容Contents of the invention
为有效解决目前厌氧氨氧工艺实时调控难和稳定性差的问题,本发明提出一种厌氧氨氧化工艺自动控制系统及其方法,通过测定厌氧氨氧化工艺进出水中电导率的变化,实现厌氧氨氧化工艺的在线监测,同时及时调控厌氧氨氧化工艺工况,进而实现厌氧氨氧化工艺的长期高效稳定运行。In order to effectively solve the problems of difficult real-time control and poor stability of the current anammox process, the present invention proposes an anammox process automatic control system and its method. On-line monitoring of the anammox process, and timely adjustment and control of the working conditions of the anammox process, so as to realize the long-term efficient and stable operation of the anammox process.
本发明所述的一种厌氧氨氧化工艺自动控制系统,其特征在于:该系统包括反应器本体、流量监测装置、流量自动调节阀、带有控制面板的数据采集分析调控器、进水口电导率探头和出水口电导率探头;所述的流量自动调节阀经流量监测装置与所述的反应器本体相连;所述的进水口电导率探头和所述的出水口电导率探头分别置于所述的进水口和所述的出水口处;所述的数据采集分析调控器分别与所述的流量监测装置、流量自动调节阀、进水口电导率探头和出水口电导率探头相连。An anaerobic ammonium oxidation process automatic control system according to the present invention is characterized in that the system includes a reactor body, a flow monitoring device, an automatic flow regulating valve, a data acquisition and analysis regulator with a control panel, and a water inlet conductance rate probe and water outlet conductivity probe; the flow automatic regulating valve is connected to the reactor body through the flow monitoring device; the water inlet conductivity probe and the water outlet conductivity probe are respectively placed in the The water inlet and the water outlet; the data acquisition and analysis controller is respectively connected with the flow monitoring device, the automatic flow control valve, the conductivity probe of the water inlet and the conductivity probe of the water outlet.
利用本发明所述的自动控制系统采用的方法,步骤如下:Utilize the method that the automatic control system of the present invention adopts, the steps are as follows:
1)开启数据采集分析调控器,以进出水口处电导率作为输入变量,进水流量作为受控变量,以进出水电导率的差值Δκ为目标值,在数据采集分析调控器的控制面板上设定Δκ的上下限;1) Turn on the data acquisition and analysis regulator, take the conductivity at the water inlet and outlet as the input variable, the inflow flow as the controlled variable, and take the difference between the inflow and outflow conductivity Δκ as the target value, and set it on the control panel of the data acquisition and analysis controller Set the upper and lower limits of Δκ;
2)数据采集分析调控器控制进水口电导探头和出水口电导探头开始工作,并将实时检测的Δκ与步骤1)中设定的Δκ上下限进行比较,若实时检测的Δκ大于上限值,数据采集分析调控器控制流量自动调节阀自动增加进水流量;若Δκ小于下限值,流量自动调节阀自动减小进水流量。2) The data acquisition and analysis controller controls the water inlet conductance probe and the water outlet conductance probe to start working, and compares the real-time detected Δκ with the upper and lower limits of Δκ set in step 1). If the real-time detected Δκ is greater than the upper limit, The data acquisition and analysis regulator controls the automatic flow regulating valve to automatically increase the influent flow; if Δκ is less than the lower limit value, the automatic flow regulating valve automatically reduces the influent flow.
本发明的有益效果是:①通过测定电导率可方便快捷地实现厌氧氨氧化工艺的在线监测;②该系统能够及时有效的调控厌氧氨氧化工艺工况,避免超负荷运行,有利于该工艺的长期高效稳定运行;③该自动控制系统操作简单,易于构建。The beneficial effects of the present invention are: ①The on-line monitoring of the anammox process can be realized conveniently and quickly by measuring the electrical conductivity; Long-term efficient and stable operation of the process; ③The automatic control system is simple to operate and easy to build.
附图说明Description of drawings
图1是本发明的结构简图(箭头代表水流方向)。Fig. 1 is a schematic diagram of the structure of the present invention (the arrow represents the direction of water flow).
具体实施方式detailed description
下面结合附图进一步说明本发明Further illustrate the present invention below in conjunction with accompanying drawing
参照附图:Referring to the attached picture:
实施例1本发明所述的一种厌氧氨氧化工艺自动控制系统包括反应器本体1、流量监测装置2、流量自动调节阀3、带有控制面板的数据采集分析调控器4、进水口电导率探头5和出水口电导率探头6;所述的流量自动调节阀3经流量监测装置2与所述的反应器本体1相连;所述的进水口电导率探头5和所述的出水口电导率探头6分别置于所述的反应器本体1的进水口11和出水口12处;所述的数据采集分析调控器4分别与所述的流量监测装置2、流量自动调节阀3、进水口电导率探头4和出水口电导率探头5相连。Embodiment 1 An anammox process automatic control system described in the present invention includes a reactor body 1, a flow monitoring device 2, an automatic flow regulating valve 3, a data acquisition and analysis controller 4 with a control panel, and a water inlet conductance The rate probe 5 and the water outlet conductivity probe 6; the flow automatic regulating valve 3 is connected to the described reactor body 1 through the flow monitoring device 2; the water inlet conductivity probe 5 and the water outlet conductivity The rate probe 6 is placed at the water inlet 11 and the water outlet 12 of the reactor body 1 respectively; The conductivity probe 4 is connected to the water outlet conductivity probe 5 .
实施例2利用实施例1所述的自动控制系统采用的方法,步骤如下:Embodiment 2 utilizes the method that the automatic control system described in embodiment 1 adopts, and the steps are as follows:
1)开启数据采集分析调控器,以进出水口处电导率作为输入变量,进水流量作为受控变量,以Δκ为目标值,在数据采集分析调控器的控制面板上设定Δκ的上下限;1) Turn on the data acquisition and analysis regulator, take the conductivity at the water inlet and outlet as the input variable, the inflow flow as the controlled variable, and take Δκ as the target value, and set the upper and lower limits of Δκ on the control panel of the data acquisition and analysis regulator;
2)数据采集分析调控器控制进水口电导探头和出水口电导探头开始工作,并将实时检测的Δκ与步骤1)中设定的Δκ上下限进行比较,若实时检测的Δκ大于上限值,数据采集分析调控器控制流量自动调节阀自动增加进水流量;若Δκ小于下限值,流量自动调节阀自动减小进水流量。2) The data acquisition and analysis controller controls the water inlet conductance probe and the water outlet conductance probe to start working, and compares the real-time detected Δκ with the upper and lower limits of Δκ set in step 1). If the real-time detected Δκ is greater than the upper limit, The data acquisition and analysis regulator controls the automatic flow regulating valve to automatically increase the influent flow; if Δκ is less than the lower limit value, the automatic flow regulating valve automatically reduces the influent flow.
本说明书实施例所述的内容仅仅是对发明构思的实现形式的列举,本发明的保护范围的不应当被视为仅限于实施例所陈述的具体形式,本发明的保护范围也及于本领域技术人员根据本发明构思所能够想到的等同技术手段。The content described in the embodiments of this specification is only an enumeration of the implementation forms of the inventive concept. The protection scope of the present invention should not be regarded as limited to the specific forms stated in the embodiments. The protection scope of the present invention also extends to the field Equivalent technical means that the skilled person can think of based on the concept of the present invention.
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