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CN103289018B - Flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer - Google Patents

Flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer Download PDF

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Publication number
CN103289018B
CN103289018B CN201310252614.4A CN201310252614A CN103289018B CN 103289018 B CN103289018 B CN 103289018B CN 201310252614 A CN201310252614 A CN 201310252614A CN 103289018 B CN103289018 B CN 103289018B
Authority
CN
China
Prior art keywords
plastic cement
octene copolymer
flame
parts
containing ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201310252614.4A
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Chinese (zh)
Other versions
CN103289018A (en
Inventor
张卫
蒋学功
张美英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Yougu Intellectual Property Service Co ltd
Original Assignee
Suzhou New District Jiahe Plastics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Jiahe Plastics Co Ltd filed Critical Suzhou New District Jiahe Plastics Co Ltd
Priority to CN201310252614.4A priority Critical patent/CN103289018B/en
Publication of CN103289018A publication Critical patent/CN103289018A/en
Application granted granted Critical
Publication of CN103289018B publication Critical patent/CN103289018B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention relates to a flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer. The plastic cement comprises following ingredients, by weight: 50 to 60 portions of ethylene-octene copolymer, 40 to 50 portions of high density polyethylene, 10 to 20 portions of a cycloheptene, 10 to 20 portions of acrylonitrile, 10 to 20 portions of aluminium hydroxide, 10 to 20 portions of ferric oxide and 10 to 20 portions of glycerin. The plastic cement containing ethylene-octene copolymer possesses excellent flame-resistance and heat-resistance. [0]

Description

A kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer
Technical field
The present invention relates to a kind of flame-proof heat-resistant plastic cement, particularly relate to a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer.
Background technology
Along with fast development economic both at home and abroad, in this context, plastic cement industry have also been obtained quick fast development.Simultaneously the demand of client to plastic cement is increasing, is also more and more higher to the quality criteria requirements of plastic cement simultaneously.Relating to the professional domain of flame-proof heat-resistant plastic cement, and some special dimensions, also be thereupon more harsh to the requirement of flame-proof heat-resistant plastic cement, have fire-retardant less with plastic cement kind that is heat-resisting effect in the market simultaneously, therefore develop the trend that a kind of plastic cement simultaneously with good flame retardant resistance and thermotolerance is a certainty.
Summary of the invention
The technical problem solved: the problem that conventional plastic is fire-retardant and heat-resisting effect is poor.
Technical scheme: the present invention is a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer, is made up of: ethylene-octene copolymer 50 ~ 60 parts, high density polyethylene(HDPE) 40 ~ 50 parts, suberene 10 ~ 20 parts, vinyl cyanide 10 ~ 20 parts, 10 ~ 20 parts, aluminium hydroxide, ferric oxide 10 ~ 20 parts, glycerine 10 ~ 20 parts following composition according to weight ratio.At 60 DEG C, various composition is dropped into reaction vessel allotment, stir, be heated to 200 DEG C and keep 10h, the plastic cement with good flame-proof heat-resistant effect after cooling, can be obtained.
Beneficial effect: after preparing the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer, its flame retardant resistance and high thermal resistance are tested.Adopt the flame retardant resistance of UL94 standard to plastic cement to test, result shows can reach the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer that the present invention makes V-1 rank, have good flame retardant effect.Plastic cement keeps 10h at burning temperature is 700 ~ 800 DEG C in addition, and the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer produces without any unusual phenomenon, has good flame-proof heat-resistant characteristic.
Embodiment
Embodiment 1
Open reaction vessel, temperature is adjusted to 60 DEG C, gets ethylene-octene copolymer 50kg, drop in reactor, stir, add high density polyethylene(HDPE) 40kg simultaneously, then add suberene 10kg, add vinyl cyanide 10kg, add aluminium hydroxide 10kg again, then add ferric oxide 10kg successively, glycerine 10kg, treat post-heating to the 200 DEG C maintenance 10h that thoroughly stirs, after cooling, obtain the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer.
Embodiment 2
Open reaction vessel, temperature is adjusted to 60 DEG C, gets ethylene-octene copolymer 60kg, drop in reactor, stir, add high density polyethylene(HDPE) 50kg simultaneously, then add suberene 20kg, add vinyl cyanide 20kg, add aluminium hydroxide 20kg again, then add ferric oxide 20kg successively, glycerine 20kg, treat post-heating to the 200 DEG C maintenance 10h that thoroughly stirs, after cooling, obtain the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer.
Embodiment 3
Open reaction vessel, temperature is adjusted to 60 DEG C, gets ethylene-octene copolymer 55kg, drop in reactor, stir, add high density polyethylene(HDPE) 45kg simultaneously, then add suberene 15kg, add vinyl cyanide 15kg, add aluminium hydroxide 15kg again, then add ferric oxide 15kg successively, glycerine 15kg, treat post-heating to the 200 DEG C maintenance 10h that thoroughly stirs, after cooling, obtain the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer.
Embodiment 4
Open reaction vessel, temperature is adjusted to 60 DEG C, gets ethylene-octene copolymer 57kg, drop in reactor, stir, add high density polyethylene(HDPE) 43kg simultaneously, then add suberene 13kg, add vinyl cyanide 17kg, add aluminium hydroxide 13kg again, then add ferric oxide 17kg successively, glycerine 13kg, treat post-heating to the 200 DEG C maintenance 10h that thoroughly stirs, after cooling, obtain the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer.
Invention effect table
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Thermotolerance Keep 10h at 700 DEG C, do not change, possess good heat resistance Keep 10h at 750 DEG C, do not change, possess good heat resistance Keep 10h at 800 DEG C, do not change, possess good heat resistance Keep 10h at 770 DEG C, do not change, possess good heat resistance
Flame retardant resistance V-1 rank, has good flame retardant effect V-1 rank, has good flame retardant effect V-1 rank, has good flame retardant effect V-1 rank, has good flame retardant effect

Claims (6)

1. the flame-proof heat-resistant plastic cement containing ethylene-octene copolymer, is characterized in that: be made up of according to weight ratio following composition: ethylene-octene copolymer 50 ~ 60 parts, high density polyethylene(HDPE) 40 ~ 50 parts, suberene 10 ~ 20 parts, vinyl cyanide 10 ~ 20 parts, 10 ~ 20 parts, aluminium hydroxide, ferric oxide 10 ~ 20 parts, glycerine 10 ~ 20 parts.
2. a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer according to claim 1, is characterized in that: in plastic cement composition, ethylene-octene copolymer is 50 parts.
3. a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer according to claim 1, is characterized in that: plastic cement composition medium high density polyethylene is 40 parts.
4. a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer according to claim 1, is characterized in that: in plastic cement composition, suberene is 20 parts.
5. a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer according to claim 1, is characterized in that: in plastic cement composition, vinyl cyanide is 10 parts.
6. a kind of flame-proof heat-resistant plastic cement containing ethylene-octene copolymer according to claim 1, is characterized in that: in plastic cement composition, ferric oxide is 10 parts.
CN201310252614.4A 2013-06-24 2013-06-24 Flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer Expired - Fee Related CN103289018B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310252614.4A CN103289018B (en) 2013-06-24 2013-06-24 Flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310252614.4A CN103289018B (en) 2013-06-24 2013-06-24 Flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer

Publications (2)

Publication Number Publication Date
CN103289018A CN103289018A (en) 2013-09-11
CN103289018B true CN103289018B (en) 2015-05-13

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310252614.4A Expired - Fee Related CN103289018B (en) 2013-06-24 2013-06-24 Flame-retardant heat-resistant plastic cement containing ethylene-octene copolymer

Country Status (1)

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CN (1) CN103289018B (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100900931B1 (en) * 2000-01-26 2009-06-08 미쓰이 가가쿠 가부시키가이샤 Olefin polymers and production processes thereof
US7629416B2 (en) * 2002-08-12 2009-12-08 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
CN102417652A (en) * 2011-09-27 2012-04-18 江苏达胜高聚物有限公司 Novel halogen-free low-smoke insulating material for photovoltaic cable and production process thereof

Also Published As

Publication number Publication date
CN103289018A (en) 2013-09-11

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Effective date of registration: 20171229

Address after: 215002 754 room, No. 379, No. 1, Tower Park Road, Suzhou high tech Zone, Jiangsu

Patentee after: SUZHOU NIUMAITIAN NEW MATERIAL TECHNOLOGY CO.,LTD.

Address before: High tech Zone Fengqiao town Suzhou city Jiangsu province 215129 Bridge Village

Patentee before: SUZHOU NEW DISTRICT JIAHE PLASTIC Co.,Ltd.

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TR01 Transfer of patent right

Effective date of registration: 20210303

Address after: 211111 p556, building 1, 12 mozhou East Road, Jiangning District, Nanjing City, Jiangsu Province

Patentee after: NANJING YOUGU INTELLECTUAL PROPERTY SERVICE Co.,Ltd.

Address before: Room 754, Building 379, Tayuan Road, Suzhou High-tech Zone, Jiangsu Province

Patentee before: SUZHOU NIUMAITIAN NEW MATERIAL TECHNOLOGY Co.,Ltd.

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150513

CF01 Termination of patent right due to non-payment of annual fee